JP7017413B2 - ポリオレフィンを生成するためのプロセス - Google Patents

ポリオレフィンを生成するためのプロセス Download PDF

Info

Publication number
JP7017413B2
JP7017413B2 JP2017561627A JP2017561627A JP7017413B2 JP 7017413 B2 JP7017413 B2 JP 7017413B2 JP 2017561627 A JP2017561627 A JP 2017561627A JP 2017561627 A JP2017561627 A JP 2017561627A JP 7017413 B2 JP7017413 B2 JP 7017413B2
Authority
JP
Japan
Prior art keywords
independently
substituted
group
unsubstituted
heterohydrocarbyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2017561627A
Other languages
English (en)
Japanese (ja)
Other versions
JP2018516294A (ja
JP2018516294A5 (enExample
Inventor
ジャッソン・ティー・パットン
トッド・ディー・セネカル
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
Dow Global Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies LLC filed Critical Dow Global Technologies LLC
Publication of JP2018516294A publication Critical patent/JP2018516294A/ja
Publication of JP2018516294A5 publication Critical patent/JP2018516294A5/ja
Application granted granted Critical
Publication of JP7017413B2 publication Critical patent/JP7017413B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/04Polymerisation in solution
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/34Polymerisation in gaseous state
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14Monomers containing five or more carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C08F4/545Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof rare earths being present, e.g. triethylaluminium + neodymium octanoate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/58Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with silicon, germanium, tin, lead, antimony, bismuth or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00Metallocene catalysts
    • C08F2420/02Cp or analog bridged to a non-Cp X anionic donor
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/03Narrow molecular weight distribution, i.e. Mw/Mn < 3

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
JP2017561627A 2015-05-29 2016-05-27 ポリオレフィンを生成するためのプロセス Active JP7017413B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562168485P 2015-05-29 2015-05-29
US62/168,485 2015-05-29
PCT/US2016/034656 WO2016196293A1 (en) 2015-05-29 2016-05-27 A process for producing a polyolefin

Publications (3)

Publication Number Publication Date
JP2018516294A JP2018516294A (ja) 2018-06-21
JP2018516294A5 JP2018516294A5 (enExample) 2020-11-12
JP7017413B2 true JP7017413B2 (ja) 2022-02-08

Family

ID=56121199

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2017561627A Active JP7017413B2 (ja) 2015-05-29 2016-05-27 ポリオレフィンを生成するためのプロセス

Country Status (7)

Country Link
US (1) US10465020B2 (enExample)
EP (1) EP3303425A1 (enExample)
JP (1) JP7017413B2 (enExample)
KR (1) KR102577009B1 (enExample)
CN (1) CN107709383B (enExample)
BR (1) BR112017025509B1 (enExample)
WO (1) WO2016196293A1 (enExample)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101920401B1 (ko) * 2016-12-06 2019-02-08 한화케미칼 주식회사 올레핀 중합 촉매용 전이금속 화합물, 이를 포함하는 올레핀 중합 촉매 및 이를 이용하여 중합된 폴리올레핀
JP7179750B2 (ja) * 2017-03-15 2022-11-29 ダウ グローバル テクノロジーズ エルエルシー マルチブロックコポリマー形成用触媒系
KR102100134B1 (ko) * 2017-08-21 2020-04-13 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 신규한 전이금속 화합물, 이를 포함하는 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000178293A (ja) 1998-08-14 2000-06-27 Basf Ag 希土類金属を基礎とする、重合活性を有し、橋かけされていない単核ビスアルキル金属のセミサンドイッチ錯体
JP2004500450A (ja) 1999-12-09 2004-01-08 ビーエーエスエフ アクチェンゲゼルシャフト 極性モノマー及び無極性モノマーの(共)重合方法
WO2006004068A1 (ja) 2004-07-02 2006-01-12 Riken メタロセン錯体を含む重合触媒組成物、およびそれを用いて製造される重合体
JP2006519902A (ja) 2003-03-07 2006-08-31 トータル・ペトロケミカルズ・リサーチ・フエリユイ フルオレニルが基になった「拘束幾何」配位子を伴うiiib族金属錯体

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4808561A (en) 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4912075A (en) 1987-12-17 1990-03-27 Exxon Chemical Patents Inc. Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization
US5008228A (en) 1988-03-29 1991-04-16 Exxon Chemical Patents Inc. Method for preparing a silica gel supported metallocene-alumoxane catalyst
US5086025A (en) 1988-03-29 1992-02-04 Exxon Chemical Patents Inc. Method for preparing a silica gel supported metallocene-alumoxane catalyst
US4914253A (en) 1988-11-04 1990-04-03 Exxon Chemical Patents Inc. Method for preparing polyethylene wax by gas phase polymerization
US5464906A (en) * 1994-11-21 1995-11-07 The Dow Chemical Company Ethylene homopolymerization using group 3 metal complexes
CN1062275C (zh) * 1995-12-15 2001-02-21 化学工业部北京化工研究院 用于乙烯聚合的茂金属催化体系及其应用
DE69703883T2 (de) 1996-05-14 2001-07-19 The Dow Chemical Co., Midland Yttrium enthaltend metallkomplexe und verfahren zur polymerisation von olefinen
ES2224266T3 (es) * 1996-08-08 2005-03-01 Dow Global Technologies Inc. Copmplejos metalicos que contienen ciclopentadienilo sustituido en la posicion 3 con un heteroatomo y procedimiento de polimerizacion de olefinas.
US6403773B1 (en) 1998-09-30 2002-06-11 Exxon Mobil Chemical Patents Inc. Cationic group 3 catalyst system
JP2002544282A (ja) * 1999-05-13 2002-12-24 ザ ダウ ケミカル カンパニー ジ−及びトリ−ヘテロ原子置換インデニル金属錯体
US7087686B2 (en) * 2001-08-06 2006-08-08 Bp Chemicals Limited Chain growth reaction process
US7851569B2 (en) 2006-07-07 2010-12-14 Sumitomo Chemical Company, Limited Rare earth metal complex, polymerization catalyst, and process for producing polymer

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000178293A (ja) 1998-08-14 2000-06-27 Basf Ag 希土類金属を基礎とする、重合活性を有し、橋かけされていない単核ビスアルキル金属のセミサンドイッチ錯体
JP2004500450A (ja) 1999-12-09 2004-01-08 ビーエーエスエフ アクチェンゲゼルシャフト 極性モノマー及び無極性モノマーの(共)重合方法
JP2006519902A (ja) 2003-03-07 2006-08-31 トータル・ペトロケミカルズ・リサーチ・フエリユイ フルオレニルが基になった「拘束幾何」配位子を伴うiiib族金属錯体
US20060264586A1 (en) 2003-03-07 2006-11-23 Abbas Razavi Group IIIb metal complexes with "constrained geometry" fluorenyl based ligands
WO2006004068A1 (ja) 2004-07-02 2006-01-12 Riken メタロセン錯体を含む重合触媒組成物、およびそれを用いて製造される重合体

Also Published As

Publication number Publication date
BR112017025509B1 (pt) 2022-05-10
KR20180013970A (ko) 2018-02-07
WO2016196293A1 (en) 2016-12-08
KR102577009B1 (ko) 2023-09-12
US10465020B2 (en) 2019-11-05
CN107709383B (zh) 2021-03-30
CN107709383A (zh) 2018-02-16
US20180171041A1 (en) 2018-06-21
JP2018516294A (ja) 2018-06-21
EP3303425A1 (en) 2018-04-11
BR112017025509A2 (pt) 2018-08-07

Similar Documents

Publication Publication Date Title
CN108779204B (zh) 烯烃聚合催化剂体系和其使用方法
JP6188715B2 (ja) 低分子量エチレン系材料及びアルファ−オレフィン系材料を製造するためのプロセス
CN110799551B (zh) 用于烯烃聚合的联芳基苯氧基iv族过渡金属催化剂
CN108884196B (zh) 烯烃聚合催化剂体系及其使用方法
KR20200021070A (ko) 올레핀 중합을 위한 비아릴 페녹시기 iv 전이 금속 촉매
JP7017413B2 (ja) ポリオレフィンを生成するためのプロセス
CN111164110A (zh) 在金属上具有烷氧基或酰胺基配体的用于改进溶解度的双-苯基-苯氧基聚烯烃催化剂
KR102459739B1 (ko) 이중 연결 포스포구아니딘 4족 금속 착체 및 이로부터 생성된 올레핀 중합 촉매
KR102448251B1 (ko) 티오구아니딘 iv 족 전이 금속 촉매 및 중합 시스템
CN113597438B (zh) 具有超高分子量能力和超低共聚单体结合的单齿氨基吡啶第iv族过渡金属烯烃共聚催化剂
CN120917031A (zh) 用于烯烃聚合的芳基-杂环-吡咯催化剂
WO2023177957A1 (en) Metal-containing bis(imino) per-substituted aryl compounds and methods thereof
KR20220031901A (ko) 올레핀 중합용 촉매로서의 두자리 디아지닐아미도 착물
WO2021086682A1 (en) Transition metal catalysts for olefin polymerization
KR20220016111A (ko) 모노-두자리 리간드, 비스-두자리 리간드 및 테트라-두자리 리간드 구아니딘 4족 전이 금속 올레핀 공중합 촉매
BR112021018118B1 (pt) Processo para polimerizar olefina

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20180129

RD03 Notification of appointment of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7423

Effective date: 20180202

RD04 Notification of resignation of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7424

Effective date: 20180501

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20190514

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20190528

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20200514

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20200707

A524 Written submission of copy of amendment under article 19 pct

Free format text: JAPANESE INTERMEDIATE CODE: A524

Effective date: 20200930

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20210126

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20210412

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20210629

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20210921

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20220105

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20220127

R150 Certificate of patent or registration of utility model

Ref document number: 7017413

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250