JP6182967B2 - 半導体素子用高熱伝導性接着フィルム - Google Patents
半導体素子用高熱伝導性接着フィルム Download PDFInfo
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- JP6182967B2 JP6182967B2 JP2013099135A JP2013099135A JP6182967B2 JP 6182967 B2 JP6182967 B2 JP 6182967B2 JP 2013099135 A JP2013099135 A JP 2013099135A JP 2013099135 A JP2013099135 A JP 2013099135A JP 6182967 B2 JP6182967 B2 JP 6182967B2
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- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
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- 229920000877 Melamine resin Polymers 0.000 description 1
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- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
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- 238000011088 calibration curve Methods 0.000 description 1
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- HTDKEJXHILZNPP-UHFFFAOYSA-N dioctyl hydrogen phosphate Chemical compound CCCCCCCCOP(O)(=O)OCCCCCCCC HTDKEJXHILZNPP-UHFFFAOYSA-N 0.000 description 1
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- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
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- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
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- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 description 1
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- 230000001678 irradiating effect Effects 0.000 description 1
- FUCCZFISQTYRNK-UHFFFAOYSA-N isocyanato(dimethyl)silane Chemical compound C[SiH](C)N=C=O FUCCZFISQTYRNK-UHFFFAOYSA-N 0.000 description 1
- NIZHERJWXFHGGU-UHFFFAOYSA-N isocyanato(trimethyl)silane Chemical compound C[Si](C)(C)N=C=O NIZHERJWXFHGGU-UHFFFAOYSA-N 0.000 description 1
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- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
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- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 description 1
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- DVYVMJLSUSGYMH-UHFFFAOYSA-N n-methyl-3-trimethoxysilylpropan-1-amine Chemical compound CNCCC[Si](OC)(OC)OC DVYVMJLSUSGYMH-UHFFFAOYSA-N 0.000 description 1
- 125000005487 naphthalate group Chemical group 0.000 description 1
- KQJBQMSCFSJABN-UHFFFAOYSA-N octadecan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCCCCCCCCCCCCCCCC[O-].CCCCCCCCCCCCCCCCCC[O-].CCCCCCCCCCCCCCCCCC[O-].CCCCCCCCCCCCCCCCCC[O-] KQJBQMSCFSJABN-UHFFFAOYSA-N 0.000 description 1
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
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- 239000005077 polysulfide Substances 0.000 description 1
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- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
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- 229910000679 solder Inorganic materials 0.000 description 1
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- 125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 150000003553 thiiranes Chemical group 0.000 description 1
- GQIUQDDJKHLHTB-UHFFFAOYSA-N trichloro(ethenyl)silane Chemical compound Cl[Si](Cl)(Cl)C=C GQIUQDDJKHLHTB-UHFFFAOYSA-N 0.000 description 1
- ZOYFEXPFPVDYIS-UHFFFAOYSA-N trichloro(ethyl)silane Chemical compound CC[Si](Cl)(Cl)Cl ZOYFEXPFPVDYIS-UHFFFAOYSA-N 0.000 description 1
- KWDQAHIRKOXFAV-UHFFFAOYSA-N trichloro(pentyl)silane Chemical compound CCCCC[Si](Cl)(Cl)Cl KWDQAHIRKOXFAV-UHFFFAOYSA-N 0.000 description 1
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
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- XYJRNCYWTVGEEG-UHFFFAOYSA-N trimethoxy(2-methylpropyl)silane Chemical compound CO[Si](OC)(OC)CC(C)C XYJRNCYWTVGEEG-UHFFFAOYSA-N 0.000 description 1
- ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 description 1
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 description 1
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- SIOVKLKJSOKLIF-HJWRWDBZSA-N trimethylsilyl (1z)-n-trimethylsilylethanimidate Chemical compound C[Si](C)(C)OC(/C)=N\[Si](C)(C)C SIOVKLKJSOKLIF-HJWRWDBZSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
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Images
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- Adhesives Or Adhesive Processes (AREA)
- Laminated Bodies (AREA)
- Adhesive Tapes (AREA)
Description
クレゾ−ルノボラック型エポキシ樹脂(エポキシ当量220、東都化成株式会社製、商品名「YDCN−700−10」)60質量部、低吸水性フェノール樹脂(三井化学株式会社製、商品名「XLC−LL」)40質量部、エポキシ基含有アクリル系共重合体(帝国化学産業株式会社製、商品名「HTR−860P−3」)200質量部、イミダゾール系硬化促進剤(四国化成株式会社製、商品名「キュアゾール2PZ−CN」)0.1質量部、シランカップリング剤(日本ユニカー株式会社製、商品名「A−189」)1.5質量部、シランカップリング剤(日本ユニカー株式会社製、商品名「A−1160」)3質量部、及びシリカフィラー(日本アエロジル株式会社製、商品名「R972」)32質量部の混合物に、シクロヘキサノンを加えて撹拌混合し、真空脱気してペースト状の樹脂組成物層形成用材料を得た。このペースト状材料を、厚さ38μmの離型処理したポリエチレンテレフタレートフィルム上に塗布し、90℃で10分間、次いで120℃で5分間加熱乾燥して、膜厚が1μmの樹脂組成物層を作製した。
実施例1と同様の材料を使用して膜厚3μmの樹脂組成物層を作製した。この樹脂組成物層を用いたこと以外は実施例1と同様の工程を経て、高熱伝導性フィルムを作製した。
実施例1と同様の材料を使用し膜厚5μmの樹脂組成物層を作製した。この樹脂組成物層を用いたこと以外は実施例1と同様の工程を経て、高熱伝導性フィルムを作製した。
実施例1と同様の材料を使用し膜厚25μmの樹脂組成物層を作製した。
ビスフェノールF型エポキシ樹脂(エポキシ当量160、東都化成株式会社製、商品名「YD−8170C」)30質量部、クレゾールノボラック型エポキシ樹脂(エポキシ当量210、東都化成株式会社製、商品名「YDCN−700−10」)10質量部、フェノールノボラック樹脂(大日本インキ化学工業株式会社製、商品名「プライオーフェンLF2882」)27質量部、エポキシ基含有アクリル系共重合体(帝国化学産業株式会社製、商品名「HTR−860P−3」)28質量部、イミダゾール系硬化促進剤(四国化成工業株式会社製、商品名「キュアゾール2PZ−CN」)0.1質量部、シリカフィラー(アドマファイン株式会社製、商品名「SO−C2」(比重:2.2g/cm3))60質量部、シランカップリング剤(日本ユニカー株式会社製、商品名「A−189」)0.25質量部、及びシランカップリング剤(日本ユニカー株式会社製、商品名「A−1160」)0.5質量部を含む混合物に、シクロヘキサノンを加えて撹拌混合し、真空脱気して接着剤ワニスを得た。この接着剤ワニスを、厚さ50μmの離型処理したポリエチレンテレフタレートフィルム上に塗布し、90℃10分間、120℃で5分間加熱乾燥し、膜厚25μmの樹脂組成物層を得た。
比較例2と同様の材料を使用し、シリカフィラーの配合量を95質量部に変更した以外は比較例2と同様にして膜厚25μmの樹脂組成物層を得た。
実施例1〜3及び比較例1〜3で得た樹脂組成物層の熱伝導率を、レーザーフラッシュ法を用いて測定した。その結果を表1に示す。
実施例1〜3で得た高熱伝導性フィルムの熱拡散率、及び比較例1〜3で得た樹脂組成物層の熱拡散率を、レーザーフラッシュ法を用いて測定した。その結果を表1に示す。
上記実施例1〜3の高熱伝導性フィルム、及び比較例1〜3の樹脂組成物層をそれぞれ半導体ウェハに80℃のヒートステージ上で加熱し貼り合せた(以下、高熱伝導性フィルム及び樹脂組成物層を「接着層」という)。ポリエチレンテレフタレートフィルムを剥離した後に、接着層を介して半導体ウェハを市販の紫外線硬化型ダイシングテープ(古河電工(株)製、商品名:UC−334 EP−110)に貼り合せた。このダイシングテープは基材上に粘着層が形成されたものであり、貼り合わせの際には、粘着層と接着層とが接合するようにした。続いて、ダイサーを用いて半導体ウェハ及び接着層をダイシングした後、ダイシングテープの基材側から紫外線を照射(500J/cm2)して接着層と粘着層との間を離間させることにより、接着層付き半導体素子を得た。
続いて、各サンプルに対して、吸湿処理(85℃、85%RH、168時間)後に、はんだのリフロー処理(265℃、3回)を施した後に、接着層が有機基板から剥離しているか否かを評価した。結果を表1に示す。表1中、「○」はボイド又は剥離が確認されなかったことを示し、「×」はボイド又は剥離が確認されたことを示す。
Claims (7)
- 金属箔と、該金属箔の両面に設けられた、熱伝導率が0.5W/m・K以下であり、厚みが10μm以下である樹脂組成物層と、を備える、半導体素子用高熱伝導性接着フィルム。
- レーザーフラッシュ法による熱拡散率が0.5m2/s以上である、請求項1記載の半導体素子用高熱伝導性接着フィルム。
- 前記樹脂組成物層の厚みが7μm以下である、請求項1又は2に記載の半導体素子用高熱伝導性接着フィルム。
- 前記樹脂組成物層の厚みが5μm以下である、請求項1又は2に記載の半導体素子用高熱伝導性接着フィルム。
- 前記半導体素子用高熱伝導性接着フィルムの総厚が50μm以下である、請求項1〜4のいずれか一項に記載の半導体素子用高熱伝導性接着フィルム。
- 前記半導体素子用高熱伝導性接着フィルムの総厚が45μm以下である、請求項1〜4のいずれか一項に記載の半導体素子用高熱伝導性接着フィルム。
- 前記半導体素子用高熱伝導性接着フィルムの総厚が40μm以下である、請求項1〜4のいずれか一項に記載の半導体素子用高熱伝導性接着フィルム。
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