JP6050897B2 - ラベルおよびそのラベルの製造方法 - Google Patents
ラベルおよびそのラベルの製造方法 Download PDFInfo
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- JP6050897B2 JP6050897B2 JP2015545244A JP2015545244A JP6050897B2 JP 6050897 B2 JP6050897 B2 JP 6050897B2 JP 2015545244 A JP2015545244 A JP 2015545244A JP 2015545244 A JP2015545244 A JP 2015545244A JP 6050897 B2 JP6050897 B2 JP 6050897B2
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- colored layer
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- crosslinking agent
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- 125000000524 functional group Chemical group 0.000 claims description 19
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- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 4
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- YGANSGVIUGARFR-UHFFFAOYSA-N dipotassium dioxosilane oxo(oxoalumanyloxy)alumane oxygen(2-) Chemical compound [O--].[K+].[K+].O=[Si]=O.O=[Al]O[Al]=O YGANSGVIUGARFR-UHFFFAOYSA-N 0.000 description 3
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- 125000005628 tolylene group Chemical group 0.000 description 1
- DFJSZWHUOKADCX-UHFFFAOYSA-N triisocyanato(methyl)silane Chemical compound O=C=N[Si](C)(N=C=O)N=C=O DFJSZWHUOKADCX-UHFFFAOYSA-N 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
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- 229910052727 yttrium Inorganic materials 0.000 description 1
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- 229910052725 zinc Inorganic materials 0.000 description 1
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Description
標示層形成工程P1は、標示層30を形成する工程である。図4は、標示層形成工程P1の様子を示す図である。図4に示すように、本工程では第1段階として基材40の一面上に所定の目印を表すパターンとなるように樹脂塗料50を塗工する。
第1着色層形成工程P2は、第1着色層10を形成する工程である。図5に示すように、本工程では、第1段階として、基材40の一面および標示層30の表面上に、樹脂塗料60を塗工する。
第2着色層形成工程P3は、第2着色層20を形成する工程である。図6は、第2着色層形成工程P3の様子を示す図である。図6に示すように、本工程では、第1段階として、第1着色層形成工程P2で形成した第1着色層10の一面上に樹脂塗料70を塗工する。第2段階として、樹脂塗料70を加熱硬化し第2着色層20を形成する。
剥離工程P4は、標示層30および第1着色層10から基材40を剥離する工程である。図7は、剥離工程P4の様子を示す図である。
<調製1>
アクリル系樹脂KP−2341(ニッセツ(株)製)50重量部、アクリル系樹脂Hi−S SP2100U4(日本カーバイド工業(株)製)50重量部、メラミン系架橋剤MS−11((株)三和ケミカル製)18重量部、リン酸エステルCT−198((株)三和ケミカル製)0.3重量部、着色剤FPGS−5910B(大日精化工業(株)製)15重量部を混合し、第1着色層を形成するための樹脂塗料を調製した。
アクリル系樹脂Hi−S SP2100U4(日本カーバイド工業(株)製)50重量部、着色剤FPGS−5010W(大日精化工業(株)製)100重量部、イソシアネート系架橋剤コロネートHK(日本ポリウレタン工業(株)製)16重量部、PTMG−1000M(三洋化成工業(株)製)5重量部を混合し、第2着色層を形成するための樹脂塗料を調製した。
アクリル・エポキシ系樹脂と着色剤を含有するインキMA31 OPニス(富士インキ工業(株)製)100重量部とイソシアネート系架橋剤NX ハードナー(富士インキ工業(株)製)10重量部を混合し、標示層を形成するための樹脂塗料を調製した。
基材としてのPETフィルム(帝人デュポンフィルム(株)製S75)に、調製3の樹脂塗料を用いて、標示層の露出面の面積割合が、ラベルの一方の面の表面積に対して0.8%になるように文字や図柄などのパターンをグラビア印刷により印刷し、厚み2マイクロメートルの標示層を得た。続いて、基材の一部と標示層の上に調製1の樹脂塗料を塗工し、150℃で3分間加熱し、厚み15マイクロメートルの第1着色層を形成した。
調製3の樹脂塗料を用いて、標示層の露出面の面積割合が、ラベルの一方の面の表面積に対して1%になるように印刷した以外はすべて実施例1と同様にラベルを作製した。
調製3の樹脂塗料を用いて、標示層の露出面の面積割合が、ラベルの一方の面の表面積に対して11%になるように印刷した以外はすべて実施例1と同様にラベルを作製した。
調製3の樹脂塗料を用いて、標示層の露出面の面積割合が、ラベルの一方の面の表面積に対して25%になるように印刷した以外はすべて実施例1と同様にラベルを作製した。
調製3の樹脂塗料を用いて、標示層の露出面の面積割合が、ラベルの一方の面の表面積に対して40%になるように印刷した以外はすべて実施例1と同様にラベルを作製した。
調製3の樹脂塗料を用いて、標示層の露出面の面積割合が、ラベルの一方の面の表面積に対して50%になるように印刷した以外はすべて実施例1と同様にラベルを作製した。
調製3の樹脂塗料を用いて、標示層の露出面の面積割合が、ラベルの一方の面の表面積に対して75%になるように印刷した以外はすべて実施例1と同様にラベルを作製した。
調製1のメラミン系架橋剤MS−11をベンゾグアナミン系架橋剤BL−60((株)三和ケミカル製)に置き換え、調製3の樹脂塗料を用いて、標示層の露出面の面積割合が、ラベルの一方の面の表面積に対して11%になるように印刷し、実施例1と同様にラベルを作製した。
調製1のメラミン系架橋剤MS−11を尿素系架橋剤MX−202((株)三和ケミカル製)に置き換え、調製3の樹脂塗料を用いて、標示層の露出面の面積割合が、ラベルの一方の面の表面積に対して11%になるように印刷し、実施例1と同様にラベルを作製した。
調製1のメラミン系架橋剤MS−11をイソシアネート系架橋剤コロネートHK(日本ポリウレタン工業(株)製)に置き換え、調製3の樹脂塗料を用いて、標示層の露出面の面積割合が、ラベルの一方の面の表面積に対して11%になるように印刷し、実施例1と同様にラベルを作製した。
Srv={(Lpv−Lav)/Lpv}×100 ・・・(1)
Srh={(Lph−Lah)/Lph}×100 ・・・(2)
Sr={(Srv2+Srh2)1/2}/2 ・・・(3)
そして、上記(3)式で得られた3枚のサンプルの収縮率を平均して、標示層サンプルの硬化収縮率、及び、それぞれの第1着色層サンプルの硬化収縮率とした。その結果を表1に示す。
10・・・第1着色層
20・・・第2着色層
30・・・標示層
40・・・基材
50,60,70・・・樹脂塗料
P1・・・標示層形成工程
P2・・・第1着色層形成工程
P3・・・第2着色層形成工程
P4・・・剥離工程
80・・・除去部
L・・・レーザー
Claims (6)
- 第1着色層と、
第1着色層の色とは異なる色の第2着色層と、
第1着色層および第2着色層の色とは異なる色の標示層と
を有し、
標示層は第1着色層の一方の面に露出面を有するように嵌設し、第2着色層は第1着色層の他方の面に積層し、
第1着色層の硬化収縮率は、標示層の硬化収縮率よりも大きい
ことを特徴とするラベル。 - 標示層の露出面の面積割合が、ラベルの一方の面の表面積に対して1%以上50%以下である
ことを特徴とする請求項1に記載のラベル。 - 標示層の露出面の面積割合が、ラベルの一方の面の表面積に対して1%以上40%以下である
ことを特徴とする請求項2に記載のラベル。 - 第1着色層に用いる架橋剤が、標示層が含有する樹脂の官能基と反応するものである
ことを特徴とする請求項1から請求項3のいずれか1項に記載のラベル。 - 第2着色層に用いる架橋剤が、第1着色層が含有する樹脂の官能基、及び標示層が含有する樹脂の官能基と反応するものである
ことを特徴とする請求項1〜請求項4いずれか1項に記載のラベル。 - 基材の一面上に樹脂塗料を配した後に加熱して標示層を形成する標示層形成工程と、
標示層形成工程で用いた樹脂塗料と異なる色の樹脂塗料を、基材の一面および標示層の表面上に配した後に加熱して第1着色層を形成する第1着色層形成工程と、
標示層形成工程で用いた樹脂塗料及び第1着色層形成工程で用いた樹脂塗料と異なる色の樹脂塗料を、第1着色層の表面上に配した後に加熱して第2着色層を形成する第2着色層形成工程と、
標示層および第1着色層から基材を剥離する剥離工程と
を備え、
第1着色層の硬化収縮率が、標示層の硬化収縮率より大きい
ことを特徴とするラベルの製造方法。
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KR102048422B1 (ko) * | 2018-04-25 | 2019-11-25 | 노예솔 | 부품점검 및 관리용 식별표시 폴리머 라벨 및 그를 이용한 식별표시방법 |
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WO2008076880A1 (en) * | 2006-12-15 | 2008-06-26 | Brady Worldwide, Inc. | Tamper indicating labels with edge ingress solvent-indicating feature |
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JP2003108003A (ja) * | 2001-09-28 | 2003-04-11 | Nissha Printing Co Ltd | レーザーエッチングラベルの製造方法、レーザーエッチング用ラベル |
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CN109233654A (zh) * | 2017-06-05 | 2019-01-18 | 3M创新有限公司 | 带有客制化水印的可激光标记物及其制备方法 |
CN109233654B (zh) * | 2017-06-05 | 2021-11-09 | 3M创新有限公司 | 带有客制化水印的可激光标记物及其制备方法 |
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WO2015064589A1 (ja) | 2015-05-07 |
JPWO2015064589A1 (ja) | 2017-03-09 |
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US20160263869A1 (en) | 2016-09-15 |
CN105723440A (zh) | 2016-06-29 |
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