JP6569068B2 - ガス遮断性に優れた車両用水素タンクライナー - Google Patents
ガス遮断性に優れた車両用水素タンクライナー Download PDFInfo
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- JP6569068B2 JP6569068B2 JP2017522886A JP2017522886A JP6569068B2 JP 6569068 B2 JP6569068 B2 JP 6569068B2 JP 2017522886 A JP2017522886 A JP 2017522886A JP 2017522886 A JP2017522886 A JP 2017522886A JP 6569068 B2 JP6569068 B2 JP 6569068B2
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- polyketone
- bis
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- terpolymer
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims description 22
- 239000001257 hydrogen Substances 0.000 title claims description 22
- 229910052739 hydrogen Inorganic materials 0.000 title claims description 22
- 239000007789 gas Substances 0.000 title description 27
- 230000004888 barrier function Effects 0.000 title description 25
- 229920001470 polyketone Polymers 0.000 claims description 153
- 238000006116 polymerization reaction Methods 0.000 claims description 45
- -1 2,2-dimethyl-1,3-dioxane-5,5-diyl Chemical group 0.000 claims description 42
- 239000000203 mixture Substances 0.000 claims description 38
- 239000003054 catalyst Substances 0.000 claims description 37
- 229920000642 polymer Polymers 0.000 claims description 32
- 239000003446 ligand Substances 0.000 claims description 28
- HFEAMIKDDWKNAG-UHFFFAOYSA-N bis(2-methoxyphenyl)phosphane Chemical compound COC1=CC=CC=C1PC1=CC=CC=C1OC HFEAMIKDDWKNAG-UHFFFAOYSA-N 0.000 claims description 26
- 239000011342 resin composition Substances 0.000 claims description 16
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- 238000009826 distribution Methods 0.000 claims description 13
- 238000001746 injection moulding Methods 0.000 claims description 10
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 10
- 239000004677 Nylon Substances 0.000 claims description 2
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- 238000000034 method Methods 0.000 description 27
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- FVZVCSNXTFCBQU-UHFFFAOYSA-N phosphanyl Chemical group [PH2] FVZVCSNXTFCBQU-UHFFFAOYSA-N 0.000 description 7
- 229910052698 phosphorus Inorganic materials 0.000 description 7
- 239000011574 phosphorus Substances 0.000 description 7
- LVEYOSJUKRVCCF-UHFFFAOYSA-N 1,3-bis(diphenylphosphino)propane Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)CCCP(C=1C=CC=CC=1)C1=CC=CC=C1 LVEYOSJUKRVCCF-UHFFFAOYSA-N 0.000 description 6
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- HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 description 4
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 4
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- IIKVDSGDRQSJPE-UHFFFAOYSA-N [3-[bis(2-methoxyphenyl)phosphanylmethyl]-1,5-dioxaspiro[5.5]undecan-3-yl]methyl-bis(2-methoxyphenyl)phosphane Chemical compound COC1=CC=CC=C1P(C=1C(=CC=CC=1)OC)CC1(CP(C=2C(=CC=CC=2)OC)C=2C(=CC=CC=2)OC)COC2(CCCCC2)OC1 IIKVDSGDRQSJPE-UHFFFAOYSA-N 0.000 description 4
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- SXXPTCXIFIOPQF-UHFFFAOYSA-N 3-bis(2-methoxyphenyl)phosphanylpropyl-bis(2-methoxyphenyl)phosphane Chemical compound COC1=CC=CC=C1P(C=1C(=CC=CC=1)OC)CCCP(C=1C(=CC=CC=1)OC)C1=CC=CC=C1OC SXXPTCXIFIOPQF-UHFFFAOYSA-N 0.000 description 3
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- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Food Science & Technology (AREA)
- Materials Engineering (AREA)
- Polyethers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
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Description
下記の一般式(1)と(2)で表される繰り返し単位からなるポリケトン共重合体として、y/xが0.03から0.3であるポリケトン共重合体を射出成形して製造されることを特徴としたガス遮断性に優れたポリケトン共重合体を課題解決のための手段として提供する。
--CO-(-CH2-CH2-)-x-CO-(G)-y-
Claims (1)
- 下記の一般式(1)と(2)で表される繰り返し単位からなるポリケトン共重合体であって、y/xが0.03〜0.3であり、固有粘度が1.0〜2.0 dl/gであり、分子量分布が1.5〜2.5であるポリケトン共重合体を含み、23℃、60%RHの条件で0.1 ccmm/m2atmday以下の水素透過率を有するポリケトン樹脂組成物を射出成形して製造され、
前記ポリケトン共重合体の重合時の触媒組成物のリガンドは、((2,2-ジメチル-1,3-ジオキサン-5,5-ジイル)ビス(メチレン))ビス(ビス(2-メトキシフェニル)ホスフィン)であり、
前記ポリケトン樹脂組成物は、前記ポリケトン共重合体75〜85重量%、ナイロン6、5〜15重量%、無水マレイン酸がグラフトされたTPE 5〜15重量%が混合されたことを特徴とした車両用水素タンクライナー。
-(CH2CH2-CO)x-(1)
-(CH2CH(CH3)-CO)y-(2)
(x、yは、ポリマー中の一般式(1)及び(2)それぞれのモル%)
Applications Claiming Priority (9)
Application Number | Priority Date | Filing Date | Title |
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KR1020140154619A KR101646035B1 (ko) | 2014-11-07 | 2014-11-07 | 폴리케톤 자동차용 연료 탱크 |
KR10-2014-0154619 | 2014-11-07 | ||
KR10-2014-0161983 | 2014-11-19 | ||
KR10-2014-0162009 | 2014-11-19 | ||
KR1020140162008A KR101684883B1 (ko) | 2014-11-19 | 2014-11-19 | 자동차 오일 팬용 폴리케톤 수지 조성물 |
KR10-2014-0162008 | 2014-11-19 | ||
KR1020140161983A KR101684891B1 (ko) | 2014-11-19 | 2014-11-19 | 식품밀폐용기용 폴리케톤 수지 |
KR1020140162009A KR101725813B1 (ko) | 2014-11-19 | 2014-11-19 | 자동차 수소탱크 라이너용 폴리케톤 수지 조성물 |
PCT/KR2015/010947 WO2016072637A2 (ko) | 2014-11-07 | 2015-10-16 | 가스 차단성이 우수한 폴리케톤 수지 조성물 |
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JP2018500400A JP2018500400A (ja) | 2018-01-11 |
JP6569068B2 true JP6569068B2 (ja) | 2019-09-04 |
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JP2017522886A Active JP6569068B2 (ja) | 2014-11-07 | 2015-10-16 | ガス遮断性に優れた車両用水素タンクライナー |
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US (1) | US20170313820A1 (ja) |
EP (1) | EP3216818A4 (ja) |
JP (1) | JP6569068B2 (ja) |
CN (1) | CN107075111B (ja) |
WO (1) | WO2016072637A2 (ja) |
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CN108367506A (zh) * | 2015-12-18 | 2018-08-03 | 帝斯曼知识产权资产管理有限公司 | 压力容器 |
KR102100784B1 (ko) * | 2017-12-21 | 2020-04-14 | 이도훈 | 폴리케톤 재질의 부품을 갖는 펌프가 장착된 화장품 용기 |
US20220073271A1 (en) * | 2019-01-11 | 2022-03-10 | Raven Industries, Inc. | Flexible bladder tanks including polyketone |
GB2595145B (en) * | 2019-01-11 | 2023-08-09 | Raven Eng Films Inc | Flexible bladder tanks including polyketone |
CN112194893B (zh) * | 2020-10-21 | 2023-04-07 | 横店集团得邦工程塑料有限公司 | 一种耐水解增强阻燃pa6-pok合金材料及其制备方法 |
TWI795242B (zh) * | 2022-03-22 | 2023-03-01 | 正隆股份有限公司 | 製備具保鮮塗料之保鮮紙箱之方法 |
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GB2214917A (en) * | 1988-02-16 | 1989-09-13 | Shell Int Research | Containers for liquid hydrocarbons made of co or so2 copolymer |
US4851482A (en) * | 1988-04-28 | 1989-07-25 | Shell Oil Company | Blends and articles of linear alternating polyketone polymer with polyurethane polymer |
US4808678A (en) * | 1988-06-13 | 1989-02-28 | Shell Oil Company | Polymer blend of carbon monoxide/olefin copolymer and a hydroxyalkyl ether |
EP0445865B1 (en) * | 1990-03-05 | 1999-06-02 | Shell Internationale Researchmaatschappij B.V. | Container made from polymeric material |
DE69601365T2 (de) * | 1995-05-30 | 1999-06-17 | Shell Internationale Research Maatschappij B.V., Den Haag/S'gravenhage | Kraftstoffbehälter und vefahren zu seiner herstellung |
WO2000029462A1 (en) * | 1998-11-16 | 2000-05-25 | Shell Internationale Research Maatschappij B.V. | Process for the preparation of polyketone polymers |
JP4282131B2 (ja) * | 1998-12-18 | 2009-06-17 | 横浜ゴム株式会社 | タイヤ用熱可塑性エラストマー組成物 |
JP4714965B2 (ja) * | 1999-11-01 | 2011-07-06 | 東レ株式会社 | 気体および/または液体バリア部品用強化樹脂組成物および成形品 |
JP2002121334A (ja) * | 2000-10-19 | 2002-04-23 | Toray Ind Inc | 樹脂構造体およびそれからなる薬液またはガス搬送および/または貯蔵用容器およびその付属部品 |
KR101307935B1 (ko) * | 2006-12-28 | 2013-09-12 | 주식회사 효성 | 폴리케톤의 제조방법 |
KR101098242B1 (ko) * | 2009-07-30 | 2011-12-23 | 주식회사 효성 | 폴리케톤 블렌드 및 그 제조방법 |
KR20110017505A (ko) * | 2009-08-14 | 2011-02-22 | 주식회사 효성 | 폴리케톤으로부터 촉매를 제거하는 방법 |
KR101546034B1 (ko) * | 2013-07-17 | 2015-08-25 | 주식회사 효성 | 폴리케톤 중합촉매 |
WO2016010407A2 (ko) * | 2014-07-18 | 2016-01-21 | (주) 효성 | 내유성이 우수한 폴리케톤 수지 조성물 |
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- 2015-10-16 WO PCT/KR2015/010947 patent/WO2016072637A2/ko active Application Filing
- 2015-10-16 EP EP15857377.4A patent/EP3216818A4/en not_active Withdrawn
- 2015-10-16 CN CN201580060248.XA patent/CN107075111B/zh active Active
- 2015-10-16 JP JP2017522886A patent/JP6569068B2/ja active Active
- 2015-10-16 US US15/524,536 patent/US20170313820A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
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WO2016072637A2 (ko) | 2016-05-12 |
EP3216818A2 (en) | 2017-09-13 |
WO2016072637A3 (ko) | 2016-06-23 |
CN107075111B (zh) | 2019-06-07 |
CN107075111A (zh) | 2017-08-18 |
JP2018500400A (ja) | 2018-01-11 |
US20170313820A1 (en) | 2017-11-02 |
EP3216818A4 (en) | 2018-10-10 |
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