JP5891016B2 - 高熱伝導性熱可塑性樹脂組成物 - Google Patents
高熱伝導性熱可塑性樹脂組成物 Download PDFInfo
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- JP5891016B2 JP5891016B2 JP2011257590A JP2011257590A JP5891016B2 JP 5891016 B2 JP5891016 B2 JP 5891016B2 JP 2011257590 A JP2011257590 A JP 2011257590A JP 2011257590 A JP2011257590 A JP 2011257590A JP 5891016 B2 JP5891016 B2 JP 5891016B2
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- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 3
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Description
一方で、特許文献3〜6に示されるような手法をそのまま特許文献2の技術に適用するのも容易ではなかった。
また本発明は、押出成形またはブロー成形により、上記請求項1に記載の高熱伝導性熱可塑性樹脂組成物を成形することを特徴とする、成形体の製造方法(請求項4)である。
このようにして得られた複合材料は、樹脂フィルム、樹脂成形品、樹脂発泡体、塗料やコーティング剤、などさまざまな形態で、電子材料、磁性材料、触媒材料、構造体材料、光学材料、医療材料、自動車材料、建築材料、等の各種の用途に幅広く用いることが可能である。本発明で得られた高分子材料は、現在広く用いられているブロー成形機や押出成形機等の一般的なプラスチック用成形機が使用可能であるため、複雑な形状を有する製品への成形も容易である。特に成形加工性、耐衝撃性、耐薬品性、熱伝導性、などの重要な諸特性のバランスに優れていることから、発熱源を内部に有する照明、ディスプレー、コンピューターなどの筐体用樹脂として、非常に有用である。
また本発明において、製品として用いられる成形体をブロー成形により得る際の、パリソン温度は、通常、240〜320℃で、好ましくは255〜295℃である。この際の金型温度は、通常、40〜180℃で、好ましくは60〜150℃である。
[熱伝導率] : 得られた押出成形品やブロー成形品から30mm角×3.0mm厚みの板柱状試験片を2個切り出し、京都電子工業製ホットディスク法熱伝導率測定装置で4φのセンサーにて熱伝導率を測定した。
熱可塑性ポリエステル系樹脂(B)として三菱化学(株)製のポリエチレンテレフタレート樹脂であるPBK−2(B−1)を用いた。(B−1)100重量部に対して、ラインケミージャパン(株)社製スタバクゾールP(以下D−1と略す。)を0.5重量部、並びに、安定剤としてアデカスタブAO−60及びアデカスタブAO−412S(いずれも(株)ADEKA製商品名)各0.2重量部をスーパーフローターにて混合した(原料1)。
得られた組成物をプラコー株式会社製のDA−50型ブロー成形機で60mm×60mm×100mm、平均肉厚2.5mmの四角柱状中空成形体をブロー成形した。成形条件は、パリソン温度約270℃、射出速度(指数)150、スクリュー回転数60rpm、ブロー圧0.59MPa(窒素)、冷却時間100秒、金型温度120℃に設定したところ、ブロー成形性は概ね良好であった。成形品を評価した結果、ブロー成形品外観:○、熱伝導率:3.2W/mK、であった。
ポリカーボネート系樹脂(A)として、出光興産(株)製ビスフェノールA型ポリカーボネート樹脂である、タフロンA−2200(A−1)を、熱可塑性ポリエステル系樹脂(B)として三菱化学(株)製のポリエチレンテレフタレート樹脂であるPBK−2(B−1)を用い、両者を体積比で(A−1)/(B−1)=30/20となるよう混合した。両者の合計100重量部に対して、(D)化合物として、ラインケミージャパン(株)社製スタバクゾールP(以下D−1と略す。)を0.5重量部、並びに、安定剤としてアデカスタブAO−60及びアデカスタブHP−10(いずれも(株)ADEKA製商品名)各0.2重量部をスーパーフローターにて混合した(原料1)。
得られた成形品の熱伝導率を評価した結果、押出成形品外観:◎、熱伝導率:1.5W/mK、であった。
得られた組成物をプラコー株式会社製のDA−50型ブロー成形機で60mm×60mm×100mm、平均肉厚2.5mmの四角柱状中空成形体をブロー成形した。成形条件は、パリソン温度約260℃、射出速度(指数)150、スクリュー回転数60rpm、ブロー圧0.59MPa(窒素)、冷却時間100秒、金型温度90℃に設定したところ、ブロー成形性は良好であった。成形品を評価した結果、ブロー成形品外観:◎、熱伝導率:1.5W/mK、であった。
(D−1)の代わりに、(D−2)ラインケミージャパン(株)社製スタバクゾールP−400を用いた以外は実施例2と同様に評価を行った。結果、押出成形性:良好、押出成形品外観:◎、熱伝導率:1.4W/mK、ブロー成形性:良好、ブロー成形品外観:◎、熱伝導率:1.4W/mK、であった。
(A−1)の代わりに、(A−2):ポリカーボネート樹脂(出光興産(株)製ビスフェノールA型ポリカーボネート樹脂である、タフロンA−2500)を用いた以外は実施例2と同様に評価を行った。結果、押出成形性:良好、押出成形品外観:◎、熱伝導率:1.5W/mK、ブロー成形性:良好、ブロー成形品外観:◎、熱伝導率:1.5W/mK、であった。
(B−1)の代わりに、(B−2):対数粘度0.85(25℃、dl/g、フェノール/テトラクロロエタン=1/1(重量比))のポリブチレンテレフタレート樹脂を用いた以外は実施例2と同様に評価を行った。結果、押出成形性:良好、押出成形品外観:◎、熱伝導率:1.6W/mK、ブロー成形性:良好、ブロー成形品外観:◎、熱伝導率:1.6W/mK、であった。
(C−1)の代わりに、(C−2):丸み状アルミナ粉末(昭和電工(株)製AS−40、単体での熱伝導率36W/m・K、体積平均粒子径20μm、電気絶縁性)を用いた以外は実施例2と同様に評価を行った。結果、押出成形性:良好、押出成形品外観:◎、熱伝導率:1.1W/mK、ブロー成形性:良好、ブロー成形品外観:◎、熱伝導率:1.1W/mK、であった。
(C−1)の代わりに、(C−3):窒化ホウ素粉末(モメンティブパフォーマンスマテリアルズ製PT−110、単体での熱伝導率80W/m・K、体積平均粒子径36μm、電気絶縁性)を用いた以外は実施例2と同様に評価を行った。結果、押出成形性:良好、押出成形品外観:◎、熱伝導率:1.8W/mK、ブロー成形性:良好、ブロー成形品外観:◎、熱伝導率:1.8W/mK、であった。
(D−1)を添加しなかった以外は実施例2と同様に評価を行った。結果、押出成形性:不良、押出成形品外観:×、熱伝導率:1.5W/mK、ブロー成形性:不良、ブロー成形品外観:×、熱伝導率:1.5W/mK、であった。
以上から本発明の熱可塑性樹脂組成物は、諸物性と熱伝導率とのバランスに優れた高熱伝導性熱可塑性樹脂組成物が得られ、かつ押出成形性やブロー成形性に優れることが分かる。
(C−1)を添加しなかった以外は実施例2と同様に評価を行った。結果、押出成形性:良好、押出成形品外観:◎、熱伝導率:0.2W/mK、ブロー成形性:良好、ブロー成形品外観:◎○、熱伝導率:0.2W/mK、となり、熱伝導率は汎用の樹脂とほぼ同等であった。
Claims (3)
- ポリカーボネート系樹脂(A)、熱可塑性ポリエステル系樹脂(B)、単体での熱伝導率が5W/m・K以上を示す高熱伝導性無機化合物(C)、カルボジイミド化合物(D)よりなることを特徴とする、高熱伝導性熱可塑性樹脂組成物。
- カルボジイミド化合物(D)が、数平均分子量が1000以上の高分子量カルボジイミド化合物であることを特徴とする、請求項1記載の高熱伝導性熱可塑性樹脂組成物。
- 押出成形またはブロー成形により、請求項1に記載の高熱伝導性熱可塑性樹脂組成物を成形することを特徴とする、成形体の製造方法。
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