JP6578285B2 - 紙複合体、包装材料及び紙複合体の製造方法 - Google Patents
紙複合体、包装材料及び紙複合体の製造方法 Download PDFInfo
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- JP6578285B2 JP6578285B2 JP2016544239A JP2016544239A JP6578285B2 JP 6578285 B2 JP6578285 B2 JP 6578285B2 JP 2016544239 A JP2016544239 A JP 2016544239A JP 2016544239 A JP2016544239 A JP 2016544239A JP 6578285 B2 JP6578285 B2 JP 6578285B2
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- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- HETCEOQFVDFGSY-UHFFFAOYSA-N Isopropenyl acetate Chemical compound CC(=C)OC(C)=O HETCEOQFVDFGSY-UHFFFAOYSA-N 0.000 description 1
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- IGIIRFSBADPLKV-UHFFFAOYSA-N N-butan-2-ylidenehydroxylamine prop-2-enoic acid Chemical compound OC(=O)C=C.CCC(C)=NO IGIIRFSBADPLKV-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229940123973 Oxygen scavenger Drugs 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- ZCHPKWUIAASXPV-UHFFFAOYSA-N acetic acid;methanol Chemical compound OC.CC(O)=O ZCHPKWUIAASXPV-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 125000005336 allyloxy group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- KQBTUOVABZLXGP-UHFFFAOYSA-N butane-1,4-diol;ethane-1,2-diol Chemical compound OCCO.OCCCCO KQBTUOVABZLXGP-UHFFFAOYSA-N 0.000 description 1
- DDPAAMHROJBRGE-UHFFFAOYSA-N butane-1,4-diol;propane-1,2-diol Chemical compound CC(O)CO.OCCCCO DDPAAMHROJBRGE-UHFFFAOYSA-N 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 238000011088 calibration curve Methods 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 235000019219 chocolate Nutrition 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000010227 cup method (microbiological evaluation) Methods 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- 235000012489 doughnuts Nutrition 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 150000002148 esters Chemical group 0.000 description 1
- HQPMKSGTIOYHJT-UHFFFAOYSA-N ethane-1,2-diol;propane-1,2-diol Chemical compound OCCO.CC(O)CO HQPMKSGTIOYHJT-UHFFFAOYSA-N 0.000 description 1
- QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical group C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 description 1
- YCUBDDIKWLELPD-UHFFFAOYSA-N ethenyl 2,2-dimethylpropanoate Chemical compound CC(C)(C)C(=O)OC=C YCUBDDIKWLELPD-UHFFFAOYSA-N 0.000 description 1
- WNMORWGTPVWAIB-UHFFFAOYSA-N ethenyl 2-methylpropanoate Chemical compound CC(C)C(=O)OC=C WNMORWGTPVWAIB-UHFFFAOYSA-N 0.000 description 1
- GADGVXXJJXQRSA-UHFFFAOYSA-N ethenyl 8-methylnonanoate Chemical compound CC(C)CCCCCCC(=O)OC=C GADGVXXJJXQRSA-UHFFFAOYSA-N 0.000 description 1
- CMDXMIHZUJPRHG-UHFFFAOYSA-N ethenyl decanoate Chemical compound CCCCCCCCCC(=O)OC=C CMDXMIHZUJPRHG-UHFFFAOYSA-N 0.000 description 1
- GLVVKKSPKXTQRB-UHFFFAOYSA-N ethenyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC=C GLVVKKSPKXTQRB-UHFFFAOYSA-N 0.000 description 1
- GFJVXXWOPWLRNU-UHFFFAOYSA-N ethenyl formate Chemical compound C=COC=O GFJVXXWOPWLRNU-UHFFFAOYSA-N 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Substances O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- AQYSYJUIMQTRMV-UHFFFAOYSA-N hypofluorous acid Chemical compound FO AQYSYJUIMQTRMV-UHFFFAOYSA-N 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 125000005394 methallyl group Chemical group 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- IQCDTWQIGNEYMY-UHFFFAOYSA-N n',n'-dimethylprop-2-enehydrazide Chemical compound CN(C)NC(=O)C=C IQCDTWQIGNEYMY-UHFFFAOYSA-N 0.000 description 1
- GBCKRQRXNXQQPW-UHFFFAOYSA-N n,n-dimethylprop-2-en-1-amine Chemical compound CN(C)CC=C GBCKRQRXNXQQPW-UHFFFAOYSA-N 0.000 description 1
- QWWGTCDRRYWYBC-UHFFFAOYSA-N n-(ethenoxymethyl)-n-ethylethanamine Chemical compound CCN(CC)COC=C QWWGTCDRRYWYBC-UHFFFAOYSA-N 0.000 description 1
- PUUULGNNRPBVBA-UHFFFAOYSA-N n-ethylprop-2-en-1-amine Chemical compound CCNCC=C PUUULGNNRPBVBA-UHFFFAOYSA-N 0.000 description 1
- SEEYREPSKCQBBF-UHFFFAOYSA-N n-methylmaleimide Chemical compound CN1C(=O)C=CC1=O SEEYREPSKCQBBF-UHFFFAOYSA-N 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- WXPWPYISTQCNDP-UHFFFAOYSA-N oct-7-en-1-ol Chemical compound OCCCCCCC=C WXPWPYISTQCNDP-UHFFFAOYSA-N 0.000 description 1
- KZCOBXFFBQJQHH-UHFFFAOYSA-N octane-1-thiol Chemical compound CCCCCCCCS KZCOBXFFBQJQHH-UHFFFAOYSA-N 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000001254 oxidized starch Substances 0.000 description 1
- 235000013808 oxidized starch Nutrition 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000013054 paper strength agent Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- LQAVWYMTUMSFBE-UHFFFAOYSA-N pent-4-en-1-ol Chemical compound OCCCC=C LQAVWYMTUMSFBE-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 235000013550 pizza Nutrition 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000001226 reprecipitation Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- LFRDHGNFBLIJIY-UHFFFAOYSA-N trimethoxy(prop-2-enyl)silane Chemical compound CO[Si](OC)(OC)CC=C LFRDHGNFBLIJIY-UHFFFAOYSA-N 0.000 description 1
- TZYULTYGSBAILI-UHFFFAOYSA-M trimethyl(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CC=C TZYULTYGSBAILI-UHFFFAOYSA-M 0.000 description 1
- NRWCNEBHECBWRJ-UHFFFAOYSA-M trimethyl(propyl)azanium;chloride Chemical compound [Cl-].CCC[N+](C)(C)C NRWCNEBHECBWRJ-UHFFFAOYSA-M 0.000 description 1
- ZQYKGADTDCTWSZ-UHFFFAOYSA-N trimethyl-[(prop-2-enoylamino)methyl]azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CNC(=O)C=C ZQYKGADTDCTWSZ-UHFFFAOYSA-N 0.000 description 1
- CCVMLEHYQVSFOM-UHFFFAOYSA-N trimethyl-[2-(prop-2-enoylamino)ethyl]azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCNC(=O)C=C CCVMLEHYQVSFOM-UHFFFAOYSA-N 0.000 description 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical class [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000012224 working solution Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
- B65D65/38—Packaging materials of special type or form
- B65D65/40—Applications of laminates for particular packaging purposes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
- B65D65/38—Packaging materials of special type or form
- B65D65/42—Applications of coated or impregnated materials
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/11—Halides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/22—Polyalkenes, e.g. polystyrene
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/22—Addition to the formed paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/10—Packing paper
Description
単量体(a):炭素数1〜6のポリフルオロアルキル基を有する(メタ)アクリレート
単量体(b):下式(1)で表される化合物
CH2=C(R1)COO−Q−N(R2)(R3) ・・・(1)
(上記式(1)中、R1は、水素原子又はメチル基であり、Qは、炭素数2以上3以下のアルキレン基における水素原子の一部若しくは全部が水酸基で置換された基、又は炭素数2以上4以下のアルキレン基であり、R2及びR3は、それぞれ独立に、ベンジル基又は炭素数1以上8以下のアルキル基である。但し、R2とR3とが結合して窒素原子と共にモルホリノ基、ピペリジノ基又はピロリジニル基を形成してもよい。)
単量体(a):炭素数1〜6のポリフルオロアルキル基を有する(メタ)アクリレート
単量体(b):下式(1)で表される化合物
CH2=C(R1)COO−Q−N(R2)(R3) ・・・(1)
(上記式(1)中、R1は、水素原子又はメチル基であり、Qは、炭素数2以上3以下のアルキレン基における水素原子の一部若しくは全部が水酸基で置換された基、又は炭素数2以上4以下のアルキレン基であり、R2及びR3は、それぞれ独立に、ベンジル基又は炭素数1以上8以下のアルキル基である。但し、R2とR3とが結合して窒素原子と共にモルホリノ基、ピペリジノ基又はピロリジニル基を形成してもよい。)
<基紙>
本発明の紙複合体を得る為に使用する基紙は、JIS−P8117(2009)に準じて測定される透気抵抗度が1000秒以下かつJIS−P8118(1998)に準じて測定される緊度が0.5g/cm3以上1.0g/cm3以下の基紙である。透気抵抗度1000秒以下かつ緊度0.5g/cm3以上1.0g/cm3以下の基紙では、既存のフッ素耐油層を設けても目的の高耐油性、水蒸気透過性及び耐水性を達成することは困難であるが、少なくとも片面に上記PVA(A)及びカチオン性含フッ素共重合体(B)を含有する耐油層を0.1g/m2以上3.0g/m2以下設けることにより、目的の達成が可能となる。
耐油層は、基紙の少なくとも一方の表面側に形成される。耐油層は、PVA(A)とカチオン性含フッ素共重合体(B)とを含む。
本発明に用いられるPVA(A)は、エチレン単位を有していることが必須であり、エチレン単位の含有量としては、2モル%以上10モル%以下であることが必須である。エチレン単位の含有量の下限としては、2.5モル%が好ましく、3モル%がより好ましく、3.5モル%がさらに好ましい。エチレン単位の含有量の上限としては、9.5モル%が好ましく、9モル%がより好ましく、8.5モル%がさらに好ましい。エチレン単位の含有量が上記下限未満の場合には、得られる紙複合体の耐油性や耐水性が問題となる場合がある。エチレン単位の含有量が上記上限より大の場合には、PVAが水に不溶となる場合があり、基紙上への塗工が困難となる。
P=([η]×104/8.29)(1/0.62)
カチオン性含フッ素共重合体(B)は、単量体(a)に由来する構成単位及び単量体(b)に由来する構成単位を有する含フッ素共重合体である。必要に応じて単量体(a)に由来する構成単位と単量体(b)に由来する構成単位以外の他の構成単位を有していてもよい。
単量体(a)は、炭素数1以上6以下のポリフルオロアルキル基を有する(メタ)アクリレートである。「ポリフルオロアルキル基」は、アルキル基の水素原子の一部又は全部がフッ素原子に置換された基である。「(メタ)アクリレート」は、アクリレート及びメタクリレートの総称である。
Rf−L−OCO−C(R4)=CH2 ・・・(2)
C6F13C2H4OCOC(CH3)=CH2
C6F13C2H4OCOCH=CH2
C6F13C2H4OCOCCl=CH2
C4F9C2H4OCOC(CH3)=CH2
C4F9C2H4OCOCH=CH2
C4F9C2H4OCOCCl=CH2
単量体(b)は、下記式(1)で表される化合物(1)である。
CH2=C(R1)COO−Q−N(R2)(R3) ・・・(1)
次に本発明の紙複合体の製造方法について説明する。本発明で製造される紙複合体は、透気抵抗度1000秒以下かつ緊度0.5g/cm3以上1.0g/cm3以下の基紙と、この基紙の少なくとも一方の表面側に形成される耐油層とを備え、1000g/m2・24h以上の水蒸気透過性を有する。当該紙複合体の製造方法は、上述のPVA(A)と、上述のカチオン性含フッ素共重合体(B)とを含む耐油層形成用組成物を上述の基紙の少なくとも一方の表面側に塗工する工程と、塗工した基紙を乾燥する工程とを備える。
[耐油層形成用組成物]
耐油層形成用組成物においては、ビニルアルコール系重合体(A)100質量部に対するカチオン性含フッ素共重合体(B)の含有量が5質量部以上50質量部以下である。耐油層形成用組成物の好適な形態としては塗工液である。塗工液の調製方法は、特に制限されないが、PVA(A)を溶媒に溶解させたもの及びカチオン性含フッ素共重合体(B)を水性媒体に分散又は溶解させたものを混合する方法が好ましい。水性媒体は、水を含み、揮発性有機溶媒の含有量が1質量%以下である液体であればよく、具体的には水、及び水を含む共沸混合物が好ましい。
耐油層形成用組成物を塗工した後の基紙の乾燥は、例えば熱風、赤外線、加熱シリンダーやこれらを組み合わせた方法により行うことができ、60℃以上の温度で乾燥、熱処理等することが好ましい。この乾燥により、当該紙複合体が得られる。また、乾燥後の当該紙複合体は、調湿及びキャレンダー処理することにより、バリヤー性を更に向上させることが出来る。キャレンダー処理条件としては、ロール温度が常温(25℃)以上100℃以下、ロール線圧が20kg/cm以上300kg/cm以下が好ましい。乾燥、熱処理等を行うことで、より優れた耐油性と耐水性とを発現できる。
本発明の紙複合体は、包装材料に好適である。そこで本発明はまた、上述の紙複合体を備える包装材料を含む。本発明の包装材料は、公知の包装材料に使用される耐油紙の代わりに上述の紙複合体を用いることにより構成することができる。
(1)耐油性評価:キットテスト
一般的な耐油度はTAPPI UM557「Repellency of Paper and Board to Grease,Oil,and Waxes(Kit Test)」によって測定した。
JIS−P8117(2009)に準じ王研式滑度透気度試験器を用いて測定した。透気抵抗度の値は、一定面積を空気100mLが通過する時間を示す。よって、透気抵抗度の値が大きいほど空気が通過し難いことを示す。
JIS−Z0208(1976)に記載の防湿包装材料の透湿度試験方法(カップ法)に従い、温度40±0.5℃、相対湿度90±2%の条件下で測定した。透湿度1000〜5000g/m2・24hを袋内部での結露と袋外部からの吸湿の発生がなく、食品包装用適性良好と判定した。
<コッブ(Cobb)吸水度(g/m2)>
JIS−P8140(1998)に準じ、紙複合体表面の水との接触時間を60秒としたときの吸収量(g/m2)を測定した。以下、コッブ吸水度とは、接触時間60秒のときのコッブ吸水度をいう。
[ビニルアルコール系重合体の製造方法]
撹拌機、窒素導入口、エチレン導入口、開始剤添加口及びディレー溶液添加口を備えた250L加圧反応槽に酢酸ビニル(VAc)107.2kg及びメタノール(MeOH)42.8kgを仕込み、60℃に昇温した後30分間窒素バブリングにより系中を窒素置換した。次いで反応槽圧力が5.9kg/cm2となるようにエチレンを導入仕込みした。開始剤として2,2’−アゾビス(4−メトキシ−2,4−ジメチルバレロニトリル)(AMV)をメタノールに溶解した濃度2.8g/L溶液を調製し、窒素ガスによるバブリングを行って窒素置換した。上記の重合槽内温を60℃に調整した後、上記の開始剤溶液204mLを注入し重合を開始した。重合中はエチレンを導入して反応槽圧力を5.9kg/cm2に、重合温度を60℃に維持し、上記の開始剤溶液を用いて640mL/hrでAMV溶液を連続添加して重合を実施した。4時間後に重合率が30%となったところで冷却して重合を停止した。反応槽を開放して脱エチレンした後、窒素ガスをバブリングして脱エチレンを完全に行った。次いで減圧下に未反応酢酸ビニルモノマーを除去しポリ酢酸ビニルのメタノール溶液とした。得られたポリ酢酸ビニル溶液にメタノールを加えて濃度が30質量%となるように調製したポリ酢酸ビニルのメタノール溶液333g(溶液中のポリ酢酸ビニル100g)に、46.5g(ポリ酢酸ビニル中の酢酸ビニル単位に対してモル比[MR]0.05)のアルカリ溶液(NaOHの10%メタノール溶液)を添加してけん化を行った。アルカリ添加後約1分で系がゲル化したものを粉砕器にて粉砕し、40℃で1時間放置してけん化を進行させた後、酢酸メチル1000gを加えて残存するアルカリを中和した。フェノールフタレイン指示薬を用いて中和の終了を確認後、濾別して得られた白色固体のPVAにメタノール1000gを加えて室温で3時間放置洗浄した。上記洗浄操作を3回繰り返した後、遠心脱液して得られたPVAを乾燥機中70℃で2日間放置して乾燥PVA(PVA−1)を得た。
PVAの粘度平均重合度及びけん化度は、JIS−K6726(1994)に記載の方法により求めた。この結果を表2に示す。
1Lのガラス製容器に、C6F13C2H4OCOC(CH3)=CH2(a)を114.0g、N,N−ジエチルアミノエチルメタクリレート(b)を18.0g、2−ヒドロキシエチルメタアクリレート(C1)を16.5g、CH2=C(CH3)COO(C2H4O)3COC(CH3)=CH2を1.5g、アセトンを450g及びジメチル2,2’−アゾビスイソブチレートを1.2g仕込み、窒素置換を3回繰り返した。撹拌回転数350rpmにて65℃で16時間重合反応を行い、固形分濃度24質量%の淡黄色溶液を得た。
上記で得られたPVAの10質量%水溶液を調製し、この水溶液中のPVA100質量部に対して、上記水分散液中のカチオン性含フッ素共重合体(B)が50質量部となるように上記水溶液及び水分散液を混合し、固形分濃度4質量%となるように調製することで塗工液を得た。
上記で得られた塗工液を、試験用2−ロールサイズプレス機(熊谷理機工業社)を用いて、坪量70g/m2、緊度0.5g/cm3、透気抵抗度15秒の基紙の両面に塗工し紙複合体を得た。上記塗工は50℃にて100m/分の条件で行った後、100℃で5分間乾燥させた。塗工液の固形分換算の塗工量は2.5g/m2(両面の合計)であった。得られた紙複合体を20℃、65%RHで72時間調湿した。
得られた紙複合体について、上記の方法に従って耐油性評価、透気抵抗度、水蒸気透過性及び吸水性評価を測定した。耐油性評価においてはキット値7を得た。透気抵抗度は15秒、水蒸気透過性は4,800g/m2・24hであり、またコッブ吸水度は20g/m2であり、いずれも実用上問題の無いレベルと判定した。
表1に示すようにビニルアルコール系重合体の製造方法を変更して(PVA−2)〜(PVA−8)を得た。(PVA−2)〜(PVA−8)の分析結果を表2に示す。得られたPVAを用いて表3に示す組成の塗工液を基紙表面に実施例1と同様の方法で塗工し紙複合体を得た。これらの紙複合体について、上述の手順により評価を行った。その結果を表3に示す。
表4に示すようにビニルアルコール系重合体の製造方法を変更して(PVA−9)〜(PVA−16)を得た。(PVA−9)〜(PVA−16)の分析結果を表5に示す。得られたPVAを用いて表6に示す様な組成の塗工液を基紙表面に実施例1と同様の方法で塗布し、紙複合体を得た後、この紙複合体の評価を行った。その結果を表6に示す。
Claims (4)
- 透気抵抗度1000秒以下かつ緊度0.5g/cm3以上1.0g/cm3以下の基紙と、この基紙の少なくとも一方の表面側に形成される耐油層とを備え、
上記耐油層が、エチレン単位の含有量が2モル%以上10モル%以下、粘度平均重合度が300以上2000以下、けん化度が91.5モル%以上99.5モル%以下のビニルアルコール系重合体(A)と、下記単量体(a)に由来する構成単位及び下記単量体(b)に由来する構成単位を有するカチオン性含フッ素共重合体(B)とを含み、
上記ビニルアルコール系重合体(A)100質量部に対するカチオン性含フッ素共重合体(B)の含有量が5質量部以上50質量部以下であり、
上記耐油層の積層量が乾燥質量換算で0.1g/m2以上3.0g/m2以下である1000g/m2・24h以上の水蒸気透過性を有する紙複合体。
単量体(a):炭素数1〜6のポリフルオロアルキル基を有する(メタ)アクリレート
単量体(b):下式(1)で表される化合物
CH2=C(R1)COO−Q−N(R2)(R3) ・・・(1)
(上記式(1)中、R1は、水素原子又はメチル基であり、Qは、炭素数2以上3以下のアルキレン基における水素原子の一部若しくは全部が水酸基で置換された基、又は炭素数2以上4以下のアルキレン基であり、R2及びR3は、それぞれ独立に、ベンジル基又は炭素数1以上8以下のアルキル基である。但し、R2とR3とが結合して窒素原子と共にモルホリノ基、ピペリジノ基又はピロリジニル基を形成してもよい。) - 上記カチオン性含フッ素共重合体(B)における単量体(a)に由来する構成単位の含有量が50質量%以上98質量%以下、単量体(b)に由来する構成単位の含有量が2質量%以上50質量%以下である請求項1に記載の紙複合体。
- 請求項1に記載の紙複合体を備える包装材料。
- 透気抵抗度1000秒以下かつ緊度0.5g/cm3以上1.0g/cm3以下の基紙と、この基紙の少なくとも一方の表面側に形成される耐油層とを備え、1000g/m2・24h以上の水蒸気透過性を有する紙複合体の製造方法であって、
エチレン単位の含有量が2モル%以上10モル%以下、粘度平均重合度が300以上2000以下、けん化度が91.5モル%以上99.5モル%以下のビニルアルコール系重合体(A)と、下記単量体(a)に由来する構成単位及び下記単量体(b)に由来する構成単位を有するカチオン性含フッ素共重合体(B)とを含む耐油層形成用組成物を上記基紙の少なくとも一方の表面側に塗工する工程と、
上記塗工した基紙を乾燥する工程とを備え、
上記ビニルアルコール系重合体(A)100質量部に対するカチオン性含フッ素共重合体(B)の含有量が5質量部以上50質量部以下であり、
上記耐油層の積層量が乾燥質量換算で0.1g/m2以上3.0g/m2以下であることを特徴とする紙複合体の製造方法。
単量体(a):炭素数1〜6のポリフルオロアルキル基を有する(メタ)アクリレート
単量体(b):下式(1)で表される化合物
CH2=C(R1)COO−Q−N(R2)(R3) ・・・(1)
(上記式(1)中、R1は、水素原子又はメチル基であり、Qは、炭素数2以上3以下のアルキレン基における水素原子の一部若しくは全部が水酸基で置換された基、又は炭素数2以上4以下のアルキレン基であり、R2及びR3は、それぞれ独立に、ベンジル基又は炭素数1以上8以下のアルキル基である。但し、R2とR3とが結合して窒素原子と共にモルホリノ基、ピペリジノ基又はピロリジニル基を形成してもよい。)
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DE102012206832A1 (de) * | 2012-04-25 | 2013-10-31 | Kuraray Europe Gmbh | Polyvinylalkohole als Mineralölbarriere in Papier und Karton |
JP2016029220A (ja) | 2012-12-21 | 2016-03-03 | 旭硝子株式会社 | 耐水耐油紙およびその製造方法 |
JP6085524B2 (ja) * | 2013-05-31 | 2017-02-22 | 株式会社クラレ | 高い耐油性を有する紙複合体 |
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