JP6567052B2 - ホルムアルデヒドを捕捉するためのポリマー材料 - Google Patents

ホルムアルデヒドを捕捉するためのポリマー材料 Download PDF

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JP6567052B2
JP6567052B2 JP2017526555A JP2017526555A JP6567052B2 JP 6567052 B2 JP6567052 B2 JP 6567052B2 JP 2017526555 A JP2017526555 A JP 2017526555A JP 2017526555 A JP2017526555 A JP 2017526555A JP 6567052 B2 JP6567052 B2 JP 6567052B2
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polymer material
group
formula
carbon atoms
alkyl
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JP2018501086A (ja
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マイケル エス. ウェンドランド,
マイケル エス. ウェンドランド,
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3M Innovative Properties Co
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/34Introducing sulfur atoms or sulfur-containing groups
    • C08F8/36Sulfonation; Sulfation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26Synthetic macromolecular compounds
    • B01J20/265Synthetic macromolecular compounds modified or post-treated polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/72Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/81Solid phase processes
    • B01D53/82Solid phase processes with stationary reactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26Synthetic macromolecular compounds
    • B01J20/261Synthetic macromolecular compounds obtained by reactions only involving carbon to carbon unsaturated bonds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26Synthetic macromolecular compounds
    • B01J20/264Synthetic macromolecular compounds derived from different types of monomers, e.g. linear or branched copolymers, block copolymers, graft copolymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057Surface area, e.g. B.E.T specific surface area
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057Surface area, e.g. B.E.T specific surface area
    • B01J20/28061Surface area, e.g. B.E.T specific surface area being in the range 100-500 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/3085Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
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    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02Monomers containing only one unsaturated aliphatic radical
    • C08F12/32Monomers containing only one unsaturated aliphatic radical containing two or more rings
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    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/34Monomers containing two or more unsaturated aliphatic radicals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/34Monomers containing two or more unsaturated aliphatic radicals
    • C08F212/36Divinylbenzene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/30Introducing nitrogen atoms or nitrogen-containing groups
    • C08F8/32Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20Organic adsorbents
    • B01D2253/202Polymeric adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30Physical properties of adsorbents
    • B01D2253/302Dimensions
    • B01D2253/306Surface area, e.g. BET-specific surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
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    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/10Copolymer characterised by the proportions of the comonomers expressed as molar percentages

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
JP2017526555A 2014-11-17 2015-11-10 ホルムアルデヒドを捕捉するためのポリマー材料 Expired - Fee Related JP6567052B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201462080817P 2014-11-17 2014-11-17
US62/080,817 2014-11-17
PCT/US2015/059909 WO2016081226A1 (en) 2014-11-17 2015-11-10 Polymeric materials for capturing formaldehyde

Publications (3)

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JP2018501086A JP2018501086A (ja) 2018-01-18
JP2018501086A5 JP2018501086A5 (US20080242721A1-20081002-C00053.png) 2018-09-13
JP6567052B2 true JP6567052B2 (ja) 2019-08-28

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JP2017526555A Expired - Fee Related JP6567052B2 (ja) 2014-11-17 2015-11-10 ホルムアルデヒドを捕捉するためのポリマー材料

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US (1) US10391471B2 (US20080242721A1-20081002-C00053.png)
EP (1) EP3221367A1 (US20080242721A1-20081002-C00053.png)
JP (1) JP6567052B2 (US20080242721A1-20081002-C00053.png)
KR (1) KR20170085550A (US20080242721A1-20081002-C00053.png)
CN (1) CN107108783B (US20080242721A1-20081002-C00053.png)
TW (1) TWI647009B (US20080242721A1-20081002-C00053.png)
WO (1) WO2016081226A1 (US20080242721A1-20081002-C00053.png)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3310474B1 (en) 2015-06-19 2019-03-27 3M Innovative Properties Company Hydrolyzed divinylbenzene/maleic anhydride polymeric sorbents for carbon dioxide
WO2016205444A1 (en) 2015-06-19 2016-12-22 3M Innovative Properties Company Divinylbenzene/maleic anhydride polymeric sorbents for carbon dioxide
EP3389851B1 (en) 2015-12-18 2021-12-08 3M Innovative Properties Company Polymeric sorbents for aldehydes
CN108367271B (zh) 2015-12-18 2021-11-19 3M创新有限公司 用于反应性气体的聚合物吸附剂
EP3389852B1 (en) 2015-12-18 2021-11-24 3M Innovative Properties Company Polymeric sorbents for carbon dioxide
US10960341B2 (en) 2016-03-14 2021-03-30 3M Innovative Properties Company Air filters comprising polymeric sorbents for aldehydes
KR102444323B1 (ko) 2016-03-14 2022-09-16 쓰리엠 이노베이티브 프로퍼티즈 캄파니 알데하이드용 중합체 수착제를 포함하는 복합 과립제
JP7010452B2 (ja) 2016-03-14 2022-02-10 スリーエム イノベイティブ プロパティズ カンパニー 反応性ガス用のポリマー収着剤を含むエアフィルタ
WO2018229677A1 (en) * 2017-06-16 2018-12-20 3M Innovative Properties Company Polymeric sorbents for aldehydes
CN110719805B (zh) 2017-06-16 2022-12-27 3M创新有限公司 包含用于醛的聚合物吸附剂的空气过滤器
DE102018114351A1 (de) * 2017-06-30 2019-01-03 Mann+Hummel Gmbh Filtermedium
ES2970735T3 (es) * 2017-12-04 2024-05-30 Stichting Technische Wetenschappen Composiciones macromoleculares que comprenden derivados de indeno
CN110156930A (zh) * 2019-04-30 2019-08-23 昆明理工大学 一种化学吸附降解甲醛的水性丙烯酸树脂及其制备方法
WO2021038347A1 (en) * 2019-08-30 2021-03-04 3M Innovative Properties Company Polymeric sorbents for aldehydes and methods of making
CN114307986B (zh) * 2021-12-28 2023-05-12 南昌航空大学 一种钯离子吸附剂的制备方法

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GB800639A (en) * 1955-07-08 1958-08-27 Wolfgang Muhlberg Manufacture of cation exchangers of the polystyrene-type
CN1062541A (zh) * 1992-01-24 1992-07-08 中国林业科学院林产化学工业研究所 Au甲醛捕捉剂生产工艺
CN1548164A (zh) * 2003-05-22 2004-11-24 王永利 甲醛吸收剂及其制备方法
CN1301780C (zh) 2004-04-30 2007-02-28 罗文圣 一种有害气体捕捉材料及其制备方法
CN103173004B (zh) * 2011-12-23 2014-12-03 万华化学(广东)有限公司 具有甲醛反应性的水性聚氨酯分散体组合物及其制备和应用
EP2900625B1 (en) * 2012-09-25 2016-10-26 3M Innovative Properties Company Polymerizable spirobisindane monomers and polymers prepared therefrom
EP2900709B1 (en) * 2012-09-25 2016-08-17 3M Innovative Properties Company Rigid and contorted divinyl crosslinkers
TWI490232B (zh) 2012-12-28 2015-07-01 Ind Tech Res Inst 甲醛捕捉劑及其製備方法
JP6309082B2 (ja) 2013-05-14 2018-04-11 スリーエム イノベイティブ プロパティズ カンパニー フリーラジカル重合性スピロビスインダンモノマーによるスルホニル含有ポリマー
US9463454B2 (en) 2013-05-14 2016-10-11 3M Innovative Properties Company Amino-containing polymeric material with rigid and contorted divinyl crosslinker
US10220370B2 (en) 2014-06-13 2019-03-05 3M Innovative Properties Company Sulfonic acid-containing polymeric materials as amine sorbents

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Publication number Publication date
CN107108783B (zh) 2019-08-30
KR20170085550A (ko) 2017-07-24
WO2016081226A1 (en) 2016-05-26
CN107108783A (zh) 2017-08-29
EP3221367A1 (en) 2017-09-27
TW201627066A (zh) 2016-08-01
JP2018501086A (ja) 2018-01-18
US10391471B2 (en) 2019-08-27
US20170333870A1 (en) 2017-11-23
TWI647009B (zh) 2019-01-11

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