JP6310536B2 - 不織布 - Google Patents
不織布 Download PDFInfo
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- JP6310536B2 JP6310536B2 JP2016237758A JP2016237758A JP6310536B2 JP 6310536 B2 JP6310536 B2 JP 6310536B2 JP 2016237758 A JP2016237758 A JP 2016237758A JP 2016237758 A JP2016237758 A JP 2016237758A JP 6310536 B2 JP6310536 B2 JP 6310536B2
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- Prior art keywords
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- liquid
- nonwoven fabric
- compound
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- 239000007788 liquid Substances 0.000 claims description 748
- 239000000835 fiber Substances 0.000 claims description 685
- 239000003795 chemical substances by application Substances 0.000 claims description 517
- 239000004745 nonwoven fabric Substances 0.000 claims description 496
- -1 fatty acid ester Chemical class 0.000 claims description 307
- 238000011282 treatment Methods 0.000 claims description 194
- 150000001875 compounds Chemical class 0.000 claims description 159
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 158
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 92
- 239000000194 fatty acid Substances 0.000 claims description 92
- 229930195729 fatty acid Natural products 0.000 claims description 92
- 229920001296 polysiloxane Polymers 0.000 claims description 90
- 239000003945 anionic surfactant Substances 0.000 claims description 85
- 150000005846 sugar alcohols Polymers 0.000 claims description 58
- 230000002745 absorbent Effects 0.000 claims description 56
- 239000002250 absorbent Substances 0.000 claims description 56
- 125000004432 carbon atom Chemical group C* 0.000 claims description 52
- 125000000217 alkyl group Chemical group 0.000 claims description 51
- 125000003368 amide group Chemical group 0.000 claims description 40
- 239000004615 ingredient Substances 0.000 claims description 39
- 125000004185 ester group Chemical group 0.000 claims description 32
- 125000001033 ether group Chemical group 0.000 claims description 32
- 125000003277 amino group Chemical group 0.000 claims description 29
- 229910052799 carbon Inorganic materials 0.000 claims description 26
- 238000003776 cleavage reaction Methods 0.000 claims description 25
- 230000007017 scission Effects 0.000 claims description 25
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 21
- 239000002280 amphoteric surfactant Substances 0.000 claims description 17
- 229910052708 sodium Inorganic materials 0.000 claims description 16
- 229910052700 potassium Inorganic materials 0.000 claims description 15
- 239000004094 surface-active agent Substances 0.000 claims description 15
- 229910052739 hydrogen Inorganic materials 0.000 claims description 14
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 13
- 229910052791 calcium Inorganic materials 0.000 claims description 13
- 229910052749 magnesium Inorganic materials 0.000 claims description 13
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical group C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 claims description 10
- 125000004356 hydroxy functional group Chemical group O* 0.000 claims 3
- 239000010410 layer Substances 0.000 description 438
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- 235000021317 phosphate Nutrition 0.000 description 90
- 239000010452 phosphate Substances 0.000 description 82
- 238000000034 method Methods 0.000 description 75
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 71
- 150000002430 hydrocarbons Chemical group 0.000 description 48
- 230000000694 effects Effects 0.000 description 47
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- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 32
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- 239000002131 composite material Substances 0.000 description 19
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol group Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 19
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 19
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 18
- 238000004049 embossing Methods 0.000 description 18
- 230000035699 permeability Effects 0.000 description 18
- 150000002148 esters Chemical class 0.000 description 17
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 16
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 16
- 239000012528 membrane Substances 0.000 description 16
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 16
- 230000002829 reductive effect Effects 0.000 description 16
- HVYJSOSGTDINLW-UHFFFAOYSA-N 2-[dimethyl(octadecyl)azaniumyl]acetate Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)CC([O-])=O HVYJSOSGTDINLW-UHFFFAOYSA-N 0.000 description 14
- 238000002156 mixing Methods 0.000 description 14
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 14
- 239000002736 nonionic surfactant Substances 0.000 description 13
- 241000283073 Equus caballus Species 0.000 description 12
- 125000002947 alkylene group Chemical group 0.000 description 12
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- 238000012986 modification Methods 0.000 description 12
- 239000011734 sodium Substances 0.000 description 12
- 239000002904 solvent Substances 0.000 description 12
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- 125000003545 alkoxy group Chemical group 0.000 description 11
- 238000000691 measurement method Methods 0.000 description 11
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 11
- 125000004430 oxygen atom Chemical group O* 0.000 description 11
- 230000008569 process Effects 0.000 description 11
- 150000003839 salts Chemical class 0.000 description 11
- 239000002356 single layer Substances 0.000 description 11
- 125000001424 substituent group Chemical group 0.000 description 11
- 210000002700 urine Anatomy 0.000 description 11
- 235000011187 glycerol Nutrition 0.000 description 10
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- 239000011575 calcium Substances 0.000 description 9
- 150000001721 carbon Chemical group 0.000 description 9
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- 235000019438 castor oil Nutrition 0.000 description 9
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical group OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 9
- 238000011156 evaluation Methods 0.000 description 9
- 230000004927 fusion Effects 0.000 description 9
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 9
- 125000001841 imino group Chemical group [H]N=* 0.000 description 9
- 239000011777 magnesium Substances 0.000 description 9
- 230000035515 penetration Effects 0.000 description 9
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 9
- 239000002994 raw material Substances 0.000 description 9
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical group OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 8
- 239000004721 Polyphenylene oxide Substances 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 8
- 125000002843 carboxylic acid group Chemical group 0.000 description 8
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- 125000001153 fluoro group Chemical group F* 0.000 description 8
- 239000000463 material Substances 0.000 description 8
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- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 125000004433 nitrogen atom Chemical group N* 0.000 description 8
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 8
- 229920000570 polyether Polymers 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 125000003710 aryl alkyl group Chemical group 0.000 description 7
- 125000003118 aryl group Chemical group 0.000 description 7
- 125000005587 carbonate group Chemical group 0.000 description 7
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 7
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 7
- 229910052731 fluorine Inorganic materials 0.000 description 7
- 125000003709 fluoroalkyl group Chemical group 0.000 description 7
- 230000002209 hydrophobic effect Effects 0.000 description 7
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 7
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 7
- 230000002441 reversible effect Effects 0.000 description 7
- 229910052710 silicon Inorganic materials 0.000 description 7
- 229920002545 silicone oil Polymers 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 230000001629 suppression Effects 0.000 description 7
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical group OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 7
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 6
- LEEDMQGKBNGPDN-UHFFFAOYSA-N 2-methylnonadecane Chemical compound CCCCCCCCCCCCCCCCCC(C)C LEEDMQGKBNGPDN-UHFFFAOYSA-N 0.000 description 6
- 206010037660 Pyrexia Diseases 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
- 125000000129 anionic group Chemical group 0.000 description 6
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 6
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 6
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- 238000013461 design Methods 0.000 description 6
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- 125000003700 epoxy group Chemical group 0.000 description 6
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 6
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- 125000000524 functional group Chemical group 0.000 description 6
- 125000005843 halogen group Chemical group 0.000 description 6
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 6
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 6
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 6
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 6
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- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 3
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- GFAZGHREJPXDMH-UHFFFAOYSA-N 1,3-dipalmitoylglycerol Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(O)COC(=O)CCCCCCCCCCCCCCC GFAZGHREJPXDMH-UHFFFAOYSA-N 0.000 description 2
- JPPRXACMNPYJNK-UHFFFAOYSA-N 1-docosoxydocosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCCCCCC JPPRXACMNPYJNK-UHFFFAOYSA-N 0.000 description 2
- HBXWUCXDUUJDRB-UHFFFAOYSA-N 1-octadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC HBXWUCXDUUJDRB-UHFFFAOYSA-N 0.000 description 2
- HANWHVWXFQSQGJ-UHFFFAOYSA-N 1-tetradecoxytetradecane Chemical compound CCCCCCCCCCCCCCOCCCCCCCCCCCCCC HANWHVWXFQSQGJ-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- DDGPBVIAYDDWDH-UHFFFAOYSA-N 3-[dodecyl(dimethyl)azaniumyl]-2-hydroxypropane-1-sulfonate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC(O)CS([O-])(=O)=O DDGPBVIAYDDWDH-UHFFFAOYSA-N 0.000 description 2
- YZYZMGGVCYIIIU-UHFFFAOYSA-N 3-sulfo-2,2-di(tridecyl)butanedioic acid Chemical compound CCCCCCCCCCCCCC(C(O)=O)(C(C(O)=O)S(O)(=O)=O)CCCCCCCCCCCCC YZYZMGGVCYIIIU-UHFFFAOYSA-N 0.000 description 2
- OQMZNAMGEHIHNN-UHFFFAOYSA-N 7-Dehydrostigmasterol Natural products C1C(O)CCC2(C)C(CCC3(C(C(C)C=CC(CC)C(C)C)CCC33)C)C3=CC=C21 OQMZNAMGEHIHNN-UHFFFAOYSA-N 0.000 description 2
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
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- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/647—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing polyether sequences
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US20040121680A1 (en) * | 2002-12-23 | 2004-06-24 | Kimberly-Clark Worldwide, Inc. | Compositions and methods for treating lofty nonwoven substrates |
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