JP6039646B2 - サンケア組成物、及び方法 - Google Patents
サンケア組成物、及び方法 Download PDFInfo
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- JP6039646B2 JP6039646B2 JP2014502729A JP2014502729A JP6039646B2 JP 6039646 B2 JP6039646 B2 JP 6039646B2 JP 2014502729 A JP2014502729 A JP 2014502729A JP 2014502729 A JP2014502729 A JP 2014502729A JP 6039646 B2 JP6039646 B2 JP 6039646B2
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- 239000000203 mixture Substances 0.000 title claims description 80
- 238000000034 method Methods 0.000 title description 6
- 239000000178 monomer Substances 0.000 claims description 117
- 229920000642 polymer Polymers 0.000 claims description 78
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 22
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 21
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 19
- 239000002253 acid Substances 0.000 claims description 15
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000011149 active material Substances 0.000 claims description 12
- 125000000524 functional group Chemical group 0.000 claims description 12
- 239000004408 titanium dioxide Substances 0.000 claims description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 9
- 239000011787 zinc oxide Substances 0.000 claims description 9
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 claims description 4
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 claims description 4
- 150000001336 alkenes Chemical class 0.000 claims description 4
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 4
- 150000001993 dienes Chemical class 0.000 claims description 4
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 3
- 229920000536 2-Acrylamido-2-methylpropane sulfonic acid Polymers 0.000 claims description 2
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 claims description 2
- WSSJONWNBBTCMG-UHFFFAOYSA-N 2-hydroxybenzoic acid (3,3,5-trimethylcyclohexyl) ester Chemical compound C1C(C)(C)CC(C)CC1OC(=O)C1=CC=CC=C1O WSSJONWNBBTCMG-UHFFFAOYSA-N 0.000 claims description 2
- FMRHJJZUHUTGKE-UHFFFAOYSA-N Ethylhexyl salicylate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1O FMRHJJZUHUTGKE-UHFFFAOYSA-N 0.000 claims description 2
- YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical compound CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 claims description 2
- XNEFYCZVKIDDMS-UHFFFAOYSA-N avobenzone Chemical compound C1=CC(OC)=CC=C1C(=O)CC(=O)C1=CC=C(C(C)(C)C)C=C1 XNEFYCZVKIDDMS-UHFFFAOYSA-N 0.000 claims description 2
- 229960005193 avobenzone Drugs 0.000 claims description 2
- 239000012965 benzophenone Substances 0.000 claims description 2
- 150000008366 benzophenones Chemical class 0.000 claims description 2
- 125000000649 benzylidene group Chemical group [H]C(=[*])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 2
- 229960004881 homosalate Drugs 0.000 claims description 2
- 229960001679 octinoxate Drugs 0.000 claims description 2
- 229960003921 octisalate Drugs 0.000 claims description 2
- FMJSMJQBSVNSBF-UHFFFAOYSA-N octocrylene Chemical group C=1C=CC=CC=1C(=C(C#N)C(=O)OCC(CC)CCCC)C1=CC=CC=C1 FMJSMJQBSVNSBF-UHFFFAOYSA-N 0.000 claims description 2
- 229960000601 octocrylene Drugs 0.000 claims description 2
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 claims description 2
- 229960001173 oxybenzone Drugs 0.000 claims description 2
- 150000003902 salicylic acid esters Chemical class 0.000 claims description 2
- 230000000475 sunscreen effect Effects 0.000 description 24
- 239000000516 sunscreening agent Substances 0.000 description 24
- -1 ethylene, ethylene Chemical class 0.000 description 21
- 229920002554 vinyl polymer Polymers 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 238000009472 formulation Methods 0.000 description 12
- 125000004432 carbon atom Chemical group C* 0.000 description 11
- 229910044991 metal oxide Inorganic materials 0.000 description 10
- 150000004706 metal oxides Chemical class 0.000 description 10
- 125000005250 alkyl acrylate group Chemical group 0.000 description 9
- 239000002245 particle Substances 0.000 description 9
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 9
- 125000000547 substituted alkyl group Chemical group 0.000 description 7
- 239000000975 dye Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000003205 fragrance Substances 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 4
- 125000002843 carboxylic acid group Chemical group 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- 239000003755 preservative agent Substances 0.000 description 4
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 3
- 125000005907 alkyl ester group Chemical group 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 239000003139 biocide Substances 0.000 description 3
- 239000006071 cream Substances 0.000 description 3
- 239000003974 emollient agent Substances 0.000 description 3
- 239000006210 lotion Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- 150000003440 styrenes Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000000077 insect repellent Substances 0.000 description 2
- 239000011859 microparticle Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000012860 organic pigment Substances 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 239000003380 propellant Substances 0.000 description 2
- 239000006254 rheological additive Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 125000000542 sulfonic acid group Chemical group 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 208000001840 Dandruff Diseases 0.000 description 1
- JDRSMPFHFNXQRB-CMTNHCDUSA-N Decyl beta-D-threo-hexopyranoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)C(O)[C@H](O)C1O JDRSMPFHFNXQRB-CMTNHCDUSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical class C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 239000004904 UV filter Substances 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 239000003619 algicide Substances 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 150000008064 anhydrides Chemical group 0.000 description 1
- 230000001166 anti-perspirative effect Effects 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000003213 antiperspirant Substances 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- UFVWHIGSVGIZRQ-UHFFFAOYSA-N bis(2-ethylhexyl) naphthalene-2,6-dicarboxylate Chemical compound C1=C(C(=O)OCC(CC)CCCC)C=CC2=CC(C(=O)OCC(CC)CCCC)=CC=C21 UFVWHIGSVGIZRQ-UHFFFAOYSA-N 0.000 description 1
- FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 125000003636 chemical group Chemical group 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 229940073499 decyl glucoside Drugs 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 229940031765 diethylhexyl 2,6-naphthalate Drugs 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 210000005069 ears Anatomy 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 238000000338 in vitro Methods 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical group O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000005641 methacryl group Chemical group 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 210000000214 mouth Anatomy 0.000 description 1
- 210000003928 nasal cavity Anatomy 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000001542 size-exclusion chromatography Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910021642 ultra pure water Inorganic materials 0.000 description 1
- 239000012498 ultrapure water Substances 0.000 description 1
- 238000002211 ultraviolet spectrum Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dermatology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
例示的なサンケア組成物は、質量/質量(質量%)に基づいて表1に詳述する構成成分を含む。
従来のサンケア組成物は、質量/質量(質量%)に基づいて表2に詳述する構成成分を含む。
実質的に例1〜2の手順に従って組成物を作り、SPF及び耐水性特性について試験した。このような組成物は耐水性の増強を与え、UV活物質分布を強化し、及び/又はSPF性能を高めた。
処方B、処方C、比較処方1、及び比較処方2を、実質的に例1〜2の手順に従って作り、接触角について試験した。
例示的なサンケア組成物、及び従来のサンケア組成物は、質量/質量(質量%)に基づいて表4に詳述する構成成分を含む。
以下、本発明の実施態様を列記する。
[項目1]
サンケア組成物であって、
(a)一つ以上の完全に可溶性のポリマーであって、重合単位として
(i)前記ポリマーの質量に基づいて30%〜75質量%の、1.490以上の屈折率を有する一つ以上のモノマー、
(ii)前記ポリマーの質量に基づいて1%〜30質量%の、一以上の酸官能性モノマー、及び
(iii)前記ポリマーの質量に基づいて5%〜69質量%の、一以上の更なるモノマーを含む、完全に可溶性のポリマーと、
(b)少なくとも一つのサンケア活物質と、
を含む、サンケア組成物。
[項目2]
前記サンケア活物質が、オクチルメトキシシンナメート、オクトクリレン、オクチサラート、オキシベンゾン、アボベンゾン、パラアミノ安息香酸、ホモサラート、二酸化チタン、酸化亜鉛、ベンゾフェノン類、ベンジリデン類、又はサリチラート類の少なくとも一つである、項目1に記載したサンケア組成物。
[項目3]
前記サンケア活物質が、少なくとも2つのサンケア活物質の混合物である、項目1に記載したサンケア組成物。
[項目4]
好ましくは、前記組成物が87より大きい接触角を有する、項目1に記載したサンケア組成物。
[項目5]
前記組成物がアルコールベースであり、ポリマー(a)がアルコールに可溶性である、項目1に記載したサンケア組成物。
[項目6]
モノマー(i)が一つ以上のビニル芳香族モノマーを含む、項目1に記載したサンケア組成物。
[項目7]
モノマー(iii)が、一つ以上のヒドロキシアルキル(メス)アクリレートを含む、項目1に記載したサンケア組成物。
[項目8]
少なくとも一つのシリコーンを更に含む、項目1に記載したサンケア組成物。
Claims (3)
- サンケア組成物であって、
(a)一つ以上の完全に可溶性のポリマーであって、重合単位として
(i−a)前記ポリマーの質量に基づいて30%〜75質量%の、1.490以上の屈折率を有する、スチレン、α―メチルスチレン、及びこれらの組合せからなる群から選択される一つ以上のモノマー、
(ii−a)前記ポリマーの質量に基づいて1%〜30質量%の、2―アクリルアミド―2―メチルプロパンスルホン酸、アクリル酸、メタクリル酸、及びこれらの組合せからなる群から選択される一以上の酸官能性モノマー、並びに
(iii−a)前記ポリマーの質量に基づいて5%〜69質量%の、オレフィン、ジエン、及び(メタ)アクリレートからなる群から選択される一以上のモノマー;又は
(i/ii−b)前記ポリマーの質量に基づいて31%〜95質量%の、1.490以上の屈折率を有し、少なくとも一つの酸官能基を有する、スチレンスルホン酸、置換スチレンスルホン酸、及びこれらの組合せからなる群から選択される一つ以上のモノマー、並びに
(iii−b)前記ポリマーの質量に基づいて5%〜69質量%の、オレフィン、ジエン、及び(メタ)アクリレートからなる群から選択される一以上のモノマー
を含む、完全に可溶性のポリマーと、
(b)少なくとも一つのサンケア活物質と、
を含み、
前記サンケア活物質が、オクチルメトキシシンナメート、オクトクリレン、オクチサラート、オキシベンゾン、アボベンゾン、パラアミノ安息香酸、ホモサラート、二酸化チタン、酸化亜鉛、ベンゾフェノン類、ベンジリデン類、又はサリチラート類の少なくとも一つであり、
前記組成物がアルコールベースであり、ポリマー(a)がアルコールに可溶性であり、前記組成物の合計質量に基づく使用濃度0.5〜7質量%において、結果として透明溶液になる、サンケア組成物。 - 前記サンケア活物質が、少なくとも2つのサンケア活物質の混合物である、請求項1に記載したサンケア組成物。
- 前記組成物が87より大きい接触角を有する、請求項1に記載したサンケア組成物。
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US201161470122P | 2011-03-31 | 2011-03-31 | |
US61/470,122 | 2011-03-31 | ||
PCT/US2012/030820 WO2012135265A2 (en) | 2011-03-31 | 2012-03-28 | Suncare compositions and methods |
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JP2014509649A JP2014509649A (ja) | 2014-04-21 |
JP2014509649A5 JP2014509649A5 (ja) | 2016-06-02 |
JP6039646B2 true JP6039646B2 (ja) | 2016-12-07 |
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US (1) | US20140017186A1 (ja) |
EP (2) | EP2670384B1 (ja) |
JP (1) | JP6039646B2 (ja) |
CN (1) | CN103458870B (ja) |
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US10463847B2 (en) * | 2015-06-11 | 2019-11-05 | Steadymed Ltd. | Infusion set |
US11185477B2 (en) | 2017-07-28 | 2021-11-30 | Dow Global Technologies Llc | SPF booster for use in alcohol base sunscreen formulations |
EP3658108A1 (en) | 2017-07-28 | 2020-06-03 | Dow Global Technologies LLC | Suncare compositions |
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---|---|---|---|---|
US4530973A (en) * | 1983-03-11 | 1985-07-23 | The Dow Chemical Company | Transparent impact resistant polymeric compositions and process for the preparation thereof |
US5223250A (en) | 1991-02-05 | 1993-06-29 | Sun Smart, Inc. | Visibly transparent UV sunblock cosmetic compositions |
WO1992013517A1 (en) | 1991-02-05 | 1992-08-20 | Sun Smart, Inc. | Visibly transparent uv sunblock agents and methods of making same |
US5204090A (en) * | 1991-05-30 | 1993-04-20 | Bristol Myers Squibb | Waterproof high-SPF sunscreen compositions |
FR2680684B1 (fr) | 1991-08-29 | 1993-11-12 | Oreal | Composition cosmetique filtrante comprenant un nanopigment d'oxyde metallique et un polymere filtre. |
GB9121153D0 (en) | 1991-10-04 | 1991-11-13 | Tioxide Chemicals Ltd | Method of preparing sunscreens |
DE4223464A1 (de) | 1992-07-16 | 1994-01-20 | Bayer Ag | Kosmetisches Sonnenschutzmittel |
GB9316437D0 (en) | 1993-08-06 | 1993-09-22 | Harcros Chemicals Uk Limited | Zinc oxide and a process for making it |
DE4327514A1 (de) * | 1993-08-17 | 1995-02-23 | Basf Ag | Wäßrige Copolymerisatdispersionen |
US5945090A (en) * | 1997-09-11 | 1999-08-31 | Randall Products International | Sunscreen preparation |
FR2779647B1 (fr) * | 1998-06-15 | 2000-08-04 | Oreal | Composition cosmetique contenant un polymere anionique et un terpolymere acrylique et utilisation de cette composition pour le traitement des matieres keratiniques |
AUPR040600A0 (en) * | 2000-09-27 | 2000-10-19 | Chemeq Ltd | Polymeric formulation |
GB0313432D0 (en) | 2003-06-11 | 2003-07-16 | Ici Plc | Particulate zinc oxide |
DE102004051541A1 (de) * | 2004-10-22 | 2006-05-04 | Basf Ag | Amphotere Ethylmethacrylat-Copolymere und deren Verwendung |
BRPI0517930A (pt) * | 2004-11-02 | 2008-10-21 | Dsm Ip Assets Bv | aditivo para preparações de protetor solar contra uv |
AU2006250914B2 (en) * | 2005-05-25 | 2012-03-01 | Chemisches Institut Schaefer Ag | Biocompatible polymers and co-polymers comprising amino acids in the side chain |
DE102007028497A1 (de) * | 2007-06-18 | 2008-12-24 | Beiersdorf Ag | Styrol/Acrylat-Copolymere in kosmetischen Sonnenschutzmitteln |
FR2921262B1 (fr) * | 2007-09-24 | 2009-11-13 | Oreal | Emulsion cosmetique de type huile dans eau |
CA2714416A1 (en) * | 2008-02-11 | 2009-08-20 | Playtex Products, Llc | Photoprotective compositions with glycol and styrene/acrylate copolymer |
EP2106784B1 (en) * | 2008-04-03 | 2015-04-22 | Rohm and Haas Company | Hair styling composition |
BRPI1006575A2 (pt) * | 2009-04-10 | 2016-02-10 | Oreal | composições de proteção contra raios uv e processo para proteção de um tecido queratinoso |
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- 2012-03-28 US US14/002,804 patent/US20140017186A1/en not_active Abandoned
- 2012-03-28 CN CN201280016439.2A patent/CN103458870B/zh active Active
- 2012-03-28 EP EP12712050.9A patent/EP2670384B1/en active Active
- 2012-03-28 WO PCT/US2012/030820 patent/WO2012135265A2/en active Application Filing
- 2012-03-28 EP EP17172777.9A patent/EP3238704A1/en not_active Withdrawn
- 2012-03-28 BR BR112013025056A patent/BR112013025056A2/pt not_active Application Discontinuation
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WO2012135265A2 (en) | 2012-10-04 |
CN103458870B (zh) | 2015-10-14 |
EP2670384A2 (en) | 2013-12-11 |
JP2014509649A (ja) | 2014-04-21 |
CN103458870A (zh) | 2013-12-18 |
BR112013025056A2 (pt) | 2016-08-23 |
US20140017186A1 (en) | 2014-01-16 |
WO2012135265A3 (en) | 2012-12-27 |
EP3238704A1 (en) | 2017-11-01 |
EP2670384B1 (en) | 2017-08-02 |
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