JP6113152B2 - シリコンウェハにおいて少数キャリア寿命劣化を抑制する方法 - Google Patents
シリコンウェハにおいて少数キャリア寿命劣化を抑制する方法 Download PDFInfo
- Publication number
- JP6113152B2 JP6113152B2 JP2014513752A JP2014513752A JP6113152B2 JP 6113152 B2 JP6113152 B2 JP 6113152B2 JP 2014513752 A JP2014513752 A JP 2014513752A JP 2014513752 A JP2014513752 A JP 2014513752A JP 6113152 B2 JP6113152 B2 JP 6113152B2
- Authority
- JP
- Japan
- Prior art keywords
- wafer
- less
- silicon wafer
- degradation
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims description 93
- 230000015556 catabolic process Effects 0.000 title claims description 61
- 238000006731 degradation reaction Methods 0.000 title claims description 58
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title claims description 40
- 229910052710 silicon Inorganic materials 0.000 title claims description 40
- 239000010703 silicon Substances 0.000 title claims description 40
- 235000012431 wafers Nutrition 0.000 title description 111
- 238000001816 cooling Methods 0.000 claims description 59
- 230000007547 defect Effects 0.000 claims description 47
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 38
- 229910052796 boron Inorganic materials 0.000 claims description 26
- 238000009792 diffusion process Methods 0.000 claims description 22
- 239000002800 charge carrier Substances 0.000 claims description 20
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 16
- 238000010438 heat treatment Methods 0.000 claims description 16
- 239000001301 oxygen Substances 0.000 claims description 16
- 229910052760 oxygen Inorganic materials 0.000 claims description 16
- 239000002019 doping agent Substances 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 239000000539 dimer Substances 0.000 claims description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 7
- 230000002829 reductive effect Effects 0.000 claims description 7
- 229910021421 monocrystalline silicon Inorganic materials 0.000 claims description 6
- 230000001678 irradiating effect Effects 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052733 gallium Inorganic materials 0.000 claims description 3
- 230000008569 process Effects 0.000 description 14
- 238000000137 annealing Methods 0.000 description 11
- 239000000047 product Substances 0.000 description 10
- 239000002244 precipitate Substances 0.000 description 9
- 230000001629 suppression Effects 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- 230000006866 deterioration Effects 0.000 description 8
- 238000011084 recovery Methods 0.000 description 8
- 239000000969 carrier Substances 0.000 description 5
- 238000009826 distribution Methods 0.000 description 4
- 230000002401 inhibitory effect Effects 0.000 description 4
- 230000006911 nucleation Effects 0.000 description 3
- 238000010899 nucleation Methods 0.000 description 3
- 238000004151 rapid thermal annealing Methods 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 230000009849 deactivation Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000000593 degrading effect Effects 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 2
- 230000006798 recombination Effects 0.000 description 2
- 238000005215 recombination Methods 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001638 boron Chemical class 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000001010 compromised effect Effects 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000002513 implantation Methods 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052756 noble gas Inorganic materials 0.000 description 1
- 150000002835 noble gases Chemical class 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F71/00—Manufacture or treatment of devices covered by this subclass
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D62/00—Semiconductor bodies, or regions thereof, of devices having potential barriers
- H10D62/80—Semiconductor bodies, or regions thereof, of devices having potential barriers characterised by the materials
- H10D62/83—Semiconductor bodies, or regions thereof, of devices having potential barriers characterised by the materials being Group IV materials, e.g. B-doped Si or undoped Ge
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/322—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to modify their internal properties, e.g. to produce internal imperfections
- H01L21/3221—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to modify their internal properties, e.g. to produce internal imperfections of silicon bodies, e.g. for gettering
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F10/00—Individual photovoltaic cells, e.g. solar cells
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F71/00—Manufacture or treatment of devices covered by this subclass
- H10F71/121—The active layers comprising only Group IV materials
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F71/00—Manufacture or treatment of devices covered by this subclass
- H10F71/128—Annealing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/547—Monocrystalline silicon PV cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
- Photovoltaic Devices (AREA)
- Testing Or Measuring Of Semiconductors Or The Like (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161493119P | 2011-06-03 | 2011-06-03 | |
| US61/493,119 | 2011-06-03 | ||
| US13/486,463 | 2012-06-01 | ||
| PCT/US2012/040492 WO2012167104A1 (en) | 2011-06-03 | 2012-06-01 | Processes for suppressing minority carrier lifetime degradation in silicon wafers |
| US13/486,463 US8969119B2 (en) | 2011-06-03 | 2012-06-01 | Processes for suppressing minority carrier lifetime degradation in silicon wafers |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2014526135A JP2014526135A (ja) | 2014-10-02 |
| JP2014526135A5 JP2014526135A5 (enExample) | 2017-01-26 |
| JP6113152B2 true JP6113152B2 (ja) | 2017-04-12 |
Family
ID=46229958
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014513752A Expired - Fee Related JP6113152B2 (ja) | 2011-06-03 | 2012-06-01 | シリコンウェハにおいて少数キャリア寿命劣化を抑制する方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US8969119B2 (enExample) |
| EP (1) | EP2715805B1 (enExample) |
| JP (1) | JP6113152B2 (enExample) |
| KR (1) | KR20140041614A (enExample) |
| CN (1) | CN103582955B (enExample) |
| MY (1) | MY181635A (enExample) |
| SG (1) | SG194904A1 (enExample) |
| WO (1) | WO2012167104A1 (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9634098B2 (en) | 2013-06-11 | 2017-04-25 | SunEdison Semiconductor Ltd. (UEN201334164H) | Oxygen precipitation in heavily doped silicon wafers sliced from ingots grown by the Czochralski method |
| CN105340085B (zh) * | 2013-06-26 | 2018-07-06 | 康斯坦茨大学 | 用于生产具有稳定效率的光伏元件的方法和设备 |
| CN103681964A (zh) * | 2013-11-29 | 2014-03-26 | 奥特斯维能源(太仓)有限公司 | 太阳能电池片效率衰减后恢复方法 |
| WO2015186288A1 (ja) * | 2014-06-02 | 2015-12-10 | 株式会社Sumco | シリコンウェーハおよびその製造方法 |
| KR101569415B1 (ko) * | 2014-06-09 | 2015-11-16 | 엘지전자 주식회사 | 태양 전지의 제조 방법 |
| JP5830147B1 (ja) * | 2014-09-04 | 2015-12-09 | 信越化学工業株式会社 | 太陽電池及び太陽電池の製造方法 |
| KR20180058750A (ko) * | 2015-09-23 | 2018-06-01 | 센트로테에름 인터내셔널 아게 | 반도체 기판들 내의 결함들을 패시베이팅하기 위한 방법들 및 장치 |
| EP3208366A1 (en) * | 2016-02-16 | 2017-08-23 | Siltronic AG | Fz silicon and method to prepare fz silicon |
| CN107369616B (zh) * | 2017-07-07 | 2021-03-12 | 苏州阿特斯阳光电力科技有限公司 | 用于处理半导体基板的方法、得到的半导体基板及其用途 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58197717A (ja) * | 1982-05-13 | 1983-11-17 | Toshiba Corp | 半導体装置の製造方法 |
| WO2001086732A1 (en) * | 2000-05-05 | 2001-11-15 | Unisearch Ltd. | Low area metal contacts for photovoltaic devices |
| JP4607304B2 (ja) * | 2000-09-26 | 2011-01-05 | 信越半導体株式会社 | 太陽電池用シリコン単結晶及び太陽電池用シリコン単結晶ウエーハ並びにその製造方法 |
| US7084048B2 (en) * | 2004-05-07 | 2006-08-01 | Memc Electronic Materials, Inc. | Process for metallic contamination reduction in silicon wafers |
| DE102006012920B3 (de) | 2006-03-21 | 2008-01-24 | Universität Konstanz | Verfahren zum Herstellen eines Photovoltaikelements mit stabilisiertem Wirkungsgrad |
| CN100536177C (zh) * | 2008-01-29 | 2009-09-02 | 江阴浚鑫科技有限公司 | 晶体硅太阳能电池的热处理方法 |
| FR2929755B1 (fr) * | 2008-04-03 | 2011-04-22 | Commissariat Energie Atomique | Procede de traitement d'un substrat semi-conducteur par activation thermique d'elements legers |
| US7943514B2 (en) * | 2009-09-03 | 2011-05-17 | Texas Instruments Incorporated | Integrated circuits having TSVs including metal gettering dielectric liners |
| US20120222741A1 (en) * | 2009-09-18 | 2012-09-06 | L'air Liquide, Societe Anonyme Pour I'etude Et I'exploitation Des Procedes Georges Claude | Solar cell with improved performance |
| US9105786B2 (en) * | 2011-04-18 | 2015-08-11 | Cisco Technology, Inc. | Thermal treatment of silicon wafers useful for photovoltaic applications |
-
2012
- 2012-06-01 EP EP12726561.9A patent/EP2715805B1/en not_active Not-in-force
- 2012-06-01 US US13/486,463 patent/US8969119B2/en not_active Expired - Fee Related
- 2012-06-01 MY MYPI2013004357A patent/MY181635A/en unknown
- 2012-06-01 JP JP2014513752A patent/JP6113152B2/ja not_active Expired - Fee Related
- 2012-06-01 CN CN201280027376.0A patent/CN103582955B/zh not_active Expired - Fee Related
- 2012-06-01 WO PCT/US2012/040492 patent/WO2012167104A1/en not_active Ceased
- 2012-06-01 SG SG2013083514A patent/SG194904A1/en unknown
- 2012-06-01 KR KR20137035025A patent/KR20140041614A/ko not_active Ceased
-
2015
- 2015-01-14 US US14/596,269 patent/US9142616B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP2715805A1 (en) | 2014-04-09 |
| WO2012167104A1 (en) | 2012-12-06 |
| SG194904A1 (en) | 2013-12-30 |
| MY181635A (en) | 2020-12-30 |
| WO2012167104A4 (en) | 2013-02-28 |
| CN103582955A (zh) | 2014-02-12 |
| JP2014526135A (ja) | 2014-10-02 |
| US20150123248A1 (en) | 2015-05-07 |
| US20130102129A1 (en) | 2013-04-25 |
| EP2715805B1 (en) | 2016-04-06 |
| US8969119B2 (en) | 2015-03-03 |
| KR20140041614A (ko) | 2014-04-04 |
| CN103582955B (zh) | 2016-06-29 |
| US9142616B2 (en) | 2015-09-22 |
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