JP6243026B2 - カーボンナノチューブ−電解質ポリマーの安定な組成物 - Google Patents

カーボンナノチューブ−電解質ポリマーの安定な組成物 Download PDF

Info

Publication number
JP6243026B2
JP6243026B2 JP2016527164A JP2016527164A JP6243026B2 JP 6243026 B2 JP6243026 B2 JP 6243026B2 JP 2016527164 A JP2016527164 A JP 2016527164A JP 2016527164 A JP2016527164 A JP 2016527164A JP 6243026 B2 JP6243026 B2 JP 6243026B2
Authority
JP
Japan
Prior art keywords
composition
polymer
copolymer
nitroxide
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2016527164A
Other languages
English (en)
Japanese (ja)
Other versions
JP2016539217A5 (https=
JP2016539217A (ja
Inventor
クリストフ ナヴァロ,
クリストフ ナヴァロ,
ウィリアン スマール,
ウィリアン スマール,
ムハンマド ムムタズ,
ムハンマド ムムタズ,
エリク クルテ,
エリク クルテ,
シリル ブロション,
シリル ブロション,
ジョルジュ ハジオアノウ,
ジョルジュ ハジオアノウ,
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Arkema France SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema France SA filed Critical Arkema France SA
Publication of JP2016539217A publication Critical patent/JP2016539217A/ja
Publication of JP2016539217A5 publication Critical patent/JP2016539217A5/ja
Application granted granted Critical
Publication of JP6243026B2 publication Critical patent/JP6243026B2/ja
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02Monomers containing only one unsaturated aliphatic radical
    • C08F12/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/14Monomers containing only one unsaturated aliphatic radical containing one ring substituted by hetero atoms or groups containing heteroatoms
    • C08F12/16Halogens
    • C08F12/20Fluorine
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02Monomers containing only one unsaturated aliphatic radical
    • C08F12/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/14Monomers containing only one unsaturated aliphatic radical containing one ring substituted by hetero atoms or groups containing heteroatoms
    • C08F12/30Sulfur
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10Esters
    • C08F20/38Esters containing sulfur
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/005Reinforced macromolecular compounds with nanosized materials, e.g. nanoparticles, nanofibres, nanotubes, nanowires, nanorods or nanolayered materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • C08K3/041Carbon nanotubes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/20Conductive material dispersed in non-conductive organic material
    • H01B1/24Conductive material dispersed in non-conductive organic material the conductive material comprising carbon-silicon compounds, carbon or silicon
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K30/00Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
    • H10K30/80Constructional details
    • H10K30/81Electrodes
    • H10K30/82Transparent electrodes, e.g. indium tin oxide [ITO] electrodes
    • H10K30/821Transparent electrodes, e.g. indium tin oxide [ITO] electrodes comprising carbon nanotubes
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/80Constructional details
    • H10K50/805Electrodes
    • H10K50/82Cathodes
    • H10K50/828Transparent cathodes, e.g. comprising thin metal layers
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/10Organic polymers or oligomers
    • H10K85/141Organic polymers or oligomers comprising aliphatic or olefinic chains, e.g. poly N-vinylcarbazol, PVC or PTFE
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/20Carbon compounds, e.g. carbon nanotubes or fullerenes
    • H10K85/221Carbon nanotubes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00Living radical polymerisation
    • C08F2438/03Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/10Transparent films; Clear coatings; Transparent materials
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/80Constructional details
    • H10K50/805Electrodes
    • H10K50/81Anodes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/549Organic PV cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Nanotechnology (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Dispersion Chemistry (AREA)
  • Optics & Photonics (AREA)
  • Manufacturing & Machinery (AREA)
  • Electromagnetism (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Photovoltaic Devices (AREA)
  • Conductive Materials (AREA)
  • Non-Insulated Conductors (AREA)
  • Hybrid Cells (AREA)
JP2016527164A 2013-10-31 2014-10-29 カーボンナノチューブ−電解質ポリマーの安定な組成物 Expired - Fee Related JP6243026B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR13.60685 2013-10-31
FR1360685A FR3012461B1 (fr) 2013-10-31 2013-10-31 Compositions stables de nanotubes de carbone - polymeres electrolytes
PCT/FR2014/052751 WO2015063417A2 (fr) 2013-10-31 2014-10-29 Compositions stables de nanotubes de carbone - polymeres electrolytes

Publications (3)

Publication Number Publication Date
JP2016539217A JP2016539217A (ja) 2016-12-15
JP2016539217A5 JP2016539217A5 (https=) 2017-11-02
JP6243026B2 true JP6243026B2 (ja) 2017-12-06

Family

ID=50976678

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2016527164A Expired - Fee Related JP6243026B2 (ja) 2013-10-31 2014-10-29 カーボンナノチューブ−電解質ポリマーの安定な組成物

Country Status (10)

Country Link
US (1) US10199135B2 (https=)
EP (1) EP3063183B9 (https=)
JP (1) JP6243026B2 (https=)
KR (1) KR101817453B1 (https=)
CN (1) CN105916887A (https=)
FR (1) FR3012461B1 (https=)
HU (1) HUE038006T2 (https=)
PL (1) PL3063183T3 (https=)
TW (1) TWI538950B (https=)
WO (1) WO2015063417A2 (https=)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6919993B2 (ja) * 2017-01-06 2021-08-18 信越化学工業株式会社 生体電極組成物、生体電極及び生体電極の製造方法
CN110415888B (zh) * 2019-06-14 2021-12-28 江西力能新能源科技有限公司 一种含有固态电解质的碳纳米管油系导电浆料及其制备方法

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2730240A1 (fr) 1995-02-07 1996-08-09 Atochem Elf Sa Stabilisation d'un polymere par un radical libre stable
JP2000082494A (ja) * 1998-09-03 2000-03-21 Sanyo Chem Ind Ltd 難燃性非水電解液およびそれを用いた二次電池
JP4407502B2 (ja) * 2004-03-31 2010-02-03 住友ベークライト株式会社 リチウムイオン伝導性電解質及びそれを用いた二次電池
JP4982734B2 (ja) * 2005-07-08 2012-07-25 国立大学法人北海道大学 カーボンナノチューブ分散ペースト、カーボンナノチューブ分散溶液およびその製造方法
CN100579901C (zh) * 2007-11-20 2010-01-13 浙江大学 酸胆碱基仿生聚合物包覆的碳纳米管及其制备方法
JP2010033889A (ja) * 2008-07-29 2010-02-12 Mitsubishi Rayon Co Ltd 耐水性導電体の製造方法
JP5359132B2 (ja) 2008-09-05 2013-12-04 コニカミノルタ株式会社 透明電極及び該透明電極を有する有機エレクトロルミネッセンス素子
EP2163190A1 (de) * 2008-09-11 2010-03-17 Roche Diagnostics GmbH Elektrodensystem für Messung einer Analytkonzentration in-vivo
US8470205B2 (en) * 2009-06-05 2013-06-25 Air Products And Chemicals, Inc. Electrically conductive films formed from dispersions comprising conductive polymers and hyperbranched polymers
KR101799556B1 (ko) * 2010-02-15 2017-11-20 국립대학법인 홋가이도 다이가쿠 탄소 나노튜브 시트 및 그 제조 방법
FR2961634B1 (fr) * 2010-06-17 2013-02-15 Centre Nat Rech Scient Procede pour l'elaboration d'une batterie au lithium ou au sodium
US8940444B2 (en) * 2011-05-20 2015-01-27 Alliance For Sustainable Energy, Llc Hybrid radical energy storage device and method of making
GB2509273A (en) * 2011-08-26 2014-06-25 Merck Patent Gmbh Organic semiconductor formulation
FR2979630B1 (fr) * 2011-09-05 2013-10-04 Univ Provence Aix Marseille 1 Copolymeres a blocs dont un polyanionique base sur un monomere anion de type tfsili comme electrolyte de batterie.
FR2989091B1 (fr) 2012-04-06 2015-07-03 Arkema France Copolymeres a bloc dispersants de nanocharges dans l'eau
FR3012462B1 (fr) * 2013-10-31 2016-01-01 Arkema France Compositions stables de poly (3,4-ethylenedioxythiophene) et de stabilisants anioniques a acidite limitee

Also Published As

Publication number Publication date
EP3063183B9 (fr) 2018-05-23
FR3012461A1 (fr) 2015-05-01
US10199135B2 (en) 2019-02-05
FR3012461B1 (fr) 2016-01-01
WO2015063417A2 (fr) 2015-05-07
TW201538598A (zh) 2015-10-16
US20160276057A1 (en) 2016-09-22
EP3063183B1 (fr) 2017-10-11
HUE038006T2 (hu) 2018-09-28
KR20160064207A (ko) 2016-06-07
KR101817453B1 (ko) 2018-01-11
JP2016539217A (ja) 2016-12-15
WO2015063417A3 (fr) 2015-06-25
CN105916887A (zh) 2016-08-31
EP3063183A2 (fr) 2016-09-07
TWI538950B (zh) 2016-06-21
PL3063183T3 (pl) 2018-04-30

Similar Documents

Publication Publication Date Title
Tian et al. Modulating the coordination environment of lithium bonds for high performance polymer electrolyte batteries
JP5265516B2 (ja) トリブロックコポリマー、特にポリスチレン−ポリ(オキシエチレン)ポリスチレンをベースにした固体ポリマー電解質
Jeong et al. Mussel-inspired self-healing metallopolymers for silicon nanoparticle anodes
CN105899547B (zh) 包含聚(3,4-亚乙基二氧噻吩)和具有有限酸性的阴离子稳定剂的稳定成分
Glynos et al. Nanostructured polymer particles as additives for high conductivity, high modulus solid polymer electrolytes
Liu et al. PVDF-HFP-based composite electrolyte membranes having high conductivity and lithium-ion transference number for lithium metal batteries
Chen et al. Confining hyperbranched star poly (ethylene oxide)-based polymer into a 3D interpenetrating network for a high-performance all-solid-state polymer electrolyte
Hwang et al. Star-shaped block copolymers: Effective polymer gelators of high-performance gel electrolytes for electrochemical devices
JP2014529863A5 (https=)
Bergfelt et al. Mechanically robust yet highly conductive diblock copolymer solid polymer electrolyte for ambient temperature battery applications
Guan et al. UV-cured interpenetrating networks of single-ion conducting polymer electrolytes for rechargeable lithium metal batteries
Zheng et al. Employing gradient copolymer to achieve gel polymer electrolytes with high ionic conductivity
JP6243026B2 (ja) カーボンナノチューブ−電解質ポリマーの安定な組成物
Guan et al. Crystal forms and microphase structures of poly (vinylidene fluoride-co-hexafluoropropylene) physically and chemically incorporated with ionic liquids
KR20140147882A (ko) 물에 나노필라멘트를 분산시키는 블록 공중합체
Wu et al. Coconstruction of supramolecular lithium-conducting cross-linked networks Based on PVDF and triblock polymer nanomicrosphere solid-state polymer electrolytes for lithium-metal batteries
Wang et al. Application of Polymer Electrolytes Prepared by Ultraviolet Polymerization in Various Lithium Metal Battery Systems
CN118983512A (zh) 一种本征高拉伸全氟聚合物电解质及其制备方法与应用
Xue et al. Elements of functional ion/block copolymer hybrids
KR101022558B1 (ko) 플러렌이 도입된 카바졸 유도체 고분자, 이의 합성 방법, 및 상기 고분자를 포함하는 비휘발성 메모리소자
JPWO2012132957A1 (ja) 高分子電解質およびリチウムポリマー電池
TW202200702A (zh) 複合體、高分子電解質、電化學裝置、高分子系固態電池及致動器
CN104479135A (zh) 异氮杂茚氧化氮自由基改性聚膦腈及其合成方法和用途
Wang et al. Self-Healing Polymer Electrolyte Based on Boronic Ester Bonds with Hydroxyl Groups Synergistically for Lithium-Metal Batteries

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20160629

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20170421

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20170425

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20170718

A524 Written submission of copy of amendment under article 19 pct

Free format text: JAPANESE INTERMEDIATE CODE: A524

Effective date: 20170922

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20171010

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20171108

R150 Certificate of patent or registration of utility model

Ref document number: 6243026

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees