JP5840761B2 - 活性炭に吸着された金の回収方法及びそれを用いた金の製造方法 - Google Patents
活性炭に吸着された金の回収方法及びそれを用いた金の製造方法 Download PDFInfo
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- JP5840761B2 JP5840761B2 JP2014502081A JP2014502081A JP5840761B2 JP 5840761 B2 JP5840761 B2 JP 5840761B2 JP 2014502081 A JP2014502081 A JP 2014502081A JP 2014502081 A JP2014502081 A JP 2014502081A JP 5840761 B2 JP5840761 B2 JP 5840761B2
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- 239000010931 gold Substances 0.000 title claims description 119
- 229910052737 gold Inorganic materials 0.000 title claims description 117
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 title claims description 115
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims description 98
- 238000000034 method Methods 0.000 title claims description 45
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 238000010828 elution Methods 0.000 claims description 41
- 239000003480 eluent Substances 0.000 claims description 28
- 239000000243 solution Substances 0.000 claims description 17
- 230000002378 acidificating effect Effects 0.000 claims description 14
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 13
- 238000011084 recovery Methods 0.000 claims description 10
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical group [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 claims description 9
- 235000019345 sodium thiosulphate Nutrition 0.000 claims description 9
- 239000007864 aqueous solution Substances 0.000 claims description 8
- 230000003796 beauty Effects 0.000 claims description 3
- 239000003638 chemical reducing agent Substances 0.000 claims description 3
- FGRVOLIFQGXPCT-UHFFFAOYSA-L dipotassium;dioxido-oxo-sulfanylidene-$l^{6}-sulfane Chemical compound [K+].[K+].[O-]S([O-])(=O)=S FGRVOLIFQGXPCT-UHFFFAOYSA-L 0.000 claims description 3
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 18
- 238000002386 leaching Methods 0.000 description 13
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 10
- 239000003463 adsorbent Substances 0.000 description 10
- 239000002253 acid Substances 0.000 description 8
- 239000012141 concentrate Substances 0.000 description 8
- 229920001021 polysulfide Polymers 0.000 description 8
- 239000005077 polysulfide Substances 0.000 description 8
- 150000008117 polysulfides Polymers 0.000 description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- -1 halide ion Chemical class 0.000 description 6
- 238000001179 sorption measurement Methods 0.000 description 6
- 238000003723 Smelting Methods 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 238000006722 reduction reaction Methods 0.000 description 5
- 229910052717 sulfur Inorganic materials 0.000 description 5
- 239000011593 sulfur Substances 0.000 description 5
- 229940006280 thiosulfate ion Drugs 0.000 description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 4
- DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 description 4
- 229910052951 chalcopyrite Inorganic materials 0.000 description 4
- 229910052976 metal sulfide Inorganic materials 0.000 description 4
- 230000001590 oxidative effect Effects 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 235000013162 Cocos nucifera Nutrition 0.000 description 3
- 244000060011 Cocos nucifera Species 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- QZPSXPBJTPJTSZ-UHFFFAOYSA-N aqua regia Chemical compound Cl.O[N+]([O-])=O QZPSXPBJTPJTSZ-UHFFFAOYSA-N 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 238000002354 inductively-coupled plasma atomic emission spectroscopy Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- XEIPQVVAVOUIOP-UHFFFAOYSA-N [Au]=S Chemical compound [Au]=S XEIPQVVAVOUIOP-UHFFFAOYSA-N 0.000 description 2
- AQLMHYSWFMLWBS-UHFFFAOYSA-N arsenite(1-) Chemical compound O[As](O)[O-] AQLMHYSWFMLWBS-UHFFFAOYSA-N 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 2
- 229910052683 pyrite Inorganic materials 0.000 description 2
- 239000011028 pyrite Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 238000000638 solvent extraction Methods 0.000 description 2
- 230000036962 time dependent Effects 0.000 description 2
- 210000003462 vein Anatomy 0.000 description 2
- 241000416536 Euproctis pseudoconspersa Species 0.000 description 1
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 229910052947 chalcocite Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007806 chemical reaction intermediate Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005188 flotation Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 231100000086 high toxicity Toxicity 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229940097275 indigo Drugs 0.000 description 1
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical compound [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 description 1
- 229940039790 sodium oxalate Drugs 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3416—Regenerating or reactivating of sorbents or filter aids comprising free carbon, e.g. activated carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/345—Regenerating or reactivating using a particular desorbing compound or mixture
- B01J20/3475—Regenerating or reactivating using a particular desorbing compound or mixture in the liquid phase
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/04—Obtaining noble metals by wet processes
- C22B11/042—Recovery of noble metals from waste materials
- C22B11/046—Recovery of noble metals from waste materials from manufactured products, e.g. from printed circuit boards, from photographic films, paper or baths
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/006—Wet processes
- C22B7/007—Wet processes by acid leaching
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Carbon And Carbon Compounds (AREA)
Description
S2O3 2- ⇔ S+SO3 2- → 酸化、加水分解 → H2SO4 (式1)
Au(HSnH)mX
(Xはハロゲン、mは1〜4の整数、nは1〜9の整数)
前者の形態(硫化金)の場合はS2-と反応して溶解することで溶離される(非特許文献1)。後者の形態の場合、NaOHと配位しているポリ硫化水素のHが反応して錯体が負電荷を帯びることで溶離される。
(非特許文献1)高木誠司、定性分析化学中巻、イオン反応編、南江堂
金を含む硫化金属精鉱(Cu:17質量%、Fe:27質量%、S:25質量%、Au:90ppm)を、浸出液に対し35g/Lとなるよう秤量した。浸出液は、Cl:180g/L、Br:20g/L、Cu:18g/L、Fe:2g/Lを含有し、pHは1.5とした。浸出液を85℃に加温し、空気を1分当たり0.1L吹き込みながら攪拌した。こうして得た金濃度が2mg/L以上の浸出液をヤシ殻由来活性炭(太平化学産業社製ヤシコールMC)を充填したカラムに通し、金を活性炭に吸着させた。適当に金を吸着させたところで活性炭を取り出し、金濃度を定量したところ9000g/ton程度であった。金の濃度は灰吹き法で濃縮した後に王水に溶解し、ICP−AESにより定量した。
塩酸と水酸化ナトリウムでpHを4、8、12に調整した水溶液にチオ硫酸ナトリウムを0.5mol/L(チオ硫酸イオンとして56g/L)となるように添加した溶離液を調製した。この金を吸着した活性炭を20g/Lの割合で溶離液に浸漬して80℃で攪拌して溶離を行った。金の濃度は過酸化水素を2mL添加し、さらに塩酸で希釈して100mLに規正した後に上澄みをICP−AESにより定量した。
実施例1と同様にして調整した活性炭を用いてpH4の希硫酸を溶離液とし、活性炭を20g/Lの割合で溶離液に浸漬して80℃で攪拌して溶離を行った。
実施例1と同様にして調整した活性炭を用いてチオ硫酸ナトリウムを0.1mol/L(チオ硫酸イオンとして11.2g/L)となるように添加した溶離液を調製した。溶離液のpHは4とした。この金を吸着した活性炭を20g/Lの割合で溶離液に浸漬して80℃で攪拌して溶離を行った。溶離液中の金濃度から換算した溶離率の経時変化を図2に示す。
実施例1と同様にして調整した活性炭を用いてチオ硫酸ナトリウムを0.1mol/L(チオ硫酸イオンとして11.2g/L)となるように添加した溶離液を調製した。溶離液のpHは4とした。この金を吸着した活性炭を20g/Lの割合で溶離液に浸漬して25℃で攪拌して溶離を行った。溶離液中の金濃度の経時変化を図2に示す。
金を9800g/t吸着した活性炭(太平化学産業社製:CC−202)19mLを内径11mm、高さ200mmのコックつきガラスカラムに充填した。活性炭はあらかじめHClにより洗浄しておいた。次に、純水に濃度:0.01mol/L、0.1mol/L、0.5mol/L、又は、1.0mol/Lとなるようチオ硫酸ナトリウムを添加し、pHを硫酸で5に調整し、これを溶離液とした。続いて、活性炭を充填したカラムに溶離液を4.1mL/分で供給して通液後液を5〜7mLごとに分画して採取した。カラム内部温度は70℃とした。カラム通液のSV:空間速度は13(1/h)とし、LV:線速度は2.6(m/h)とし、BV:通液量は156(mL)とした。次に、分画液中の金濃度をICP−AESで測定し、活性炭に含まれる金の品位を算出した。上記試験条件を表1に示し、得られた通液量と活性炭中の金品位との関係を表2に示し、そのグラフを図3に示す。
Claims (8)
- 活性炭に吸着された金を、酸性水溶液にチオ硫酸塩を添加して調製された溶離液で溶離して、酸性の濃厚金溶液を得る工程を備えた金の回収方法。
- 前記酸性水溶液はpH4〜7である請求項1に記載の金の回収方法。
- 前記チオ硫酸塩はチオ硫酸ナトリウム、及び、チオ硫酸カリウムから選択された少なくとも一種を含む還元剤である請求項1又は2に記載の金の回収方法。
- 前記溶離液中のチオ硫酸塩の濃度が0.01mol/L以上である請求項1〜3のいずれかに記載の金の回収方法。
- 前記溶離液中のチオ硫酸塩の濃度が0.01〜1.0mol/Lである請求項4に記載の金の回収方法。
- 前記溶離を、溶離温度を20〜100℃として回分式反応器を用いて行う請求項1〜5のいずれかに記載の金の回収方法。
- 前記溶離温度を60〜85℃とする請求項6に記載の金の回収方法。
- 請求項1〜7のいずれかに記載の金の回収方法で得られた濃厚金溶液から還元によって単体の金を作製する金の製造方法。
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JPPCT/JP2012/079855 | 2012-11-16 | ||
JP2014502081A JP5840761B2 (ja) | 2012-03-01 | 2013-01-30 | 活性炭に吸着された金の回収方法及びそれを用いた金の製造方法 |
PCT/JP2013/052101 WO2013129017A1 (ja) | 2012-03-01 | 2013-01-30 | 活性炭に吸着された金の回収方法及びそれを用いた金の製造方法 |
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EP (1) | EP2821513A4 (ja) |
JP (1) | JP5840761B2 (ja) |
AU (1) | AU2013200947B2 (ja) |
CA (1) | CA2865721C (ja) |
CL (1) | CL2014002292A1 (ja) |
PE (2) | PE20190559A1 (ja) |
WO (1) | WO2013129017A1 (ja) |
Families Citing this family (6)
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US10161016B2 (en) | 2013-05-29 | 2018-12-25 | Barrick Gold Corporation | Method for pre-treatment of gold-bearing oxide ores |
WO2016104113A1 (ja) | 2014-12-26 | 2016-06-30 | Jx金属株式会社 | 活性炭からの金の回収方法 |
CN104928487A (zh) * | 2015-06-06 | 2015-09-23 | 长春黄金研究院 | 一种炭浆提金工艺中粉炭的处理方法 |
CN107400778B (zh) * | 2017-08-08 | 2019-01-18 | 中南大学 | 一种从强碱性阴离子交换树脂上解吸金硫代硫酸根配离子的方法 |
PE20211512A1 (es) | 2019-01-21 | 2021-08-11 | Barrick Gold Corp | Metodo para la lixiviacion con tiosulfato catalizado con carbon de materiales que contienen oro |
CN115385413A (zh) * | 2021-11-03 | 2022-11-25 | 董河贵 | 一种含金废水的处理组合物及其使用方法 |
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ZA785464B (en) * | 1978-09-26 | 1980-01-30 | Anglo Amer Corp South Africa | Noble metal recovery |
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GB8726158D0 (en) * | 1987-11-07 | 1987-12-09 | British Petroleum Co Plc | Separation process |
US4968346A (en) * | 1989-09-29 | 1990-11-06 | E. I. Du Pont De Nemours And Company | Method for eluting adsorbed gold from carbon |
JP3079035B2 (ja) | 1996-05-27 | 2000-08-21 | 日鉱金属株式会社 | 金の回収方法 |
JP3616314B2 (ja) | 2000-03-03 | 2005-02-02 | 日鉱金属株式会社 | 銅電解殿物の処理方法 |
MXPA05007123A (es) | 2002-12-31 | 2006-02-08 | Intec Ltd | Recuperacion de metales a partir de materiales sulfidicos. |
JP4642796B2 (ja) * | 2006-09-28 | 2011-03-02 | Jx日鉱日石金属株式会社 | 金の浸出方法 |
JP2010270368A (ja) * | 2009-05-21 | 2010-12-02 | Suminoe Textile Co Ltd | 貴金属回収用フィルター及び貴金属回収フィルターから貴金属を分離する方法。 |
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2013
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- 2013-01-30 JP JP2014502081A patent/JP5840761B2/ja active Active
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PE20190559A1 (es) | 2019-04-17 |
CA2865721C (en) | 2017-08-01 |
CA2865721A1 (en) | 2013-09-06 |
EP2821513A1 (en) | 2015-01-07 |
WO2013129017A1 (ja) | 2013-09-06 |
CL2014002292A1 (es) | 2014-11-21 |
AU2013200947A1 (en) | 2013-09-19 |
PE20142107A1 (es) | 2014-12-13 |
EP2821513A4 (en) | 2015-12-09 |
AU2013200947B2 (en) | 2013-12-12 |
JPWO2013129017A1 (ja) | 2015-07-30 |
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