JP5854549B2 - 燃料油の低温特性を向上させるための添加剤 - Google Patents
燃料油の低温特性を向上させるための添加剤 Download PDFInfo
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- JP5854549B2 JP5854549B2 JP2007185139A JP2007185139A JP5854549B2 JP 5854549 B2 JP5854549 B2 JP 5854549B2 JP 2007185139 A JP2007185139 A JP 2007185139A JP 2007185139 A JP2007185139 A JP 2007185139A JP 5854549 B2 JP5854549 B2 JP 5854549B2
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- terpolymer
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- 239000000203 mixture Substances 0.000 claims description 50
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 40
- 230000000996 additive effect Effects 0.000 claims description 38
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- 125000004432 carbon atom Chemical group C* 0.000 claims description 33
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- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
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- 238000009833 condensation Methods 0.000 description 4
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- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
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- 150000002430 hydrocarbons Chemical class 0.000 description 4
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 4
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 4
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 229920006395 saturated elastomer Polymers 0.000 description 4
- 239000003760 tallow Substances 0.000 description 4
- 239000004711 α-olefin Substances 0.000 description 4
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 3
- FXNDIJDIPNCZQJ-UHFFFAOYSA-N 2,4,4-trimethylpent-1-ene Chemical group CC(=C)CC(C)(C)C FXNDIJDIPNCZQJ-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
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- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 3
- IGBZOHMCHDADGY-UHFFFAOYSA-N ethenyl 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OC=C IGBZOHMCHDADGY-UHFFFAOYSA-N 0.000 description 3
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- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
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- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
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- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 230000010399 physical interaction Effects 0.000 description 1
- 229920001603 poly (alkyl acrylates) Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000000135 prohibitive effect Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 150000004666 short chain fatty acids Chemical class 0.000 description 1
- 235000021391 short chain fatty acids Nutrition 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 150000000000 tetracarboxylic acids Chemical class 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000006276 transfer reaction Methods 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- KQBSGRWMSNFIPG-UHFFFAOYSA-N trioxane Chemical compound C1COOOC1 KQBSGRWMSNFIPG-UHFFFAOYSA-N 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 125000002348 vinylic group Chemical group 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
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- C10L1/00—Liquid carbonaceous fuels
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- C10L1/00—Liquid carbonaceous fuels
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- C10L1/14—Organic compounds
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- C10L1/192—Macromolecular compounds
- C10L1/195—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C10L1/197—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and an acyloxy group of a saturated carboxylic or carbonic acid
- C10L1/1973—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and an acyloxy group of a saturated carboxylic or carbonic acid mono-carboxylic
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- C10L10/00—Use of additives to fuels or fires for particular purposes
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- C10L1/192—Macromolecular compounds
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Description
a) 少なくとも一種のエチレン性不飽和エステルに由来する構造単位を12.0〜16.0 モル%含有し、
b) 脂肪族炭素原子100個当りプロペンに由来するメチル基を1.0〜4.0個含有し、そして
c) 100 個のCH2 基に付き鎖末端から生じるメチル基が6.5個より少ない
エチレンと、少なくとも一種のエチレン性不飽和エステルと、プロペンとのターポリマーを提供する。
CH2=CH-OCOR1 (1)
式中、R1 は、C1-〜C11-アルキルであり、好ましくは C1-〜C8-アルキルであり、特に C1-〜C4-アルキルである。アルキルラジカルは、線状でもまたは枝分かれしていてもよい。
CH2=CR2-COOR3 (2)
式中、R2 は、水素またはメチルであり、R3は、C1-〜C12-アルキルであり、好ましくは C1-〜C8-アルキルであり、特にC1-〜C6-アルキルであり、例えば C1-〜C4-アルキルである。適したアクリル酸エステルは、例えば, メチル(メタ)アクリラート, エチル(メタ)アクリラート, プロピル(メタ)アクリラート, n- およびイソブチル (メタ)アクリラート, ヘキシル, オクチル, 2-エチルヘキシル(メタ)アクリラート, およびこれらのコモノマーの混合物を含む。メチルアクリラートおよびエチルアクリラートが特に好適である。
G = [不飽和エステルのモル%] + [プロペン-CH3]
は、好ましくは14.5〜18.0であり、好ましくは15.0〜17.8であり、例えば15.5〜17.5である。2つの加数を無次元数として加えるべきである。
CH2=CH-OCOR11 (3)
式中、R11 は、C1-〜C30-アルキル, 好ましくは C4-〜C16-アルキル, 特に C6-〜C12-アルキルである。更なる実施態様では、上述したアルキル基は、1個以上のヒドロキシル基によって置換されてもよい。
CH2=CR2-COOR4 (4)
式中、R2 は、水素 またはメチルであり、R4 は、C1- 〜C30-アルキルであり、好ましくはC4- 〜C16-アルキルであり、特にC6- 〜C12-アルキルである。適したアクリル酸エステルは、例えば, メチル (メタ)アクリラート, エチル (メタ)アクリラート, プロピル (メタ)アクリラート, n- およびイソブチル (メタ)アクリラート, ヘキシル, オクチル, 2-エチルヘキシル, デシル, ドデシル, テトラデシル, ヘキサデシル, オクタデシル (メタ)アクリラートおよびこれらのコモノマーの混合物を含む。更なる実施態様では、上述したアルキル基は、一個以上のヒドロキシル基によって置換されてもよい。そのようなアクリル酸エステルの例は、ヒドロキシエチルメタクリラートである。
CH2=CH-OR5 (5)
式中、R5 は、C1-〜C30-アルキルであり、好ましくはC4-〜C16-アルキルであり、特にC6-〜C12-アルキルである。例は、メチルビニルエーテル, エチルビニルエーテル, イソブチルビニルエーテルを含む 。更なる実施態様では、上述したアルキル基は、一個以上のヒドロキシル基によって置換されてもよい。
> C = O
アミンと反応させるのに適したカルボニル化合物は、カルボキシル基を1個以上有するモノマー性かまたはポリマー性のいずれかの化合物である。好ましいのは、カルボニル基を2, 3 または4個有するそれらのモノマー性カルボニル化合物である。それらは、また、酸素, イオウおよび窒素のようなヘテロ原子を含有してもよい。 適したカルボン酸は、例えば, マレイン酸, フマル酸, クロトン酸, イタコン酸, コハク酸, C1-C40-アルケニルコハク酸, アジピン酸, グルタル酸, セバシン酸およびマロン酸, 並びにまた、安息香酸, フタル酸, トリメリット酸およびピロメリト酸, ニトリロ三酢酸, エチレンジアミン四酢酸およびそれらの反応性誘導体, 例えばエステル, 無水物および酸ハライドである。有用なポリマー性カルボニル化合物は、特にエチレン性不飽和酸, 例えばアクリル酸, メタクリル酸, マレイン酸, フマル酸およびイタコン酸のコポリマーであることを見出した; 特に好ましいのは、無水マレインのコポリマーである。適したコモノマーは、コポリマーに油溶性を与えるものである。油溶性は、本明細書中、コポリマーが、脂肪アミンと反応した後に、特に関連した用量で添加剤を添加する中間留分中に残渣無く溶解することを意味する。適したコモノマーは、例えば, オレフィン、アルキルラジカル中に炭素原子を2〜75個, 好ましくは4〜40個、特に8〜20個を有する, アクリル酸およびメタクリル酸のアルキルエステル, アルキルビニルエステル,アルキルビニルエーテルである。オレフィンの場合には,炭素数は、二重結合に結び付いているアルキルラジカルに基づく。ポリマー性カルボニル化合物の分子量は、好ましくは400〜20 000, より好ましくは500〜10 000, 例えば1000〜5000である。
A は、R', COOR', OCOR', R''-COOR', OR'であり;
D は、H, CH3, AまたはR''であり;
E は、H, Aであり;
G は、H, R'', R''-COOR',アリールラジカルまたは複素環式ラジカルであり;
M は、H, COOR'', OCOR'', OR'', COOHであり;
N は、H, R'', COOR'', OCOR",アリールラジカルであり;
R' は、炭素原子8〜50個を有する炭化水素鎖であり;
R'' は、炭素原子1〜10個を有する炭化水素鎖であり;
m は、0.4〜1.0であり; そして
n は、0〜0.6である。
なお、本願は特許請求の範囲に記載の発明に関するものであるが、他の態様として以下も包含し得る:
1.a) 少なくとも一種のエチレン性不飽和エステルに由来する構造単位を12.0〜16.0モル%含有し、
b) 脂肪族炭素原子100個当りプロペンに由来するメチル基を1.0〜4.0個含有し、そして
c) 100個のCH 2 基に付き鎖末端から生じるメチル基が6.5個より少ない
エチレンと、少なくとも一種のエチレン性不飽和エステルと、プロペンとのターポリマー。
2.エチレン性不飽和エステルが、炭素原子2〜12個を有するカルボン酸のビニルエステルである、上記1記載のポリマー。
3.エチレン性不飽和エステルが、ビニルアセタートである、上記1または2記載のポリマー。
4.ビニルアセタート含量が28.0〜36.0重量%である、上記3記載のポリマー。
5.不飽和エステルのモル含量a) およびポリマーの脂肪族炭素原子100個当りのプロペンに由来するメチル基の数 b)の合計G
G = [不飽和エステルのモル%] + [プロペン−CH 3 ]
が、14.5〜18.0である、上記1〜4の一以上に記載のポリマー。
6.カルボニル基を含む少なくとも一種の調節剤に由来する構造単位を更に含有する、上記1〜5の一以上に記載のポリマー。
7.カルボニル基を含む調節剤に由来する少なくとも一つの構造単位を0.5〜7.0重量%含有する、上記6記載のポリマー。
8.エチレンと、プロペンと、少なくとも一種のビニルエステルとの混合物をフリーラジカル形成用開始剤の存在下に高圧および高温で反応させ、そしてカルボニル基を含む調節剤によって分子量を調節することによって、上記1〜7の一以上に記載のポリマーの製造方法。
9.高圧バルク重合を少なくとも100 MPaの圧力下で行う、上記8記載の方法。
10.高圧バルク重合を220°Cより低いピーク温度で行う、上記8または9記載の方法。
11.上記1〜7の一以上に記載の少なくとも一種のポリマーおよび少なくとも一種の異なるエチレンコポリマーを含む組成物。
12.更なるエチレンコポリマーの合計のコモノマー含量が、上記1〜7記載のポリマーの合計のコモノマー含量に比べて少なくとも2モル%低い、上記11記載の組成物。
13.上記1〜7の一以上に記載の少なくとも一種のポリマーあるいは上記11または12に記載の組成物および少なくとも一種の油溶性極性窒素化合物を含む組成物。
14.上記1〜7の一以上に記載の少なくとも一種のポリマーあるいは上記11、12または13に記載の組成物および少なくとも一種のアルキルフェノール−アルデヒド樹脂を含む組成物。
15.上記1〜7の一以上に記載の少なくとも一種のポリマーあるいは上記11、12、13または14に記載の組成物および少なくとも一種の櫛形ポリマーを含む組成物。
16.上記1〜7の一以上に記載の少なくとも一種のポリマーあるいは上記11、12、13、14または15に記載の組成物および少なくとも一種のポリオキシアルキレン化合物を含む組成物。
17.中間留分の低温流動特性を改良するための、先の上記1〜7の一以上に記載のターポリマーの使用。
18.上記1〜7の一以上に記載の少なくとも一種のターポリマーを20−40重量%および少なくとも一種の溶媒を60−80重量%含有する、中間留分の流動特性を改良するための固有の流動点が−10°C以下の易流動性添加剤濃厚物。
19.上記1〜7の一以上に記載の少なくとも一種のターポリマーを少なくとも20重量%含有する配合物を温度0°C以下で燃料油に加えることによって、燃料油の低温流動特性を改良する方法。
20.中間留分および上記1〜7の一以上に記載の少なくとも一種のポリマーを含む燃料油。
鉱油および鉱油留分についての本発明の添加剤の優れた有効性を、CFPP テスト(Cold Filter Plugging Test to EN 116) に準拠して記載する、
下記の添加剤を使用した:
使用したエチレンコポリマーの特性決定
プロセス A): 連続管状反応装置において、エチレン, プロペンおよびビニルアセタートを、200 MPaおよびピーク温度220°C で、表 1に具体的に挙げる分子量調整剤を加えて、共重合させた。形成されたポリマーを反応混合物から取り出し、次いで、残留モノマーを取り除いた。
プロセス B):連続高圧オートクレーブにおいて、エチレン, ビニルアセタートおよびプロピレンを、開始剤としてのビス(2-エチルヘキシル) ペルオキソジカルボナートの10重量%溶液および表 1に具体的に挙げる分子量調整剤を加えて、共重合させた。形成されたポリマーを反応混合物から取り出し、次いで、残留モノマーを取り除いた。
表 1: ポリマーの特性表示
使用したテスト油は、ヨーロッパの精油所からの現時の油であった。CFPP値を求めてEN 116にしかつ雲り点を求めてISO 3015にした。
本発明のポリマー75重量%を、ビニルアセタート24重量%および140°Cにおいて測定した溶融粘度280 mPasを有するエチレンコポリマー25重量%と組み合わせて、テスト油 2における本発明のターポリマーの有効性を求めた。
Claims (17)
- a) 少なくとも一種のエチレン性不飽和エステルに由来する構造単位を12.0〜16.0モル%含有し、
b) 13C NMR分光分析によって測定された場合に、脂肪族炭素原子100個当りプロペンに由来するメチル基を1.0〜4.0個含有し、そして
c) 100個のCH2基に付き鎖末端から生じるメチル基が6.5個より少ない(ここで、鎖末端から生じるメチル基の数は、 13 C NMR分光分析によって測定されるプロペンに由来するメチル基の数を、 1 H NMR分光分析によって測定されるメチル基の数から引くことにより測定され、後者はエチレン性不飽和エステルの側鎖からのメチル基を除く)、
フリーラジカル形成開始剤を用いる高圧バルク重合によって得られた、エチレンと、少なくとも一種のエチレン性不飽和エステルと、プロペンとのターポリマーであって、その際、エチレン性不飽和エステルが、2〜12個の炭素原子を有するカルボン酸のビニルエステル及び1〜12個の炭素原子を有する脂肪アルコールとアクリル酸とのエステル及び該脂肪アルコールとメタクリル酸とのエステルから選択される、上記のターポリマー。 - エチレン性不飽和エステルが、炭素原子2〜12個を有するカルボン酸のビニルエステルである、請求項1記載のポリマー。
- エチレン性不飽和エステルが、ビニルアセタートである、請求項1または2記載のポリマー。
- ビニルアセタート含量が28.0〜36.0重量%である、請求項3記載のポリマー。
- ターポリマーが1000〜25000g/モルの分子量を有する、請求項1〜4のいずれか一に記載のポリマー。
- ターポリマーが、フリーラジカル開始剤を用いる誘発によって、および100〜300 MPaの圧力および100〜260°Cの温度で行われる本質的に溶媒が存在しない高圧バルク重合において、モノマーから重合される、請求項1〜5のいずれか一に記載のポリマー。
- カルボニル基を含む調節剤に由来する少なくとも一つの構造単位を0.5〜7.0重量%含有する、請求項1〜5のいずれか一に記載のポリマー。
- 請求項1〜7のいずれか一に記載の少なくとも一種のポリマーおよび少なくとも一種の異なるエチレンコポリマーを含む組成物。
- 更なるエチレンコポリマーの合計のコモノマー含量が、請求項1〜7のいずれか一に記載のポリマーの合計のコモノマー含量に比べて少なくとも2モル%低い、請求項8記載の組成物。
- 請求項1〜7のいずれか一に記載の少なくとも一種のポリマーあるいは請求項8または9に記載の組成物および少なくとも一種の油溶性極性窒素化合物を含む組成物。
- 請求項1〜7のいずれか一に記載の少なくとも一種のポリマーあるいは請求項8〜10のいずれか一つに記載の組成物および少なくとも一種のアルキルフェノール−アルデヒド樹脂を含む組成物。
- 請求項1〜7のいずれか一に記載の少なくとも一種のポリマーあるいは請求項8〜11のいずれか一つに記載の組成物および少なくとも一種の櫛形ポリマーを含む組成物。
- 請求項1〜7のいずれか一に記載の少なくとも一種のポリマーあるいは請求項8〜12のいずれか一つに記載の組成物および少なくとも一種のポリオキシアルキレン化合物を含む組成物。
- 中間留分の低温流動特性を改良するための、先の請求項1〜7のいずれか一に記載のターポリマーの使用。
- 請求項1〜7のいずれか一に記載の少なくとも一種のターポリマーを20−40重量%および少なくとも一種の溶媒を60−80重量%含有する、中間留分の流動特性を改良するための固有の流動点が−10℃以下の易流動性添加剤濃厚物。
- 請求項1〜7のいずれか一に記載の少なくとも一種のターポリマーを少なくとも20重量%含有する配合物を温度0℃以下で燃料油に加えることによって、燃料油の低温流動特性を改良する方法。
- 中間留分および請求項1〜7のいずれか一に記載の少なくとも一種のポリマーを含む燃料油。
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