JP6991971B2 - スルホン酸モノマーを含むポリマーおよびピリジンジカルボン酸誘導体を含む組成物、ならびに美容トリートメント方法 - Google Patents
スルホン酸モノマーを含むポリマーおよびピリジンジカルボン酸誘導体を含む組成物、ならびに美容トリートメント方法 Download PDFInfo
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- JP6991971B2 JP6991971B2 JP2018529108A JP2018529108A JP6991971B2 JP 6991971 B2 JP6991971 B2 JP 6991971B2 JP 2018529108 A JP2018529108 A JP 2018529108A JP 2018529108 A JP2018529108 A JP 2018529108A JP 6991971 B2 JP6991971 B2 JP 6991971B2
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- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 206010019049 Hair texture abnormal Diseases 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 208000002720 Malnutrition Diseases 0.000 description 1
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical class [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 description 1
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical class NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 1
- MBBZMMPHUWSWHV-BDVNFPICSA-N N-methylglucamine Chemical compound CNC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO MBBZMMPHUWSWHV-BDVNFPICSA-N 0.000 description 1
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 229930003537 Vitamin B3 Natural products 0.000 description 1
- 229930003571 Vitamin B5 Natural products 0.000 description 1
- LXNHXLLTXMVWPM-UHFFFAOYSA-N Vitamin B6 Natural products CC1=NC=C(CO)C(CO)=C1O LXNHXLLTXMVWPM-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 150000001253 acrylic acids Chemical class 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 125000004423 acyloxy group Chemical group 0.000 description 1
- UDMBCSSLTHHNCD-KQYNXXCUSA-N adenosine 5'-monophosphate Chemical compound C1=NC=2C(N)=NC=NC=2N1[C@@H]1O[C@H](COP(O)(O)=O)[C@@H](O)[C@H]1O UDMBCSSLTHHNCD-KQYNXXCUSA-N 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 229940063655 aluminum stearate Drugs 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- JQRRFDWXQOQICD-UHFFFAOYSA-N biphenylen-1-ylboronic acid Chemical compound C12=CC=CC=C2C2=C1C=CC=C2B(O)O JQRRFDWXQOQICD-UHFFFAOYSA-N 0.000 description 1
- KTUQUZJOVNIKNZ-UHFFFAOYSA-N butan-1-ol;hydrate Chemical compound O.CCCCO KTUQUZJOVNIKNZ-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229960001631 carbomer Drugs 0.000 description 1
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 230000003778 catagen phase Effects 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 125000003724 cholesterol ester group Chemical group 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000000490 cosmetic additive Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- DDTBPAQBQHZRDW-UHFFFAOYSA-N cyclododecane Chemical compound C1CCCCCCCCCCC1 DDTBPAQBQHZRDW-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 1
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 1
- 229940113120 dipropylene glycol Drugs 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- DHUSXRNOMZWNNA-UHFFFAOYSA-N ethanesulfonic acid;prop-2-enamide Chemical compound NC(=O)C=C.CCS(O)(=O)=O DHUSXRNOMZWNNA-UHFFFAOYSA-N 0.000 description 1
- QUPDWYMUPZLYJZ-UHFFFAOYSA-N ethyl Chemical group C[CH2] QUPDWYMUPZLYJZ-UHFFFAOYSA-N 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 230000003700 hair damage Effects 0.000 description 1
- 239000000118 hair dye Substances 0.000 description 1
- 210000003780 hair follicle Anatomy 0.000 description 1
- 230000003779 hair growth Effects 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 230000003054 hormonal effect Effects 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229940031674 laureth-7 Drugs 0.000 description 1
- 125000002669 linoleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 230000001071 malnutrition Effects 0.000 description 1
- 235000000824 malnutrition Nutrition 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- BFOQBMCQGCJJTA-UHFFFAOYSA-N methanesulfonic acid;prop-2-enamide Chemical compound CS(O)(=O)=O.NC(=O)C=C BFOQBMCQGCJJTA-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- HOZLHJIPBBRFGM-UHFFFAOYSA-N n-dodecyl-2-methylprop-2-enamide Chemical compound CCCCCCCCCCCCNC(=O)C(C)=C HOZLHJIPBBRFGM-UHFFFAOYSA-N 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 229920001206 natural gum Polymers 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229960003512 nicotinic acid Drugs 0.000 description 1
- DFPAKSUCGFBDDF-UHFFFAOYSA-N nicotinic acid amide Natural products NC(=O)C1=CC=CN=C1 DFPAKSUCGFBDDF-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 208000015380 nutritional deficiency disease Diseases 0.000 description 1
- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- 229940101267 panthenol Drugs 0.000 description 1
- 229940023735 panthenyl ethyl ether Drugs 0.000 description 1
- 235000020957 pantothenol Nutrition 0.000 description 1
- 239000011619 pantothenol Substances 0.000 description 1
- WCVRQHFDJLLWFE-UHFFFAOYSA-N pentane-1,2-diol Chemical compound CCCC(O)CO WCVRQHFDJLLWFE-UHFFFAOYSA-N 0.000 description 1
- RJQRCOMHVBLQIH-UHFFFAOYSA-N pentane-1-sulfonic acid Chemical compound CCCCCS(O)(=O)=O RJQRCOMHVBLQIH-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 230000004962 physiological condition Effects 0.000 description 1
- 230000009894 physiological stress Effects 0.000 description 1
- 229950001046 piroctone Drugs 0.000 description 1
- BTSZTGGZJQFALU-UHFFFAOYSA-N piroctone olamine Chemical compound NCCO.CC(C)(C)CC(C)CC1=CC(C)=CC(=O)N1O BTSZTGGZJQFALU-UHFFFAOYSA-N 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229940068968 polysorbate 80 Drugs 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000012673 precipitation polymerization Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- AZIQALWHRUQPHV-UHFFFAOYSA-N prop-2-eneperoxoic acid Chemical compound OOC(=O)C=C AZIQALWHRUQPHV-UHFFFAOYSA-N 0.000 description 1
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
- AAYRWMCIKCRHIN-UHFFFAOYSA-N propane-1-sulfonic acid;prop-2-enamide Chemical compound NC(=O)C=C.CCCS(O)(=O)=O AAYRWMCIKCRHIN-UHFFFAOYSA-N 0.000 description 1
- RADKZDMFGJYCBB-UHFFFAOYSA-N pyridoxal hydrochloride Natural products CC1=NC=C(CO)C(C=O)=C1O RADKZDMFGJYCBB-UHFFFAOYSA-N 0.000 description 1
- ZUFQODAHGAHPFQ-UHFFFAOYSA-N pyridoxine hydrochloride Chemical compound Cl.CC1=NC=C(CO)C(CO)=C1O ZUFQODAHGAHPFQ-UHFFFAOYSA-N 0.000 description 1
- 229940083082 pyrimidine derivative acting on arteriolar smooth muscle Drugs 0.000 description 1
- 150000003230 pyrimidines Chemical class 0.000 description 1
- 229960001141 pyrithione zinc Drugs 0.000 description 1
- 239000007870 radical polymerization initiator Substances 0.000 description 1
- 230000001932 seasonal effect Effects 0.000 description 1
- 210000002966 serum Anatomy 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229940047670 sodium acrylate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- AZGINNVTHJQMPB-UHFFFAOYSA-M sodium;2-methylpropane-1-sulfonate;prop-2-enamide Chemical compound [Na+].NC(=O)C=C.CC(C)CS([O-])(=O)=O AZGINNVTHJQMPB-UHFFFAOYSA-M 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- VPYJNCGUESNPMV-UHFFFAOYSA-N triallylamine Chemical compound C=CCN(CC=C)CC=C VPYJNCGUESNPMV-UHFFFAOYSA-N 0.000 description 1
- ZTWTYVWXUKTLCP-UHFFFAOYSA-N vinylphosphonic acid Chemical compound OP(O)(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-N 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 235000019160 vitamin B3 Nutrition 0.000 description 1
- 239000011708 vitamin B3 Substances 0.000 description 1
- 235000009492 vitamin B5 Nutrition 0.000 description 1
- 239000011675 vitamin B5 Substances 0.000 description 1
- 239000011726 vitamin B6 Substances 0.000 description 1
- 235000019158 vitamin B6 Nutrition 0.000 description 1
- 235000021468 vitamin B8 Nutrition 0.000 description 1
- 229940011671 vitamin b6 Drugs 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q7/00—Preparations for affecting hair growth
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
- A61K8/4926—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having six membered rings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5424—Polymers characterized by specific structures/properties characterized by the charge anionic
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Description
- (i)一般式(I)
[式中、R1およびR2は、互いに独立して、水素原子、飽和もしくは不飽和の、直鎖状もしくは分岐状のC1~C18脂肪族炭化水素ラジカル、またはC6~C18アラルキルラジカルを表すが、前記ラジカルは、場合によっては、OH、NH2、-OR、-OCOR、および-NHR(ここで、RはC1~C18アルキル基を表す)から選択される1個または複数の基によって置換されていてもよく、R1基およびR2基の少なくとも1つは、水素原子以外のものである];および、
- (ii)スルホン酸基を含む少なくとも1種のモノマーを含む少なくとも1種のポリマー;
その組成物は、その組成物の全重量を規準にして、20重量%~80重量%、さらには30重量%~50重量%の範囲の量で水を含む。
本発明による組成物には、したがって、少なくとも1種のピリジンジカルボン酸エステルが含まれる。そのエステルは、モノエステルでもジエステルでもよいが、好ましくはジエステルである。それは、そのようなエステルの塩であってもよい。
R1基およびR2基の少なくとも1つは、水素原子以外のものであると理解されたい]またはそれらの塩に相当する。
- 2,4-ピリジンジカルボン酸ジメチル、
- 2,3-ピリジンジカルボン酸ジメチル、
- 2,4-ピリジンジカルボン酸ジエチル、
- 2,3-ピリジンジカルボン酸ジエチル、
- 2,5-ピリジンジカルボン酸ジエチル、
- 2,5-ピリジンジカルボン酸ジメチル、
- 2,4-ピリジンジカルボン酸ジイソプロピル、
- ピリジン-2,4-ジカルボン酸ジ(アセチルオキシメチル)(R1およびR2が-CH2-O-COCH3を表す式(I)の誘導体)。
本発明による組成物にはさらに、スルホン酸基を含む少なくとも1種のモノマーを含む1種または複数のポリマーが含まれる。
(a)遊離の形態にあるたとえば2-アクリルアミド-2-メチルプロパンスルホン酸のようなモノマーを、tert-ブタノール、または水およびtert-ブタノールの溶液の中に、分散または溶解させる工程;
(b)(a)で得られたモノマーの溶液または分散体を、ポリマーのスルホン酸官能基を90%~100%の範囲の中和度を得ることが可能な量の、1種もしくは複数の鉱物質塩基または有機塩基、好ましくはアンモニアNH3水溶液を用いて中和する工程;
(c)(b)で得られた溶液または分散体に、架橋性モノマーを添加する工程;
(d)フリーラジカル重合開始剤の存在下、10~150℃の範囲の温度で、標準的なフリーラジカル重合を実施し、ポリマーを、tert-ブタノールベースの溶液または分散体の中で沈降させる工程。
a)90重量%~99.9重量%の、次の一般式(II):
b)0.01重量%~10重量%の、少なくとも2個のオレフィン性二重結合を含む少なくとも1種のモノマーに由来する、架橋単位(それらの重量比は、ポリマーの全重量を規準に定義されたものである)。
- (1)アクリルアミドまたはメタクリルアミドと2-アクリルアミド-2-メチル-プロパンスルホン酸との架橋されたアニオン性コポリマー、特にW/Oエマルションの形態にあるもの、たとえば、SEPPICによりSepigel 305の名称で販売されているもの(INCI名称:ポリアクリルアミド/C13-14 イソパラフィン/Laureth-7)、SEPPICによりSimulgel 600の名称で販売されているもの(INCI名称:アクリルアミド/アクリロイルジメチルタウリン酸ナトリウムコポリマー/イソヘキサデカン/Polysorbate 80);
- (2)(メタ)アクリル酸または(メタ)アクリレートおよび2-アクリルアミド-2-メチルプロパンスルホン酸のコポリマー、特にW/Oエマルションの形態にあるもの、たとえば、SEPPICによりSimulgel NSの名称で販売されているもの(Polysorbate 60およびスクアラン中40%逆相エマルションとしてのアクリルアミド-2-メチルプロパンスルホン酸ナトリウム/アクリル酸ヒドロキシエチルのコポリマー)(INCI名称:アクリル酸ヒドロキシエチル/アクリロイルジメチルタウリン酸ナトリウムコポリマー/スクアラン/Polysorbate 60)、またはSEPPICによりSimulgel EGの名称で販売されているもの(イソヘキサデカン/水中45%逆相エマルションとしての、ナトリウム塩の形態にある、アクリル酸/アクリルアミド-2-メチルプロパンスルホン酸のコポリマー)(INCI名称:アクリル酸ナトリウム/アクリロイルジメチルタウリン酸ナトリウムコポリマー/イソヘキサデカン/Polysorbate 80)、またはそうでなければ、SEPPICによりSepinov EMT 10の名称で販売されているもの(INCI名称:アクリル酸ヒドロキシエチル/アクリロイルジメチルタウリン酸ナトリウムコポリマー);ならびに
- (3)2-アクリルアミド-2-メチルプロパンスルホン酸と、ビニルピロリドンまたはビニルホルムアミドとのコポリマー、たとえば、ClariantによりAristoflex AVCの名称で販売されている製品。
- コポリマーであって、架橋されていても、されていなくてもよく、そして中和されていても、されていなくてもよく、ポリマーを規準にして、15重量%~60重量%の2-アクリルアミド-2-メチルプロパンスルホン酸単位と、40重量%~85重量%の(C8~C16)アルキル(メタ)アクリルアミド単位または(C8~C16)アルキル(メタ)アクリレート単位とを含むコポリマーで、たとえば欧州特許出願公開第A-750,899号明細書に記載されているようなもの;
- ターポリマーであって、ポリマーを規準にして、10mol%~90mol%のアクリルアミド単位と、0.1mol%~10mol%の2-アクリルアミド-2-メチルプロパンスルホン酸単位と、5mol%~80mol%のn-(C6~C18)アルキルアクリルアミド単位とを含むターポリマー、たとえば、米国特許第A-5,089,578号明細書に記載されているようなもの;
- 非架橋のコポリマーであって、部分的もしくは全面的に中和された2-アクリルアミド-2-メチルプロパンスルホン酸と、n-ドデシル、n-ヘキサデシルもしくはn-オクタデシルメタクリレートとのコポリマー;
- 架橋もしくは非架橋のコポリマーであって、部分的もしくは全面的に中和された2-アクリルアミド-2-メチルプロパンスルホン酸とn-ドデシルメタクリルアミドとの、コポリマー。
- 8molのエチレンオキシドを用いてオキシエチレン化したC10~C18アルコール(Genapol(登録商標)C-080、Clariant製)、
- 8molのエチレンオキシドを用いてオキシエチレン化したC11オキソアルコール(Genapol(登録商標)UD-080、Clariant製)、
- 7molのエチレンオキシドを用いてオキシエチレン化したC11オキソアルコール(Genapol(登録商標)UD-070、Clariant製)、
- 7molのエチレンオキシドを用いてオキシエチレン化したC12~C14アルコール(Genapol(登録商標)LA-070、Clariant製)、
- 9molのエチレンオキシドを用いてオキシエチレン化したC12~C14アルコール(Genapol(登録商標)LA-090、Clariant製)、
- 11molのエチレンオキシドを用いてオキシエチレン化したC12~C14アルコール(Genapol(登録商標)LA-110、Clariant製)、
- 8molのエチレンオキシドを用いてオキシエチレン化したC16~C18アルコール(Genapol(登録商標)T-080、Clariant製)、
- 15molのエチレンオキシドを用いてオキシエチレン化したC16~C18アルコール(Genapol(登録商標)T-150、Clariant製)、
- 11molのエチレンオキシドを用いてオキシエチレン化したC16~C18アルコール(Genapol(登録商標)T-110、Clariant製)、
- 20molのエチレンオキシドを用いてオキシエチレン化したC16~C18アルコール(Genapol(登録商標)T-200、Clariant製)、
- 25molのエチレンオキシドを用いてオキシエチレン化したC16~C18アルコール(Genapol(登録商標)T-250、Clariant製)、
- 25molのエチレンオキシドを用いてオキシエチレン化したC18~C22アルコール、および/または25molのエチレンオキシドを用いてオキシエチレン化したC16~C18イソアルコール。
本発明による組成物は、化粧料用途または医薬品用途とすることができる。本発明による組成物は、化粧料用途に使用するのが好ましい。「化粧料」という用語は、本発明の意味合いの範囲内では、快適な外観、香り、および手触りを有する組成物を意味していると理解されたい。その組成物が、皮膚、およびケラチン繊維、より特には、頭皮、毛髪、および睫毛に局所適用するものであれば好ましい。
次の組成物を調製する(重量%、AM=活性物質)。
- 2,4-ピリジンジカルボン酸のジエチルエステル(INCI名称:ジエチルルチジネート):5%
- アンモニウムポリアクリロイルジメチルタウレート(INCI名称)、Hostacerin AMPS、Clariant製:0.5%AM
- エタノール:56.5%
- 水 : 100%とするに十分な量
次の組成物を調製する(重量%、AM=活性物質)。
- 2,4-ピリジンジカルボン酸のジエチルエステル(INCI名称:ジエチルルチジネート):5%
- アンモニウムポリアクリロイルジメチルタウレート(INCI名称)、Hostacerin AMPS、Clariant製:0.75%AM
- PVM/MAコポリマーのエチルエステル:0.5%
- エタノール:56.5%
- 水:100%とするに十分な量
Claims (8)
- 化粧料組成物であって、
- (i)一般式(I):
- (ii)ランダムに分散された、
a)90重量%~99.9重量%の、次の一般式(II):
b)0.01重量%~10重量%の、少なくとも2個のオレフィン性二重結合を含む少なくとも1種のモノマーに由来する、架橋単位
(それらの重量比は、ポリマーの全重量を規準に定義されたものである)、
を含む、少なくとも1種の2-アクリルアミド-2-メチルプロパンスルホン酸のホモポリマーを含み、かつ、
化粧料組成物の全重量を基準にして、20重量%~80重量%の範囲の量で水を含む、化粧料組成物。 - R1とR2がエチル基を表す、請求項1に記載の化粧料組成物。
- (I)の化合物として、
- 2,4-ピリジンジカルボン酸ジメチル、
- 2,3-ピリジンジカルボン酸ジメチル、
- 2,4-ピリジンジカルボン酸ジエチル、
- 2,3-ピリジンジカルボン酸ジエチル、
- 2,5-ピリジンジカルボン酸ジエチル、
- 2,5-ピリジンジカルボン酸ジメチル、
- 2,4-ピリジンジカルボン酸ジイソプロピル、
の化合物の1つを含む、請求項1に記載の化粧料組成物。 - 化粧料組成物の全重量を基準にして、0.5重量%~20重量%の間の量で、式(I)の化合物を含む、請求項1~3のいずれか1項に記載の化粧料組成物。
- 前記化粧料組成物の全重量を基準にして、0.01重量%~10重量%の範囲の量で、前記1種または複数の2-アクリルアミド-2-メチルプロパンスルホン酸のホモポリマー(ii)を含む、請求項1~4のいずれか1項に記載の化粧料組成物。
- 1種または複数のC2~C4モノアルコールを、化粧料組成物の全重量を基準にして、10重量%~90重量%の範囲で含む、請求項1~5のいずれか1項に記載の化粧料組成物。
- - 1種または複数の追加の有機溶媒、および/または
- 1種または複数の追加の増粘剤、および/または
- 1種または複数の固定ポリマー、および/または
- 少なくとも1種のビタミンBおよび/またはその類似体もしくは誘導体、および/または
- ヒトケラチン繊維の再成長を促すか、および/またはその脱毛を抑制する活性薬剤、
を含む、請求項1~6のいずれか1項に記載の化粧料組成物。 - ケラチン物質を美容トリートメントするための方法であって、請求項1~7のいずか1項において定義された化粧料組成物を、前記ケラチン物質に適用し、そして前記ケラチン物質を濯ぐ又は濯がない、方法。
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FR1561958A FR3044548B1 (fr) | 2015-12-08 | 2015-12-08 | Composition comprenant un polymere a monomere sulfonique et un derive d'acide pyridine-dicarboxylique, et procede de traitement cosmetique |
FR1561958 | 2015-12-08 | ||
PCT/EP2016/080119 WO2017097849A1 (en) | 2015-12-08 | 2016-12-07 | Composition comprising a polymer containing a sulfonic monomer and a pyridinedicarboxylic acid derivative, and cosmetic treatment method |
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FR3044548B1 (fr) | 2019-10-25 |
WO2017097849A1 (en) | 2017-06-15 |
EP3386476A1 (en) | 2018-10-17 |
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