JP5968957B2 - 太陽電池モジュール用粘着シートおよび太陽電池モジュール - Google Patents
太陽電池モジュール用粘着シートおよび太陽電池モジュール Download PDFInfo
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- JP5968957B2 JP5968957B2 JP2014143336A JP2014143336A JP5968957B2 JP 5968957 B2 JP5968957 B2 JP 5968957B2 JP 2014143336 A JP2014143336 A JP 2014143336A JP 2014143336 A JP2014143336 A JP 2014143336A JP 5968957 B2 JP5968957 B2 JP 5968957B2
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- solar cell
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- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- JPPHEZSCZWYTOP-UHFFFAOYSA-N trimethoxysilylmethyl prop-2-enoate Chemical compound CO[Si](OC)(OC)COC(=O)C=C JPPHEZSCZWYTOP-UHFFFAOYSA-N 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/52—PV systems with concentrators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/546—Polycrystalline silicon PV cells
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- Photovoltaic Devices (AREA)
Description
(アクリル系ポリマーの調製)
アクリル酸ブチル95重量部およびアクリル酸5重量部からなるモノマー成分を重合することにより、アクリル系ポリマーを調製した。
アクリル系ポリマー100重量部、蛍光染料(Lumogen F Blue650、BASF社製)0.04重量部、架橋剤(商品名:テトラッドC、ポリグリシジル化合物、三菱瓦斯化学製)0.075重量部、紫外線吸収剤(ADK STAB LA46、ヒドロキシフェニルトリアジン系紫外線吸収剤、ADEKA社製)3重量部、光安定剤(ADK STAB LA63P、ヒンダードアミン系光安定剤、ADEKA社製)0.3重量部を、トルエンに混合して、固形分濃度19重量%の塗布液を調製した。
ガラスからなる被覆層(厚み3mm)を用意し、太陽電池モジュール用粘着シートの表面側の離型フィルムを引き剥がし、太陽電池モジュール用粘着シートを、被覆層の裏面に貼着した。
蛍光染料(Lumogen F Blue650、BASF社製)の配合割合を0.01重量部に変更した以外は、実施例1と同様に処方して、太陽電池モジュール用粘着シートを作製し、続いて、太陽電池モジュールを作製した。
蛍光染料(Lumogen F Blue650、BASF社製)の配合割合を0.07重量部に変更した以外は、実施例1と同様に処方して、太陽電池モジュール用粘着シートを作製し、続いて、太陽電池モジュールを作製した。
蛍光染料(Lumogen F Blue650、BASF社製)の配合割合を0.1重量部に変更した以外は、実施例1と同様に処方して、太陽電池モジュール用粘着シートを作製し、続いて、太陽電池モジュールを作製した。
蛍光染料(Lumogen F Blue650、BASF社製)0.04重量部に代えて、蛍光染料(BASF社製、商品名 Lumogen F Yellow170)0.01重量部を用いた以外は、実施例1と同様に処方して、太陽電池モジュール用粘着シートを作製し、続いて、太陽電池モジュールを作製した。
蛍光染料(Lumogen F Blue650、BASF社製)0.04重量部に代えて、蛍光染料(BASF社製、商品名 Lumogen F Yellow170)0.04重量部を用いた以外は、実施例1と同様に処方して、太陽電池モジュール用粘着シートを作製し、続いて、太陽電池モジュールを作製した。
蛍光染料(Lumogen F Blue650、BASF社製)0.04重量部に代えて、蛍光染料(BASF社製、商品名 Lumogen F Yellow170)0.1重量部を用いた以外は、実施例1と同様に処方して、太陽電池モジュール用粘着シートを作製し、続いて、太陽電池モジュールを作製した。
(太陽電池モジュールの作製)
EVAからなる封止樹脂層に代えて、ポリフッ化ビニリデンからなる封止樹脂層を用いた以外は、実施例1と同様に処理して、太陽電池モジュールを作製した。
蛍光染料(Lumogen F Blue650、BASF社製)を用いなかった以外は、実施例1と同様に処方して、太陽電池モジュール用粘着シートを作製し、続いて、太陽電池モジュールを作製した。
(太陽電池モジュール用粘着シートの作製)
蛍光染料(Lumogen F Blue650、BASF社製)を用いなかった以外は、実施例1と同様に処方して、太陽電池モジュール用粘着シートを作製した。
上記により作製した太陽電池モジュール用粘着シートを用い、さらに、EVAからなる封止樹脂層に代えて、EVA100重量部に対して、蛍光染料(Lumogen F Blue650、BASF社製)0.04重量部が均一に分散された封止樹脂層を設けた以外は、実施例1と同様に処理して、太陽電池モジュールを作製した。
実施例1および5で作製した太陽電池モジュール用粘着シートについて、励起スペクトルおよび蛍光スペクトルを、分光蛍光光度計を用いて測定した。
測定条件
(実施例1)
励起スペクトル測定範囲:300〜400nm
蛍光スペクトル測定範囲:400〜600nm
(実施例5)
励起スペクトル測定範囲:300〜515nm
蛍光スペクトル測定範囲:515〜700nm
実施例1および実施例5の結果を、それぞれ、図3および図4に示す。
各実施例、各参考例および各比較例の太陽電池モジュールをソーラーシミュレーターに設置して、最大発電量を測定した。
光源 :高圧キセノンランプ
光量 :100mW/cm2
時間 : 30分間
その結果を、表1に示す。
3 太陽電池モジュール
4 太陽電池素子
5 封止樹脂層
6 被覆層
Claims (8)
- 結晶シリコン系の太陽電池素子と、
前記太陽電池素子を封止する封止樹脂層と、
前記封止樹脂層の上に、前記封止樹脂層を被覆するように形成される被覆層と、
前記封止樹脂層と、前記被覆層との間に介在される太陽電池モジュール用粘着シートと
を備え、
前記太陽電池モジュール用粘着シートは、
アクリル系ポリマーと、
光の波長を長波長側に変換するための波長変換材料と、
光安定剤と
を含有し、
厚みが、5〜100μmであり、
屈折率が、1.400〜1.480であり、
前記太陽電池素子に入射する光の波長を変換可能であり、
前記波長変換材料の含有割合が、前記アクリル系ポリマー100重量部に対して、0.001〜0.07重量部である
ことを特徴とする、太陽電池モジュール。 - 前記太陽電池モジュール用粘着シートの屈折率は、前記封止樹脂層の屈折率に比べて低いかあるいは同一であることを特徴とする、請求項1に記載の太陽電池モジュール。
- 前記アクリル系ポリマーが、(メタ)アクリル酸エステルを主成分とするモノマー成分を、重合させることにより、得られることを特徴とする、請求項1または2に記載の太陽電池モジュール。
- 前記(メタ)アクリル酸エステルの配合割合が、前記モノマー成分100重量部に対して、50重量部以上であることを特徴とする、請求項3に記載の太陽電池モジュール。
- 前記光安定剤が、ヒンダードアミン系光安定剤であることを特徴とする、請求項1〜4のいずれか一項に記載の太陽電池モジュール。
- 前記波長変換材料の励起スペクトルは、350〜550nmにピーク波長を有し、
前記波長変換材料の蛍光スペクトルは、400〜700nmにピーク波長を有することを特徴とする、請求項1〜5のいずれか一項に記載の太陽電池モジュール。 - 前記光安定剤の配合割合が、前記アクリル系ポリマー100重量部に対して、0.1重量部以上、0.5重量部以下であることを特徴とする、請求項1〜6のいずれか一項に記載の太陽電池モジュール。
- 紫外線吸収剤をさらに含有することを特徴とする、請求項1〜7のいずれか一項に記載の太陽電池モジュール。
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