JP5896536B2 - 重質炭化水素原料をアップグレードするため反応器に供給を行うために用いられる触媒前駆体からなる触媒調製反応器 - Google Patents
重質炭化水素原料をアップグレードするため反応器に供給を行うために用いられる触媒前駆体からなる触媒調製反応器 Download PDFInfo
- Publication number
- JP5896536B2 JP5896536B2 JP2013517353A JP2013517353A JP5896536B2 JP 5896536 B2 JP5896536 B2 JP 5896536B2 JP 2013517353 A JP2013517353 A JP 2013517353A JP 2013517353 A JP2013517353 A JP 2013517353A JP 5896536 B2 JP5896536 B2 JP 5896536B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- reactor
- process according
- hydroconversion
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003054 catalyst Substances 0.000 title claims description 61
- 238000002360 preparation method Methods 0.000 title claims description 32
- 239000012018 catalyst precursor Substances 0.000 title claims description 27
- 229930195733 hydrocarbon Natural products 0.000 title claims description 21
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 19
- 239000004215 Carbon black (E152) Substances 0.000 title claims description 18
- 238000000034 method Methods 0.000 claims description 33
- 239000002994 raw material Substances 0.000 claims description 28
- 229910052751 metal Inorganic materials 0.000 claims description 21
- 239000002184 metal Substances 0.000 claims description 20
- 229910052750 molybdenum Inorganic materials 0.000 claims description 19
- 229910052739 hydrogen Inorganic materials 0.000 claims description 18
- 239000001257 hydrogen Substances 0.000 claims description 18
- 239000002243 precursor Substances 0.000 claims description 18
- 239000003446 ligand Substances 0.000 claims description 16
- 229910052723 transition metal Inorganic materials 0.000 claims description 16
- 150000003624 transition metals Chemical class 0.000 claims description 16
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 15
- 229910052742 iron Inorganic materials 0.000 claims description 12
- 229910052717 sulfur Inorganic materials 0.000 claims description 12
- 239000000126 substance Substances 0.000 claims description 11
- 125000001424 substituent group Chemical group 0.000 claims description 11
- -1 polycyclic aryl hydrocarbon Chemical class 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 229910052759 nickel Inorganic materials 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 8
- 229910052720 vanadium Inorganic materials 0.000 claims description 7
- 230000000737 periodic effect Effects 0.000 claims description 6
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims description 5
- 125000002950 monocyclic group Chemical group 0.000 claims description 5
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims description 4
- 125000003342 alkenyl group Chemical group 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 4
- 125000005609 naphthenate group Chemical group 0.000 claims description 4
- 125000002524 organometallic group Chemical group 0.000 claims description 4
- 125000005474 octanoate group Chemical group 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical group O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 2
- 125000002252 acyl group Chemical group 0.000 claims description 2
- 125000002723 alicyclic group Chemical group 0.000 claims description 2
- 150000004703 alkoxides Chemical class 0.000 claims description 2
- 125000000304 alkynyl group Chemical group 0.000 claims description 2
- 150000001408 amides Chemical class 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- 150000004820 halides Chemical class 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims description 2
- 150000004678 hydrides Chemical class 0.000 claims description 2
- 125000003367 polycyclic group Chemical group 0.000 claims description 2
- 229910052711 selenium Inorganic materials 0.000 claims description 2
- 229910052714 tellurium Inorganic materials 0.000 claims description 2
- 150000007944 thiolates Chemical class 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 239000000571 coke Substances 0.000 description 20
- 238000006243 chemical reaction Methods 0.000 description 17
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 17
- 239000000203 mixture Substances 0.000 description 14
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 14
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 12
- 239000011733 molybdenum Substances 0.000 description 12
- 230000015572 biosynthetic process Effects 0.000 description 10
- 239000011593 sulfur Substances 0.000 description 10
- WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 description 8
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 7
- 239000002002 slurry Substances 0.000 description 7
- 239000000654 additive Substances 0.000 description 6
- VLXBWPOEOIIREY-UHFFFAOYSA-N dimethyl diselenide Natural products C[Se][Se]C VLXBWPOEOIIREY-UHFFFAOYSA-N 0.000 description 6
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 5
- RBFQJDQYXXHULB-UHFFFAOYSA-N arsane Chemical compound [AsH3] RBFQJDQYXXHULB-UHFFFAOYSA-N 0.000 description 4
- 238000004821 distillation Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 230000035484 reaction time Effects 0.000 description 4
- 238000011144 upstream manufacturing Methods 0.000 description 4
- YQZUTDPJTAZPQJ-UHFFFAOYSA-L cyclopentane;dichloromolybdenum Chemical compound Cl[Mo]Cl.[CH]1[CH][CH][CH][CH]1.[CH]1[CH][CH][CH][CH]1 YQZUTDPJTAZPQJ-UHFFFAOYSA-L 0.000 description 3
- 238000004817 gas chromatography Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 238000005984 hydrogenation reaction Methods 0.000 description 3
- WWZKQHOCKIZLMA-UHFFFAOYSA-M octanoate Chemical compound CCCCCCCC([O-])=O WWZKQHOCKIZLMA-UHFFFAOYSA-M 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000003079 shale oil Substances 0.000 description 3
- UVPKUTPZWFHAHY-UHFFFAOYSA-L 2-ethylhexanoate;nickel(2+) Chemical compound [Ni+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O UVPKUTPZWFHAHY-UHFFFAOYSA-L 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000005194 fractionation Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 238000000197 pyrolysis Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical compound CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 1
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 description 1
- 229910017318 Mo—Ni Inorganic materials 0.000 description 1
- 229910003294 NiMo Inorganic materials 0.000 description 1
- 125000005595 acetylacetonate group Chemical group 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000010504 bond cleavage reaction Methods 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000011088 calibration curve Methods 0.000 description 1
- SHZIWNPUGXLXDT-UHFFFAOYSA-N caproic acid ethyl ester Natural products CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 239000012084 conversion product Substances 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000002006 petroleum coke Substances 0.000 description 1
- 239000011295 pitch Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 150000004291 polyenes Chemical class 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 125000002577 pseudohalo group Chemical group 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/20—Sulfiding
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
- C10G49/04—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used containing nickel, cobalt, chromium, molybdenum, or tungsten metals, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/10—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 with moving solid particles
- C10G49/12—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 with moving solid particles suspended in the oil, e.g. slurries
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/12—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/646—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of aromatic or heteroaromatic rings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
- B01J2531/56—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/64—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/842—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
- B01J35/27—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a liquid or molten state
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1011—Biomass
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1077—Vacuum residues
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/70—Catalyst aspects
- C10G2300/703—Activation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/70—Catalyst aspects
- C10G2300/708—Coking aspect, coke content and composition of deposits
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Description
(a)Mは、元素周期表のIIA、IIIB、IVB、VB、VIB、VIIB、VIII、IB及びIIB族のなかから選択される遷移金属であり、
(b)-C1及び-C2は、Mにπ結合した単環式又は多環式のアリール炭化水素配位子、あるいはMにπ結合した単環式又は多環式のポリエン配位子であり、C1及び-C2は同じ又は異なり、各-C1又は-C2は0から5の置換基Rを含み、各置換基Rは同じ又は異なり、Rを、
(i)置換された又は置換されていない、配位子-C1及び-C2に融合した又は融合していない、部分的不飽和、不飽和又は芳香族のC3−C8の単環式又は多環式環状構造と、
(ii)置換された又は置換されていない、部分的不飽和又は不飽和の、直鎖又は分岐したC3−C8の脂環式ヒドロカルビルラジカルと、
(iii)置換された又は置換されていない、直鎖又は分岐したC1−C8の飽和ヒドロカルビルラジカルと、
のなかから選択し、ここで-C1及び-C2は独立しており又は少なくとも一つの置換基Rを介して結合しており、
(c)-LはMとσ結合した配位子であり、nは0から3に等しい整数であり、各-Lは、単独で、一価の配位子である。
・水素化物(-L=-H)
・ハロゲン化物(-L=-F,-Cl,-Br,-I)
「疑似ハロゲン化物」(-L=-CN(シアン化物))
・アルコキシド(-L=-OR)
チオレート(-L=-SR)
・アミド(-L=-NR2)
リン化物(-L=-PR2)
・-L=-ER3又は-EX3(ここでE=Si,Ge,Sn;)
・アルキル(-L=-CH2R又はその他)
アルケニル(-L=-CHCHR)
アルキニル(-L=-CCR)
・アシル(-L=-COR)
・イソシアン化物(-L=-CNR)
ニトロシル(-L=-NO)
ジアゼニド(Diazenide)(-L=-NNR)
イミド(-L==NR)
・-L=-PR3, -PX3, -AsR3, -SbR3及びアミン類
・L=ER2(ここでE=O,S,Se,Te)
ここで、Xはハロゲン原子であり、Rは、直鎖もしくは分岐したC1−C8、好ましくはC1−C6のアルキル、アルケニル基、又はC3−C8の脂環式もしくは芳香族基である。
1.Analytical Controlsから入手可能なA C5−C28混合物(AC partno.:59.50.101A)
2.Analytical Controlsから入手可能なA C30−C120混合物(AC partno.:59.50.100B)
真空残油の水素化変換及び水素化処理を実施した。試験した真空残油は以下の特性を示す。
この試験シリーズでは、全触媒金属の(モルの)含有量を一定に維持し、一方でNi/Mo比は0と0.5の間で変化させた。この試験シリーズにおいて、動作温度は一時間430℃に固定した。
真空残油の水素化変換について、活性触媒相の前駆体としてのフェロセンとオクタン酸鉄を比較するために、試験シリーズが実施された。
真空残油の水素化変換について、活性触媒相の前駆体としてのビス(シクロペンタジエニル)モリブデン二塩化物とMo−オクタン酸塩を比較するために、試験が実施された。
同じ試験が、触媒を使用せずにかつ常圧残油のブレンドを用いて行われた。この原料の組成を表14に示す。水素流は0Nl/時に設定された。原料は、温度420.5℃で30分間処理された。コークスの重要量が生成され、このことは触媒がコークスの抑制に与える影響を説明している。
Claims (16)
- 重質炭化水素原料を水素化変換するための一以上の水素化変換反応器と、前記重質炭化水素原料を水素化処理するための一以上の水素化処理反応器と、で前記重質炭化水素原料をアップグレードするプロセスであって、
前記プロセスが、二以上の触媒を調製することを含み、
各触媒を、少なくとも第一の調製反応器と該第一の調製反応器とは別の第二の調製反応器とを含む調製反応器内で一以上の触媒前駆体から調製し、
前記水素化変換反応器及び前記水素化処理反応器のうち一方に、触媒と前記重質炭化水素原料とを供給し、
前記水素化変換反応器及び前記水素化処理反応器のうち他方に、触媒と、前記水素化変換反応器及び前記水素化処理反応器のうち一方から流出した流出物と、を供給し、
前記水素化変換において前記第一の調製反応器で調製された触媒を用い、前記水素化処理において前記第二の調製反応器で調製された触媒を用い、
前記触媒前駆体は、元素周期表のIIA、IIIB、IVB、VB、VIB、VIIB、VIII、IB及びIIB族から選択される一以上の遷移金属を含む
ことを特徴とするプロセス。 - 前記各調製反応器に、前記アップグレードする原料の一部を供給することを特徴とする請求項1に記載のプロセス。
- 前記各調製反応器に硫化剤を供給することを特徴とする請求項1又は2に記載のプロセス。
- 前記各調製反応器に水素を供給することを特徴とする請求項1〜3の何れか一項に記載のプロセス。
- 前記各調製反応器に分散剤を供給することを特徴とする請求項1〜4の何れか一項に記載のプロセス。
- 各触媒を、二以上の調製反応器内で調製することを特徴とする請求項1〜5の何れか一項に記載のプロセス。
- 水素化変換に用いる触媒が、活性状態の、VB、VIB、VIII族から選択される一つの遷移金属を含み、
水素化処理に用いる触媒が、活性状態の二つの遷移金属を含み、そのうちの一つの遷移金属をVB、VIB、VIII族から選択し、もう一つの遷移金属をVIII族から選択する
ことを特徴とする請求項1〜6の何れか一項に記載のプロセス。 - 水素化変換に用いる触媒がV、Mo又はFeを含み、水素化処理に用いる(複数の)触媒がMoとNi、又はMoとV、又はFeとNiを含むことを特徴とする請求項7に記載のプロセス。
- 水素化変換に用いる触媒が、20ppmから700ppmの遷移金属を含むことを特徴とする請求項1〜8の何れか一項に記載のプロセス。
- 水素化処理に用いる触媒中の遷移金属の全含有量が、200から1000ppmの範囲であることを特徴とする請求項1〜9の何れか一項に記載のプロセス。
- 前記触媒前駆体を、ナフテン酸塩、オクタン酸塩及び酸化物のなかから選択することを特徴とする請求項1〜10の何れか一項に記載のプロセス。
- 単一金属触媒の前記前駆体が、化学式C1C2MLn(I)を有する有機金属配位化合物であり、ここで、
(a)Mは、元素周期表のIIA、IIIB、IVB、VB、VIB、VIIB、VIII、IB及びIIB族から選択される遷移金属であり、
(b)-C1及び-C2は、Mとπ結合した単環式又は多環式のアリール炭化水素配位子であり、C1及び-C2は同じ又は異なり、各-C1又は-C2は0から5の置換基Rを含み、各置換基Rは同じ又は異なり、前記置換基Rを、
(i)置換された又は置換されていない、配位子-C1及び-C2に融合した又は融合していない、部分的不飽和、不飽和又は芳香族のC3−C8の単環式又は多環式の環状構造と、
(ii)置換された又は置換されていない、部分的不飽和又は不飽和の、直鎖又は分岐したC3−C8の脂環式ヒドロカルビルラジカルと、
(iii)置換された又は置換されていない、直鎖又は分岐したC1−C8の飽和ヒドロカルビルラジカルと、
のなかから選択し、ここで-C1及び-C2は独立しており又は少なくとも一つの置換基Rを介して結合しており、
(c)-LはMとσ結合した配位子であり、nは0から3に等しい整数であり、各-Lは、単独で、一価の配位子である
ことを特徴とする請求項1〜10の何れか一項に記載のプロセス。 - 前記配位子-Lを、水素化物(-L=-H)、ハロゲン化物(-L=-F,-Cl,-Br,-I)、シアン化物(-L=-CN)、アルコキシド(-L=-OR)、チオレート(-L=-SR)、アミド(-L=-NR2)、リン化物(-L=-PR2)、アルキル(-L=-CH2R又はその他)、アルケニル(-L=-CHCHR)、アルキニル(-L=-CCR)、アシル(-L=-COR)、イソシアン化物(-L=-CNR)、ニトロシル(-L=-NO)、ジアゼニド(-L=-NNR)、イミド(-L==NR)、L=-ER3又は-EX3(ここでE=Si,Ge,Sn)、-L=-PR3, -PX3, -AsR3, -SbR3、アミン類、L=ER2(ここでE=O,S,Se,Te)から選択し、ここでXはハロゲン原子であり、Rは直鎖若しくは分岐したC1−C8のアルキル、アルケニル基、又はC3−C8の脂環式若しくは芳香族基であることを特徴とする請求項12又は13に記載のプロセス。
- 前記Mを、元素周期表のIIA、IIB、IIIB、IVB、VB、VIB、VIIB及びVIII族から選択することを特徴とする請求項12〜14の何れか一項に記載のプロセス。
- 前記炭素原料が、原子のH/C比が少なくとも0.25であることを特徴とする請求項1〜15の何れか一項に記載のプロセス。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP10305744.4 | 2010-07-06 | ||
EP10305744A EP2404982A1 (en) | 2010-07-06 | 2010-07-06 | Catalyst preparation reactors from catalyst precursor used for feeding reactors to upgrade heavy hydrocarbonaceous feedstocks |
PCT/EP2011/061284 WO2012004246A2 (en) | 2010-07-06 | 2011-07-05 | Catalyst preparation reactors from catalyst precursor used for feeding reactors to upgrade heavy hydrocarbonaceous feedstocks. |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2013535517A JP2013535517A (ja) | 2013-09-12 |
JP5896536B2 true JP5896536B2 (ja) | 2016-03-30 |
Family
ID=43415352
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2013517353A Expired - Fee Related JP5896536B2 (ja) | 2010-07-06 | 2011-07-05 | 重質炭化水素原料をアップグレードするため反応器に供給を行うために用いられる触媒前駆体からなる触媒調製反応器 |
Country Status (7)
Country | Link |
---|---|
US (1) | US9233363B2 (ja) |
EP (2) | EP2404982A1 (ja) |
JP (1) | JP5896536B2 (ja) |
KR (1) | KR101893424B1 (ja) |
CN (1) | CN103080278B (ja) |
AU (1) | AU2011275813B2 (ja) |
WO (1) | WO2012004246A2 (ja) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3015514B1 (fr) | 2013-12-23 | 2016-10-28 | Total Marketing Services | Procede ameliore de desaromatisation de coupes petrolieres |
JP6685317B2 (ja) * | 2014-11-06 | 2020-04-22 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 高活性および自己活性化特性を有する自己活性型水素化触媒と残油原料を処理するためのその使用 |
IT201600080528A1 (it) * | 2016-08-01 | 2018-02-01 | Luigi Patron | Sistema di idroconversione di oli pesanti esente da coking in singolo stadio di reazione con riciclo mediante un reattore a catalizzatore disperso comprendente molibdeno, e relativo metodo di idroconversione |
CN111841630A (zh) * | 2020-06-24 | 2020-10-30 | 中国石油大学(华东) | 用于煤/重油加氢共炼的脂肪酸镍油溶性催化剂及其应用 |
WO2023156742A1 (fr) | 2022-02-17 | 2023-08-24 | Totalenergies Onetech | Procede de production d'une huile de biomasse stabilisee |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5665636A (en) | 1979-10-31 | 1981-06-03 | Chiyoda Chem Eng & Constr Co Ltd | Metal-carrying fine particles catalyst and preparation thereof |
US4430442A (en) * | 1982-07-20 | 1984-02-07 | Exxon Research And Engineering Co. | Catalysts from molybdenum polysulfide precursors and their preparation |
US4592827A (en) * | 1983-01-28 | 1986-06-03 | Intevep, S.A. | Hydroconversion of heavy crudes with high metal and asphaltene content in the presence of soluble metallic compounds and water |
GB2142930B (en) * | 1983-03-19 | 1987-07-01 | Asahi Chemical Ind | A process for cracking a heavy hydrocarbon |
JPS59172587A (ja) | 1983-05-16 | 1984-09-29 | Asahi Chem Ind Co Ltd | 重質炭化水素油の軽質化方法 |
US4824821A (en) * | 1983-08-29 | 1989-04-25 | Chevron Research Company | Dispersed group VIB metal sulfide catalyst promoted with Group VIII metal |
US4839326A (en) * | 1985-04-22 | 1989-06-13 | Exxon Research And Engineering Company | Promoted molybdenum and tungsten sulfide catalysts, their preparation and use |
US5578197A (en) * | 1989-05-09 | 1996-11-26 | Alberta Oil Sands Technology & Research Authority | Hydrocracking process involving colloidal catalyst formed in situ |
US5372705A (en) * | 1992-03-02 | 1994-12-13 | Texaco Inc. | Hydroprocessing of heavy hydrocarbonaceous feeds |
JPH0790282A (ja) * | 1993-09-27 | 1995-04-04 | Asahi Chem Ind Co Ltd | 重質油分解・水素化処理方法 |
US5620591A (en) * | 1994-12-22 | 1997-04-15 | Exxon Research & Engineering Company | Hydroconversion process with plug-flow molybdenum catalyst concentrate preparation |
US5594945A (en) | 1995-02-14 | 1997-01-14 | Bellsouth Corporation | Method of providing registration reminder message to a roaming pager upon entry into a new service area |
CN1121274C (zh) | 2001-02-28 | 2003-09-17 | 北京燕山石油化工公司研究院 | 茂金属催化剂及其制备方法、应用和选择加氢方法 |
ES2585891T3 (es) | 2004-04-28 | 2016-10-10 | Headwaters Heavy Oil, Llc | Métodos y sistemas de hidroprocesamiento en lecho en ebullición |
US20060058175A1 (en) * | 2004-09-10 | 2006-03-16 | Chevron U.S.A. Inc. | Highly active slurry catalyst composition |
WO2007008097A1 (fr) * | 2005-07-11 | 2007-01-18 | Institut Kataliza Imeni G.K. Boreskova Sibirskogo Otdeleniya Rosiiskoi Akademii Nauk | Catalyseur, procede de fabrication correspondant et procede d'isomerisation d'hydrocarbures utilisant ce catalyseur |
US7842635B2 (en) * | 2006-01-06 | 2010-11-30 | Headwaters Technology Innovation, Llc | Hydrocarbon-soluble, bimetallic catalyst precursors and methods for making same |
US8034232B2 (en) * | 2007-10-31 | 2011-10-11 | Headwaters Technology Innovation, Llc | Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker |
US7931797B2 (en) * | 2009-07-21 | 2011-04-26 | Chevron U.S.A. Inc. | Systems and methods for producing a crude product |
-
2010
- 2010-07-06 EP EP10305744A patent/EP2404982A1/en not_active Withdrawn
-
2011
- 2011-07-05 WO PCT/EP2011/061284 patent/WO2012004246A2/en active Application Filing
- 2011-07-05 JP JP2013517353A patent/JP5896536B2/ja not_active Expired - Fee Related
- 2011-07-05 EP EP11741539.8A patent/EP2591077B1/en not_active Not-in-force
- 2011-07-05 US US13/808,469 patent/US9233363B2/en not_active Expired - Fee Related
- 2011-07-05 CN CN201180039143.8A patent/CN103080278B/zh not_active Expired - Fee Related
- 2011-07-05 KR KR1020137003198A patent/KR101893424B1/ko active IP Right Grant
- 2011-07-05 AU AU2011275813A patent/AU2011275813B2/en not_active Ceased
Also Published As
Publication number | Publication date |
---|---|
JP2013535517A (ja) | 2013-09-12 |
AU2011275813A1 (en) | 2013-01-31 |
WO2012004246A2 (en) | 2012-01-12 |
EP2404982A1 (en) | 2012-01-11 |
CN103080278B (zh) | 2016-03-16 |
KR101893424B1 (ko) | 2018-08-31 |
EP2591077A2 (en) | 2013-05-15 |
WO2012004246A3 (en) | 2012-04-12 |
CN103080278A (zh) | 2013-05-01 |
US9233363B2 (en) | 2016-01-12 |
AU2011275813B2 (en) | 2015-08-13 |
KR20130091326A (ko) | 2013-08-16 |
US20130193035A1 (en) | 2013-08-01 |
EP2591077B1 (en) | 2016-08-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA2803727C (en) | Hydroconversion process for heavy hydrocarbonaceous feedstock | |
JP5896534B2 (ja) | 低品質の炭化水素原料を水素化変換するためのプロセス | |
JP4874977B2 (ja) | 重油のアップグレードにおける活性スラリー触媒組成物のリサイクル法 | |
US4134825A (en) | Hydroconversion of heavy hydrocarbons | |
US4298454A (en) | Hydroconversion of an oil-coal mixture | |
GB1576039A (en) | Hydroconversion of an oil-coal mixture | |
JP5896536B2 (ja) | 重質炭化水素原料をアップグレードするため反応器に供給を行うために用いられる触媒前駆体からなる触媒調製反応器 | |
JPH05214345A (ja) | 石炭の液化方法及びそれに用いる触媒組成物 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20140630 |
|
RD04 | Notification of resignation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7424 Effective date: 20141021 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20150612 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20150623 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20150916 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20160209 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20160226 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5896536 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
LAPS | Cancellation because of no payment of annual fees |