JP6630270B2 - アルカリ金属重炭酸塩粒子の製造方法 - Google Patents
アルカリ金属重炭酸塩粒子の製造方法 Download PDFInfo
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- JP6630270B2 JP6630270B2 JP2016522504A JP2016522504A JP6630270B2 JP 6630270 B2 JP6630270 B2 JP 6630270B2 JP 2016522504 A JP2016522504 A JP 2016522504A JP 2016522504 A JP2016522504 A JP 2016522504A JP 6630270 B2 JP6630270 B2 JP 6630270B2
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- Prior art keywords
- additive
- solution
- alkali metal
- crystallization
- bicarbonate particles
- Prior art date
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- 239000002245 particle Substances 0.000 title claims description 134
- -1 alkali metal bicarbonate Chemical class 0.000 title claims description 80
- 229910052783 alkali metal Inorganic materials 0.000 title claims description 63
- 238000004519 manufacturing process Methods 0.000 title description 20
- 239000000654 additive Substances 0.000 claims description 123
- 238000000034 method Methods 0.000 claims description 86
- 239000000243 solution Substances 0.000 claims description 68
- 230000000996 additive effect Effects 0.000 claims description 61
- 238000002425 crystallisation Methods 0.000 claims description 50
- 230000008025 crystallization Effects 0.000 claims description 47
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 36
- 238000009826 distribution Methods 0.000 claims description 31
- 238000001816 cooling Methods 0.000 claims description 19
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 18
- 238000004090 dissolution Methods 0.000 claims description 16
- 235000010443 alginic acid Nutrition 0.000 claims description 11
- 229920000615 alginic acid Polymers 0.000 claims description 11
- 229910000288 alkali metal carbonate Inorganic materials 0.000 claims description 11
- 150000008041 alkali metal carbonates Chemical class 0.000 claims description 11
- 239000000783 alginic acid Substances 0.000 claims description 10
- 229960001126 alginic acid Drugs 0.000 claims description 10
- 150000004781 alginic acids Chemical class 0.000 claims description 10
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 9
- 239000001569 carbon dioxide Substances 0.000 claims description 9
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 9
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 9
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 9
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 8
- 238000001704 evaporation Methods 0.000 claims description 8
- 230000008020 evaporation Effects 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 6
- 239000003513 alkali Substances 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 238000000926 separation method Methods 0.000 claims description 5
- 244000007835 Cyamopsis tetragonoloba Species 0.000 claims description 4
- 239000011549 crystallization solution Substances 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 61
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 30
- 235000017557 sodium bicarbonate Nutrition 0.000 description 30
- 239000000843 powder Substances 0.000 description 20
- 239000007789 gas Substances 0.000 description 16
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 14
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 12
- 229910019142 PO4 Inorganic materials 0.000 description 12
- 239000013543 active substance Substances 0.000 description 11
- 229910052708 sodium Inorganic materials 0.000 description 11
- 239000011734 sodium Substances 0.000 description 11
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 10
- 235000021317 phosphate Nutrition 0.000 description 10
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 10
- 239000007788 liquid Substances 0.000 description 9
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 8
- 150000001412 amines Chemical class 0.000 description 8
- 238000005259 measurement Methods 0.000 description 8
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 8
- 239000000725 suspension Substances 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 7
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 7
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 7
- 229920000058 polyacrylate Polymers 0.000 description 7
- 229910052700 potassium Inorganic materials 0.000 description 7
- 239000011591 potassium Substances 0.000 description 7
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 6
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 6
- 150000001340 alkali metals Chemical class 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- 239000013078 crystal Substances 0.000 description 6
- 229920001282 polysaccharide Polymers 0.000 description 6
- 239000005017 polysaccharide Substances 0.000 description 6
- 150000004804 polysaccharides Chemical class 0.000 description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 description 6
- ADTJISSNQWNGFP-UHFFFAOYSA-N 4-dodecan-3-ylbenzenesulfonic acid;propan-2-amine Chemical compound CC(C)N.CCCCCCCCCC(CC)C1=CC=C(S(O)(=O)=O)C=C1 ADTJISSNQWNGFP-UHFFFAOYSA-N 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 229920005646 polycarboxylate Polymers 0.000 description 5
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 5
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 5
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 4
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 4
- 239000011976 maleic acid Substances 0.000 description 4
- 238000010899 nucleation Methods 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 229960003237 betaine Drugs 0.000 description 3
- 125000002843 carboxylic acid group Chemical group 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 150000004028 organic sulfates Chemical class 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- 150000003141 primary amines Chemical class 0.000 description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 description 3
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- HNLXNOZHXNSSPN-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[4-(2,4,4-trimethylpentan-2-yl)phenoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(OCCOCCOCCOCCOCCOCCOCCO)C=C1 HNLXNOZHXNSSPN-UHFFFAOYSA-N 0.000 description 2
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 2
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 2
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 229940077388 benzenesulfonate Drugs 0.000 description 2
- 239000011362 coarse particle Substances 0.000 description 2
- WJRMGBWBIGOIOF-UHFFFAOYSA-N dodecyl benzenesulfonate;propan-2-amine Chemical compound CC(C)N.CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 WJRMGBWBIGOIOF-UHFFFAOYSA-N 0.000 description 2
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 2
- 229940043264 dodecyl sulfate Drugs 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229940005740 hexametaphosphate Drugs 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000011859 microparticle Substances 0.000 description 2
- 239000012452 mother liquor Substances 0.000 description 2
- 238000000879 optical micrograph Methods 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical class CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- PGNVUJSDMSFWEC-UHFFFAOYSA-N 1,2,3-tris(2-phenylethenyl)-4-[2,3,4-tris(2-phenylethenyl)phenoxy]benzene Chemical compound C=1C=C(C=CC=2C=CC=CC=2)C(C=CC=2C=CC=CC=2)=C(C=CC=2C=CC=CC=2)C=1OC(C(=C1C=CC=2C=CC=CC=2)C=CC=2C=CC=CC=2)=CC=C1C=CC1=CC=CC=C1 PGNVUJSDMSFWEC-UHFFFAOYSA-N 0.000 description 1
- PZNPLUBHRSSFHT-RRHRGVEJSA-N 1-hexadecanoyl-2-octadecanoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCCCC(=O)O[C@@H](COP([O-])(=O)OCC[N+](C)(C)C)COC(=O)CCCCCCCCCCCCCCC PZNPLUBHRSSFHT-RRHRGVEJSA-N 0.000 description 1
- IXOCGRPBILEGOX-UHFFFAOYSA-N 3-[3-(dodecanoylamino)propyl-dimethylazaniumyl]-2-hydroxypropane-1-sulfonate Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC(O)CS([O-])(=O)=O IXOCGRPBILEGOX-UHFFFAOYSA-N 0.000 description 1
- GKFPPCXIBHQRQT-UHFFFAOYSA-N 6-(2-carboxy-4,5-dihydroxy-6-methoxyoxan-3-yl)oxy-4,5-dihydroxy-3-methoxyoxane-2-carboxylic acid Chemical compound OC1C(O)C(OC)OC(C(O)=O)C1OC1C(O)C(O)C(OC)C(C(O)=O)O1 GKFPPCXIBHQRQT-UHFFFAOYSA-N 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000282372 Panthera onca Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 125000002648 azanetriyl group Chemical group *N(*)* 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- ZMCUDHNSHCRDBT-UHFFFAOYSA-M caesium bicarbonate Chemical compound [Cs+].OC([O-])=O ZMCUDHNSHCRDBT-UHFFFAOYSA-M 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229940112107 cellugel Drugs 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 description 1
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 229940009626 etidronate Drugs 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 238000000386 microscopy Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 229940067003 orabase Drugs 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- KKDONKAYVYTWGY-UHFFFAOYSA-M sodium;2-(methylamino)ethanesulfonate Chemical compound [Na+].CNCCS([O-])(=O)=O KKDONKAYVYTWGY-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 239000008347 soybean phospholipid Substances 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D7/00—Carbonates of sodium, potassium or alkali metals in general
- C01D7/38—Preparation in the form of granules, pieces or other shaped products
- C01D7/40—Influencing the crystallisation process
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D7/00—Carbonates of sodium, potassium or alkali metals in general
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D7/00—Carbonates of sodium, potassium or alkali metals in general
- C01D7/10—Preparation of bicarbonates from carbonates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D7/00—Carbonates of sodium, potassium or alkali metals in general
- C01D7/22—Purification
- C01D7/24—Crystallisation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/02—Particle morphology depicted by an image obtained by optical microscopy
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/51—Particles with a specific particle size distribution
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/10—Solid density
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/11—Powder tap density
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- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Medicinal Preparation (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
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Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1356160A FR3007753A1 (fr) | 2013-06-26 | 2013-06-26 | Procede de preparation de particules de bicarbonate de metal alcalin |
| FR1356160 | 2013-06-26 | ||
| PCT/EP2014/063555 WO2014207120A2 (fr) | 2013-06-26 | 2014-06-26 | Procédé de préparation de particules de bicarbonate de métal alcalin |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2019126800A Division JP2019206474A (ja) | 2013-06-26 | 2019-07-08 | アルカリ金属重炭酸塩粒子の製造方法 |
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| Publication Number | Publication Date |
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| JP2016523803A JP2016523803A (ja) | 2016-08-12 |
| JP2016523803A5 JP2016523803A5 (enExample) | 2017-07-06 |
| JP6630270B2 true JP6630270B2 (ja) | 2020-01-15 |
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| JP2016522504A Active JP6630270B2 (ja) | 2013-06-26 | 2014-06-26 | アルカリ金属重炭酸塩粒子の製造方法 |
| JP2019126800A Pending JP2019206474A (ja) | 2013-06-26 | 2019-07-08 | アルカリ金属重炭酸塩粒子の製造方法 |
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| EP (3) | EP3013750A2 (enExample) |
| JP (2) | JP6630270B2 (enExample) |
| CN (4) | CN105492390B (enExample) |
| AU (1) | AU2014301127B2 (enExample) |
| BR (1) | BR112015032278A2 (enExample) |
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| MX (1) | MX2015017859A (enExample) |
| PL (2) | PL3013751T3 (enExample) |
| RU (1) | RU2016102166A (enExample) |
| WO (3) | WO2014207120A2 (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013092754A1 (en) | 2011-12-23 | 2013-06-27 | Solvay Sa | Process for the joint production of sodium carbonate and sodium bicarbonate |
| FR3007753A1 (fr) | 2013-06-26 | 2015-01-02 | Solvay | Procede de preparation de particules de bicarbonate de metal alcalin |
| US10766782B2 (en) | 2015-09-23 | 2020-09-08 | Solvay Sa | Production of crystalline sodium bicarbonate |
| US10392257B2 (en) | 2015-09-23 | 2019-08-27 | Solvay Sa | Method for enhancing sodium bicarbonate flowability |
| KR20190111060A (ko) | 2017-01-24 | 2019-10-01 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 다당류를 이용한 침전된 탄산칼슘의 제조 방법 |
| KR102022939B1 (ko) * | 2018-01-30 | 2019-09-19 | 가톨릭대학교 산학협력단 | 수산화나트륨이 용해된 알코올-물 혼합 수용액의 탄산화를 통한 중탄산나트륨 제조방법 |
| JP7448926B1 (ja) | 2023-05-31 | 2024-03-13 | 株式会社徳岡テクノ | 二酸化炭素吸着方法、二酸化炭素処理装置、及び、二酸化炭素吸着システム |
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| NL70417C (enExample) | 1950-04-24 | |||
| US2954282A (en) * | 1954-12-13 | 1960-09-27 | Fmc Corp | Method of crystallizing |
| US2954262A (en) | 1957-06-26 | 1960-09-27 | Bendix Corp | Anti-skid device |
| US3072466A (en) * | 1960-08-12 | 1963-01-08 | Fmc Corp | Method of crystallizing sodium bicarbonate |
| US3111379A (en) * | 1961-04-12 | 1963-11-19 | Fmc Corp | Manufacture of potassium bicarbonate |
| US3347623A (en) * | 1966-11-03 | 1967-10-17 | Kali Chemie Ag | Preparation of potassium bicarbonate |
| JPS4817160B1 (enExample) * | 1970-01-14 | 1973-05-26 | ||
| US3653847A (en) * | 1970-09-14 | 1972-04-04 | American Potash & Chem Corp | Inhibition of sodium bicarbonate crystallization during crystallization of other materials using polyphosphates |
| US3725014A (en) * | 1971-04-21 | 1973-04-03 | Allied Chem | Sodium carbonate crystallization process with foam prevention |
| US3855397A (en) | 1973-04-12 | 1974-12-17 | Allied Chem | Method of producing sodium carbonate and bicarbonate spherules from brine |
| US3852427A (en) | 1973-04-12 | 1974-12-03 | Allied Chem | Sodium bicarbonate spherulites from sodium d esquicarbonate |
| US3981686A (en) * | 1974-10-24 | 1976-09-21 | Intermountain Research And Development Corporation | Clarifier process for producing sodium carbonate |
| DE2940614C2 (de) * | 1979-10-06 | 1982-09-16 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur Herstellung von Natriumhydrogencarbonat und Chlorwasserstoff |
| US4478599A (en) * | 1982-05-25 | 1984-10-23 | Kerr-Mcgee Chemical Corporation | Method of continuously controlling crystal fines formation |
| FR2646154B1 (fr) * | 1989-04-24 | 1991-06-28 | Solvay | Bicarbonate de sodium et procede pour la cristallisation de bicarbonate de sodium |
| JPH0397617A (ja) | 1989-06-29 | 1991-04-23 | Tosoh Corp | 重炭酸ナトリウムの製造方法 |
| US6042622A (en) * | 1996-07-31 | 2000-03-28 | Basf Corporation | Process for crystallization of alkali metal bicarbonate salts |
| US6270740B2 (en) | 1997-03-20 | 2001-08-07 | General Chemical Corporation | Method of producing modified sodium carbonate crystals for the production of sodium bicarbonate |
| CA2284967A1 (en) * | 1998-10-13 | 2000-04-13 | Aristos Capital Corporation | Method of formulating alkali earth salts |
| JP4817160B2 (ja) | 2001-03-07 | 2011-11-16 | 日立バルブ株式会社 | 空気調和システム及び電動操作機 |
| US6667021B2 (en) * | 2001-09-12 | 2003-12-23 | General Chemical Corporation | Method for producing enhanced sodium carbonate crystals for making sodium bicarbonate |
| CN100348489C (zh) * | 2003-04-24 | 2007-11-14 | 狮王株式会社 | 表面处理水溶性无机化合物颗粒及其制造方法、以及粒状洗涤剂组合物 |
| KR101102273B1 (ko) * | 2003-04-24 | 2012-01-03 | 라이온 가부시키가이샤 | 표면처리 수용성 무기 화합물 입자 및 그 제조방법, 및입상 세제 조성물 |
| CN1780671A (zh) | 2003-04-29 | 2006-05-31 | 阿克佐诺贝尔股份有限公司 | 涉及使用反溶剂结晶的方法 |
| US20060150892A1 (en) | 2003-04-29 | 2006-07-13 | Akzo Nobel N.V. | Processes Involving the Use of Antisolvent Crystallisation |
| EP1997780A1 (en) | 2006-03-15 | 2008-12-03 | Asahi Glass Company, Limited | High-purity sodium hydrogen carbonate crystal grain and process for producing the same |
| EP2399866A1 (en) * | 2010-06-22 | 2011-12-28 | Solvay SA | Process for the joint production of sodium carbonate and sodium bicarbonate |
| EP2607312A1 (en) * | 2011-12-21 | 2013-06-26 | Solvay Sa | Process for preparing sodium bicarbonate particles |
| WO2013092754A1 (en) | 2011-12-23 | 2013-06-27 | Solvay Sa | Process for the joint production of sodium carbonate and sodium bicarbonate |
| GB201202797D0 (en) | 2012-02-20 | 2012-04-04 | Eminate Ltd | Sodium bicarbonate product |
| CN102940307B (zh) * | 2012-11-19 | 2016-06-08 | 湖南中烟工业有限责任公司 | 一种用于口含型烟草制品的缓释碱性微胶囊及其制备方法和应用 |
| FR3007753A1 (fr) | 2013-06-26 | 2015-01-02 | Solvay | Procede de preparation de particules de bicarbonate de metal alcalin |
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2013
- 2013-06-26 FR FR1356160A patent/FR3007753A1/fr active Pending
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2014
- 2014-06-26 PL PL14758095T patent/PL3013751T3/pl unknown
- 2014-06-26 WO PCT/EP2014/063555 patent/WO2014207120A2/fr not_active Ceased
- 2014-06-26 WO PCT/EP2014/063558 patent/WO2014207123A2/fr not_active Ceased
- 2014-06-26 CN CN201480047400.6A patent/CN105492390B/zh active Active
- 2014-06-26 PL PL14735513T patent/PL3013749T3/pl unknown
- 2014-06-26 RU RU2016102166A patent/RU2016102166A/ru not_active Application Discontinuation
- 2014-06-26 EP EP14735515.0A patent/EP3013750A2/fr not_active Withdrawn
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- 2014-06-26 CA CA2916157A patent/CA2916157A1/en not_active Abandoned
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- 2014-06-26 CN CN201480047401.0A patent/CN105492391B/zh active Active
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- 2014-06-26 CN CN201810548049.9A patent/CN109553117A/zh active Pending
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2019
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