JP7092459B2 - Cement composition - Google Patents

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JP7092459B2
JP7092459B2 JP2016218610A JP2016218610A JP7092459B2 JP 7092459 B2 JP7092459 B2 JP 7092459B2 JP 2016218610 A JP2016218610 A JP 2016218610A JP 2016218610 A JP2016218610 A JP 2016218610A JP 7092459 B2 JP7092459 B2 JP 7092459B2
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cement
water
bubbles
cement composition
mass
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JP2018076200A (en
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真弥 城出
隆人 野崎
康秀 肥後
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Taiheiyo Cement Corp
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Description

本発明は、セメント組成物に関する。 The present invention relates to a cement composition.

モルタルやコンクリートにAE剤等を添加して微細な空気泡を連行することにより、モルタルやコンクリートの流動性を向上させることが知られている。
また、特許文献1には、従来のAE剤等の混和剤の添加に代わる、微細な空気泡を連行する方法として、少なくとも練混ぜ水とセメントとを含み、必要に応じて骨材とを混合して練混ぜたセメントミルク、モルタル又はコンクリートのセメント系材料において、該セメントミルク、モルタル又はコンクリートの材料混練時にマイクロバブルを導入したことを特徴とするマイクロバブル混入セメント系材料が記載されている。
It is known that the fluidity of mortar or concrete is improved by adding an AE agent or the like to mortar or concrete to entrain fine air bubbles.
Further, Patent Document 1 contains at least kneading water and cement as a method for entraining fine air bubbles instead of adding an admixture such as a conventional AE agent, and mixes aggregate with necessary. In the cement-based material of cement milk, mortar or concrete that has been kneaded in the same manner, a microbubble-mixed cement-based material is described in which microbubbles are introduced when the material of the cement milk, mortar or concrete is kneaded.

特開2007-191358号公報Japanese Unexamined Patent Publication No. 2007-191358

本発明の目的は、流動性に優れたセメント組成物を提供することである。 An object of the present invention is to provide a cement composition having excellent fluidity.

本発明者は、上記課題を解決するために鋭意検討した結果、セメントおよび水を含むセメント組成物であって、上記水が、1μm以下の粒径を有する気泡を含むセメント組成物によれば、上記目的を達成できることを見出し、本発明を完成した。
すなわち、本発明は、以下の[1]~[4]を提供するものである。
[1] セメントおよび水を含むセメント組成物であって、上記水が、1μm以下の粒径を有する気泡を含むことを特徴とするセメント組成物。
[2] 上記水1ミリリットル中の上記気泡の数が、10個以上である前記[1]に記載のセメント組成物。
[3] 上記セメント組成物が、セメント分散剤を含む前記[1]又は[2]に記載のセメント組成物。
[4] 前記[1]~[3]のいずれかに記載のセメント組成物の硬化体からなる表面形成部分を含む構造物。
As a result of diligent studies to solve the above problems, the present inventor has found that a cement composition containing cement and water, wherein the water contains bubbles having a particle size of 1 μm or less. The present invention has been completed by finding that the above object can be achieved.
That is, the present invention provides the following [1] to [4].
[1] A cement composition containing cement and water, wherein the water contains bubbles having a particle size of 1 μm or less.
[2] The cement composition according to the above [1], wherein the number of the bubbles in 1 ml of the water is 107 or more.
[3] The cement composition according to the above [1] or [2], wherein the cement composition contains a cement dispersant.
[4] A structure containing a surface-forming portion made of a cured product of the cement composition according to any one of the above [1] to [3].

本発明のセメント組成物によれば、セメント組成物の流動性を向上することができる。 According to the cement composition of the present invention, the fluidity of the cement composition can be improved.

本発明のセメント組成物は、セメントおよび水を含むセメント組成物であって、上記水が、1μm以下の粒径を有する気泡を含むものである。
本発明で用いられるセメントは、特に限定されるものではなく、例えば、普通ポルトランドセメント、早強ポルトランドセメント、中庸熱ポルトランドセメント、低熱ポルトランドセメント等の各種ポルトランドセメントや、高炉セメント、フライアッシュセメント等の混合セメントや、エコセメント等を使用することができる。
The cement composition of the present invention is a cement composition containing cement and water, wherein the water contains bubbles having a particle size of 1 μm or less.
The cement used in the present invention is not particularly limited, and is, for example, various Portland cements such as ordinary Portland cement, early-strength Portland cement, moderate heat Portland cement, low heat Portland cement, blast furnace cement, fly ash cement and the like. Mixed cement, eco-cement, etc. can be used.

本発明で用いられる水は、1μm以下の粒径を有する気泡を含むものである。なお、1μm以下の粒径を有する気泡は、ウルトラファインバブルまたはナノバブルと称されている。
気泡の粒径は、1μm(1,000nm)以下、好ましくは700nm以下、より好ましくは500nm以下、さらに好ましくは300nm以下、特に好ましくは200nm以下である。該粒径が1μmを超えると、セメント組成物の流動性の向上効果が小さくなる。
本発明で用いられる水は、気泡の全量(100体積%)中、好ましくは、粒径が10~1,000nmの範囲内である気泡を80体積%以上(好ましくは90体積%以上)含むものであり、より好ましくは、粒径が10~700nmの範囲内である気泡を80体積%以上(好ましくは90体積%以上)含むものであり、さらに好ましくは、粒径が10~500nmの範囲内である気泡を80体積%以上(好ましくは90体積%以上)含むものであり、さらに好ましくは、粒径が10~300nmの範囲内である気泡を80体積%以上(好ましくは90体積%以上)含むものであり、特に好ましくは、粒径が10~200nmの範囲内である気泡を80体積%以上(好ましくは90体積%以上)含むものである。
気泡の平均粒径は、好ましくは1μm以下、より好ましくは700nm以下、さらに好ましくは500nm以下、さらに好ましくは300nm以下、特に好ましくは200nm以下である。該平均粒径が1μm以下であれば、セメント組成物の流動性の向上効果がより大きくなる。
なお、本明細書中、気泡の平均粒径とは、市販のナノ粒子解析装置を用いて、トラッキング法により得られる値をいう。
The water used in the present invention contains bubbles having a particle size of 1 μm or less. Bubbles having a particle size of 1 μm or less are called ultrafine bubbles or nanobubbles.
The particle size of the bubbles is 1 μm (1,000 nm) or less, preferably 700 nm or less, more preferably 500 nm or less, still more preferably 300 nm or less, and particularly preferably 200 nm or less. When the particle size exceeds 1 μm, the effect of improving the fluidity of the cement composition becomes small.
The water used in the present invention contains 80% by volume or more (preferably 90% by volume) of bubbles having a particle size in the range of 10 to 1,000 nm in the total amount (100% by volume) of the bubbles. It is more preferably contained in 80% by volume or more (preferably 90% by volume or more) of bubbles having a particle size in the range of 10 to 700 nm, and more preferably in the range of 10 to 500 nm. It contains 80% by volume or more (preferably 90% by volume or more) of bubbles, and more preferably 80% by volume or more (preferably 90% by volume or more) of bubbles having a particle size in the range of 10 to 300 nm. It contains 80% by volume or more (preferably 90% by volume or more) of bubbles having a particle size in the range of 10 to 200 nm.
The average particle size of the bubbles is preferably 1 μm or less, more preferably 700 nm or less, still more preferably 500 nm or less, still more preferably 300 nm or less, and particularly preferably 200 nm or less. When the average particle size is 1 μm or less, the effect of improving the fluidity of the cement composition becomes greater.
In the present specification, the average particle size of bubbles means a value obtained by a tracking method using a commercially available nanoparticle analyzer.

上記水1ミリリットル中の上記気泡(1μm以下の粒径を有するもの)の数は、好ましくは10個以上、より好ましくは10個以上、さらに好ましくは10個以上、特に好ましくは5×10個以上である。該数が10個以上であれば、カーボンの浮き上がりを抑制する効果がより向上する。また、セメント組成物の流動性や凍結融解抵抗性がより向上する。該数の上限は特に限定されるものではないが、気泡形成の容易性の観点から、好ましくは1011個以下、より好ましくは1010個以下である。
気泡を構成する気体の種類としては、特に限定するものではなく、例えば、空気、酸素、窒素等が挙げられる。中でも、汎用性の観点から、空気が好ましい。
The number of the bubbles (having a particle size of 1 μm or less) in 1 ml of the water is preferably 107 or more, more preferably 108 or more, still more preferably 109 or more, and particularly preferably 5 ×. There are 109 or more. When the number is 107 or more, the effect of suppressing the floating of carbon is further improved. In addition, the fluidity and freeze-thaw resistance of the cement composition are further improved. The upper limit of the number is not particularly limited, but is preferably 10 11 or less, more preferably 10 10 or less, from the viewpoint of ease of bubble formation.
The type of gas constituting the bubble is not particularly limited, and examples thereof include air, oxygen, and nitrogen. Above all, air is preferable from the viewpoint of versatility.

本発明のセメント組成物において、水の配合量は特に限定されるものではなく、モルタルやコンクリート等のセメント組成物における一般的な配合量であればよい。例えば、水の配合量は、水とセメントの質量比(水/セメント)の値として、好ましくは0.3~0.8、より好ましくは0.4~0.7となる量である。該比が0.3以上であれば、セメント組成物のワーカビリティが向上する。該比が0.8以下であれば、セメント組成物の強度(例えば、モルタル圧縮強さ)が向上する。 In the cement composition of the present invention, the blending amount of water is not particularly limited, and may be any general blending amount in cement compositions such as mortar and concrete. For example, the blending amount of water is preferably 0.3 to 0.8, more preferably 0.4 to 0.7 as the value of the mass ratio (water / cement) of water and cement. When the ratio is 0.3 or more, the workability of the cement composition is improved. When the ratio is 0.8 or less, the strength of the cement composition (for example, the compressive strength of mortar) is improved.

本発明のセメント組成物は、分散作用によりセメント組成物の流動性や強度(例えば、モルタル圧縮強さ)を向上させる観点から、セメント分散剤を含むことが好ましい。
セメント分散剤としては、例えば、減水剤、AE減水剤、高性能減水剤、高性能AE減水剤、及び流動化剤等が挙げられる。これらは1種を単独で用いてもよく、2種以上を組み合わせて用いてもよい。
セメント100質量部に対するセメント分散剤の配合量(複数の種類を用いる場合、合計量)は、液状の場合の値として、好ましくは0.02~5質量部、より好ましくは0.03~3質量部、さらに好ましくは0.04~2質量部、さらに好ましくは0.05~1.5質量部、さらに好ましくは0.05~1質量部、特に好ましくは0.05~0.5質量部であり、また、粉状等の固体の場合の値として、好ましくは0.001~2.5質量部、より好ましくは0.002~1質量部、さらに好ましくは0.005~0.5質量部、特に好ましくは0.01~0.3質量部である。
The cement composition of the present invention preferably contains a cement dispersant from the viewpoint of improving the fluidity and strength (for example, mortar compressive strength) of the cement composition by a dispersing action.
Examples of the cement dispersant include a water reducing agent, an AE water reducing agent, a high-performance water reducing agent, a high-performance AE water reducing agent, and a fluidizing agent. These may be used individually by 1 type and may be used in combination of 2 or more type.
The blending amount of the cement dispersant (in the case of using a plurality of types, the total amount) with respect to 100 parts by mass of the cement is preferably 0.02 to 5 parts by mass, more preferably 0.03 to 3 parts by mass as a value in the case of a liquid state. Parts, more preferably 0.04 to 2 parts by mass, still more preferably 0.05 to 1.5 parts by mass, still more preferably 0.05 to 1 part by mass, and particularly preferably 0.05 to 0.5 parts by mass. In the case of a solid such as powder, the value is preferably 0.001 to 2.5 parts by mass, more preferably 0.002 to 1 part by mass, and further preferably 0.005 to 0.5 part by mass. Particularly preferably 0.01 to 0.3 parts by mass.

また、本発明のセメント組成物は、微細な空気泡を連行することにより、セメント組成物のワーカビリティや凍結融解抵抗性を向上させる観点から、AE剤を含むことが好ましい。
セメント100質量部に対するAE剤(通常、液状)の配合量は、好ましくは0.0002~1質量部、より好ましくは0.001~0.8質量部、さらに好ましくは0.002~0.6質量部、さらに好ましくは0.005~0.4質量部、さらに好ましくは0.005~0.2質量部、特に好ましくは0.01~0.1質量部である。
Further, the cement composition of the present invention preferably contains an AE agent from the viewpoint of improving the workability and freeze-thaw resistance of the cement composition by entraining fine air bubbles.
The blending amount of the AE agent (usually liquid) with respect to 100 parts by mass of the cement is preferably 0.0002 to 1 part by mass, more preferably 0.001 to 0.8 part by mass, and further preferably 0.002 to 0.6. It is by mass, more preferably 0.005 to 0.4 parts by mass, still more preferably 0.005 to 0.2 parts by mass, and particularly preferably 0.01 to 0.1 parts by mass.

本発明のセメント組成物は、必要に応じて他の材料を含むことができる。他の材料としては、細骨材や、粗骨材や、高炉スラグ微粉末等の各種混和材等が挙げられる。
本発明で用いる細骨材としては、特に限定されず、例えば、川砂、山砂、陸砂、海砂、砕砂、珪砂、スラグ細骨材、軽量細骨材、またはこれらの混合物等が挙げられる。
細骨材の配合量は特に限定されず、コンクリート等における一般的な配合量であればよい。例えば、セメント100質量部に対する細骨材の配合量は、好ましくは50~700質量部、より好ましくは100~600質量部である。該配合量が上記範囲内であれば、セメント組成物のワーカビリティーや成形のし易さが向上する。
本発明で用いる粗骨材としては、特に限定されず、例えば、川砂利、山砂利、陸砂利、海砂利、砕石、スラグ粗骨材、軽量粗骨材、又はこれらの混合物等が挙げられる。
粗骨材の配合量は特に限定されず、コンクリート等における一般的な配合量であればよい。例えば、ポルトランドセメント100質量部に対する粗骨材の配合量は、好ましくは100~700質量部、より好ましくは200~600質量部である。
The cement composition of the present invention may contain other materials as needed. Examples of other materials include fine aggregates, coarse aggregates, and various admixtures such as blast furnace slag fine powder.
The fine aggregate used in the present invention is not particularly limited, and examples thereof include river sand, mountain sand, land sand, sea sand, crushed sand, silica sand, slag fine aggregate, lightweight fine aggregate, and mixtures thereof. ..
The blending amount of the fine aggregate is not particularly limited, and may be a general blending amount in concrete or the like. For example, the blending amount of the fine aggregate with respect to 100 parts by mass of cement is preferably 50 to 700 parts by mass, and more preferably 100 to 600 parts by mass. When the blending amount is within the above range, the workability and the ease of molding of the cement composition are improved.
The coarse aggregate used in the present invention is not particularly limited, and examples thereof include river gravel, mountain gravel, land gravel, sea gravel, crushed stone, slag coarse aggregate, lightweight coarse aggregate, and mixtures thereof.
The blending amount of the coarse aggregate is not particularly limited, and may be a general blending amount in concrete or the like. For example, the blending amount of the coarse aggregate with respect to 100 parts by mass of Portland cement is preferably 100 to 700 parts by mass, and more preferably 200 to 600 parts by mass.

本発明のセメント組成物は、流動性に優れたものである。
本発明のセメント組成物を用いて、モルタルやコンクリートの構造体を形成してもよいが、低コストで構造体を得る観点から、該構造体の表面形成部分(表層)のみを、本発明のセメント組成物の硬化体からなるものにしてもよい。この場合、表面形成部分の厚みは、特に限定されるものではないが、例えば、3~30cm(好ましくは5~20cm)である。
The cement composition of the present invention has excellent fluidity.
The cement composition of the present invention may be used to form a mortar or concrete structure, but from the viewpoint of obtaining the structure at low cost, only the surface-forming portion (surface layer) of the structure is used in the present invention. It may consist of a cured product of the cement composition. In this case, the thickness of the surface-forming portion is not particularly limited, but is, for example, 3 to 30 cm (preferably 5 to 20 cm).

以下、本発明を実施例により具体的に説明するが、本発明はこれらの実施例に限定されるものではない。
[使用材料]
(1)セメント;普通ポルトランドセメント(太平洋セメント社製)
(2)細骨材;陸砂
(3)気泡含有水;ウルトラファインバブル水(ナノクス社製、表1中、「UFB水」と略して記載する。)、溶存気泡量:7.6×10(76億)個/ml、気泡の全量(100体積%)中の、10~200nmの粒径を有する気泡の割合:90体積%以上、気泡の平均粒径(ナノ粒子解析装置を用いてトラッキング法により測定した値):68nm、実測密度:1.02g/cm、気泡を構成する気体が空気であるもの
(4)水;水道水
(5)AE剤;BASFジャパン社製、商品名「マスターエア 303A」(液状)
(6)高性能AE減水剤;BASFジャパン社製、商品名「マスターグレニウム SP8SV」(液状)
Hereinafter, the present invention will be specifically described with reference to Examples, but the present invention is not limited to these Examples.
[Material used]
(1) Cement; Ordinary Portland cement (manufactured by Taiheiyo Cement)
(2) Fine aggregate; Land sand (3) Bubble-containing water; Ultrafine bubble water (manufactured by Nanox Co., Ltd., abbreviated as "UFB water" in Table 1), dissolved bubble amount: 7.6 × 10 9 (7.6 billion) cells / ml, proportion of bubbles having a particle size of 10 to 200 nm in the total amount of bubbles (100% by volume): 90% by volume or more, average particle size of bubbles (using a nanoparticle analyzer) Value measured by tracking method): 68 nm, measured density: 1.02 g / cm 3 , the gas constituting the bubble is air (4) water; tap water (5) AE agent; manufactured by BASF Japan, trade name "Master Air 303A" (liquid)
(6) High-performance AE water reducing agent; manufactured by BASF Japan, trade name "Master Grenium SP8SV" (liquid)

[実施例1]
上記材料を使用し、表1に示す配合に従ってモルタルを作製した。具体的には、セメント、および細骨材をホバートミキサーに投入して30秒間空練りした後、さらに、高性能AE減水剤を溶解した気泡含有水を投入して120秒間混練し、モルタルを調製した。
該モルタルのモルタルフロー値(15打)を、「JIS R 5201(セメントの物理試験方法)11.フロー試験」に記載の方法に準拠して測定した。
また、該モルタルの空気量を「JIS A 1116(フレッシュコンクリートの単位容積質量試験方法および空気量の質量による試験方法(質量方法))」に準拠して測定した。
[Example 1]
Using the above materials, mortar was prepared according to the formulation shown in Table 1. Specifically, cement and fine aggregate are put into a Hobart mixer and kneaded for 30 seconds, and then bubble-containing water in which a high-performance AE water reducing agent is dissolved is put and kneaded for 120 seconds to prepare a mortar. did.
The mortar flow value (15 strokes) of the mortar was measured according to the method described in "JIS R 5201 (Physical test method for cement) 11. Flow test".
In addition, the amount of air in the mortar was measured in accordance with "JIS A 1116 (Unit volume mass test method for fresh concrete and test method based on mass of air volume (mass method))".

[実施例2]
セメント、石炭灰、および細骨材をパン型ミキサーに投入して30秒間空練りした後、さらに、高性能AE減水剤とAE剤とを溶解した気泡含有水を投入して120秒間混練する以外は、実施例1と同様にして、モルタルを調製した。
実施例1と同様にして、モルタルフロー値の測定等を行った。
[比較例1]
気泡含有水の代わりに、水を使用する以外は、実施例1と同様にして、モルタルを調製した。
実施例1と同様にして、モルタルフロー値の測定等を行った。
[比較例2]
気泡含有水の代わりに、水を使用する以外は、実施例2と同様にして、モルタルを調製した。
実施例1と同様にして、モルタルフロー値の測定等を行った。
結果を表2に示す。
[Example 2]
Other than putting cement, coal ash, and fine aggregate into a bread pan mixer and kneading for 30 seconds, then adding bubble-containing water containing a high-performance AE water reducing agent and an AE agent and kneading for 120 seconds. Prepared a mortar in the same manner as in Example 1.
The mortar flow value and the like were measured in the same manner as in Example 1.
[Comparative Example 1]
A mortar was prepared in the same manner as in Example 1 except that water was used instead of the bubble-containing water.
The mortar flow value and the like were measured in the same manner as in Example 1.
[Comparative Example 2]
A mortar was prepared in the same manner as in Example 2 except that water was used instead of the bubble-containing water.
The mortar flow value and the like were measured in the same manner as in Example 1.
The results are shown in Table 2.

Figure 0007092459000001
Figure 0007092459000001

Figure 0007092459000002
Figure 0007092459000002

表2から、本発明のセメント組成物(実施例1~2)は、比較例1~2(通常の水を使用したセメント組成物)よりもモルタルフロー値が大きく、流動性に優れていることがわかる。 From Table 2, the cement compositions of the present invention (Examples 1 and 2) have a larger mortar flow value and excellent fluidity than Comparative Examples 1 and 2 (cement compositions using ordinary water). I understand.

Claims (2)

セメント、水、高性能AE減水剤およびAE剤を含むセメント組成物であって、上記水が、1μm以下の粒径を有する気泡を含み、
上記水に含まれる気泡の全量中、粒径が10~200nmの範囲内である気泡の割合が80体積%以上であり、
上記水1ミリリットル中の1μm以下の粒径を有する気泡の数が、10 個以上であることを特徴とするセメント組成物。
A cement composition comprising cement , water, a high performance AE water reducing agent and an AE agent , wherein the water contains bubbles having a particle size of 1 μm or less.
The proportion of bubbles having a particle size in the range of 10 to 200 nm is 80% by volume or more in the total amount of bubbles contained in the water.
A cement composition comprising 107 or more bubbles having a particle size of 1 μm or less in 1 ml of water .
請求項1に記載のセメント組成物の硬化体からなる表面形成部分を含む構造物。 A structure including a surface-forming portion made of a cured product of the cement composition according to claim 1 .
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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007191358A (en) 2006-01-20 2007-08-02 Univ Of Tsukuba Micorobubble incorporated material, microbubble incorporated cement based material, and method and apparatus for producing the microbubble incorporated cement based material
JP2007261242A (en) 2006-03-28 2007-10-11 Japan Landcare Technologies Co Ltd Method for producing kneading water for hydraulic cement
JP2009137026A (en) 2007-12-03 2009-06-25 Nikko Co Ltd Concrete producing apparatus using fine closed cell
JP2009190184A (en) 2008-02-12 2009-08-27 Kyushu Soho Project:Kk Aqueous solution for mixing concrete, and manufacturing method therefor
JP2011218308A (en) 2010-04-12 2011-11-04 Asupu:Kk Gas-dissolved liquid generating apparatus and method for generation
JP2014159503A (en) 2013-02-19 2014-09-04 Ohbayashi Corp Production method of foundation injection material, and foundation improving method
JP2015048290A (en) 2013-09-03 2015-03-16 電気化学工業株式会社 Method for producing cement cured body and cement hardened body
JP2015231927A (en) 2014-06-10 2015-12-24 デンカ株式会社 Manufacturing method of cement cured body and cement cured body
JP2018076201A (en) 2016-11-09 2018-05-17 太平洋セメント株式会社 Cement composition

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007191358A (en) 2006-01-20 2007-08-02 Univ Of Tsukuba Micorobubble incorporated material, microbubble incorporated cement based material, and method and apparatus for producing the microbubble incorporated cement based material
JP2007261242A (en) 2006-03-28 2007-10-11 Japan Landcare Technologies Co Ltd Method for producing kneading water for hydraulic cement
JP2009137026A (en) 2007-12-03 2009-06-25 Nikko Co Ltd Concrete producing apparatus using fine closed cell
JP2009190184A (en) 2008-02-12 2009-08-27 Kyushu Soho Project:Kk Aqueous solution for mixing concrete, and manufacturing method therefor
JP2011218308A (en) 2010-04-12 2011-11-04 Asupu:Kk Gas-dissolved liquid generating apparatus and method for generation
JP2014159503A (en) 2013-02-19 2014-09-04 Ohbayashi Corp Production method of foundation injection material, and foundation improving method
JP2015048290A (en) 2013-09-03 2015-03-16 電気化学工業株式会社 Method for producing cement cured body and cement hardened body
JP2015231927A (en) 2014-06-10 2015-12-24 デンカ株式会社 Manufacturing method of cement cured body and cement cured body
JP2018076201A (en) 2016-11-09 2018-05-17 太平洋セメント株式会社 Cement composition

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