JP7071282B2 - 硬化性シリコーン組成物およびそのアプリケーションおよび使用 - Google Patents
硬化性シリコーン組成物およびそのアプリケーションおよび使用 Download PDFInfo
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- JP7071282B2 JP7071282B2 JP2018554076A JP2018554076A JP7071282B2 JP 7071282 B2 JP7071282 B2 JP 7071282B2 JP 2018554076 A JP2018554076 A JP 2018554076A JP 2018554076 A JP2018554076 A JP 2018554076A JP 7071282 B2 JP7071282 B2 JP 7071282B2
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- Prior art keywords
- bicyclo
- spiro
- group
- octane
- heptane
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims description 119
- 229920001296 polysiloxane Polymers 0.000 title claims description 90
- -1 C20 hydrocarbon radical Chemical class 0.000 claims description 80
- 150000002430 hydrocarbons Chemical group 0.000 claims description 32
- 150000001875 compounds Chemical class 0.000 claims description 31
- 229930195733 hydrocarbon Natural products 0.000 claims description 31
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 31
- 239000003054 catalyst Substances 0.000 claims description 28
- 125000000524 functional group Chemical group 0.000 claims description 26
- 239000004215 Carbon black (E152) Substances 0.000 claims description 23
- 239000001257 hydrogen Substances 0.000 claims description 23
- 229910052739 hydrogen Inorganic materials 0.000 claims description 23
- 239000000463 material Substances 0.000 claims description 23
- 238000006243 chemical reaction Methods 0.000 claims description 21
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 21
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 21
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 claims description 20
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N methylene hexane Natural products CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 claims description 20
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 claims description 19
- 239000003112 inhibitor Substances 0.000 claims description 18
- 125000000962 organic group Chemical group 0.000 claims description 18
- 125000003118 aryl group Chemical group 0.000 claims description 17
- 125000004122 cyclic group Chemical group 0.000 claims description 17
- 230000003287 optical effect Effects 0.000 claims description 17
- 125000003003 spiro group Chemical group 0.000 claims description 17
- WPHGSKGZRAQSGP-UHFFFAOYSA-N norcarane Chemical compound C1CCCC2CC21 WPHGSKGZRAQSGP-UHFFFAOYSA-N 0.000 claims description 16
- 229920002554 vinyl polymer Polymers 0.000 claims description 15
- DCTOHCCUXLBQMS-UHFFFAOYSA-N 1-undecene Chemical group CCCCCCCCCC=C DCTOHCCUXLBQMS-UHFFFAOYSA-N 0.000 claims description 13
- 125000003367 polycyclic group Chemical group 0.000 claims description 13
- 239000000654 additive Substances 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 239000002184 metal Substances 0.000 claims description 12
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 12
- 230000035699 permeability Effects 0.000 claims description 12
- 239000003963 antioxidant agent Substances 0.000 claims description 11
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 claims description 10
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 10
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical group C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 claims description 10
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 10
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 claims description 10
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims description 10
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 claims description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 9
- 239000002318 adhesion promoter Substances 0.000 claims description 9
- YZLCEXRVQZNGEK-UHFFFAOYSA-N bicyclo[2.2.0]hexane Chemical compound C1CC2CCC21 YZLCEXRVQZNGEK-UHFFFAOYSA-N 0.000 claims description 9
- WNTGVOIBBXFMLR-UHFFFAOYSA-N bicyclo[3.3.1]nonane Chemical compound C1CCC2CCCC1C2 WNTGVOIBBXFMLR-UHFFFAOYSA-N 0.000 claims description 9
- RPZUBXWEQBPUJR-UHFFFAOYSA-N bicyclo[4.2.0]octane Chemical compound C1CCCC2CCC21 RPZUBXWEQBPUJR-UHFFFAOYSA-N 0.000 claims description 9
- 125000000582 cycloheptyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 9
- 125000000640 cyclooctyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 claims description 9
- AFFLGGQVNFXPEV-UHFFFAOYSA-N n-decene Natural products CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 claims description 9
- UMRZSTCPUPJPOJ-KNVOCYPGSA-N norbornane Chemical compound C1C[C@H]2CC[C@@H]1C2 UMRZSTCPUPJPOJ-KNVOCYPGSA-N 0.000 claims description 9
- 238000006116 polymerization reaction Methods 0.000 claims description 9
- OGNAOIGAPPSUMG-UHFFFAOYSA-N spiro[2.2]pentane Chemical compound C1CC11CC1 OGNAOIGAPPSUMG-UHFFFAOYSA-N 0.000 claims description 9
- FYGUBWKMMCWIKB-UHFFFAOYSA-N spiro[2.3]hexane Chemical compound C1CC11CCC1 FYGUBWKMMCWIKB-UHFFFAOYSA-N 0.000 claims description 9
- HEMCGZPSGYRIOL-UHFFFAOYSA-N spiro[2.4]heptane Chemical compound C1CC11CCCC1 HEMCGZPSGYRIOL-UHFFFAOYSA-N 0.000 claims description 9
- FOEYMRPOKBCNCR-UHFFFAOYSA-N spiro[2.5]octane Chemical compound C1CC11CCCCC1 FOEYMRPOKBCNCR-UHFFFAOYSA-N 0.000 claims description 9
- LBJQKYPPYSCCBH-UHFFFAOYSA-N spiro[3.3]heptane Chemical compound C1CCC21CCC2 LBJQKYPPYSCCBH-UHFFFAOYSA-N 0.000 claims description 9
- IWDANOJGJIFBEL-UHFFFAOYSA-N spiro[3.4]octane Chemical compound C1CCC21CCCC2 IWDANOJGJIFBEL-UHFFFAOYSA-N 0.000 claims description 9
- VMWOETMUNAQFAX-UHFFFAOYSA-N spiro[3.5]nonane Chemical compound C1CCC21CCCCC2 VMWOETMUNAQFAX-UHFFFAOYSA-N 0.000 claims description 9
- NECLQTPQJZSWOE-UHFFFAOYSA-N spiro[5.5]undecane Chemical compound C1CCCCC21CCCCC2 NECLQTPQJZSWOE-UHFFFAOYSA-N 0.000 claims description 9
- CTDQAGUNKPRERK-UHFFFAOYSA-N spirodecane Chemical compound C1CCCC21CCCCC2 CTDQAGUNKPRERK-UHFFFAOYSA-N 0.000 claims description 9
- AEBWATHAIVJLTA-UHFFFAOYSA-N 1,2,3,3a,4,5,6,6a-octahydropentalene Chemical compound C1CCC2CCCC21 AEBWATHAIVJLTA-UHFFFAOYSA-N 0.000 claims description 8
- IBVPVTPPYGGAEL-UHFFFAOYSA-N 1,3-bis(prop-1-en-2-yl)benzene Chemical compound CC(=C)C1=CC=CC(C(C)=C)=C1 IBVPVTPPYGGAEL-UHFFFAOYSA-N 0.000 claims description 8
- INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 claims description 8
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 8
- LASLVGACQUUOEB-UHFFFAOYSA-N bicyclo[1.1.0]butane Chemical compound C1C2CC21 LASLVGACQUUOEB-UHFFFAOYSA-N 0.000 claims description 8
- MKCBRYIXFFGIKN-UHFFFAOYSA-N bicyclo[1.1.1]pentane Chemical compound C1C2CC1C2 MKCBRYIXFFGIKN-UHFFFAOYSA-N 0.000 claims description 8
- JSMRMEYFZHIPJV-UHFFFAOYSA-N bicyclo[2.1.1]hexane Chemical compound C1C2CC1CC2 JSMRMEYFZHIPJV-UHFFFAOYSA-N 0.000 claims description 8
- PBVMIPXCKZYJMA-UHFFFAOYSA-N bicyclo[3.1.1]hept-4-ene Chemical group C1C2=CCCC1C2 PBVMIPXCKZYJMA-UHFFFAOYSA-N 0.000 claims description 8
- LPCWKMYWISGVSK-UHFFFAOYSA-N bicyclo[3.2.1]octane Chemical compound C1C2CCC1CCC2 LPCWKMYWISGVSK-UHFFFAOYSA-N 0.000 claims description 8
- GNTFBMAGLFYMMZ-UHFFFAOYSA-N bicyclo[3.2.2]nonane Chemical compound C1CC2CCC1CCC2 GNTFBMAGLFYMMZ-UHFFFAOYSA-N 0.000 claims description 8
- MHLPKAGDPWUOOT-UHFFFAOYSA-N housane Chemical compound C1CC2CC21 MHLPKAGDPWUOOT-UHFFFAOYSA-N 0.000 claims description 8
- 150000002734 metacrylic acid derivatives Chemical class 0.000 claims description 8
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 claims description 8
- PHICBFWUYUCFKS-UHFFFAOYSA-N spiro[4.4]nonane Chemical compound C1CCCC21CCCC2 PHICBFWUYUCFKS-UHFFFAOYSA-N 0.000 claims description 8
- SHOMMGQAMRXRRK-UHFFFAOYSA-N bicyclo[3.1.1]heptane Chemical compound C1C2CC1CCC2 SHOMMGQAMRXRRK-UHFFFAOYSA-N 0.000 claims description 7
- AWYMFBJJKFTCFO-UHFFFAOYSA-N bicyclo[3.2.0]heptane Chemical compound C1CCC2CCC21 AWYMFBJJKFTCFO-UHFFFAOYSA-N 0.000 claims description 7
- NAVGAEZCCRCJQT-UHFFFAOYSA-N bicyclo[3.3.3]undecane Chemical compound C1CCC2CCCC1CCC2 NAVGAEZCCRCJQT-UHFFFAOYSA-N 0.000 claims description 7
- BNRNAKTVFSZAFA-UHFFFAOYSA-N hydrindane Chemical compound C1CCCC2CCCC21 BNRNAKTVFSZAFA-UHFFFAOYSA-N 0.000 claims description 7
- 238000006459 hydrosilylation reaction Methods 0.000 claims description 7
- RSJKGSCJYJTIGS-BJUDXGSMSA-N undecane Chemical group CCCCCCCCCC[11CH3] RSJKGSCJYJTIGS-BJUDXGSMSA-N 0.000 claims description 7
- OOXMQACSWCZQLX-UHFFFAOYSA-N 3,9-bis(ethenyl)-2,4,8,10-tetraoxaspiro[5.5]undecane Chemical compound C1OC(C=C)OCC21COC(C=C)OC2 OOXMQACSWCZQLX-UHFFFAOYSA-N 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- 125000005073 adamantyl group Chemical group C12(CC3CC(CC(C1)C3)C2)* 0.000 claims description 6
- 230000003078 antioxidant effect Effects 0.000 claims description 6
- GPRLTFBKWDERLU-UHFFFAOYSA-N bicyclo[2.2.2]octane Chemical compound C1CC2CCC1CC2 GPRLTFBKWDERLU-UHFFFAOYSA-N 0.000 claims description 6
- JAPMJSVZDUYFKL-UHFFFAOYSA-N bicyclo[3.1.0]hexane Chemical compound C1CCC2CC21 JAPMJSVZDUYFKL-UHFFFAOYSA-N 0.000 claims description 6
- WMRPOCDOMSNXCQ-UHFFFAOYSA-N bicyclo[3.3.2]decane Chemical compound C1CCC2CCCC1CC2 WMRPOCDOMSNXCQ-UHFFFAOYSA-N 0.000 claims description 6
- CRPUJAZIXJMDBK-UHFFFAOYSA-N camphene Chemical compound C1CC2C(=C)C(C)(C)C1C2 CRPUJAZIXJMDBK-UHFFFAOYSA-N 0.000 claims description 6
- 239000000945 filler Substances 0.000 claims description 6
- 239000010408 film Substances 0.000 claims description 6
- 239000003999 initiator Substances 0.000 claims description 6
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 claims description 6
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 6
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 6
- GRWFGVWFFZKLTI-YGPZHTELSA-N (5r)-4,6,6-trimethylbicyclo[3.1.1]hept-3-ene Chemical group C1C2CC=C(C)[C@]1([H])C2(C)C GRWFGVWFFZKLTI-YGPZHTELSA-N 0.000 claims description 5
- WGGHTQJCLFQFTA-UHFFFAOYSA-N 1,2,3,3a,4,5-hexahydropentalene Chemical compound C1CC=C2CCCC21 WGGHTQJCLFQFTA-UHFFFAOYSA-N 0.000 claims description 5
- OKFAYTDWPOEJQT-UHFFFAOYSA-N 2-ethenyladamantane Chemical compound C1C(C2)CC3CC1C(C=C)C2C3 OKFAYTDWPOEJQT-UHFFFAOYSA-N 0.000 claims description 5
- JTCQPLINQYIRDZ-UHFFFAOYSA-N 2-methylideneadamantane Chemical compound C1C(C2)CC3CC1C(=C)C2C3 JTCQPLINQYIRDZ-UHFFFAOYSA-N 0.000 claims description 5
- KUKRLSJNTMLPPK-UHFFFAOYSA-N 4,7,7-trimethylbicyclo[2.2.1]hept-2-ene Chemical group C1CC2(C)C=CC1C2(C)C KUKRLSJNTMLPPK-UHFFFAOYSA-N 0.000 claims description 5
- GLVKGYRREXOCIB-UHFFFAOYSA-N Bornylene Chemical group CC1CCC(C(C)(C)C)C=C1 GLVKGYRREXOCIB-UHFFFAOYSA-N 0.000 claims description 5
- 230000000996 additive effect Effects 0.000 claims description 5
- 125000002947 alkylene group Chemical group 0.000 claims description 5
- URDZMVZWPCLMJT-UHFFFAOYSA-N bicyclo[1.1.0]but-2-ene Chemical compound C1=C2CC21 URDZMVZWPCLMJT-UHFFFAOYSA-N 0.000 claims description 5
- VIQRCOQXIHFJND-UHFFFAOYSA-N bicyclo[2.2.2]oct-2-ene Chemical compound C1CC2CCC1C=C2 VIQRCOQXIHFJND-UHFFFAOYSA-N 0.000 claims description 5
- SSPNLRVPYROWLU-UHFFFAOYSA-N bicyclo[3.2.1]oct-4-ene Chemical compound C1CC(C2)CCC2=C1 SSPNLRVPYROWLU-UHFFFAOYSA-N 0.000 claims description 5
- JSIYGGNTVMFDHJ-UHFFFAOYSA-N bicyclo[4.1.0]hept-5-ene Chemical compound C1CCC=C2CC21 JSIYGGNTVMFDHJ-UHFFFAOYSA-N 0.000 claims description 5
- 125000001995 cyclobutyl group Chemical group [H]C1([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 claims description 5
- URYYVOIYTNXXBN-UPHRSURJSA-N cyclooctene Chemical group C1CCC\C=C/CC1 URYYVOIYTNXXBN-UPHRSURJSA-N 0.000 claims description 5
- 239000004913 cyclooctene Chemical group 0.000 claims description 5
- 125000002433 cyclopentenyl group Chemical group C1(=CCCC1)* 0.000 claims description 5
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentenylidene Natural products C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 claims description 5
- 125000003700 epoxy group Chemical group 0.000 claims description 5
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims description 5
- 229920000647 polyepoxide Polymers 0.000 claims description 5
- 229920006395 saturated elastomer Polymers 0.000 claims description 5
- 239000004065 semiconductor Substances 0.000 claims description 5
- YGSMGHRVKGFZPG-UHFFFAOYSA-N spiro[2.2]pent-1-ene Chemical compound C1CC11C=C1 YGSMGHRVKGFZPG-UHFFFAOYSA-N 0.000 claims description 5
- KYSZFXOVOHPNSF-UHFFFAOYSA-N spiro[2.4]hept-1-ene Chemical compound C1CCCC21C=C2 KYSZFXOVOHPNSF-UHFFFAOYSA-N 0.000 claims description 5
- BJYHKTCNIMBULR-UHFFFAOYSA-N spiro[3.3]hept-2-ene Chemical compound C1CCC21C=CC2 BJYHKTCNIMBULR-UHFFFAOYSA-N 0.000 claims description 5
- UNROQYRUBXNDGR-UHFFFAOYSA-N spiro[3.4]oct-2-ene Chemical compound C1C=CC11CCCC1 UNROQYRUBXNDGR-UHFFFAOYSA-N 0.000 claims description 5
- LPNXOOLDBYYZIG-UHFFFAOYSA-N spiro[3.5]non-2-ene Chemical compound C1C=CC11CCCCC1 LPNXOOLDBYYZIG-UHFFFAOYSA-N 0.000 claims description 5
- RWXPSIRAVCNFPR-UHFFFAOYSA-N spiro[4.4]non-3-ene Chemical compound C1CCCC21C=CCC2 RWXPSIRAVCNFPR-UHFFFAOYSA-N 0.000 claims description 5
- 125000003396 thiol group Chemical class [H]S* 0.000 claims description 5
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- BZSHLPGOHIOWDF-UHFFFAOYSA-N bicyclo[2.1.1]hex-3-ene Chemical compound C1C2=CCC1C2 BZSHLPGOHIOWDF-UHFFFAOYSA-N 0.000 claims description 4
- 239000008393 encapsulating agent Substances 0.000 claims description 4
- 239000012760 heat stabilizer Substances 0.000 claims description 4
- CCEFMUBVSUDRLG-KXUCPTDWSA-N (4R)-limonene 1,2-epoxide Natural products C1[C@H](C(=C)C)CC[C@@]2(C)O[C@H]21 CCEFMUBVSUDRLG-KXUCPTDWSA-N 0.000 claims description 3
- WEEGYLXZBRQIMU-UHFFFAOYSA-N 1,8-cineole Natural products C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 claims description 3
- AOIYTIDHFMNVOO-UHFFFAOYSA-N 2,3,3a,4,5,6-hexahydro-1h-indene Chemical compound C1CCC=C2CCCC21 AOIYTIDHFMNVOO-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 3
- CCEFMUBVSUDRLG-XNWIYYODSA-N Limonene-1,2-epoxide Chemical compound C1[C@H](C(=C)C)CCC2(C)OC21 CCEFMUBVSUDRLG-XNWIYYODSA-N 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 3
- PXRCIOIWVGAZEP-UHFFFAOYSA-N Primaeres Camphenhydrat Natural products C1CC2C(O)(C)C(C)(C)C1C2 PXRCIOIWVGAZEP-UHFFFAOYSA-N 0.000 claims description 3
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- UTODCSRVEOLXKS-UHFFFAOYSA-N bicyclo[3.2.2]non-4-ene Chemical compound C1CC(CC2)CCC2=C1 UTODCSRVEOLXKS-UHFFFAOYSA-N 0.000 claims description 3
- SIVKZPBURVINMX-UHFFFAOYSA-N bicyclo[3.3.1]non-4-ene Chemical compound C1CC=C2CCCC1C2 SIVKZPBURVINMX-UHFFFAOYSA-N 0.000 claims description 3
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- LZWKDAMVYOAKLT-UHFFFAOYSA-N bicyclo[4.2.0]oct-5-ene Chemical compound C1CCC2CCC2=C1 LZWKDAMVYOAKLT-UHFFFAOYSA-N 0.000 claims description 3
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- ZYPYEBYNXWUCEA-UHFFFAOYSA-N camphenilone Natural products C1CC2C(=O)C(C)(C)C1C2 ZYPYEBYNXWUCEA-UHFFFAOYSA-N 0.000 claims description 3
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- AFXNVCRLTCZVIN-UHFFFAOYSA-N spiro[5.5]undec-4-ene Chemical compound C1CCCCC21C=CCCC2 AFXNVCRLTCZVIN-UHFFFAOYSA-N 0.000 claims description 3
- POPHMOPNVVKGRW-UHFFFAOYSA-N 1,2,3,4,4a,5,6,7-octahydronaphthalene Chemical compound C1CCC2CCCCC2=C1 POPHMOPNVVKGRW-UHFFFAOYSA-N 0.000 claims description 2
- NKVRTCKOMFDPBX-UHFFFAOYSA-N 1,3-bis(ethenyl)adamantane Chemical compound C1C(C2)CC3CC1(C=C)CC2(C=C)C3 NKVRTCKOMFDPBX-UHFFFAOYSA-N 0.000 claims description 2
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- 150000002431 hydrogen Chemical class 0.000 claims 6
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- ONHWEKNXUWQYQP-UHFFFAOYSA-N bicyclo[2.1.0]pent-3-ene Chemical compound C1C=C2CC21 ONHWEKNXUWQYQP-UHFFFAOYSA-N 0.000 claims 2
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- MTADUJBFHBFCHU-UHFFFAOYSA-N spiro[2.3]hex-1-ene Chemical compound C1CCC21C=C2 MTADUJBFHBFCHU-UHFFFAOYSA-N 0.000 claims 2
- UFVSPYWGYRRXOF-UHFFFAOYSA-N spiro[2.5]oct-1-ene Chemical compound C1CCCCC21C=C2 UFVSPYWGYRRXOF-UHFFFAOYSA-N 0.000 claims 2
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- ZWUBFMWIQJSEQS-UHFFFAOYSA-N 1,1-bis(ethenyl)cyclohexane Chemical compound C=CC1(C=C)CCCCC1 ZWUBFMWIQJSEQS-UHFFFAOYSA-N 0.000 claims 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 39
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 27
- 239000003431 cross linking reagent Substances 0.000 description 19
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- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- UEVAMYPIMMOEFW-UHFFFAOYSA-N trolamine salicylate Chemical compound OCCN(CCO)CCO.OC(=O)C1=CC=CC=C1O UEVAMYPIMMOEFW-UHFFFAOYSA-N 0.000 description 1
- 229940030300 trolamine salicylate Drugs 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000001717 vitis vinifera seed extract Substances 0.000 description 1
- 235000020334 white tea Nutrition 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/80—Siloxanes having aromatic substituents, e.g. phenyl side groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/48—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
- C08G77/50—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms by carbon linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/14—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/81—Preparation or application process involves irradiation
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Description
(A)下記式を有するオルガノポリシロキサン:
ここでR1は、C1~C20の二価の炭化水素、C4~C20の分岐の二価の炭化水素またはC4~C30環含有炭化水素基から選択される二価の有機基であり;
R2は、ビニル、ビニル含有基、不飽和炭化水素、不飽和環状炭化水素、アクリレート、メタクリレート、ヒドロキシ、アルコキシおよびエポキシから独立して選択される硬化性官能基であり;
R3~R14は、水素、C1~C10の一価の炭化水素基、C6~C20の一価の芳香族基、およびC4~C30の一価の飽和または不飽和のシクロアルキル基から独立して選択され、
xおよびzは独立して1~30であり;
yおよびwは独立して0~30であり;そして
nは1~30であり;
(B)少なくとも1つの-SiH基、少なくとも1つの-SH基、またはそれらの2つ以上の組み合わせを含む化合物から選択される架橋剤;
(C)光開始剤、熱開始剤、金属含有触媒、またはそれらの2つ以上の組み合わせから選択される反応促進剤;
(D)任意の防止剤;および
(E)任意の1つ以上の添加剤、を含む硬化性シリコーン組成物を提供する。
ここでR19はC1~C20の二価炭化水素基、C4~C20の二価の炭化水素基またはC4~C30の環含有の二価の炭化水素基から選ばれる二価の有機基であり、
R20は、水素、アクリレート、メタクリレート、チオールまたはR2から選択される官能基であり;
R21~R32は、水素、C1~C10の一価の炭化水素基、C6~C20の一価の芳香族基、およびC4~C30の一価のシクロアルキル基から独立して選択され;
aおよびdは独立して1~30であり;
bおよびcは独立して0~30であり;そして
mは1~30である。
(A)下記式を有するオルガノポリシロキサン:
ここでR1はC1~C20の二価の炭化水素、C4~C20の分岐の二価の炭化水素またはC4~C30の環含有炭化水素基から選択される二価の有機基であり;
R2は、ビニル、ビニル含有基、不飽和炭化水素、不飽和環状炭化水素、アクリレート、メタクリレート、ヒドロキシ、アルコキシおよびエポキシから独立して選択される硬化性官能基であり;
R3~R14は、水素、C1~C10の一価の炭化水素基、C6~C20の一価の芳香族基、およびC4~C30の一価の飽和または不飽和のシクロアルキル基から独立して選択され;
xおよびzは独立して1~30であり;
yおよびwは独立して0~30であり;そして
nは1~30であり;
(B)少なくとも1つの-SiH基、少なくとも1つの-SH基、またはそれらの2つ以上の組み合わせを含む化合物から選択される架橋剤;
(C)光開始剤、熱開始剤、金属含有触媒、またはそれらの2つ以上の組み合わせから選択される反応促進剤;
(D)任意の防止剤;および
(E)任意の1以上の添加剤を含む。
ここでR19はC1~C20の二価の炭化水素、C4~C20の二価の炭化水素またはC4~C30の環含有の二価の炭化水素基から選ばれる二価の有機基であり;
R20は、水素、アクリレート、メタクリレート、チオールまたはR2から選択される官能基であり;
R21~R32は、水素、C1~C10の一価の炭化水素基、C6~C20の一価の芳香族基、およびC4~C30の一価のシクロアルキル基から独立して選択され;
aおよびdは独立して1~30であり;
bおよびcは独立して0~30であり;そして
mは1~30である。
ここでR1は、C1~C20の炭化水素、C4~C20の分岐の炭化水素、またはC4~C30の環含有炭化水素基から選択される二価の有機基であり;
R2は、ビニル、ビニル含有基、不飽和炭化水素、不飽和環状炭化水素、アクリレート、メタクリレート、ヒドロキシ、アルコキシおよびエポキシから独立して選択される硬化性官能基であり;
R3~R14は、水素、C1~C10の一価の炭化水素基、C6~C20の一価の芳香族基、およびC4~C30の一価の飽和または不飽和のシクロアルキル基から独立して選択され;
xおよびzは独立して1~30であり;
yおよびwは独立して0~30であり;そして
nは1~30である。
ここでR19は、C1~C20の二価の炭化水素基、C4~C20の分岐の二価の炭化水素基またはC4~C30の環含有の二価の炭化水素基から選択される二価の有機基であり;
R20は、水素、アクリレート、メタクリレート、チオールまたはR2から選択される官能基であり;
R21~R32は、水素、C1~C10の一価の炭化水素基、C6~C20の一価の芳香族基、およびC4~C30の一価のシクロアルキル基から独立して選択され;
aおよびdは独立して1~30であり;
bおよびcは独立して0~30であり;そして
mは1~30である。
分子量3kDを有するノルボルネン末端封鎖フェニルメチルシリコーンノルボルニルエチルブロックコポリマー(A-1)を以下のスキームに従って合成した。
分子量140kDを有するノルボルネン末端封鎖フェニルメチルシリコーンノルボルネニルエチルブロックコポリマー(成分A-2)を、A-1について記載した方法と同様にして合成した。
ヒドリド末端封鎖フェニルメチルシリコーンノルボルネニルエチルブロックコポリマー(成分B)を以下のスキームに従って合成した。
例1で得られたコポリマー(以下、A-1と称する)87.7質量部、硬化触媒として白金ビニルシロキサン錯体(白金濃度:1,3,5,7-テトラビニルメチルシクロシロキサン油溶液にて1.8質量%)0.025質量部、反応防止剤としてジアリルマレエート0.125質量部を混合して硬化性シリコーン組成物を調製した。次いで、得られた混合物にB-2成分(架橋剤1と称する)12.15質量部を添加した。組成物の均質な配合が達成されるまで、組成物をスピードミキサーで完全に混合した。この組成物をガラス板からなる成形型に流し込み、厚さ1mmとした後、130℃で1時間加熱して硬化生成物を得た。
例1で得られたコポリマー(A-1)85.5質量部、硬化触媒として白金-ビニルシロキサン錯体(白金濃度:1,3,5,7-テトラビニルメチルシクロシロキサン油溶液にて1.8%)0.025質量部、および反応防止剤としてジアリルマレエート0.125を混合して硬化性シリコーン組成物を調製した。次いで、得られた混合物に架橋剤としてB-3成分14.35質量部を添加した。成分の均質な配合が達成されるまで、組成物全体がスピードミキサー中で完全に混合された。この組成物をガラス板からなる成形型に1mmの厚さで流し込み、130℃で1時間加熱して硬化生成物を得た。
例1で得られたコポリマー(A-1)86.6質量部、硬化触媒として白金-ビニルシロキサン錯体(白金濃度:1,3,5,7-テトラビニルメチルシクロシロキサン油溶液にて1.8%)0.025質量部、および反応防止剤としてジアリルマレエート0.125質量部を混合して硬化性シリコーン組成物を調製した。次いで、得られた混合物に、架橋剤として成分B-2を6.075質量部、成分B-3を7.175質量部添加した。成分の均質な配合が達成されるまで、組成物全体がスピードミキサー中で完全に混合された。この組成物をガラス板からなる成形型に1mmの厚さで流し込み、130℃で1時間加熱して硬化生成物を得た。
ジアリルマレエートを反応防止剤として3,5-ジメチルヘクス-1-イン-3-オール0.125質量部に代えた以外は例6と同様にして硬化性組成物を調製した。組成物は、上述の例に記載の手順に従って130℃で1時間硬化させた。
例2で得られたコポリマー(A-2)91.1質量部、硬化触媒として白金-ビニルシロキサン錯体(白金濃度:1,3,5,7-テトラビニルメチルシクロシロキサン油溶液で1.8%)0.025質量部、および反応防止剤としてジアリルマレエート0.125質量部を混合して硬化性シリコーン組成物を調製した。次いで、得られた混合物に、架橋剤としてB-2成分8.75質量部を添加した。成分の均質な配合が達成されるまで、組成物全体がスピードミキサー中で完全に混合された。この組成物をガラス板からなる成形型に流し込み、厚さ1mmとし、130℃で1時間加熱して硬化生成物を得た。
例7に記載の組成物と同様に、1,3,5-トリス[4-ヒドロキシ-3,5-ビス(2-メチル-2-プロパニル)ベンジル]-1,3,5-トリアジナン-2,4,6-トリオン(BASF製、商品名Irganox 3114)0.1質量部をさらに加えて、硬化性組成物を調製した。上述したようにガラス板から形成された成形型にて130℃で1時間硬化させることにより、1mmの硬化シートを得た。
例1のシリコーン組成物95部、チオール架橋剤4.5部および式MDDSHM(Gelest, Inc.から入手可能なSMS-992)の光開始剤(Darcour 1173)0.5部を含み、組成物を4500mJ/cm2の線量でUV線に暴露することによって硬化性シリコーン組成物を調製した。得られた硬化生成物は非常に透明と観察された。
例で得られた硬化シートの特性を以下の方法で評価した(1mm)。結果を表1に要約している。
Claims (27)
- (A)下記式を有するオルガノポリシロキサン:
式中、R1はC4~C30の環含有炭化水素基から選択される二価の有機基であり;
R2は、ビニル、ビニル含有基、不飽和炭化水素、不飽和環状炭化水素、アクリレート、メタクリレート、およびエポキシから独立して選択される硬化性官能基であり;
R3~R14は、水素、C1~C10の一価の炭化水素基、C6~C20の一価の芳香族基、およびC4~C30の一価の飽和または不飽和のシクロアルキル基から独立して選択され;
xおよびzは独立して1~30であり;
yおよびwは独立して0~30であり;そして
nは1~30であり;
(B)
ここでR19は、C1~C20の二価の炭化水素基、C4~C20の分岐の二価の炭化水素基またはC4~C30の環含有の二価の炭化水素基から選択される二価の有機基であり;
R20は、水素、アクリレート、メタクリレート、チオ―ルまたはR2から選択される官能基であり、ここで少なくとも一つのR20は水素またはチオ―ルであり;
R21~R32は、水素、C1~C10の一価の炭化水素基、C6~C20の一価の芳香族基、およびC4~C30の一価のシクロアルキル基から独立して選択され;
aおよびdは独立して1~30であり;
bおよびcは独立して0~30であり;そして
mは1~30であり;または
の式で表される化合物から選択される少なくとも1つの-SiH基、少なくとも1つの-SH基、またはそれらの2つ以上の組み合わせを含むシリコーン含有化合物;
(C)光開始剤、熱開始剤、金属含有触媒、またはそれらの2つ以上の組み合わせから選択される反応促進剤;
(D)任意に重合防止剤;および
(E)任意に1つ以上の添加剤、を含む硬化性シリコーン組成物。 - R1が、シクロブチル基、シクロペンチル基、シクロヘキシル基、シクロヘプチル基、シクロオクチル基、1,1-ジエテニルシクロヘキサン;1,3-ジエテニルシクロヘキサン;ビシクロ[2.2.1]-2,5-ジエテニルヘプタン;1,4-ジ-2-プロペ-1-ニルシクロヘキサン;1,3-ジイソプロペニルベンゼン;スピロ[5.5]-3,8-ジエテニルウンデカン;1,3-ジエテニルアダマンタン;ビニルノルボルネン;3,9-ジビニル-2,4,8,10-テトラオキサスピロ[5.5]ウンデカン;ピナン、ボルナン、ノルピナン、ノルボルナン、スピロ[2.2]ペンタン、スピロ[2.3]ヘキサン、スピロ[2.4]ヘプタン、スピロ[2.5]オクタン、スピロ[3.3]ヘプタン、スピロ[3.4]オクタン、スピロ[3.5]ノナン、スピロ[4.4]ノナン、スピロ[4.5]デカン、スピロ[5.5]ウンデカン、ビシクロ[1.1.0]ブタン、ビシクロ[2.1.0]ペンタン、ビシクロ[2.2.0]ヘキサン、ビシクロ[3.1.0]ヘキサン、ビシクロ[3.2.0]ヘプタン、ビシクロ[3.3.0]オクタン、ビシクロ[4.1.0]ヘプタン、ビシクロ[4.2.0]オクタン、ビシクロ[4.3.0]ノナン、ビシクロ[4.4.0]デカン、ビシクロ[1.1.1]ペンタン、ビシクロ[2.1.1]ヘキサン、ビシクロ[2.2.1]ヘプタン、ビシクロ[2.2.2]オクタン、ビシクロ[3.1.1]ヘプタン、ビシクロ[3.2.1]オクタン、ビシクロ[3.2.2]ノナン、ビシクロ[3.3.1]ノナン、ビシクロ[3.3.2]デカン、ビシクロ[3.3.3]ウンデカン、アダマンチル、トリシクロ[5.2.1.02,6]デカン、トリシクロ[4.3.1.12,5]ウンデカン環から選択されるC4~C30の環含有炭化水素基を含む二価の基から選択される、請求項1に記載の硬化性シリコーン組成物。
- R2が、ビニル官能基を含むC1~C20の炭化水素ラジカル、ビニル官能基を含む一価のC4~C20の分岐の炭化水素ラジカル、またはビニル官能基を含む一価のC4~C30の環状の炭化水素ラジカルから選択される、請求項1または2に記載の硬化性シリコーン組成物。
- R2が式X-R16-であり、式中、Xが、ビニル基(CH2=CH2-)、不飽和環式基、不飽和多環式基から選択される硬化性官能基であり、そしてR16が、結合または二価の炭化水素である、請求項1~3のいずれかに記載の硬化性シリコーン組成物。
- Xが、シクロペンテン、シクロヘキセン、シクロオクテン、ピネン、ボルネン、ノルピネン、ノルボルネン、スピロ[2.2]ペンテン、スピロ[2.3]ヘキセン、スピロ[2.4]ヘプテン、スピロ[2.5]オクテン、スピロ[3.3]ヘプテン、スピロ[3.4]オクテン、スピロ[3.5]ノネン、スピロ[4.4]ノネン、スピロ[4.5]デセン、スピロ[5.5]ウンデセン、ビシクロ[1.1.0]ブテン、ビシクロ[2.1.0]ペンテン、ビシクロ[2.2.0]ヘキセン、ビシクロ[3.1.0]ヘキセン、ビシクロ[3.2.0]ヘプテン、ビシクロ[3.3.0]オクテン、ビシクロ[4.1.0]ヘプテン、ビシクロ[4.2.0]オクテン、ビシクロ[4.3.0]ノネン、ビシクロ[4.4.0]デセン、ビシクロ[1.1.1]ペンテン、ビシクロ[2.1.1]ヘキセン、ビシクロ[2.2.1]ヘプテン、ビシクロ[2.2.2]オクテン、ビシクロ[3.1.1]ヘプテン、ビシクロ[3.2.1]オクテン、ビシクロ[3.2.2]ノネン、ビシクロ[3.3.1]ノネン、ビシクロ[3.3.2]デセン、ビシクロ[3.3.3]ウンデセン、アダマンテン、トリシクロ[5.2.1.02,6]デセン、トリシクロ[4.3.1.12,5]ウンデセン環、リモネン、カンフェン、リモネンオキシド、ビニルシクロヘキシルエポキシド、ジシクロペンタジエン、5-エチリデン-2-ノルボルネン、2-ビニルアダマンタン、2-メチレンアダマンタン、ジシクロペンタジエン、(-)-ベータ-カミグレン、または4-ビニルシクロヘキシルから選択される、請求項4に記載の硬化性シリコーン組成物。
- 前記シリコーン含有化合物が、環状シリコーン、直鎖状シリコーン、またはそれらの2つ以上の組み合わせから選択される、請求項1~5のいずれかに記載の硬化性シリコーン組成物。
- R19が、シクロペンチル基、シクロヘキシル基、シクロヘプチル基、シクロオクチル基;ピナン、ボルナン、ノルピナン、ノルボルナン、スピロ[2.2]ペンタン、スピロ[2.3]ヘキサン、スピロ[2.4]ヘプタン、スピロ[2.5]オクタン、スピロ[3.3]ヘプタン、スピロ[3.4]オクタン、スピロ[3.5]ノナン、スピロ[4.4]ノナン、スピロ[4.5]デカン、スピロ[5.5]ウンデカン、ビシクロ[1.1.0]ブタン、ビシクロ[2.1.0]ペンタン、ビシクロ[2.2.0]ヘキサン、ビシクロ[3.1.0]ヘキサン、ビシクロ[3.2.0]ヘプタン、ビシクロ[3.3.0]オクタン、ビシクロ[4.1.0]ヘプタン、ビシクロ[4.2.0]オクタン、ビシクロ[4.3.0]ノナン、ビシクロ[4.4.0]デカン、ビシクロ[1.1.1]ペンタン、ビシクロ[2.1.1]ヘキサン、ビシクロ[2.2.1]ヘプタン、ビシクロ[2.2.2]オクタン、ビシクロ[3.1.1]ヘプタン、ビシクロ[3.2.1]オクタン、ビシクロ[3.2.2]ノナン、ビシクロ[3.3.1]ノナン、ビシクロ[3.3.2]デカン、ビシクロ[3.3.3]ウンデカン、アダマンチル、トリシクロ[5.2.1.02,6]デカン、トリシクロ[4.3.1.12,5]ウンデカン環から選択されるC4~C30の環含有炭化水素基を含む二価の有機基、及び、ビシクロ[2.2.1]ヘプタ-2,5-ジエン、1,1-ジエテニルシクロヘキサン、1,3-ジエテニルシクロヘキサン、ビシクロ[2.2.1]-2,5-ジエテニルヘプタン、1,4-ジ-2-プロペ-1-ニルシクロヘキサン、1,3-ジイソプロペニルベンゼン、スピロ[5.5]-3,8-ジエテニルウンデカン、1,3-ジエテニルアダマンタン、ビニルノルボルネン、3,9-ジビニル-2,4,8,10-テトラオキサスピロ[5.5]ウンデカンがヒドロシリル化することにより生成する二価の飽和有機基、から選択される、請求項1に記載の硬化性シリコーン組成物。
- 前記反応促進剤が、金属含有触媒から選択される、請求項1~7のいずれかに記載の硬化性シリコーン組成物。
- 前記重合防止剤が、エチレン化合物、アセチレン化合物、またはそれらの組み合わせから選択される、請求項1~8のいずれかに記載の硬化性シリコーン組成物。
- 前記添加剤が、酸化防止剤、熱安定剤、接着促進剤、充填剤、またはそれらの2つ以上の組み合わせから選択される、請求項1~9のいずれかに記載の硬化性シリコーン組成物。
- 前記組成物が1.45~1.51の屈折率を有する、請求項1~10のいずれかに記載の硬化性シリコーン組成物。
- 前記組成物が95%以上の透明度を有する、請求項1~11のいずれかに記載の硬化性シリコーン組成物。
- 前記組成物が10-1~10g/m2日のMVTR、WVTR、Oの透過性を有する、請求項1~12のいずれかに記載の硬化性シリコーン組成物。
- 硬化性シリコーン組成物から形成された硬化物品であって、前記硬化性シリコーン組成物が、
(A)下記一般式を有するオルガノポリシロキサン:
式中、R1はC4~C30の環含有炭化水素基から選択される二価の有機基であり;
R2は、ビニル、ビニル含有基、不飽和炭化水素、不飽和環状炭化水素、アクリレート、メタクリレート、およびエポキシから独立して選択される硬化性官能基であり;
R3~R14は、水素、C1~C10の一価の炭化水素基、C6~C20の一価の芳香族基、およびC4~C30の一価の飽和または不飽和のシクロアルキル基から独立して選択され;
xおよびzは独立して1~30であり;
yおよびwは独立して0~30であり;そして
nは1~30であり;
(B)
ここでR19は、C1~C20の二価の炭化水素基、C4~C20の分岐の二価の炭化水素基またはC4~C30の環含有の二価の炭化水素基から選択される二価の有機基であり;
R20は、水素、アクリレート、メタクリレート、チオ―ルまたはR2から選択される官能基であり、ここで少なくとも一つのR20は水素またはチオ―ルであり;
R21~R32は、水素、C1~C10の一価の炭化水素基、C6~C20の一価の芳香族基、およびC4~C30の一価のシクロアルキル基から独立して選択され;
aおよびdは独立して1~30であり;
bおよびcは独立して0~30であり;そして
mは1~30であり;または
の式で表される化合物から選択される少なくとも1つの-SiH基、少なくとも1つの-SH基、またはそれらの2つ以上の組み合わせを含むシリコーン含有化合物;
(C)光開始剤、熱開始剤および金属含有触媒から選択される反応促進剤;
(D)任意に重合防止剤;
(E)任意に1つ以上の添加剤、を含む、硬化物品。 - R1が、シクロブチル基、シクロペンチル基、シクロヘキシル基、シクロヘプチル基、シクロオクチル基、1,1-ジエテニルシクロヘキサン;1,3-ジエテニルシクロヘキサン;ビシクロ[2.2.1]-2,5-ジエテニルヘプタン;1,4-ジ-2-プロペ-1-ニルシクロヘキサン;1,3-ジイソプロペニルベンゼン;スピロ[5.5]-3,8-ジエテニルウンデカン;1,3-ジエテニルアダマンタン;ビニルノルボルネン;3,9-ジビニル-2,4,8,10-テトラオキサスピロ[5.5]ウンデカン;ピナン、ボルナン、ノルピナン、ノルボルナン、スピロ[2.2]ペンタン、スピロ[2.3]ヘキサン、スピロ[2.4]ヘプタン、スピロ[2.5]オクタン、スピロ[3.3]ヘプタン、スピロ[3.4]オクタン、スピロ[3.5]ノナン、スピロ[4.4]ノナン、スピロ[4.5]デカン、スピロ[5.5]ウンデカン、ビシクロ[1.1.0]ブタン、ビシクロ[2.1.0]ペンタン、ビシクロ[2.2.0]ヘキサン、ビシクロ[3.1.0]ヘキサン、ビシクロ[3.2.0]ヘプタン、ビシクロ[3.3.0]オクタン、ビシクロ[4.1.0]ヘプタン、ビシクロ[4.2.0]オクタン、ビシクロ[4.3.0]ノナン、ビシクロ[4.4.0]デカン、ビシクロ[1.1.1]ペンタン、ビシクロ[2.1.1]ヘキサン、ビシクロ[2.2.1]ヘプタン、ビシクロ[2.2.2]オクタン、ビシクロ[3.1.1]ヘプタン、ビシクロ[3.2.1]オクタン、ビシクロ[3.2.2]ノナン、ビシクロ[3.3.1]ノナン、ビシクロ[3.3.2]デカン、ビシクロ[3.3.3]ウンデカン、アダマンチル、トリシクロ[5.2.1.02,6]デカン、トリシクロ[4.3.1.12,5]ウンデカン環から選択されるC4~C30の環含有炭化水素基を含む二価の有機基から選択される、請求項14に記載の硬化物品。
- R2官能基が、ビニル官能基を含むC1~C20の炭化水素ラジカル、ビニル官能基を含む一価のC4~C20の分岐の炭化水素ラジカル、またはビニル官能基を含む一価のC4~C30の環状炭化水素ラジカルから選択される、請求項14または15に記載の硬化物品。
- R2基が、式X-R16-であり、式中、Xは硬化性官能基であり、R16が、結合または二価の炭化水素ラジカルであり、実施態様では、R16が、C1~C20のアルキレン基;C1~C10のアルキレン基;さらにはC1~C6アルキレン基でありえ、Xが、ビニル基(CH2=CH2-)、不飽和環式基、不飽和多環式基から選択されうる、請求項14~16のいずれかに記載の硬化物品。
- Xが、シクロペンテン、シクロヘキセン、シクロオクテン、ピネン、ボルネン、ノルピネン、ノルボルネン、スピロ[2.2]ペンテン、スピロ[2.3]ヘキセン、スピロ[2.4]ヘプテン、スピロ[2.5]オクテン、スピロ[3.3]ヘプテン、スピロ[3.4]オクテン、スピロ[3.5]ノネン、スピロ[4.4]ノネン、スピロ[4.5]デセン、スピロ[5.5]ウンデセン、ビシクロ[1.1.0]ブテン、ビシクロ[2.1.0]ペンテン、ビシクロ[2.2.0]ヘキセン、ビシクロ[3.1.0]ヘキセン、ビシクロ[3.2.0]ヘプテン、ビシクロ[3.3.0]オクテン、ビシクロ[4.1.0]ヘプテン、ビシクロ[4.2.0]オクテン、ビシクロ[4.3.0]ノネン、ビシクロ[4.4.0]デセン、ビシクロ[1.1.1]ペンテン、ビシクロ[2.1.1]ヘキセン、ビシクロ[2.2.1]ヘプテン、ビシクロ[2.2.2]オクテン、ビシクロ[3.1.1]ヘプテン、ビシクロ[3.2.1]オクテン、ビシクロ[3.2.2]ノネン、ビシクロ[3.3.1]ノネン、ビシクロ[3.3.2]デセン、ビシクロ[3.3.3]ウンデセン、アダマンテン、トリシクロ[5.2.1.02,6]デセン、トリシクロ[4.3.1.12,5]ウンデセン環、リモネン、カンフェン、リモネンオキシド、ビニルシクロヘキシルエポキシド、ジシクロペンタジエン、5-エチリデン-2-ノルボルネン、2-ビニルアダマンタン、2-メチレンアダマンタン、ジシクロペンタジエン、(-)-ベータ-カミグレン、4-ビニルシクロヘキシルから選択される、請求項17に記載の硬化物品。
- シリコーン含有化合物が、環状シリコーン、直鎖状シリコーン、またはそれらの2つ以上の組み合わせから選択される、請求項14~18のいずれかに記載の硬化物品。
- R19が、シクロペンチル基、シクロヘキシル基、シクロヘプチル基、シクロオクチル基;ピナン、ボルナン、ノルピナン、ノルボルナン、スピロ[2.2]ペンタン、スピロ[2.3]ヘキサン、スピロ[2.4]ヘプタン、スピロ[2.5]オクタン、スピロ[3.3]ヘプタン、スピロ[3.4]オクタン、スピロ[3.5]ノナン、スピロ[4.4]ノナン、スピロ[4.5]デカン、スピロ[5.5]ウンデカン、ビシクロ[1.1.0]ブタン、ビシクロ[2.1.0]ペンタン、ビシクロ[2.2.0]ヘキサン、ビシクロ[3.1.0]ヘキサン、ビシクロ[3.2.0]ヘプタン、ビシクロ[3.3.0]オクタン、ビシクロ[4.1.0]ヘプタン、ビシクロ[4.2.0]オクタン、ビシクロ[4.3.0]ノナン、ビシクロ[4.4.0]デカン、ビシクロ[1.1.1]ペンタン、ビシクロ[2.1.1]ヘキサン、ビシクロ[2.2.1]ヘプタン、ビシクロ[2.2.2]オクタン、ビシクロ[3.1.1]ヘプタン、ビシクロ[3.2.1]オクタン、ビシクロ[3.2.2]ノナン、ビシクロ[3.3.1]ノナン、ビシクロ[3.3.2]デカン、ビシクロ[3.3.3]ウンデカン、アダマンチル、トリシクロ[5.2.1.02,6]デカン、トリシクロ[4.3.1.12,5]ウンデカン環から選択されるC4~C30の環含有基を含む二価の有機基、及び、1,1-ジエテニルシクロヘキサン、1,3-ジエテニルシクロヘキサン、ビシクロ[2.2.1]-2,5-ジエテニルヘプタン、1,4-ジ-2-プロペ-1-ニルシクロヘキサン、1,3-ジイソプロペニルベンゼン、スピロ[5.5]-3,8-ジエテニルウンデカン、1,3-ジエテニルアダマンタン、3,9-ジビニル-2,4,8,10-テトラオキサスピロ[5.5]ウンデカンがヒドロシリル化することにより生成する二価の飽和有機基、から選択される、請求項14に記載の硬化物品。
- 前記反応促進剤が金属含有触媒から選択される、請求項14~20のいずれかに記載の硬化物品。
- 前記重合防止剤が、エチレン化合物またはアセチレン化合物またはそれらの組み合わせから選択される、請求項14~21のいずれかに記載の硬化物品。
- 前記添加剤が、酸化防止剤、熱安定剤、接着促進剤、充填剤、またはそれらの組み合わせから選択される、請求項14~22のいずれかに記載の硬化物品。
- 前記物品が1.45~1.51の屈折率を有する、請求項14~23のいずれかに記載の硬化物品。
- 前記物品が95%以上の透明度を有する、請求項14~24のいずれかに記載の硬化物品。
- 前記硬化物品が、10-1~10g/m2日のMVTR、WVTR、Oの透過性を有する、請求項14~25のいずれかに記載の硬化物品。
- 前記物品が、電子部品または半導体デバイスとの組み合わせにおける、LED封止材、光導波路、光学レンズ、光学結合材料、光学接着剤、光学フィルムまたはシート、積層フィルムとシートから選択される、請求項14~26のいずれかに記載の硬化物品。
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US10385210B2 (en) * | 2017-06-20 | 2019-08-20 | Momentive Performance Materials Inc. | Curable silicone composition and applications and uses thereof |
TWI788442B (zh) * | 2017-11-16 | 2023-01-01 | 美商陶氏有機矽公司 | 矽氫化可固化聚矽氧組成物 |
US11472925B2 (en) * | 2018-03-22 | 2022-10-18 | Momentive Performance Materials Inc. | Silicone polymer |
WO2020031773A1 (ja) * | 2018-08-07 | 2020-02-13 | コニカミノルタ株式会社 | インクジェット用インク、それを用いた膜形成方法、インク塗膜、硬化シリコーンゴム膜及び多機能性膜 |
CN114641520A (zh) * | 2019-11-24 | 2022-06-17 | 陶氏东丽株式会社 | 可光固化的有机硅组合物及其固化产物 |
AU2021279018A1 (en) * | 2020-05-27 | 2023-02-02 | The Johns Hopkins University | Functional skin coating polymer |
US20230227625A1 (en) * | 2020-07-02 | 2023-07-20 | Fuji Polymer Industries Co., Ltd. | Silicone gel composition and silicone gel sheet |
FR3146276A1 (fr) * | 2023-03-03 | 2024-09-06 | L'oreal | Procede de traitement des fibres keratiniques mettant en œuvre un compose reticulable, un photo-initiateur polymerique et une irradiation lumineuse |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008069210A (ja) | 2006-09-12 | 2008-03-27 | Shin Etsu Chem Co Ltd | 多環式炭化水素基含有シリコーン系硬化性組成物 |
Family Cites Families (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL7502544A (nl) | 1974-03-07 | 1975-09-09 | Bayer Ag | Werkwijze voor het bereiden van siliciumhou- dende polymeren. |
JPS62207333A (ja) * | 1986-03-08 | 1987-09-11 | Nippon Petrochem Co Ltd | シリコ−ン共重合体 |
DE19734251A1 (de) | 1997-08-07 | 1999-02-11 | Wacker Chemie Gmbh | Bicyclen aufweisende Organosiliciumverbindungen |
US6072016A (en) * | 1997-12-29 | 2000-06-06 | Dow Corning Toray Silicone Co., Ltd. | Silphenylene polymer and composition containing same |
EP1524708A3 (en) | 1998-12-16 | 2006-07-26 | Battelle Memorial Institute | Environmental barrier material and methods of making. |
US6911518B2 (en) | 1999-12-23 | 2005-06-28 | Hybrid Plastics, Llc | Polyhedral oligomeric -silsesquioxanes, -silicates and -siloxanes bearing ring-strained olefinic functionalities |
DK1230276T3 (da) | 1999-10-20 | 2006-03-20 | Ciba Sc Holding Ag | Fotoinitiatorformuleringer |
US6413645B1 (en) | 2000-04-20 | 2002-07-02 | Battelle Memorial Institute | Ultrabarrier substrates |
US20030203210A1 (en) | 2002-04-30 | 2003-10-30 | Vitex Systems, Inc. | Barrier coatings and methods of making same |
JP4455318B2 (ja) | 2002-05-06 | 2010-04-21 | ケール コーポレーション | メタセシス反応による硬化性組成物 |
US7018713B2 (en) | 2003-04-02 | 2006-03-28 | 3M Innovative Properties Company | Flexible high-temperature ultrabarrier |
TW200513483A (en) * | 2003-10-10 | 2005-04-16 | Shinetsu Chemical Co | Curable composition |
TWI432805B (zh) | 2003-11-21 | 2014-04-01 | Sumitomo Bakelite Co | 形成光波導結構之方法 |
JP4371211B2 (ja) * | 2003-12-09 | 2009-11-25 | 信越化学工業株式会社 | 熱硬化性樹脂組成物及び光半導体封止剤 |
JP2005272697A (ja) | 2004-03-25 | 2005-10-06 | Shin Etsu Chem Co Ltd | 硬化性シリコーン樹脂組成物、光半導体用封止材および光半導体装置 |
DE102005063355B4 (de) | 2005-09-21 | 2015-08-20 | Carl Freudenberg Kg | Kautschukcompound, Verfahren zu deren Herstellung und Verwendungen |
CN101518151B (zh) | 2006-11-06 | 2015-09-16 | 新加坡科技研究局 | 纳米粒子封装阻障叠层 |
EP2083293A4 (en) | 2006-11-16 | 2010-09-01 | Sumitomo Bakelite Co | GUIDE OF LIGHT AND STRUCTURE OF GUIDE OF LIGHT |
EP1942125A1 (en) | 2006-12-20 | 2008-07-09 | 3M Innovative Properties Company | Compositions curable by ring opening metathesis polymerarization at low temperatures and their application in the dental field |
JP5279197B2 (ja) | 2007-05-07 | 2013-09-04 | 信越化学工業株式会社 | 硬化性有機ケイ素組成物およびその硬化物 |
CA2719796C (en) | 2008-03-31 | 2012-05-08 | Nok Corporation | Rubber composition and use thereof |
JP5155255B2 (ja) | 2009-06-30 | 2013-03-06 | 信越化学工業株式会社 | シロキサン官能性環状オレフィン(共)重合体の非対称膜及びその製造方法 |
JP5397350B2 (ja) | 2009-09-11 | 2014-01-22 | 信越化学工業株式会社 | 液状シリコーンゴムコーティング剤組成物、カーテンエアーバッグ及びその製造方法 |
JP2012046604A (ja) * | 2010-08-26 | 2012-03-08 | Shin-Etsu Chemical Co Ltd | 多環式炭化水素骨格含有成分を含む硬化性シリコーン系組成物 |
JP5533906B2 (ja) | 2011-02-28 | 2014-06-25 | 信越化学工業株式会社 | 付加反応硬化型オルガノポリシルメチレンシロキサンコポリマー組成物 |
JP5522111B2 (ja) * | 2011-04-08 | 2014-06-18 | 信越化学工業株式会社 | シリコーン樹脂組成物及び当該組成物を使用した光半導体装置 |
JP6148204B2 (ja) | 2014-06-03 | 2017-06-14 | 信越化学工業株式会社 | 硬化性組成物及び半導体装置 |
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Publication number | Priority date | Publication date | Assignee | Title |
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