JP5836819B2 - 連続撹拌式槽型反応器 - Google Patents
連続撹拌式槽型反応器 Download PDFInfo
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- JP5836819B2 JP5836819B2 JP2012014227A JP2012014227A JP5836819B2 JP 5836819 B2 JP5836819 B2 JP 5836819B2 JP 2012014227 A JP2012014227 A JP 2012014227A JP 2012014227 A JP2012014227 A JP 2012014227A JP 5836819 B2 JP5836819 B2 JP 5836819B2
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- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000001508 potassium citrate Chemical class 0.000 description 1
- 229960002635 potassium citrate Drugs 0.000 description 1
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical class [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 1
- 235000011082 potassium citrates Nutrition 0.000 description 1
- 239000004224 potassium gluconate Chemical class 0.000 description 1
- 235000013926 potassium gluconate Nutrition 0.000 description 1
- 229960003189 potassium gluconate Drugs 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000012176 shellac wax Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229940087562 sodium acetate trihydrate Drugs 0.000 description 1
- BHZOKUMUHVTPBX-UHFFFAOYSA-M sodium acetic acid acetate Chemical compound [Na+].CC(O)=O.CC([O-])=O BHZOKUMUHVTPBX-UHFFFAOYSA-M 0.000 description 1
- 239000001509 sodium citrate Chemical class 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical class O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 229960001790 sodium citrate Drugs 0.000 description 1
- 235000011083 sodium citrates Nutrition 0.000 description 1
- 239000000176 sodium gluconate Chemical class 0.000 description 1
- 235000012207 sodium gluconate Nutrition 0.000 description 1
- 229940005574 sodium gluconate Drugs 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- AGGKEGLBGGJEBZ-UHFFFAOYSA-N tetramethylenedisulfotetramine Chemical compound C1N(S2(=O)=O)CN3S(=O)(=O)N1CN2C3 AGGKEGLBGGJEBZ-UHFFFAOYSA-N 0.000 description 1
- UZVUJVFQFNHRSY-OUTKXMMCSA-J tetrasodium;(2s)-2-[bis(carboxylatomethyl)amino]pentanedioate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CC[C@@H](C([O-])=O)N(CC([O-])=O)CC([O-])=O UZVUJVFQFNHRSY-OUTKXMMCSA-J 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- GINSRDSEEGBTJO-UHFFFAOYSA-N thietane 1-oxide Chemical compound O=S1CCC1 GINSRDSEEGBTJO-UHFFFAOYSA-N 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 229940117957 triethanolamine hydrochloride Drugs 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- AISMNBXOJRHCIA-UHFFFAOYSA-N trimethylazanium;bromide Chemical compound Br.CN(C)C AISMNBXOJRHCIA-UHFFFAOYSA-N 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/0802—Preparation methods
- G03G9/0804—Preparation methods whereby the components are brought together in a liquid dispersing medium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/40—Static mixers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/14—Treatment of polymer emulsions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/14—Treatment of polymer emulsions
- C08F6/18—Increasing the size of the dispersed particles
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Developing Agents For Electrophotography (AREA)
- Colloid Chemistry (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Glanulating (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/025,664 | 2011-02-11 | ||
| US13/025,664 US8663565B2 (en) | 2011-02-11 | 2011-02-11 | Continuous emulsification—aggregation process for the production of particles |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012166191A JP2012166191A (ja) | 2012-09-06 |
| JP2012166191A5 JP2012166191A5 (enExample) | 2015-03-05 |
| JP5836819B2 true JP5836819B2 (ja) | 2015-12-24 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012014227A Active JP5836819B2 (ja) | 2011-02-11 | 2012-01-26 | 連続撹拌式槽型反応器 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8663565B2 (enExample) |
| EP (1) | EP2487544B1 (enExample) |
| JP (1) | JP5836819B2 (enExample) |
| KR (1) | KR101798245B1 (enExample) |
| BR (1) | BR102012003121B1 (enExample) |
| CA (1) | CA2766716C (enExample) |
| MX (1) | MX336335B (enExample) |
| TW (1) | TWI561298B (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9329508B2 (en) * | 2013-03-26 | 2016-05-03 | Xerox Corporation | Emulsion aggregation process |
| US20150104742A1 (en) * | 2013-10-11 | 2015-04-16 | Xerox Corporation | Emulsion aggregation toners |
| JPWO2015080190A1 (ja) * | 2013-11-29 | 2017-03-16 | 三菱化学株式会社 | スラリーの洗浄装置及び洗浄システム |
| JP2015175913A (ja) * | 2014-03-13 | 2015-10-05 | 三菱化学株式会社 | 静電荷像現像用トナーの製造方法 |
| US9134635B1 (en) | 2014-04-14 | 2015-09-15 | Xerox Corporation | Method for continuous aggregation of pre-toner particles |
| WO2015186710A1 (ja) * | 2014-06-04 | 2015-12-10 | 三菱化学株式会社 | 連続式反応装置及びトナーの製造装置 |
| EP3154674B1 (de) * | 2014-06-16 | 2018-07-18 | Bayer Aktiengesellschaft | Reaktionskammer für einen chemischen reaktor und hieraus aufgebauter chemischer reaktor |
| US9464173B2 (en) * | 2014-12-16 | 2016-10-11 | Xerox Corporation | Latex preparation using an agitated reactor column |
| JP7292743B2 (ja) * | 2018-12-26 | 2023-06-19 | エム・テクニック株式会社 | 流体処理装置 |
| KR102077818B1 (ko) * | 2019-10-21 | 2020-02-14 | 금성이엔씨 주식회사 | 반응기장치 |
| KR102314019B1 (ko) * | 2019-12-20 | 2021-10-15 | 주식회사 포스코 | 과산화리튬의 입도 조절 방법 및 입도가 조절된 리튬산화물의 제조방법 |
| CN116832755A (zh) * | 2023-08-06 | 2023-10-03 | 陈大志 | 一种连续流反应器 |
Family Cites Families (83)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3590000A (en) | 1967-06-05 | 1971-06-29 | Xerox Corp | Solid developer for latent electrostatic images |
| US4113796A (en) | 1969-11-21 | 1978-09-12 | Bayer Aktiengesellschaft | Process for working up dispersions of elastic-thermoplastic or thermoplastic plastics |
| US3720617A (en) | 1970-05-20 | 1973-03-13 | Xerox Corp | An electrostatic developer containing modified silicon dioxide particles |
| US3800588A (en) | 1971-04-30 | 1974-04-02 | Mts System Corp | Multiple axis control system for vibration test apparatus |
| US3847604A (en) | 1971-06-10 | 1974-11-12 | Xerox Corp | Electrostatic imaging process using nodular carriers |
| US3983045A (en) | 1971-10-12 | 1976-09-28 | Xerox Corporation | Three component developer composition |
| US3944493A (en) | 1974-05-16 | 1976-03-16 | Eastman Kodak Company | Electrographic toner and developer composition |
| US4007293A (en) | 1976-03-01 | 1977-02-08 | Xerox Corporation | Mechanically viable developer materials |
| US4079014A (en) | 1976-07-21 | 1978-03-14 | Eastman Kodak Company | Electrographic toner and developer composition containing a 4-aza-1-azoniabicyclo(2.2.2) octane salt as a charge control agent |
| US4265990A (en) | 1977-05-04 | 1981-05-05 | Xerox Corporation | Imaging system with a diamine charge transport material in a polycarbonate resin |
| EP0023230B1 (de) | 1979-07-26 | 1984-05-16 | J.T. Baker Chemicals B.V. | Reagenz zur quantitativen Bestimmung von Wasser und seine Verwendung zur quantitativen Bestimmung von Wasser |
| US4394430A (en) | 1981-04-14 | 1983-07-19 | Eastman Kodak Company | Electrophotographic dry toner and developer compositions |
| US4560635A (en) | 1984-08-30 | 1985-12-24 | Xerox Corporation | Toner compositions with ammonium sulfate charge enhancing additives |
| US4584253A (en) | 1984-12-24 | 1986-04-22 | Xerox Corporation | Electrophotographic imaging system |
| US4563408A (en) | 1984-12-24 | 1986-01-07 | Xerox Corporation | Photoconductive imaging member with hydroxyaromatic antioxidant |
| US4935326A (en) | 1985-10-30 | 1990-06-19 | Xerox Corporation | Electrophotographic carrier particles coated with polymer mixture |
| US4937166A (en) | 1985-10-30 | 1990-06-26 | Xerox Corporation | Polymer coated carrier particles for electrophotographic developers |
| US4855113A (en) * | 1986-10-27 | 1989-08-08 | Pennwalt Corporation | Apparatus for removing sulfur from organic polysulfides |
| US4858884A (en) | 1988-09-22 | 1989-08-22 | Suntex Industries Incorporated | Diaphragm-actuated valve for a gear pump |
| US5236629A (en) | 1991-11-15 | 1993-08-17 | Xerox Corporation | Conductive composite particles and processes for the preparation thereof |
| US5227460A (en) | 1991-12-30 | 1993-07-13 | Xerox Corporation | Cross-linked toner resins |
| US5302486A (en) | 1992-04-17 | 1994-04-12 | Xerox Corporation | Encapsulated toner process utilizing phase separation |
| US5264315A (en) * | 1992-04-20 | 1993-11-23 | Xerox Corporation | Process for the continuous preparation of encapsulated toner |
| US5290654A (en) | 1992-07-29 | 1994-03-01 | Xerox Corporation | Microsuspension processes for toner compositions |
| US5278020A (en) | 1992-08-28 | 1994-01-11 | Xerox Corporation | Toner composition and processes thereof |
| US5330874A (en) | 1992-09-30 | 1994-07-19 | Xerox Corporation | Dry carrier coating and processes |
| US5308734A (en) | 1992-12-14 | 1994-05-03 | Xerox Corporation | Toner processes |
| US5346797A (en) | 1993-02-25 | 1994-09-13 | Xerox Corporation | Toner processes |
| US5348832A (en) | 1993-06-01 | 1994-09-20 | Xerox Corporation | Toner compositions |
| US5418108A (en) | 1993-06-25 | 1995-05-23 | Xerox Corporation | Toner emulsion aggregation process |
| US5344738A (en) | 1993-06-25 | 1994-09-06 | Xerox Corporation | Process of making toner compositions |
| US5364729A (en) | 1993-06-25 | 1994-11-15 | Xerox Corporation | Toner aggregation processes |
| US5370963A (en) | 1993-06-25 | 1994-12-06 | Xerox Corporation | Toner emulsion aggregation processes |
| US5405728A (en) | 1993-06-25 | 1995-04-11 | Xerox Corporation | Toner aggregation processes |
| US5403693A (en) | 1993-06-25 | 1995-04-04 | Xerox Corporation | Toner aggregation and coalescence processes |
| US5366841A (en) | 1993-09-30 | 1994-11-22 | Xerox Corporation | Toner aggregation processes |
| US5501935A (en) | 1995-01-17 | 1996-03-26 | Xerox Corporation | Toner aggregation processes |
| US5527658A (en) | 1995-03-13 | 1996-06-18 | Xerox Corporation | Toner aggregation processes using water insoluble transition metal containing powder |
| US5496676A (en) | 1995-03-27 | 1996-03-05 | Xerox Corporation | Toner aggregation processes |
| FR2749310B1 (fr) | 1996-06-03 | 1998-08-14 | Atochem Elf Sa | Procede pour produire des particules de latex polymere coagulees |
| US5585215A (en) | 1996-06-13 | 1996-12-17 | Xerox Corporation | Toner compositions |
| US5650255A (en) | 1996-09-03 | 1997-07-22 | Xerox Corporation | Low shear toner aggregation processes |
| US5650256A (en) | 1996-10-02 | 1997-07-22 | Xerox Corporation | Toner processes |
| US5733758A (en) * | 1997-01-10 | 1998-03-31 | Nguyen; Quang A. | Tower reactors for bioconversion of lignocellulosic material |
| US5853943A (en) | 1998-01-09 | 1998-12-29 | Xerox Corporation | Toner processes |
| US6063827A (en) | 1998-07-22 | 2000-05-16 | Xerox Corporation | Polyester process |
| US6214507B1 (en) | 1998-08-11 | 2001-04-10 | Xerox Corporation | Toner compositions |
| US6190815B1 (en) | 1998-08-11 | 2001-02-20 | Xerox Corporation | Toner compositions |
| US6004714A (en) | 1998-08-11 | 1999-12-21 | Xerox Corporation | Toner compositions |
| DE60040344D1 (de) * | 1999-11-05 | 2008-11-06 | Univ Utah Res Found | Abbau von polyzyklischen, aromatischen kohlenwasserstoffen |
| CA2292862A1 (en) * | 1999-12-22 | 2001-06-22 | Bayer Inc. | Modular reactor system allowing control of particle size during chemical precipitation |
| TWI227384B (en) | 2000-10-12 | 2005-02-01 | Mitsui Chemicals Inc | A toner binder for electrophotography and toner for electrophotography |
| DE10108484A1 (de) * | 2001-02-22 | 2002-09-05 | Bayer Ag | Verbessertes Verfahren zur Herstelung von Polyetherpolyolen |
| US6593049B1 (en) | 2001-03-26 | 2003-07-15 | Xerox Corporation | Toner and developer compositions |
| DE10139293A1 (de) * | 2001-08-09 | 2003-02-27 | Basf Ag | Verbessertes Verfahren zur Herstellung von Polytetrahydrofuran |
| US6764802B2 (en) | 2002-07-29 | 2004-07-20 | Xerox Corporation | Chemical aggregation process using inline mixer |
| US6756176B2 (en) | 2002-09-27 | 2004-06-29 | Xerox Corporation | Toner processes |
| US6830860B2 (en) | 2003-01-22 | 2004-12-14 | Xerox Corporation | Toner compositions and processes thereof |
| US6803166B2 (en) | 2003-02-18 | 2004-10-12 | Xerox Corporation | Toner processes |
| US6984480B2 (en) * | 2003-06-25 | 2006-01-10 | Xerox Corporation | Toner processes |
| US7037633B2 (en) | 2003-06-25 | 2006-05-02 | Xerox Corporation | Toner processes |
| US20050272851A1 (en) | 2004-06-04 | 2005-12-08 | Xerox Corporation | Wax emulsion for emulsion aggregation toner |
| US7179575B2 (en) | 2004-06-28 | 2007-02-20 | Xerox Corporation | Emulsion aggregation toner having gloss enhancement and toner release |
| US7402371B2 (en) | 2004-09-23 | 2008-07-22 | Xerox Corporation | Low melt toners and processes thereof |
| US20090264585A1 (en) | 2004-10-15 | 2009-10-22 | Avramidis Kostas S | Emulsion polymerization of hydrophobic monomers |
| US7329476B2 (en) | 2005-03-31 | 2008-02-12 | Xerox Corporation | Toner compositions and process thereof |
| US7622234B2 (en) | 2005-03-31 | 2009-11-24 | Xerox Corporation | Emulsion/aggregation based toners containing a novel latex resin |
| US20060269859A1 (en) | 2005-05-31 | 2006-11-30 | Xerox Corporation | Emulsion aggregation toner and developer |
| US7459258B2 (en) | 2005-06-17 | 2008-12-02 | Xerox Corporation | Toner processes |
| US8080360B2 (en) | 2005-07-22 | 2011-12-20 | Xerox Corporation | Toner preparation processes |
| US20070020542A1 (en) | 2005-07-22 | 2007-01-25 | Xerox Corporation | Emulsion aggregation, developer, and method of making the same |
| US7452646B2 (en) | 2005-08-08 | 2008-11-18 | Xerox Corporation | External surface additive compositions |
| US7683142B2 (en) * | 2005-10-11 | 2010-03-23 | Xerox Corporation | Latex emulsion polymerizations in spinning disc reactors or rotating tubular reactors |
| US7507517B2 (en) | 2005-10-11 | 2009-03-24 | Xerox Corporation | Toner processes |
| US7390606B2 (en) | 2005-10-17 | 2008-06-24 | Xerox Corporation | Emulsion aggregation toner incorporating aluminized silica as a coagulating agent |
| US7977024B2 (en) | 2005-12-16 | 2011-07-12 | Xerox Corporation | Solvent-free toner making process using phase inversion |
| US7785763B2 (en) | 2006-10-13 | 2010-08-31 | Xerox Corporation | Emulsion aggregation processes |
| US7862971B2 (en) | 2007-01-31 | 2011-01-04 | Xerox Corporation | Emulsion aggregation toner composition |
| US7749673B2 (en) | 2007-03-29 | 2010-07-06 | Xerox Corporation | Toner processes |
| US7695884B2 (en) | 2007-08-15 | 2010-04-13 | Xerox Corporation | Toner compositions and processes |
| US8450040B2 (en) * | 2009-10-22 | 2013-05-28 | Xerox Corporation | Method for controlling a toner preparation process |
| US8394568B2 (en) * | 2009-11-02 | 2013-03-12 | Xerox Corporation | Synthesis and emulsification of resins |
| US8685612B2 (en) * | 2011-01-18 | 2014-04-01 | Xerox Corporation | Continuous emulsification-aggregation process for the production of particles |
-
2011
- 2011-02-11 US US13/025,664 patent/US8663565B2/en active Active
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2012
- 2012-01-26 JP JP2012014227A patent/JP5836819B2/ja active Active
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Also Published As
| Publication number | Publication date |
|---|---|
| US8663565B2 (en) | 2014-03-04 |
| TWI561298B (en) | 2016-12-11 |
| EP2487544A1 (en) | 2012-08-15 |
| KR101798245B1 (ko) | 2017-11-15 |
| BR102012003121B1 (pt) | 2019-10-29 |
| TW201238648A (en) | 2012-10-01 |
| JP2012166191A (ja) | 2012-09-06 |
| CA2766716C (en) | 2016-05-24 |
| MX2012001655A (es) | 2012-08-30 |
| BR102012003121A2 (pt) | 2013-07-02 |
| US20120208123A1 (en) | 2012-08-16 |
| MX336335B (es) | 2016-01-15 |
| KR20120092514A (ko) | 2012-08-21 |
| EP2487544B1 (en) | 2016-01-20 |
| CA2766716A1 (en) | 2012-08-11 |
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