JP6140809B2 - 炭化ホウ素高重合ポリマー繊維 - Google Patents
炭化ホウ素高重合ポリマー繊維 Download PDFInfo
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- JP6140809B2 JP6140809B2 JP2015506081A JP2015506081A JP6140809B2 JP 6140809 B2 JP6140809 B2 JP 6140809B2 JP 2015506081 A JP2015506081 A JP 2015506081A JP 2015506081 A JP2015506081 A JP 2015506081A JP 6140809 B2 JP6140809 B2 JP 6140809B2
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- boron carbide
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- 229910052580 B4C Inorganic materials 0.000 title claims description 33
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 title claims description 33
- 239000000835 fiber Substances 0.000 title description 9
- 229920005594 polymer fiber Polymers 0.000 claims description 16
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 11
- 239000004698 Polyethylene Substances 0.000 claims description 10
- 239000003963 antioxidant agent Substances 0.000 claims description 10
- 230000003078 antioxidant effect Effects 0.000 claims description 10
- 239000003054 catalyst Substances 0.000 claims description 10
- 239000000839 emulsion Substances 0.000 claims description 10
- -1 polyethylene Polymers 0.000 claims description 10
- 229920000573 polyethylene Polymers 0.000 claims description 10
- 239000002994 raw material Substances 0.000 claims description 9
- 239000012535 impurity Substances 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 5
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 239000002243 precursor Substances 0.000 claims description 4
- WJKHJLXJJJATHN-UHFFFAOYSA-N triflic anhydride Chemical group FC(F)(F)S(=O)(=O)OS(=O)(=O)C(F)(F)F WJKHJLXJJJATHN-UHFFFAOYSA-N 0.000 claims description 4
- IRFSXVIRXMYULF-UHFFFAOYSA-N 1,2-dihydroquinoline Chemical compound C1=CC=C2C=CCNC2=C1 IRFSXVIRXMYULF-UHFFFAOYSA-N 0.000 claims description 2
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 claims description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 229920000592 inorganic polymer Polymers 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- 238000009987 spinning Methods 0.000 claims description 2
- 238000004381 surface treatment Methods 0.000 claims description 2
- PPWPWBNSKBDSPK-UHFFFAOYSA-N [B].[C] Chemical compound [B].[C] PPWPWBNSKBDSPK-UHFFFAOYSA-N 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 230000007123 defense Effects 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229920006253 high performance fiber Polymers 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/62227—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products obtaining fibres
- C04B35/62272—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products obtaining fibres based on non-oxide ceramics
- C04B35/62277—Fibres based on carbides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/632—Organic additives
- C04B35/634—Polymers
- C04B35/63404—Polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B35/63408—Polyalkenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3437—Six-membered rings condensed with carbocyclic rings
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F1/00—Shielding characterised by the composition of the materials
- G21F1/02—Selection of uniform shielding materials
- G21F1/10—Organic substances; Dispersions in organic carriers
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F3/00—Shielding characterised by its physical form, e.g. granules, or shape of the material
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/38—Non-oxide ceramic constituents or additives
- C04B2235/3817—Carbides
- C04B2235/3821—Boron carbides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2101/00—Inorganic fibres
- D10B2101/10—Inorganic fibres based on non-oxides other than metals
- D10B2101/14—Carbides; Nitrides; Silicides; Borides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/02—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
- D10B2321/021—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polyethylene
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Ceramic Engineering (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- High Energy & Nuclear Physics (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Nanotechnology (AREA)
- Mechanical Engineering (AREA)
- Inorganic Fibers (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Artificial Filaments (AREA)
Description
炭化ホウ素:50〜60部、
質量濃度40%〜50%の高いポリエチレンエマルジョン:150〜193部、
質量濃度37%の塩酸:116部、
酸化防止剤:3〜5部、
触媒:7部
という重量部の原料から調製される。
前記炭化ホウ素は炭化ホウ素のw14、w20、w28、w40から選ばれる一つである。
前記高重合ポリエチレンエマルジョンはポリエチレンエマルジョンにおけるHA-soft80、GFN、85-CDITの中から選ばれる一つである。
前記酸化防止剤は酸化防止剤におけるジフェニルアミン、P-フェニレンジアミンとジヒドロキノリン等化合物及びその誘導体またはポリマーの中から選ばれるいずれか一つである。
前記触媒は触媒であるトリフルオロメタンスルホン酸無水物である。
本発明は新材料である炭化ホウ素高重合ポリマー繊維の作成方法をさらに提供し、上記重量部の原料を使用して作成し、以下の手順を含む。
1)炭化ホウ素を塩酸に入れて90〜120分間で浸漬(ソーク)し、不純物を除去し、
2)不純物が除去され、且つ乾燥させられた炭化ホウ素を2500〜2800℃の高温高圧溶解炉に入れて溶融させ、得られた炭化ホウ素溶融液体を耐高温紡糸炉内で処理して炭化ホウ素前駆体を作製し、
3)酸化防止剤を含む高重合ポリエチレンエマルジョンに触媒を入れ、炭化ホウ素前駆体を入れ、15〜30大気圧下で、無機高分子ポリマー、即ち炭化ホウ素高重合ポリマー繊維の最初の生成物を作成し、最初の生成物を水酸化カルシウム溶液を用いて表面処理を行い、不純物を除去し、且つ乾燥させた後、最終的にこの炭化ホウ素高重合ポリマー繊維が得られる。
Claims (7)
- 炭化ホウ素高重合ポリマー繊維を作製するために必要とされる原料は炭化ホウ素、高重合ポリエチレンエマルジョン、塩酸、酸化防止剤、触媒であることを特徴とする炭化ホウ素高重合ポリマー繊維。
- 炭化ホウ素高重合ポリマー繊維を作製するために必要とされる原料の重量部は、
炭素ホウ素:50〜60重量部、
濃度40%〜50%の高重合ポリエチレンエマルジョン:150〜193重量部、
濃度37%の塩酸:116重量部、
酸化防止剤:3〜5重量部、
触媒:7重量部
である請求項1に記載の炭化ホウ素高重合ポリマー繊維。 - 前記炭化ホウ素は炭化ホウ素のw14、w20、w28、w40の中から選ばれる一つである請求項1または2に記載の原料。
- 前記高重合ポリエチレンエマルジョンは、ポリエチレンエマルジョンにおけるHA〜soft80、GFN、85〜CDITの中から選ばれる一つである請求項1または2に記載の原料。
- 前記酸化防止剤は酸化防止剤におけるジフェニルアミン、P-フェニレンジアミンとジヒドロキノリン等化合物及びその誘導体またはポリマーの中から選ばれるいずれか一つである請求項1または2に記載の原料。
- 前記触媒は触媒におけるトリフルオロメタンスルホン酸無水物である請求項1または2に記載の原料。
- 1)炭化ホウ素を塩酸に入れて90〜120分間でソークし、不純物を除去し、
2)不純物が除去され、且つ乾燥させられた炭化ホウ素を2500〜2800℃の高温高圧溶解炉に入れて溶融させ、得られた炭化ホウ素溶融液体を耐高温紡糸炉内で処理して炭化ホウ素前駆体を作製し、
3)酸化防止剤を含む高重合ポリエチレンエマルジョンに触媒を入れ、炭化ホウ素前駆体を入れ、15〜30大気圧下で、無機高分子ポリマー、即ち炭化ホウ素高重合ポリマー繊維の最初の生成物を作成し、最初生成物を水酸化カルシウム溶液を通じて表面処理を行い、不純物を除去し、且つ乾燥させた後、最終的にこの炭化ホウ素高重合ポリマー繊維が得られる
という手順を含むであることを特徴とする新材料である炭化ホウ素高重合ポリマー繊維の製造方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2012101087018A CN102644131B (zh) | 2012-04-16 | 2012-04-16 | 碳化硼高聚纤维 |
CN201210108701.8 | 2012-04-16 | ||
PCT/CN2013/071485 WO2013155891A1 (zh) | 2012-04-16 | 2013-02-07 | 碳化硼高聚纤维 |
Publications (2)
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JP2015517037A JP2015517037A (ja) | 2015-06-18 |
JP6140809B2 true JP6140809B2 (ja) | 2017-05-31 |
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JP2015506081A Active JP6140809B2 (ja) | 2012-04-16 | 2013-02-07 | 炭化ホウ素高重合ポリマー繊維 |
Country Status (6)
Country | Link |
---|---|
US (1) | US9187618B2 (ja) |
EP (1) | EP2840171B1 (ja) |
JP (1) | JP6140809B2 (ja) |
KR (1) | KR20140147892A (ja) |
CN (1) | CN102644131B (ja) |
WO (1) | WO2013155891A1 (ja) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104591737A (zh) * | 2014-12-31 | 2015-05-06 | 东莞市高能磁电技术有限公司 | 碳化硼材料及其制造方法 |
CN107160789A (zh) * | 2017-04-06 | 2017-09-15 | 江阴中达软塑新材料股份有限公司 | 一种药用包装专用薄膜 |
KR20200019068A (ko) | 2018-08-13 | 2020-02-21 | 에스케이씨솔믹스 주식회사 | 탄화붕소 소결체 및 이를 포함하는 식각장치 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3971840A (en) * | 1973-03-27 | 1976-07-27 | The Carborundum Company | Production of high strength carbide fibers by heat treatment |
US4321298A (en) * | 1980-02-26 | 1982-03-23 | Hitco | Carbon fabrics sequentially resin coated with (1) a metal-containing composition and (2) a boron-containing composition are laminated and carbonized |
JPS62131065A (ja) | 1985-12-03 | 1987-06-13 | Idemitsu Kosan Co Ltd | 高分子正温度特性組成物 |
US4908340A (en) * | 1987-07-16 | 1990-03-13 | The Standard Oil Company | Non-oxide sintered ceramic fibers |
US7476889B2 (en) * | 1998-12-07 | 2009-01-13 | Meridian Research And Development | Radiation detectable and protective articles |
KR20080107850A (ko) | 2007-06-08 | 2008-12-11 | 건국대학교 산학협력단 | 볼탄 방어용 복합 방탄 헬멧 |
CN102066247B (zh) * | 2008-06-18 | 2014-02-12 | 高级金属陶瓷有限公司 | 碳化硼陶瓷纤维 |
CN101791859A (zh) | 2009-12-10 | 2010-08-04 | 江苏金波新材料科技有限公司 | 超高分子量聚乙烯抗辐射板材的制造方法 |
-
2012
- 2012-04-16 CN CN2012101087018A patent/CN102644131B/zh not_active Expired - Fee Related
-
2013
- 2013-02-07 KR KR20147032011A patent/KR20140147892A/ko not_active Application Discontinuation
- 2013-02-07 WO PCT/CN2013/071485 patent/WO2013155891A1/zh active Application Filing
- 2013-02-07 JP JP2015506081A patent/JP6140809B2/ja active Active
- 2013-02-07 EP EP13778425.2A patent/EP2840171B1/en not_active Not-in-force
- 2013-02-07 US US14/394,970 patent/US9187618B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US9187618B2 (en) | 2015-11-17 |
EP2840171A1 (en) | 2015-02-25 |
CN102644131A (zh) | 2012-08-22 |
WO2013155891A1 (zh) | 2013-10-24 |
CN102644131B (zh) | 2013-12-04 |
EP2840171A4 (en) | 2015-12-23 |
US20150126649A1 (en) | 2015-05-07 |
EP2840171B1 (en) | 2017-09-27 |
KR20140147892A (ko) | 2014-12-30 |
JP2015517037A (ja) | 2015-06-18 |
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