JP6856843B2 - ベンゾトリアゾール誘導体化合物の製造方法 - Google Patents
ベンゾトリアゾール誘導体化合物の製造方法 Download PDFInfo
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- JP6856843B2 JP6856843B2 JP2018024821A JP2018024821A JP6856843B2 JP 6856843 B2 JP6856843 B2 JP 6856843B2 JP 2018024821 A JP2018024821 A JP 2018024821A JP 2018024821 A JP2018024821 A JP 2018024821A JP 6856843 B2 JP6856843 B2 JP 6856843B2
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- benzotriazole
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- ultraviolet
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- -1 benzotriazole derivative compound Chemical class 0.000 title claims description 76
- 238000004519 manufacturing process Methods 0.000 title claims description 17
- 125000004432 carbon atom Chemical group C* 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 10
- DPZNOMCNRMUKPS-UHFFFAOYSA-N 1,3-Dimethoxybenzene Chemical compound COC1=CC=CC(OC)=C1 DPZNOMCNRMUKPS-UHFFFAOYSA-N 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- SWZIMDSLNKAMBV-UHFFFAOYSA-N N#[N+]C(C([N+]([O-])=O)=C1)=CC=C1C([O-])=O Chemical class N#[N+]C(C([N+]([O-])=O)=C1)=CC=C1C([O-])=O SWZIMDSLNKAMBV-UHFFFAOYSA-N 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 description 52
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 39
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 24
- 238000005259 measurement Methods 0.000 description 23
- 239000000203 mixture Substances 0.000 description 16
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
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- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 14
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- 238000010521 absorption reaction Methods 0.000 description 12
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- 238000000862 absorption spectrum Methods 0.000 description 10
- 238000004128 high performance liquid chromatography Methods 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 9
- 230000000903 blocking effect Effects 0.000 description 9
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- 230000015572 biosynthetic process Effects 0.000 description 8
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- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 230000008033 biological extinction Effects 0.000 description 6
- 238000005562 fading Methods 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
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- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 6
- SLENERZXAVGSTE-UHFFFAOYSA-N C(=O)(O)C1=CC=2C(=NN(N=2)C2=C(C=C(C=C2)OC)OC)C=C1 Chemical compound C(=O)(O)C1=CC=2C(=NN(N=2)C2=C(C=C(C=C2)OC)OC)C=C1 SLENERZXAVGSTE-UHFFFAOYSA-N 0.000 description 5
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 5
- 239000006096 absorbing agent Substances 0.000 description 5
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- 238000002834 transmittance Methods 0.000 description 5
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- 150000001565 benzotriazoles Chemical class 0.000 description 4
- 210000000695 crystalline len Anatomy 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
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- 239000011342 resin composition Substances 0.000 description 4
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- WQDJOBFDRQOUBK-UHFFFAOYSA-N C(=O)(O)C1=CC=2C(=NN(N=2)C2=C(C=C(C=C2)O)O)C=C1 Chemical compound C(=O)(O)C1=CC=2C(=NN(N=2)C2=C(C=C(C=C2)O)O)C=C1 WQDJOBFDRQOUBK-UHFFFAOYSA-N 0.000 description 3
- HIOPDLFCDMJPCH-UHFFFAOYSA-N C(=O)(O)C1=CC=2C(=NN(N=2)C2=C(C=C(C=C2)OC)O)C=C1 Chemical compound C(=O)(O)C1=CC=2C(=NN(N=2)C2=C(C=C(C=C2)OC)O)C=C1 HIOPDLFCDMJPCH-UHFFFAOYSA-N 0.000 description 3
- 239000012964 benzotriazole Substances 0.000 description 3
- 210000005252 bulbus oculi Anatomy 0.000 description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 238000004040 coloring Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000012788 optical film Substances 0.000 description 3
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- 229920006027 ternary co-polymer Polymers 0.000 description 3
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- 150000003918 triazines Chemical class 0.000 description 3
- 238000005160 1H NMR spectroscopy Methods 0.000 description 2
- ZZNAYFWAXZJITH-UHFFFAOYSA-N 4-amino-3-nitrobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1[N+]([O-])=O ZZNAYFWAXZJITH-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- WERKBRLBHRIWIY-UHFFFAOYSA-N C(=O)(O)C1=CC=2C(=NN(N=2)C2=C(C=C(C=C2)OCCCCCCCC)O)C=C1 Chemical compound C(=O)(O)C1=CC=2C(=NN(N=2)C2=C(C=C(C=C2)OCCCCCCCC)O)C=C1 WERKBRLBHRIWIY-UHFFFAOYSA-N 0.000 description 2
- FFKNFOCASBOTCT-UHFFFAOYSA-N C(=O)(O)C1=CC=2C(=[N+](N(N=2)C2=C(C=C(C=C2)OC)OC)[O-])C=C1 Chemical compound C(=O)(O)C1=CC=2C(=[N+](N(N=2)C2=C(C=C(C=C2)OC)OC)[O-])C=C1 FFKNFOCASBOTCT-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
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- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 125000005197 alkyl carbonyloxy alkyl group Chemical group 0.000 description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 239000012954 diazonium Substances 0.000 description 2
- 150000001989 diazonium salts Chemical class 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
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- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 2
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- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine hydrate Chemical compound O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 2
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- AOJFQRQNPXYVLM-UHFFFAOYSA-N pyridin-1-ium;chloride Chemical compound [Cl-].C1=CC=[NH+]C=C1 AOJFQRQNPXYVLM-UHFFFAOYSA-N 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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- AYTSDBGAHOKDHJ-UHFFFAOYSA-N 2-nitrobenzenediazonium Chemical class [O-][N+](=O)C1=CC=CC=C1[N+]#N AYTSDBGAHOKDHJ-UHFFFAOYSA-N 0.000 description 1
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- RYYXDZDBXNUPOG-UHFFFAOYSA-N 4,5,6,7-tetrahydro-1,3-benzothiazole-2,6-diamine;dihydrochloride Chemical compound Cl.Cl.C1C(N)CCC2=C1SC(N)=N2 RYYXDZDBXNUPOG-UHFFFAOYSA-N 0.000 description 1
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- HPZGZGUSRKNCOC-UHFFFAOYSA-N OC1=C(C=CC(=C1)OCCCCCCCC)N1N=C2C(=N1)C=CC(=C2)C(=O)OCCCCCCCC Chemical compound OC1=C(C=CC(=C1)OCCCCCCCC)N1N=C2C(=N1)C=CC(=C2)C(=O)OCCCCCCCC HPZGZGUSRKNCOC-UHFFFAOYSA-N 0.000 description 1
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- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
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- 239000002250 absorbent Substances 0.000 description 1
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- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
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- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 description 1
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- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229920003180 amino resin Polymers 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000008366 benzophenones Chemical class 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 125000004181 carboxyalkyl group Chemical group 0.000 description 1
- ZJPJECQPVMSILT-UHFFFAOYSA-N chloroethene 3-(2-phenylethenyl)furan-2,5-dione Chemical compound ClC=C.O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 ZJPJECQPVMSILT-UHFFFAOYSA-N 0.000 description 1
- IEJNAGSUKYCWCR-UHFFFAOYSA-N chloroethene;1,1-dichloroethene;ethenyl acetate Chemical compound ClC=C.ClC(Cl)=C.CC(=O)OC=C IEJNAGSUKYCWCR-UHFFFAOYSA-N 0.000 description 1
- VSJDEWYENWWMAV-UHFFFAOYSA-N chloroethene;2-methylprop-2-enoic acid Chemical compound ClC=C.CC(=C)C(O)=O VSJDEWYENWWMAV-UHFFFAOYSA-N 0.000 description 1
- KRGNPJFAKZHQPS-UHFFFAOYSA-N chloroethene;ethene Chemical group C=C.ClC=C KRGNPJFAKZHQPS-UHFFFAOYSA-N 0.000 description 1
- SQNNHEYXAJPPKH-UHFFFAOYSA-N chloroethene;prop-2-enoic acid Chemical compound ClC=C.OC(=O)C=C SQNNHEYXAJPPKH-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
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- NLCKLZIHJQEMCU-UHFFFAOYSA-N cyano prop-2-enoate Chemical class C=CC(=O)OC#N NLCKLZIHJQEMCU-UHFFFAOYSA-N 0.000 description 1
- 150000005575 dimethoxybenzenes Chemical class 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- LNCPIMCVTKXXOY-UHFFFAOYSA-N hexyl 2-methylprop-2-enoate Chemical compound CCCCCCOC(=O)C(C)=C LNCPIMCVTKXXOY-UHFFFAOYSA-N 0.000 description 1
- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 206010023332 keratitis Diseases 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 description 1
- NZIDBRBFGPQCRY-UHFFFAOYSA-N octyl 2-methylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C(C)=C NZIDBRBFGPQCRY-UHFFFAOYSA-N 0.000 description 1
- 229940065472 octyl acrylate Drugs 0.000 description 1
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001643 poly(ether ketone) Polymers 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920005671 poly(vinyl chloride-propylene) Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920001601 polyetherimide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229940068918 polyethylene glycol 400 Drugs 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
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- 239000011116 polymethylpentene Substances 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002578 polythiourethane polymer Polymers 0.000 description 1
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- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
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- 238000002360 preparation method Methods 0.000 description 1
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- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 150000003873 salicylate salts Chemical class 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- OZTYRAWXWCSOAF-DIYDOPDJSA-N tetramethylsilane;trichloro(deuterio)methane Chemical compound [2H]C(Cl)(Cl)Cl.C[Si](C)(C)C OZTYRAWXWCSOAF-DIYDOPDJSA-N 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 239000001043 yellow dye Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Images
Landscapes
- Cosmetics (AREA)
Description
[一般式(2)中、R1およびR2は、それぞれ独立して、水素原子、または炭素数1〜8のアルキル基である]
<測定条件>
装置:LC−20AT((株)島津製作所製)
使用カラム:SUMIPAX ODS A−212 6.0×150mm 5μm
カラム温度:25℃
移動相: メタノール/水=95/5(リン酸3ml/L)
流速:1.0ml/min
検出:UV250nm
<測定結果>
HPLC面百純度97.2%
なお、以下の実施例4〜6も本実施例と同様の測定条件でHPLC測定を行った。
<測定条件>
装置:UV−2450((株)島津製作所製)
測定波長:250〜 500nm
溶媒:クロロホルム
濃度:10ppm
なお、以下の実施例7〜8も本実施例と同様の測定条件で紫外〜可視吸収スペクトルの測定を行った。
<測定条件>
装置:JEOL JNM−AL300
共振周波数:300MHz(1H−NMR)
溶媒:クロロホルム−d
1H−NMRの内部標準物質として、テトラメチルシランを用い、ケミカルシフト値はδ値(ppm)、カップリング定数はHertzで示した。またsはsinglet、dはdoublet、tはtriplet、mはmultipletの略とする。以下の実施例4〜8においても同様である。なお、以下の実施例4〜8も本実施例と同様の測定条件でNMR測定を行った。得られたNMRスペクトルの内容は以下のとおりである。
δ=11.27(s,1H,phenol−OH),8.71(m,1H,benzotriazole−H),8.32(d,1H,J=9.0Hz,benzotriazole−H),8.04(m,2H,benzotriazole−H,phenol−H),6.71(d,1H,J=3.0Hz,phenol−H),6.64(m,1H,phenol−H),6.18(m,1H,C=CH2−H),5.62(m,1H,C=CH2−H),4.60(m,4H,methacryloyl−O−CH2−CH2−H),3.94(s,3H,phenol−O−CH3−H),1.97(m,3H,CH2=C−CH3−H)
<測定条件>
装置:UV−1850((株)島津製作所製)
測定波長:250〜 500nm
溶媒:クロロホルム
濃度:10ppm
なお、以下の実施例5〜6も本実施例と同様の測定条件で紫外〜可視吸収スペクトルの測定を行った。
δ=11.23(s,1H,phenol−OH),8.69(m,1H,benzotriazole−H),8.28(d,1H,J=9.3Hz,benzotriazole−H),8.09(m,1H,benzotriazole−H),7.92(m,1H,phenol−H),6.69(m,1H,phenol−H),6.61(m,1H,phenol−H),6.45(m,1H,CH=CH2−H),6.20(m,1H,CH2=CH−H),5.87(m,1H,CH=CH2−H),4.58(m,4H,acryloyl−O−CH2−H,acryloyl−O−CH2−CH2−H),3.87(s,3H,phenol−O−CH3−H)
δ=11.23(s,1H,phenol−OH),8.65(m,1H,benzotriazole−H),8.26(d,J=9.0Hz,1H,benzotriazole−H),8.07(m,1H,benzotriazole−H),7.89(m,1H,phenol−H),6.67(m,1H,phenol−H),6.59(m,1H,phenol−H),3.86,3.99(each s,each 3H,phenol−O−CH3−H and C=O−O−CH3−H)
δ=11.26(s,1H,phenol−OH),8.67(m,1H,benzotriazole−H),8.28(d,1H,J=9.3Hz,benzotriazole−H),8.09(m,1H,benzotriazole−H),7.92(m,1H,phenol−H),6.69(m,1H,phenol−H),6.61(m,1H,phenol−H),4.31(m,2H,benzotriazole−CO−O−CH2−H),3.87(s,3H,phenol−O−CH3−H),1.78(m,1H,2−ethylhexyl−CH),1.51(m,8H,2−ethylhexyl−CH2),0.96( m,6H,2−ethylhexyl−CH3)
<測定条件>
装置:L−2130((株)日立ハイテクノロジーズ製)
使用カラム:SUMIPAX ODS A−212 6.0×150mm 5μm
カラム温度:40℃
移動相: メタノール/水=99/1
流速:1.0ml/min
検出:UV250nm
<測定結果>
HPLC面百純度99.0%
なお、以下の実施例8も本実施例と同様の測定条件でHPLC測定を行った。
δ=11.26(s,1H,phenol−OH),8.68(s,1H,benzotriazole−H),8.29(d,1H,J=9.0Hz,benzotriazole−H),8.11(d,1H,J=8.9Hz,benzotriazole−H),7.93(d,1H,J=9.0Hz,phenol−H),6.69(m,2H,phenol−H),4.38(t,2H,benzotriazole−CO−O−CH2−H),4.01(t,2H,phenol−O−CH2−H),1.46(m,24H,octyl−CH2),0.91(s,6H,octyl−CH3)
δ=11.24(s,1H,phenol−OH),8.70(s,1H,benzotriazole−H),8.31(d,1H,J=12.9Hz,benzotriazole−H),8.11(d,1H,J=10.5Hz,benzotriazole−H),7.95(d,1H,J=9.0Hz,phenol−H),6.69(m,2H,phenol−H),6.18(s,1H,C=CH2−H),5.62(s,1H,C=CH2−H),4.64(m,2H,methacryloyl−O−CH2−H),4.56(m,2H,benzotriazole−CO−O−CH2−H),4.01(t,2H,phenol−O−CH2−H),1.97(s,3H,CH2=C−CH3−H),1.45(m,12H,octyl−CH2),0.90(s,3H,octyl−CH3)
従来の一般的な紫外線吸収剤である化合物(g);3−(2H−ベンゾトリアゾール −2−イル)−4−ヒドロキシフェネチルメタクリレート、および長波長域を強く吸収することが出来るセサモールを有するベンゾトリアゾール誘導体化合物である化合物(h);2−[2−(6−ヒドロキシベンゾ[1,3]ジオキソール−5−イル)−2H−ベンゾトリアゾール−5−イル]エチルメタクリレートを比較例として合成した。
実施例7で得られた化合物(e)を0.1g、ポリメタクリル酸メチル1.9g、メチルエチルケトン4.0g、トルエン4.0gを混合して溶解し、紫外線吸収剤を有した樹脂組成物の溶液を得た。得られた紫外線吸収剤を有した樹脂組成物の溶液を、バーコーターNo.20を用いてガラス板(厚み2mm)に塗布し、加熱乾燥90℃を2分、120℃を3分の順で行った後、減圧乾燥40℃を12時間実施して溶媒を除去し、膜厚4μmの紫外線吸収剤を5%有するポリメタクリル酸メチルフィルムを得た。一方、比較例で合成した化合物(g)、(h)をそれぞれメタクリル酸メチルと共重合して、5%の紫外線吸収剤を含む共重合体とし、次いで化合物(e)と同様の方法でフィルム化して、膜厚4μmの紫外線吸収剤を5%有するポリメタクリル酸メチルフィルムを得た。
市販の昇華転写方式コンパクトフォトプリンター(Canon SELPHY CP600)に使用されているイエロー染料、シアン染料、マゼンダ染料の転写フィルムに、上記で得られた化合物(e)、(g)、(h)の紫外線吸収剤を5%有するポリメタクリル酸メチルフィルムを乗せて転写フィルムを保護し、ウェザーメーターで100時間疑似太陽光を照射して退色を確認した。レベル5は退色なし、レベル4はわずかに退色、レベル3はある程度退色、レベル2はほとんど退色、レベル1は完全に退色として、5段階で評価した結果を表1に示す。
上記で得られた化合物(e)、(h)のクロロホルム中での可視光透過率を表2に示す。
装置:スーパーキセノンウェザーメーター SX−75(スガ試験機(株))
照射照度:180W/m2
照射時間:100時間
ブラックパネル温度:63℃
槽内湿度:50%
装置:UV−1850((株)島津製作所製)
測定波長:400〜 500nm
溶媒:クロロホルム
濃度:10000ppm
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