JP6185070B2 - 有機金属触媒錯体及びこれを使用する重合方法 - Google Patents

有機金属触媒錯体及びこれを使用する重合方法 Download PDF

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Publication number
JP6185070B2
JP6185070B2 JP2015534792A JP2015534792A JP6185070B2 JP 6185070 B2 JP6185070 B2 JP 6185070B2 JP 2015534792 A JP2015534792 A JP 2015534792A JP 2015534792 A JP2015534792 A JP 2015534792A JP 6185070 B2 JP6185070 B2 JP 6185070B2
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group
polymerization
aluminum
polymer
catalyst
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JP2016500715A5 (enExample
JP2016500715A (ja
Inventor
スティーブン ルオ
スティーブン ルオ
ツァンキアン キン
ツァンキアン キン
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Bridgestone Corp
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Bridgestone Corp
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/003—Compounds containing elements of Groups 3 or 13 of the Periodic Table without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C08F4/545—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof rare earths being present, e.g. triethylaluminium + neodymium octanoate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/64082—Tridentate ligand
    • C08F4/6411—Monoanionic ligand
    • C08F4/64117—NNO
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/64082—Tridentate ligand
    • C08F4/6411—Monoanionic ligand
    • C08F4/6412—ONN

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
JP2015534792A 2012-09-30 2013-09-30 有機金属触媒錯体及びこれを使用する重合方法 Active JP6185070B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261708027P 2012-09-30 2012-09-30
US61/708,027 2012-09-30
PCT/US2013/062611 WO2014052957A1 (en) 2012-09-30 2013-09-30 Organometallic catalyst complex and polymerization method employing same

Related Child Applications (1)

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JP2017144183A Division JP6445629B2 (ja) 2012-09-30 2017-07-26 有機金属触媒錯体及びこれを使用する重合方法

Publications (3)

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JP2016500715A JP2016500715A (ja) 2016-01-14
JP2016500715A5 JP2016500715A5 (enExample) 2016-09-08
JP6185070B2 true JP6185070B2 (ja) 2017-08-23

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JP2017144183A Expired - Fee Related JP6445629B2 (ja) 2012-09-30 2017-07-26 有機金属触媒錯体及びこれを使用する重合方法

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Country Link
US (1) US9403848B2 (enExample)
EP (1) EP2900702B1 (enExample)
JP (2) JP6185070B2 (enExample)
CN (1) CN104903358B (enExample)
WO (1) WO2014052957A1 (enExample)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112013019814B1 (pt) 2011-02-05 2022-07-12 Bridgestone Corporation Catalisador de complexo de lantanídeo e método de polimerização empregando o mesmo
EP2673280B1 (en) 2011-02-05 2016-12-21 Bridgestone Corporation Metal complex catalysts and polymerization methods employing same
WO2012106694A2 (en) 2011-02-05 2012-08-09 Bridgestone Corporation Lanthanide complex catalyst and polymerization method employing same
WO2016175963A1 (en) * 2015-04-28 2016-11-03 Exxonmobil Chemical Patents Inc. Process to produce ethylene conjugated diene copolymers and copolymers therefrom
US9879104B2 (en) 2015-04-28 2018-01-30 Exxonmobil Chemical Patents Inc. Process to produce ethylene conjugated diene copolymers and copolymers therefrom
WO2019108969A1 (en) * 2017-12-01 2019-06-06 University Of Florida Research Foundation, Inc. Compositions and methods for stereoregular ring expansion metathesis polymerization

Family Cites Families (64)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3873489A (en) 1971-08-17 1975-03-25 Degussa Rubber compositions containing silica and an organosilane
US3978103A (en) 1971-08-17 1976-08-31 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler Sulfur containing organosilicon compounds
SU580840A3 (ru) 1974-02-07 1977-11-15 Дегусса (Фирма) Способ получени серосодержащих кремнийорганических соединений
US4015061A (en) 1975-02-14 1977-03-29 The Firestone Tire & Rubber Company Protected amino-functional initiators and amino-terminated polymers and their production
US4002594A (en) 1975-07-08 1977-01-11 Ppg Industries, Inc. Scorch retardants for rubber reinforced with siliceous pigment and mercapto-type coupling agent
US4616069A (en) 1984-10-26 1986-10-07 Nippon Zeon Co., Ltd. Process for making diene polymer rubbers
US4906706A (en) 1986-09-05 1990-03-06 Japan Synthetic Rubber Co., Ltd. Modified conjugated diene polymer and process for production thereof
US5064910A (en) 1986-09-05 1991-11-12 Japan Synthetic Rubber Co., Ltd. Preparation of conjugated diene polymers modified with an organo-tin or germanium halide
US4935471A (en) 1987-10-15 1990-06-19 The Goodyear Tire & Rubber Company Capped polydienes
IT1230756B (it) 1989-02-17 1991-10-29 Enichem Elastomers Metodo per la preparazione di polibutadiene a lavorabilita' migliorata.
US5149457A (en) 1989-06-30 1992-09-22 Cyprus Foote Mineral Company Stable mixed lithium amide reagent compositions
US5196138A (en) 1989-06-30 1993-03-23 Cyprus Foote Mineral Company Preparation of mixed lithium amide reagents
US5153159A (en) 1990-04-09 1992-10-06 Bridgestone/Firestone, Inc. Elastomers and products having reduced hysteresis
US5329005A (en) 1992-10-02 1994-07-12 Bridgestone Corporation Soluble anionic polymerization initiators and preparation thereof
WO1995004090A1 (en) 1993-07-30 1995-02-09 Nippon Zeon Co., Ltd. Modified conjugated diene copolymer, process for producing the same, and composition thereof
US5567815A (en) 1994-07-18 1996-10-22 Bridgestone Corporation Teritary amine containing antonic initiators used in preparing polymers and process for the preparation thereof
DE4436059A1 (de) 1994-10-10 1996-04-11 Bayer Ag Verfahren zur Herstellung von mittels Nd-Katalysatoren polymerisierten Dienkautschuken mit niedrigem cold-flow und geringem Eigengeruch
US5521309A (en) 1994-12-23 1996-05-28 Bridgestone Corporation Tertiary-amino allyl-or xylyl-lithium initiators and method of preparing same
US5496940A (en) 1995-02-01 1996-03-05 Bridgestone Corporation Alkyllithium compounds containing cyclic amines and their use in polymerization
US5580919A (en) 1995-03-14 1996-12-03 The Goodyear Tire & Rubber Company Silica reinforced rubber composition and use in tires
US5610227A (en) 1995-06-07 1997-03-11 Bridgestone/Firestone, Inc. Lithium amino magnesiate polymerization initiators and elastomers having reduced hysteresis
US5583245A (en) 1996-03-06 1996-12-10 The Goodyear Tire & Rubber Company Preparation of sulfur-containing organosilicon compounds
US5663398A (en) 1996-05-17 1997-09-02 Fmc Corporation Processes for preparing functionalized alkyllithium compounds
US5696197A (en) 1996-06-21 1997-12-09 The Goodyear Tire & Rubber Company Heterogeneous silica carbon black-filled rubber compound
US5663396A (en) 1996-10-31 1997-09-02 The Goodyear Tire & Rubber Company Preparation of sulfur-containing organosilicon compounds
US5786441A (en) 1996-12-31 1998-07-28 Bridgestone Corporation Polymers, elastomeric compounds and products thereof, derived from novel amine compounds containing side-chain organolithium moieties
US5684171A (en) 1997-02-11 1997-11-04 The Goodyear Tire & Rubber Company Process for the preparation of organosilicon polysulfide compounds
US5684172A (en) 1997-02-11 1997-11-04 The Goodyear Tire & Rubber Company Process for the preparation of organosilicon polysulfide compounds
ES2198651T3 (es) 1997-03-05 2004-02-01 Jsr Corporation Metodo para producir polimeros dieno conjugados.
TW420693B (en) 1997-04-25 2001-02-01 Mitsui Chemicals Inc Olefin polymerization catalysts, transition metal compounds, and <alpha>-olefin/conjugated diene copolymers
US6525118B2 (en) 1997-07-11 2003-02-25 Bridgestone Corporation Processability of silica-filled rubber stocks with reduced hysteresis
FR2799468B1 (fr) 1999-10-12 2006-04-28 Michelin Soc Tech Systeme catalytique utilisable pour la copolymerisation de l'ethylene et d'un diene conjugue, procede de preparation de ce systeme catalytique et d'un copolymere d'ethylene et d'un diene conjugue
EP1099711B1 (en) 1999-11-12 2006-03-29 JSR Corporation Modified conjugated diene polymer, method of producing it and rubber composition comprising the same
US6992147B1 (en) 1999-11-12 2006-01-31 Bridgestone Corporation Modified polymers prepared with lanthanide-based catalysts
US6977281B1 (en) 1999-11-12 2005-12-20 Bridgestone Corporation Modified polymers prepared with lanthanide-based catalysts
US6531424B2 (en) * 1999-12-17 2003-03-11 E. I. Du Pont De Nemours And Company Polymerization of olefins
BR0112516A (pt) 2000-07-17 2003-09-09 Univation Tech Llc Sistema catalisador e seu emprego em um processo de polimerização
EP1332162B1 (en) 2000-11-10 2013-05-01 Bridgestone Corporation Functionalized high cis-1,4-polybutadiene prepared using novel functionalizing agents
GB2389855B (en) 2001-02-01 2005-09-21 Fmc Corp Functionalized initiators for anionic polymerization,protected funtionalized polymers,deprotected analogues thereof,and method of making the same
EP1426385B1 (en) * 2001-07-23 2012-08-22 Shanghai Institute Of Organic Chemistry, Chinese Academy Of Sciences Catalyst for polymerization or copolymerization of olefins, preparation and use of the same
US6699813B2 (en) 2001-11-07 2004-03-02 Bridgestone Corporation Lanthanide-based catalyst composition for the manufacture of polydienes
CN101045770A (zh) 2002-10-16 2007-10-03 米其林技术公司 用于合成乙烯和丁二烯共聚物的催化体系
JP4522947B2 (ja) 2002-10-30 2010-08-11 株式会社ブリヂストン モノマーのアニオン重合に硫黄含有開始剤を使用する方法
AU2003282957A1 (en) 2002-11-07 2004-06-03 Dow Global Technologies, Inc. Process for homo- or copolymerization of conjugated dienes and in situ formation of polymer blends and products made thereby
FR2858817B1 (fr) 2003-08-13 2006-02-03 Michelin Soc Tech Systeme catalytique pour l'obtention de copolymeres diene(s) conjugue(s)/ mono-olefine(s) et ces copolymeres
EP1765889B1 (en) 2004-03-02 2016-03-30 Bridgestone Corporation Bulk polymerization process
WO2006047328A1 (en) 2004-10-26 2006-05-04 Bridgestone Corporation Functionalized polymer with linking group
US7816483B2 (en) 2005-08-11 2010-10-19 Bridgestone Corporation Amine functionalized polymer
JP5079294B2 (ja) 2005-10-04 2012-11-21 株式会社ブリヂストン アミンで官能化されたポリマー
US7879952B2 (en) 2005-12-28 2011-02-01 Bridgestone Corporation Functionalized polymers
US7671138B2 (en) 2006-05-26 2010-03-02 Bridgestone Corporation Polymers functionized with hydrobenzamides
US7732534B2 (en) 2006-08-28 2010-06-08 Bridgestone Corporation Polymers functionalized with nitro compounds
US8088868B2 (en) 2006-12-19 2012-01-03 Bridgestone Corporation Polymers functionalized with protected oxime compounds
ZA200711158B (en) 2006-12-28 2009-03-25 Bridgestone Corp A method for producing functionalized cis-1,4-polydienes having high cis-1,4-linkage content and high functionality
MY152879A (en) * 2007-07-04 2014-11-28 Mitsui Chemicals Inc Transition metal complex compounds, olefin oligomerization catalysts including the compounds, and processes for producing olefin oligomers using the catalysts
US7879958B2 (en) 2007-08-07 2011-02-01 Bridgestone Corporation Polyhydroxy compounds as polymerization quenching agents
US8324329B2 (en) 2007-08-07 2012-12-04 Bridgestone Corporation Process for producing functionalized polymers
WO2009052700A1 (en) * 2007-10-16 2009-04-30 Sinopec Yangzi Petrochemical Company Ltd. Supported non-metallocene catalyst and its preparation method
US8716416B2 (en) * 2007-10-16 2014-05-06 Sinopec Yangzi Petrochemical Company Ltd. Magnesium-compound supported nonmetallocene catalyst and preparation thereof
EP2243870B1 (en) 2008-07-16 2012-10-10 Japan Exlan Co., Ltd. An antistatic acrylic fiber and a method for manufacturing the same
CN101402694B (zh) * 2008-11-17 2010-10-27 中国科学院长春应用化学研究所 三齿水杨醛亚胺钒烯烃聚合催化剂及制备方法和应用
WO2011002930A2 (en) 2009-06-30 2011-01-06 Bridgestone Corporation Hydroxyaryl functionalized polymers
BR112013019814B1 (pt) 2011-02-05 2022-07-12 Bridgestone Corporation Catalisador de complexo de lantanídeo e método de polimerização empregando o mesmo
WO2012106694A2 (en) 2011-02-05 2012-08-09 Bridgestone Corporation Lanthanide complex catalyst and polymerization method employing same

Also Published As

Publication number Publication date
EP2900702A4 (en) 2016-06-08
EP2900702A1 (en) 2015-08-05
JP6445629B2 (ja) 2018-12-26
JP2018021028A (ja) 2018-02-08
CN104903358B (zh) 2017-11-17
CN104903358A (zh) 2015-09-09
WO2014052957A1 (en) 2014-04-03
US9403848B2 (en) 2016-08-02
EP2900702B1 (en) 2018-05-02
JP2016500715A (ja) 2016-01-14
US20150259361A1 (en) 2015-09-17

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