JP5828613B2 - Catalyst layer with reinforcing membrane-electrolyte membrane laminate, electrode with reinforcing membrane-electrolyte membrane laminate, and polymer electrolyte fuel cell - Google Patents

Description

  The present invention relates to a catalyst layer-electrolyte membrane laminate with a reinforcing membrane, an electrode-electrolyte membrane laminate with a reinforcing membrane, and a polymer electrolyte fuel cell.

  A fuel cell is a cell in which electrodes are arranged on both sides of an electrolyte membrane and generates electricity by an electrochemical reaction between hydrogen and oxygen, and only water is generated during power generation. Thus, unlike the conventional internal combustion engine, it is expected to spread as a next-generation clean energy system because it does not generate environmental load gas such as carbon dioxide. In particular, the polymer electrolyte fuel cell has a low operating temperature and a low resistance of the electrolyte membrane. In addition, since it uses a highly active catalyst, it can obtain a high output even in a small size, as a home cogeneration system, etc. Early commercialization is expected.

  This polymer electrolyte fuel cell normally uses a solid polymer electrolyte membrane having proton conductivity, and an electrode is formed by sequentially laminating a catalyst layer and a gas diffusion layer on both surfaces of the electrolyte membrane. And it has the structure which has arrange | positioned the gasket so that the circumference | surroundings of the electrode which consists of this catalyst layer and gas diffusion layer may be enclosed, and also this was pinched | interposed with the separator (for example, refer FIG. 1 of patent document 1).

JP 2006-236671 A

  By the way, in the polymer electrolyte fuel cell, since the gasket is installed so as to surround the outer side of the electrode from the viewpoint of positional accuracy, a gap is formed between the gasket and the electrode. The electrolyte membrane corresponding to is in a state where it is not pressed by either the electrode or the gasket. Here, when the polymer electrolyte fuel cell repeats power generation / non-power generation, the electrolyte membrane repeats a wet state and a dry state, but the electrolyte membrane corresponding to the gap portion is not pressed by an electrode or a gasket. Expansion and contraction are repeated. As a result, stress is generated in the electrolyte membrane, resulting in fatigue and the electrolyte membrane may be damaged.

  Further, in the polymer electrolyte fuel cell, the outer peripheral edge of the electrolyte membrane on which the gasket is installed is a portion that does not contribute to power generation, and there is a problem that generally an expensive electrolyte membrane cannot be effectively used. .

  Therefore, the present invention provides a catalyst layer-electrolyte membrane laminate, an electrode-electrolyte membrane laminate, and a polymer electrolyte fuel cell that can reliably prevent damage to the electrolyte membrane and can effectively use the electrolyte membrane. The issue is to provide.

  A catalyst layer-electrolyte membrane laminate with a reinforcing membrane according to the present invention is made in order to solve the above problems, and a solid polymer electrolyte membrane made of a perfluorocarbonsulfonic acid-based fluorine ion exchange resin, The catalyst layer formed on both surfaces of the electrolyte membrane and a perfluorocarbon sulfonic acid-based fluorine ion exchange resin are used as materials to cover the outer peripheral edge of the catalyst layer-electrolyte membrane laminate comprising the electrolyte membrane and the catalyst layer. And a reinforcing membrane having a frame-like welded layer welded to at least one surface of the catalyst layer-electrolyte membrane laminate.

According to the present invention described above, the reinforcing membrane is welded to at least one surface of the catalyst layer-electrolyte membrane laminate so as to cover the outer peripheral edge portion of the catalyst layer-electrolyte membrane laminate, so that the catalyst layer rather than the electrolyte membrane. Is small, the outer peripheral edge of the electrolyte membrane in which the catalyst layer is not formed can be restrained by the reinforcing membrane. For this reason, it becomes possible to suppress expansion / contraction of the electrolyte membrane, and damage to the electrolyte membrane can be prevented. In addition, since the reinforcing membrane is welded to at least one surface of the catalyst layer-electrolyte membrane laminate, a gasket is installed on the reinforcing membrane by forming this reinforcing membrane one size larger than the catalyst layer-electrolyte membrane laminate. can do. Since there is no need to install a gasket on the electrolyte membrane in this way, the catalyst layer and the electrolyte membrane can be made the same size, and consequently the electrolyte membrane that does not contribute to power generation is reduced and the electrolyte membrane is used effectively. Can do. Furthermore, since the reinforcing membrane uses a perfluorocarbon sulfonic acid-based fluorine ion exchange resin like the electrolyte membrane, it expands and contracts in the same manner as the electrolyte membrane, and as a result, the reinforcing membrane peels off from the electrolyte membrane. This can be surely prevented. And since the catalyst layer usually contains the same material as the electrolyte membrane, that is, a perfluorocarbon sulfonic acid-based fluorine ion exchange resin, it is possible to reliably prevent the reinforcing membrane from being peeled off from the catalyst layer.

  The catalyst layer-electrolyte membrane laminate with the reinforcing membrane can have various configurations. For example, the reinforcing membrane is preferably made of the same material as the electrolyte membrane. According to this structure, it can prevent more reliably that a reinforcement film | membrane peels from an electrolyte membrane or a catalyst layer.

  Moreover, it is preferable that the said reinforcement film | membrane further has a protective layer formed on a welding layer and protecting a welding layer. According to this structure, it can prevent that the catalyst layer-electrolyte membrane laminated body with a reinforcement film | membrane is damaged at the time of transportation or handling.

  The reinforcing film preferably further includes a gas barrier layer that is formed on the weld layer and prevents the permeation of fuel gas and oxidant gas. According to this configuration, gas leakage can be reliably prevented.

  The gas barrier layer is preferably a polyester resin from the viewpoint of gas barrier properties.

  Further, in the catalyst layer-electrolyte membrane laminate, the catalyst layer is formed on the electrolyte membrane except for the outer peripheral edge portion of the electrolyte membrane, and the reinforcing film has a welding layer between the outer peripheral edge portion of the catalyst layer and the electrolyte membrane. It can comprise so that it may weld to an outer periphery part. In addition, in the catalyst layer-electrolyte membrane laminate, the catalyst layer is formed on both surfaces of the electrolyte membrane, and the reinforcing membrane is formed slightly larger than the catalyst layer-electrolyte membrane laminate. It can also comprise so that welding layer may mutually weld in the part beyond a layer-electrolyte membrane laminated body.

  In addition, an electrode-electrolyte membrane laminate with a reinforcing membrane according to the present invention is made to solve the above problems, and the catalyst layer-electrolyte membrane laminate with a reinforcing membrane according to any one of the above and the reinforcement And a gas diffusion layer formed on the catalyst layer exposed from the opening of the membrane.

  The polymer electrolyte fuel cell according to the present invention has been made to solve the above-mentioned problems, and each electrode comprising the above-mentioned electrode-electrolyte membrane laminate with reinforcing membrane, the catalyst layer and the gas diffusion layer. And a separator respectively installed on the reinforcing film so as to surround the periphery of the electrode, and a separator respectively installed on each of the electrodes and the gasket.

  According to the present invention, a catalyst layer-electrolyte membrane laminate, an electrode-electrolyte membrane laminate, and a polymer electrolyte fuel cell that can reliably prevent damage to the electrolyte membrane and can effectively use the electrolyte membrane are provided. Can be provided.

1 is a front sectional view showing an embodiment of a polymer electrolyte fuel cell according to the present invention. 1 is a plan view showing an embodiment of a polymer electrolyte fuel cell according to the present invention. It is a partially expanded sectional view which shows the detail of the outer periphery part of the polymer electrolyte fuel cell which concerns on this embodiment. It is explanatory drawing which shows the manufacturing method of the polymer electrolyte fuel cell which concerns on this embodiment. It is explanatory drawing which shows a part of manufacturing method of the polymer electrolyte fuel cell which concerns on this embodiment. It is front sectional drawing which shows other embodiment of the polymer electrolyte fuel cell which concerns on this invention. It is front sectional drawing which shows other embodiment of the polymer electrolyte fuel cell which concerns on this invention.

  Hereinafter, embodiments of a polymer electrolyte fuel cell according to the present invention will be described with reference to the drawings. FIG. 1 is a front sectional view of a polymer electrolyte fuel cell according to this embodiment, FIG. 2 is a plan view of the polymer electrolyte fuel cell according to this embodiment, and FIG. 3 is an electrode-electrolyte membrane laminate with a reinforcing membrane. It is an enlarged front sectional view showing details of an outer peripheral edge part. In FIG. 2, the description of the separator and the gasket is omitted for easy understanding, and the reinforcing film is indicated by an imaginary line (two-dot chain line).

  As shown in FIGS. 1 and 2, the polymer electrolyte fuel cell 1 includes an electrolyte membrane 2 having a rectangular shape in plan view, and a plan view that is slightly smaller than the electrolyte membrane 2 on the upper and lower surfaces of the electrolyte membrane 2. A rectangular catalyst layer 3 is formed. The catalyst layer 3 formed on both surfaces of the electrolyte membrane 2 is referred to as a catalyst layer-electrolyte membrane laminate 10. Thus, since the catalyst layer 3 is formed slightly smaller than the electrolyte membrane 2, the catalyst layer 3 is not formed on the outer peripheral edge 21 of the electrolyte membrane 2. In addition, it is preferable that the distance C (refer FIG. 3) from the outer periphery of the electrolyte membrane 2 to the outer periphery of the catalyst layer 3 is 0-5 mm.

  And the frame-shaped reinforcement film | membrane 4 which has the opening part 41 in the center is installed in the upper surface and lower surface of this catalyst layer-electrolyte membrane laminated body 10, respectively. The reinforcing membrane 4 has a two-layer structure, and is welded to the gas barrier layer 42 that prevents permeation of fuel gas and oxidant gas used for power generation of the fuel cell and the outer peripheral edge of the catalyst layer-electrolyte membrane laminate 10. It is comprised from the welding layer 43. FIG. The thickness of the gas barrier layer 42 is preferably 10 to 100 μm, and the thickness of the welding layer 43 is preferably 5 to 100 μm. In a state where the reinforcing membrane 4 is welded to the catalyst layer-electrolyte membrane laminate 10, the catalyst layer 3 is exposed from the opening 41 of the reinforcing membrane 4 except for the outer peripheral edge portion 31, and the reinforcing membrane 4 is the catalyst layer. 3 and the outer peripheral edge 31 of the electrolyte 2. In addition, it is preferable that the distance B (refer FIG. 3) from the outer periphery of the catalyst layer 3 to the inner periphery of the reinforcement film | membrane 4 shall be 1-10 mm. Further, since the reinforcing membrane 4 is formed to be slightly larger than the electrolyte membrane 2, the outer peripheral edge portions 45 of the reinforcing membranes 4 protruding from the electrolyte membrane 2 are welded at portions beyond the electrolyte membrane 2. The distance D (see FIG. 3) from the outer peripheral edge of the reinforcing membrane 4 to the outer peripheral edge of the electrolyte membrane 2 is preferably 1 to 100 mm. In addition, what the reinforcement film | membrane 4 was welded to the catalyst layer-electrolyte membrane laminated body 10 in this way is equivalent to the catalyst layer-electrolyte membrane laminated body with a reinforcement film of this invention.

  A gas diffusion layer 5 having a rectangular shape in plan view is provided on the catalyst layer 3 exposed from the opening 41 of the reinforcing membrane 4. The distance A (see FIG. 3) from the outer peripheral edge of the gas diffusion layer 5 to the inner peripheral edge of the reinforcing film 4 is preferably 0 to 5 mm. Thus, the gas diffusion layer 5 is formed on the catalyst layer 3 to constitute the electrode E, and the electrode E formed on both surfaces of the electrolyte membrane 2 is referred to as an electrode-electrolyte membrane laminate 20. In addition, what the reinforcement film | membrane 4 is installed in the electrode-electrolyte membrane laminated body 20 like this embodiment is equivalent to the electrode-electrolyte membrane laminated body with a reinforcement film | membrane of this invention.

  A frame-shaped gasket 6 is installed on each reinforcing film 4 so as to surround the periphery of the electrode E, and a separator 7 is installed on the electrode E and the gasket 6. In the separator 7, a gas flow path 71 is formed in a region facing the gas diffusion layer 5.

  Next, the material of each component of the polymer electrolyte fuel cell 1 configured as described above will be described.

The electrolyte membrane 2 is formed, for example, by applying a solution containing a hydrogen ion conductive polymer electrolyte on a substrate and drying it. Examples of the hydrogen ion conductive polymer electrolyte include a perfluorosulfonic acid-based fluorine ion exchange resin, more specifically, a perfluorocarbonsulfonic acid-based resin in which the C—H bond of a hydrocarbon ion-exchange membrane is substituted with fluorine. Examples include polymers (PFS polymers). By introducing a fluorine atom having high electronegativity, it is chemically very stable, the dissociation degree of the sulfonic acid group is high, and high ion conductivity can be realized. Specific examples of such a hydrogen ion conductive polymer electrolyte include “Nafion” (registered trademark) manufactured by DuPont, “Flemion” (registered trademark) manufactured by Asahi Glass Co., Ltd., and “Aciplex” manufactured by Asahi Kasei Corporation. ”(Registered trademark),“ Gore Select ”(registered trademark) manufactured by Gore, and the like. The concentration of the hydrogen ion conductive polymer electrolyte contained in the hydrogen ion conductive polymer electrolyte-containing solution is usually about 5 to 60% by weight, preferably about 20 to 40% by weight. In addition, the film thickness of the electrolyte membrane 2 is about 20-250 micrometers normally, Preferably it is about 20-80 micrometers.

  The catalyst layer 3 is a known platinum-containing catalyst layer (cathode catalyst and anode catalyst). Specifically, the catalyst layer 3 contains carbon particles supporting catalyst particles and a hydrogen ion conductive polymer electrolyte. Examples of the catalyst particles include platinum and platinum compounds. Examples of the platinum compound include an alloy of platinum and at least one metal selected from the group consisting of ruthenium, palladium, nickel, molybdenum, iridium, iron and the like. In general, the catalyst particles contained in the cathode catalyst layer are platinum, and the catalyst particles contained in the anode catalyst layer are an alloy of the metal and platinum. Moreover, as a hydrogen ion conductive polymer electrolyte, the same material as what is used for the electrolyte membrane 2 mentioned above can be used, for example, perfluorocarbon sulfonic acid type fluorine ion exchange resin can be mentioned.

  The reinforcing film 4 is composed of a gas barrier layer 42 and a welded layer 43. The gas barrier layer 42 can preferably use a polyester-based resin or polycarbonate having a barrier property against water vapor, water, fuel gas and oxidant gas. Specific examples include polyethylene terephthalate, polyethylene naphthalate, polybutylene terephthalate, polybutylene naphthalate, and copolymer polyester.

  Examples of the material of the weld layer 43 include the same material as that of the electrolyte membrane 2 such as perfluorocarbon sulfonic acid-based fluorine ion exchange resin. Specifically, “Nafion” (manufactured by DuPont) Registered trademark), “Flemion” (registered trademark) manufactured by Asahi Glass Co., Ltd., “Aciplex” (registered trademark) manufactured by Asahi Kasei Co., Ltd., “Gore Select” (registered trademark) manufactured by Gore, Inc. be able to. In addition, preferred examples of the material of the weld layer 43 include polyolefin resins, such as medium density polyethylene, high density polyethylene, linear low density polyethylene, ethylene-α / olefin copolymer, polypropylene, polybutene, and polyisobutene. Copolymer of ethylene and unsaturated carboxylic acid such as polyisobutylene, polybutadiene, polyisoprene, ethylene-methacrylic acid copolymer, or ethylene-acrylic acid copolymer, or acid-modified polyolefin-based resin obtained by modifying them. Silane-modified polyolefin resins, ethylene-ethyl acrylate copolymers, ionomer resins, ethylene-vinyl acetate copolymers, and the like can be used.

  As the gas diffusion layer 5, various types of gas diffusion layers constituting a fuel electrode and an air electrode can be used. In order to efficiently supply fuel gas and oxidant gas as fuel to the catalyst layer 3, the gas diffusion layer 5 is porous. It is made of a conductive substrate. Examples of the porous conductive substrate include carbon paper and carbon cloth.

  As the gasket 6, it is possible to use a gasket that has a strength sufficient to withstand heat pressing and has a gas barrier property that does not leak fuel and oxidant to the outside. For example, a polyethylene terephthalate sheet or Teflon ( (Registered trademark) sheet, silicon rubber sheet, and the like.

  The separator 7 may be any known conductive plate that is known and stable even in the environment within the fuel cell. In general, a carbon plate in which a gas flow path 71 is formed is used. In addition, the separator 7 is made of a metal such as stainless steel, and the surface of the metal is formed with a coating made of a conductive material such as chromium, a platinum group metal or oxide thereof, or a conductive polymer. It is also possible to use a metal having a metal surface plated with a material such as silver, a platinum group composite oxide, or chromium nitride.

  Next, a method for producing the above-described polymer electrolyte fuel cell 1 will be described with reference to the drawings. FIG. 4 is an explanatory view showing a method for producing the polymer electrolyte fuel cell 1 according to this embodiment.

  First, the electrolyte membrane 2 made of the above-described material is prepared, and the catalyst layer forming transfer sheet 8 is placed on both surfaces of the electrolyte membrane 2 (FIG. 4A). Here, the transfer sheet 8 for forming a catalyst layer is one in which the transferred catalyst layer 3 is formed on a transfer substrate 81. The production method of the catalyst layer forming transfer sheet 8 will be described. First, the above-described carbon particles supporting the catalyst particles and the hydrogen ion conductive polymer electrolyte are mixed and dispersed in an appropriate solvent to prepare a catalyst paste. . Then, the catalyst paste is applied onto the transfer substrate 81 through a release layer as necessary in accordance with a known method so that the formed catalyst layer 3 has a desired film thickness. At this time, the catalyst paste is applied to the transfer substrate 81 so that the catalyst layer 3 has a shape slightly smaller than the electrolyte membrane 2. Examples of the method for applying the catalyst paste include known coating methods such as screen printing, spray coating, die coating, and knife coating. Examples of the solvent include various alcohols, various ethers, various dialkyl sulfoxides, water, or a mixture thereof. Of these, alcohols are preferable. Examples of alcohols include monohydric alcohols having 1 to 4 carbon atoms such as methanol, ethanol, n-propanol, isopropanol, n-butanol, and tert-butanol, and various polyhydric alcohols. Examples of the transfer base material 81 include polyimide, polyethylene terephthalate, polyparvanic acid aramid, polyamide (nylon), polysulfone, polyethersulfone, polyphenylene sulfide, polyether ether ketone, polyetherimide, polyarylate, and polyethylene naphthalate. And the like. Further, heat resistance of ethylene tetrafluoroethylene copolymer (ETFE), tetrafluoroethylene-hexafluoropropylene copolymer (FEP), tetrafluoroperfluoroalkyl vinyl ether copolymer (PFA), polytetrafluoroethylene (PTFE), etc. Fluorine resin can also be used. Further, the transfer substrate 81 may be coated paper such as art paper, coated paper, lightweight coated paper, non-coated paper such as notebook paper, copy paper, etc. in addition to the polymer film. The thickness of the transfer substrate 81 is usually about 6 to 100 μm, preferably about 10 to 30 μm, from the viewpoints of handleability and economy. Therefore, the transfer substrate 81 is preferably a polymer film that is inexpensive and easily available, and more preferably polyethylene terephthalate.

  Then, after applying the catalyst paste, the catalyst layer 3 is formed on the transfer substrate 81 by drying at a predetermined temperature and time. A drying temperature is about 40-100 degreeC normally, Preferably it is about 60-80 degreeC. Although depending on the drying temperature, the drying time is usually about 5 minutes to 2 hours, preferably about 10 minutes to 1 hour.

  The description of the method for producing the polymer electrolyte fuel cell will be continued. The transfer sheet 8 for forming a catalyst layer produced as described above is disposed so that the catalyst layer 3 faces the electrolyte membrane 1 (FIG. 4A), and a heat press is applied from the back side of the transfer sheet 8 to apply the catalyst layer. 3 is transferred to the electrolyte membrane 2, and the transfer substrate 81 of the transfer sheet 8 is peeled off (FIG. 4B). In consideration of workability, it is preferable to simultaneously laminate the catalyst layer 3 on both surfaces of the electrolyte membrane 2, but the catalyst layer 3 can also be formed on each side. The pressure level of the heating press is usually about 0.5 to 20 MPa, preferably about 1 to 10 MPa in order to avoid transfer failure. Further, it is preferable to heat the pressing surface during this pressing operation in order to avoid transfer failure. The heating temperature is usually 200 ° C. or lower, preferably 150 ° C. or lower, in order to avoid damage or deformation of the electrolyte membrane 2. Thus, the catalyst layer-electrolyte membrane laminated body 10 is formed by forming the catalyst layer 3 on both surfaces of the electrolyte membrane 2. At this time, since the catalyst layer 3 is slightly smaller than the electrolyte membrane 2, the outer peripheral edge 21 of the electrolyte membrane 2 is exposed.

Next, the reinforcing membrane 4 is attached to the catalyst layer-electrolyte membrane laminate 10 thus formed (FIG. 4C). This process will be described in detail with reference to FIG. FIG. 5 is a plan view showing a process of attaching the reinforcing membrane 4 to the catalyst layer-electrolyte membrane laminate 10. As shown in FIG. 5, the two reinforcing films 4 made of the above-described materials are overlapped, and the remaining three sides with one side remaining are welded together. As a result, the two reinforcing films 4 form a bag body in which a welded portion is formed in a U-shape and the left side is open (FIG. 5A). As this welding method, various known methods can be adopted. For example, high-frequency welding, hot air welding, hot plate welding, impulse welding, trowel welding, ultrasonic welding, etc. can be adopted. .

  When the bag is formed by the reinforcing film 4, an easy-removal region 44 that is slightly smaller than the catalyst layer 3 of the catalyst layer-electrolyte membrane laminate 10 is then formed at the center of each reinforcing film 4 constituting the bag. (FIG. 5B). The easy removal region 44 refers to a region that can be easily removed. For example, the easy removal region 44 can be formed by making a perforation in the outer peripheral edge or making a cut while leaving only a part. Thus, the catalyst layer-electrolyte membrane laminated body 10 is inserted into the bag body in which the easy-removal region 44 is formed from the left side which is not welded and moved to a predetermined position (FIG. 5C). The predetermined position refers to a position where the catalyst layer 3 of the catalyst layer-electrolyte membrane laminate 10 faces the easy removal region 44 except for the outer peripheral edge 31.

  After moving the catalyst layer-electrolyte membrane laminate 10 to a predetermined position, the perforation at the outer periphery of the easy-removal region 44 is cut and the easy-removal regions 44 are removed from the respective reinforcing membranes 4. An opening 41 is formed at the center (FIG. 5D). As described above, when the easy removal regions 44 are removed from the respective reinforcing membranes 4 and the openings 41 are formed, the catalyst layers 3 of the catalyst layer-electrolyte membrane laminate 10 are removed from the respective openings 41 except for the outer peripheral edge 31. It will be exposed. In this state, the reinforcement film 4 is welded by a known method so that the reinforcement film 4 is not welded, so that the reinforcement film 4 has the outer peripheral edge 31 of the catalyst layer 3 of the electrolyte-catalyst layer assembly 10, While being welded to the outer peripheral edge 21 of the electrolyte membrane 2, the reinforcing membranes 4 are also welded together. The catalyst layer-electrolyte membrane laminate with a reinforcing membrane is completed through the above steps (FIGS. 5 (e) and 4 (c)).

  Returning to FIG. 4, the description of the method for producing the polymer electrolyte fuel cell 1 will be continued. On the catalyst layer 3 exposed from the opening 41 of the above-described catalyst layer-electrolyte membrane laminate with reinforcing film, the gas diffusion layer 5 is laminated by pressure bonding to complete the electrode-electrolyte membrane laminate with reinforcing film. (FIG. 4D). And the gasket 6 is arrange | positioned on the reinforcement film | membrane 4 so that the circumference | surroundings of the electrode E which consists of the catalyst layer 3 and the gas diffusion layer 5 may be enclosed. The separator 7 is disposed on the gas diffusion layer 5 and the gasket 6 so that the gas flow path 71 faces the gas diffusion layer 5 so that the gas diffusion layer 5 and the separator 7 are electrically connected. By sandwiching the electrode-electrolyte membrane laminate with the separator 7, the polymer electrolyte fuel cell 1 is completed (FIG. 4E).

  As described above, in the present embodiment, the outer peripheral edge portion 21 of the electrolyte membrane 2 is restrained by the welded reinforcing membrane 4, so that the expansion / contraction of the electrolyte membrane 2 can be suppressed. Breakage of the electrolyte membrane 2 can be prevented. Further, since the reinforcing membrane 4 uses the same perfluorocarbon sulfonic acid type fluorine ion exchange resin as the electrolyte membrane 2, it exhibits the same behavior as the electrolyte membrane 2, and as a result, prevents the peeling from the electrolyte membrane 2. Can do. Further, since the catalyst layer 3 also contains a perfluorocarbon sulfonic acid-based fluorine ion exchange resin, the reinforcing film 4 can be prevented from being peeled off from the catalyst layer 3.

As mentioned above, although embodiment of this invention was described, this invention is not limited to these, A various change is possible unless it deviates from the meaning of this invention. For example, in the above-described embodiment, the manufacturing method in which the reinforcing membrane 4 is once formed into a bag and the catalyst layer-electrolyte membrane laminate 10 is inserted is adopted, but the present invention is not particularly limited thereto. For example, the reinforcing film 4 in which the opening portions 41 are formed in advance on both surfaces of the catalyst layer-electrolyte membrane laminate 10 is disposed so that the weld layer 43 faces the catalyst layer-electrolyte membrane laminate 10, respectively. Depending on the method, etc.
The reinforcing membrane 4 can be welded to both surfaces of the electrolyte membrane laminate 10 to produce a catalyst layer-electrolyte membrane laminate with a reinforcing membrane.

  Moreover, in the said embodiment, although the reinforcement film | membrane 4 is comprised from two layers, the gas barrier layer 42 and the welding layer 43, it is not necessarily limited to this two-layer structure, For example, one layer of only the welding layer 43 The structure can be made, or a layer structure having three or more layers can be formed by further including layers having other functions. Further, the gas barrier layer 42 may be a protective layer that does not have gas barrier properties and is merely for protecting the welding layer 43. As this protective layer, for example, a backing film previously attached to the reinforcing film 4 from the time of purchase can be used.

  Moreover, in the said embodiment, although the catalyst layer 3 is formed in the size slightly smaller than the electrolyte membrane 2, as shown in FIG. 6, the catalyst layer 3 is made into the substantially same size as the electrolyte membrane 2, and the electrolyte membrane 2 is shown. It is also possible to form the catalyst layer 3 on the entire upper and lower surfaces. In this case, the gasket 6 is installed on the reinforcing membrane 4 by welding the welded layer 43 of the reinforcing membrane 4 to the outer peripheral edge 31 of the catalyst layer 3. With this configuration, all of the electrolyte membrane 2 can contribute to power generation, and thus the electrolyte membrane 2 can be used effectively.

  In the above embodiment, the electrolyte membrane 2, the catalyst layer 3, and the gas diffusion layer 5 constituting the solid polymer fuel cell 1 are all described as a rectangular shape in plan view, but the shape is not particularly limited, For example, it can be a circular shape in plan view.

  Moreover, in the said embodiment, although the reinforcement film | membrane 4 is formed in both surfaces of the catalyst layer-electrolyte membrane laminated body 10, as shown in FIG. 7, it is formed only in the single side | surface of the catalyst layer-electrolyte membrane laminated body 10. As shown in FIG. It may be. In this case, the gasket 6 on the side where the reinforcing film 4 is not formed is in a state of being installed on the back side of the reinforcing film 4 or on the outer peripheral edge of the electrolyte membrane 2. Further, when the reinforcing membrane 4 is formed only on one side of the catalyst layer-electrolyte membrane laminate 10, the swelling and shrinkage of the electrolyte membrane 2 can be suppressed regardless of whether it is formed on either the anode side or the cathode side. By forming the fuel cell on the side, it is possible to more effectively suppress the shrinkage of the electrolyte membrane 2 on the anode side when the fuel cell is operated with low or no humidification. Moreover, by forming on the cathode side, the expansion of the electrolyte membrane 2 due to the generated water can be more effectively suppressed.

  Moreover, in the said embodiment, although the magnitude | size of the catalyst layer 3 of a cathode side and an anode side is formed the same, the catalyst layer 3 of a cathode side and an anode side can also be formed in a mutually different magnitude | size. In this case, from the viewpoint of preventing the generation of radicals, it is preferable that the size of the catalyst layer 3 on the anode side is larger than that of the catalyst layer 3 on the cathode side, but the present invention is not particularly limited thereto.

  The present invention will be described more specifically with reference to the following examples and comparative examples. In addition, this invention is not limited to the following Example.

Example 1
As the electrolyte membrane 2, NRE212CS (manufactured by Dupont) having a film thickness of 53 μm cut to a size of 63 × 63 mm was used.

  Next, a catalyst-forming transfer sheet 8 was produced in the following manner. First, 1 g of 1-butanol, 10 g of 3-butanol, and a fluorine ion exchange resin (5 wt% Nafion binder, manufactured by DuPont) are added to 2 g of platinum catalyst-supported carbon (platinum supported amount: 45.7 wt%, manufactured by Tanaka Kikinzoku Co., Ltd., TEC10E50E). An ink composition for forming a catalyst was prepared by adding 20 g and 6 g of water and stirring and mixing them with a disperser. Next, the ink was applied to a PET film (E5100, manufactured by Toyobo Co., Ltd., 12 μm) so that the platinum weight after drying the catalyst layer was 0.4 mg / cm 2, thereby preparing a transfer sheet 8 for forming a catalyst.

  The catalyst-forming transfer sheet 8 produced as described above was cut into a size of 60 × 60 mm, and placed on both surfaces of the electrolyte membrane 2 so that the catalyst layer 3 was directed to the electrolyte membrane 2 side. And the catalyst layer 3 was formed in both surfaces of the electrolyte membrane 2 by hot-pressing on conditions of 130 degreeC, 5.0 Mpa, and 150 second, and the catalyst layer-electrolyte membrane laminated body 10 was produced. The catalyst layer 3 has a thickness of 20 μm.

  Subsequently, a reinforcing film 4 having a single layer structure was produced. NRE212CS (manufactured by Dupont, film thickness 53 μm) was used as the welded layer 43 of the reinforcing film 4. The reinforcing film 4 was cut to a size of 80 × 80 mm, and an opening 41 having a size of 50 × 50 mm was formed at the center. Then, the reinforcing film 4 is placed centering on both surfaces of the catalyst layer-electrolyte membrane laminate 10 and hot pressed under the conditions of 130 ° C., 1.0 MPa, 30 seconds, so that the reinforcing film 4 is catalyst layer-electrolyte film. It welded to the laminated body 10, and produced the catalyst layer-electrolyte membrane laminated body with a reinforcement film | membrane.

  Subsequently, a 49 × 49 mm gas diffusion layer 5 (carbon paper TGP-H090 manufactured by Toray Industries, Inc.) is formed on the catalyst layer 3 exposed from the opening 41, and an electrode-electrolyte membrane laminate with a reinforcing membrane is formed. Formed.

(Example 2)
As the electrolyte membrane 2, Aciplex SF-702X (manufactured by Asahi Kasei Co., Ltd.) having a thickness of 50 μm cut to a size of 63 × 63 mm was used.

  Next, a catalyst-forming transfer sheet 8 was produced in the following manner. First, 2 g of platinum catalyst supported carbon (platinum supported amount: 45.7 wt%, manufactured by Tanaka Kikinzoku Co., Ltd., TEC10E50E), 10 g of 1-butanol, 10 g of 3-butanol, and a fluorine ion exchange resin (5 wt% Aciplex ionomer, manufactured by Asahi Kasei) An ink composition for forming a catalyst was prepared by adding 20 g and 6 g of water and stirring and mixing them with a disperser. Next, the ink was applied to a PET film (E5100, manufactured by Toyobo Co., Ltd., 12 μm) so that the platinum weight after drying the catalyst layer was 0.4 mg / cm 2, thereby preparing a transfer sheet 8 for forming a catalyst.

  The catalyst-forming transfer sheet 8 produced as described above was cut into a size of 60 × 60 mm, and placed on both surfaces of the electrolyte membrane 2 so that the catalyst layer 3 was directed to the electrolyte membrane 2 side. And the catalyst layer 3 was formed in both surfaces of the electrolyte membrane 2 by hot-pressing on 150 degreeC, 5.0 Mpa, and 150 second conditions, and the catalyst layer-electrolyte membrane laminated body 10 was produced. The catalyst layer 3 has a thickness of 20 μm.

  Subsequently, a reinforcing film 4 having a single layer structure was produced. As the welded layer 43 of the reinforcing film 4, Aciplex SF-702X (manufactured by Asahi Kasei Co., Ltd., film thickness 50 μm) was used. The reinforcing film 4 was cut to a size of 80 × 80 mm, and an opening 41 having a size of 50 × 50 mm was formed at the center. Then, the reinforcing membrane 4 is placed on both sides of the catalyst layer-electrolyte membrane laminate 10 in the center, and hot-pressed under the conditions of 150 ° C., 1.0 MPa, 30 seconds, so that the reinforcing membrane 4 is the catalyst layer-electrolyte membrane. It welded to the laminated body 10, and produced the catalyst layer-electrolyte membrane laminated body with a reinforcement film | membrane.

  Subsequently, a 49 × 49 mm gas diffusion layer 5 (carbon paper TGP-H090 manufactured by Toray Industries, Inc.) is formed on the catalyst layer 3 exposed from the opening 41, and an electrode-electrolyte membrane laminate with a reinforcing membrane is formed. Formed.

(Example 3)
A catalyst layer-electrolyte membrane laminate 10 was prepared in the same manner as in Example 1.

  Subsequently, a reinforcing film 4 having a two-layer structure was produced. As the gas barrier layer 42 of the reinforcing film 4, biaxially stretched polyethylene terephthalate (Teonex, 12 μm manufactured by Teijin Limited) was used. On this polyethylene terephthalate, a fluorine ion exchange resin (5 wt% Nafion binder, manufactured by DuPont) was formed by die coating so as to have a thickness of 20 μm after drying to form a weld layer 43. This reinforcing film was cut into a size of 80 × 80 mm, and an opening with a size of 50 × 50 mm was formed at the center. Then, the reinforcing film 4 is placed centering on both surfaces of the catalyst layer-electrolyte membrane laminate 10 and hot pressed under the conditions of 130 ° C., 1.0 MPa, 30 seconds, so that the reinforcing film 4 is catalyst layer-electrolyte film. It welded to the laminated body 10, and produced the catalyst layer-electrolyte membrane laminated body with a reinforcement film | membrane.

  Subsequently, a 49 × 49 mm gas diffusion layer 5 (carbon paper TGP-H090 manufactured by Toray Industries, Inc.) is formed on the catalyst layer 3 exposed from the opening 41, and an electrode-electrolyte membrane laminate with a reinforcing membrane is formed. Formed.

Example 4
A catalyst layer-electrolyte membrane laminate 10 was prepared in the same manner as in Example 1.

  Subsequently, a reinforcing film 4 having a two-layer structure was produced. NRE212CS (manufactured by Dupont, film thickness 53 μm) was used as the welding layer 43 of the reinforcing film 4, and a NRE212CS back film (polyester film, film thickness 50 μm) was used as the gas barrier layer 42. The reinforcing film 4 was cut to a size of 80 × 80 mm, and an opening 41 having a size of 50 × 50 mm was formed at the center. Then, the reinforcing film 4 is placed centering on both surfaces of the catalyst layer-electrolyte membrane laminate 10 and hot pressed under the conditions of 130 ° C., 1.0 MPa, 30 seconds, so that the reinforcing film 4 is catalyst layer-electrolyte film. It welded to the laminated body 10, and produced the catalyst layer-electrolyte membrane laminated body with a reinforcement film | membrane.

  Subsequently, a 49 × 49 mm gas diffusion layer 5 (carbon paper TGP-H090 manufactured by Toray Industries, Inc.) is formed on the catalyst layer 3 exposed from the opening 41, and an electrode-electrolyte membrane laminate with a reinforcing membrane is formed. Formed.

(Example 5)
As the electrolyte membrane 2, NRE212CS (manufactured by Dupont) having a film thickness of 53 μm cut to a size of 63 × 63 mm was used.

  Subsequently, the catalyst-forming transfer sheet 8 produced in the same manner as in Example 1 was cut into a size of 60 × 60 mm for the cathode and 50 × 50 mm for the anode, and the catalyst layer 3 was formed on each side of the electrolyte membrane 2. The center was arranged so as to face the electrolyte membrane 2 side. And the catalyst layer 3 from which a magnitude | size differs on both surfaces of the electrolyte membrane 2 was formed by heat-pressing on conditions of 130 degreeC, 5.0 MPa, and 150 second, and the catalyst layer-electrolyte membrane laminated body 10 was produced.

  Subsequently, as in Example 1, the single-layered reinforcing film 4 having an opening was placed centered only on the cathode side of the catalyst layer-electrolyte membrane laminate 10, and the temperature was 130 ° C., 1.0 MPa, 30 seconds. The reinforcing membrane 4 was welded only on the cathode side of the catalyst layer-electrolyte membrane laminate 10 by hot pressing under the above conditions to produce a catalyst layer-electrolyte membrane laminate with a reinforcing membrane.

  Subsequently, a 49 × 49 mm gas diffusion layer 5 (carbon paper TGP-H090 manufactured by Toray Industries, Inc.) was formed on the catalyst layer 3 of both electrodes to form an electrode-electrolyte membrane laminate with a reinforcing membrane.

(Example 6)
A catalyst layer-electrolyte membrane laminate 10 was produced in the same manner as in Example 5.

  Subsequently, the same reinforcing membrane 4 as in Example 3 was placed centered only on the cathode side of the catalyst layer-electrolyte membrane laminate 10, and hot pressed under conditions of 130 ° C., 1.0 MPa, 30 seconds. The reinforcing membrane 4 was welded to the catalyst layer-electrolyte membrane laminate 10 to prepare a catalyst layer-electrolyte membrane laminate with a reinforcing membrane.

  Subsequently, a 49 × 49 mm gas diffusion layer 5 (carbon paper TGP-H090 manufactured by Toray Industries, Inc.) was formed on the catalyst layer 3 of both electrodes to form an electrode-electrolyte membrane laminate with a reinforcing membrane.

(Example 7)
A catalyst layer-electrolyte membrane laminate 10 was produced in the same manner as in Example 5.

  Subsequently, the reinforcing membrane 4 similar to that of Example 4 is arranged centered only on the cathode side of the catalyst layer-electrolyte membrane laminate 10, and hot pressed under the conditions of 130 ° C., 1.0 MPa, 30 seconds. The reinforcing membrane 4 was welded to the catalyst layer-electrolyte membrane laminate 10 to prepare a catalyst layer-electrolyte membrane laminate with a reinforcing membrane.

  Subsequently, a 49 × 49 mm gas diffusion layer 5 (carbon paper TGP-H090 manufactured by Toray Industries, Inc.) was formed on the catalyst layer 3 of both electrodes to form an electrode-electrolyte membrane laminate with a reinforcing membrane.

(Example 8)
A catalyst layer-electrolyte membrane laminate 10 was prepared in the same manner as in Example 1.

  Subsequently, a reinforcing film 4 similar to that of Example 3 was prepared as the cathode-side reinforcing film 4. Further, an unsaturated carboxylic acid-modified polypropylene as the weld layer 43 is formed on the biaxially stretched polyethylene terephthalate (PEN: Teonex, Teijin Ltd., 12 μm) as the gas barrier layer 42 as the anode-side reinforcing film 4 by a melt extrusion method. A two-layered reinforcing film 4 was formed so as to have a thickness of 20 μm.

  Subsequently, these reinforcing membranes 4 are each cut into a size of 80 × 80 mm, an opening 41 having a size of 50 × 50 mm is formed at the center thereof, and the anode side of the catalyst layer-electrolyte membrane laminate 10, The center of each was arranged on the cathode side. Each reinforcing membrane 4 was welded to the catalyst layer-electrolyte membrane laminate 10 by hot pressing under conditions of 130 ° C., 1.0 MPa, 30 seconds, and a catalyst layer-electrolyte membrane laminate with a reinforcing membrane was produced.

  Then, a 49 × 49 mm gas diffusion layer 5 (carbon paper TGP-H090 manufactured by Toray Industries, Inc.) was formed on the catalyst layer 3 exposed from the opening 41 to form an electrode-electrolyte membrane laminate with a reinforcing membrane. .

Example 9
As the electrolyte membrane 2, NRE212CS (manufactured by Dupont) having a film thickness of 53 μm cut to a size of 63 × 63 mm was used.

  Subsequently, the catalyst-forming transfer sheet 8 produced in the same manner as in Example 1 was cut to a size of 60 × 60 mm for the anode, and cut to a size of 50 × 50 mm for the cathode, and both surfaces of the electrolyte membrane 2 were cut. The centers were arranged so that the catalyst layers 3 face the electrolyte membrane 2 side. And the catalyst layer 3 from which a magnitude | size differs on both surfaces of the electrolyte membrane 2 was formed by heat-pressing on conditions of 130 degreeC, 5.0 MPa, and 150 second, and the catalyst layer-electrolyte membrane laminated body 10 was produced.

  Subsequently, the reinforcing membrane 4 similar to that of Example 4 is placed centered only on the anode side of the catalyst layer-electrolyte membrane laminate 10, and hot pressed under conditions of 130 ° C., 1.0 MPa, 30 seconds. The reinforcing membrane 4 was welded to the catalyst layer-electrolyte membrane laminate 10 to prepare a catalyst layer-electrolyte membrane laminate with a reinforcing membrane.

  Subsequently, a 49 × 49 mm gas diffusion layer 5 (carbon paper TGP-H090 manufactured by Toray Industries, Inc.) was formed on the catalyst layer 3 of both electrodes to form an electrode-electrolyte membrane laminate with a reinforcing membrane.

(Example 10)
As the electrolyte membrane 2, NRE212CS (manufactured by Dupont) having a film thickness of 53 μm cut to a size of 63 × 63 mm was used.

  Subsequently, the catalyst-forming transfer sheet 8 produced in the same manner as in Example 1 was cut into a size of 56 × 56 mm for the anode and the cathode, and the catalyst layer 3 was placed on both sides of the electrolyte membrane 2 on the electrolyte membrane 2 side. It was placed with its center aligned. And the catalyst layer 3 of the same size was formed on both surfaces of the electrolyte membrane 2 by carrying out the condition hot press of 130 degreeC, 5.0 MPa, and 150 second, and the catalyst layer-electrolyte membrane laminated body 10 was produced.

  Subsequently, as in Example 1, the single-layered reinforcing membrane 4 having an opening was placed in the center of the cathode surface of the catalyst layer-electrolyte membrane laminate 10 at 130 ° C., 1.0 MPa, 30 seconds. The reinforcing membrane 4 was welded to the catalyst layer-electrolyte membrane laminate 10 by hot pressing under conditions to prepare a catalyst layer-electrolyte membrane laminate with a reinforcing membrane.

  Subsequently, a gas diffusion layer 5 (carbon paper TGP-H090 manufactured by Toray Industries, Inc.) of 49 × 49 mm and 55 × 55 mm is formed on the catalyst layer 3 of the cathode electrode, and a reinforcing film is provided. An electrode-electrolyte membrane laminate was formed.

(Comparative Example 1)
An electrode-electrolyte membrane laminate 20 was produced with the same material and production method as in Example 1 except that the reinforcing membrane 4 was not installed.

(Comparative Example 2)
An electrode-electrolyte membrane laminate 20 was produced with the same material and production method as in Example 2 described above, except that the reinforcing membrane 4 was not installed.

(Evaluation method)
For the electrode-electrolyte membrane laminates with reinforcing membranes of Examples 1 to 10 and the electrode-electrolyte membrane laminates of Comparative Examples 1 and 2, a gasket 6 and a separator 7 were installed to produce solid polymer fuel cells, respectively. A load fluctuation cycle test was conducted. The measurement conditions at this time were a cell temperature of 80 ° C., a fuel utilization rate of 70%, an oxidant utilization rate of 40%, and a humidification temperature of 50 ° C. As a result of the current voltage measurement evaluation, the durability time of the fuel cells of Examples 1 to 10 was 1000 hours, and no damage to the electrolyte membrane was observed after the evaluation. On the other hand, the durability time of the fuel cells of Comparative Examples 1 and 2 was 300 hours. After the evaluation for 300 hours, the electrolyte membrane was damaged.

  Thus, in the polymer electrolyte fuel cells of Examples 1 to 10, since the endurance time was increased, the problem of electrolyte membrane breakage was solved by using the polymer electrolyte fuel cell of the present invention. I understand. In addition, after the load fluctuation cycle test was performed, the solid polymer fuel cells of Examples 1 to 10 were visually confirmed. As a result, the reinforcing membrane 4 was maintained in a state of being welded to the electrolyte membrane 2 or the catalyst layer 3. As a result, the electrolyte membrane 2 and the catalyst layer 3 were not peeled off.

DESCRIPTION OF SYMBOLS 1 Polymer electrolyte fuel cell 2 Electrolyte membrane 3 Catalyst layer 4 Reinforcement membrane 42 Gas barrier layer 43 Welding layer 5 Gas diffusion layer 6 Gasket 7 Separator 10 Catalyst layer-electrolyte membrane laminated body 20 Electrode-electrolyte membrane laminated body

Claims (10)

A solid polymer electrolyte membrane made of a perfluorocarbon sulfonic acid ion exchange resin; and
Catalyst layers respectively formed on both surfaces of the electrolyte membrane;
The ion exchange resin of perfluorocarbon sulfonic acid as a material, a catalyst layer made of the electrolyte membrane and the catalyst layer - the catalyst layer so as to cover the peripheral edge of the electrolyte membrane laminate - a frame shape on at least one surface of the electrolyte membrane laminate A reinforcing film having a weld layer of
With
The reinforcing membrane is a catalyst layer-electrolyte membrane laminate with a reinforcing membrane, further comprising a protective layer that is formed on the welding layer and protects the welding layer. A solid polymer electrolyte membrane made of a perfluorocarbon sulfonic acid ion exchange resin; and
Catalyst layers respectively formed on both surfaces of the electrolyte membrane;
The ion exchange resin of perfluorocarbon sulfonic acid as a material, a catalyst layer made of the electrolyte membrane and the catalyst layer - the catalyst layer so as to cover the peripheral edge of the electrolyte membrane laminate - a frame shape on at least one surface of the electrolyte membrane laminate A reinforcing film having a weld layer of
With
The reinforcing film further includes a gas barrier layer formed on the weld layer and preventing permeation of fuel gas and oxidant gas, and the weld layer is welded to an outer peripheral edge of the catalyst layer, and the gas barrier layer The catalyst layer-electrolyte membrane laminated body with a reinforcement film | membrane which covers the outer periphery part of the said catalyst layer.   The catalyst layer-electrolyte membrane laminate according to claim 2, wherein the gas barrier layer is selected from the group consisting of a polyester resin and a polycarbonate.   The said welding layer is a catalyst layer-electrolyte membrane laminated body with a reinforcement film | membrane in any one of Claims 1-3 comprised by the same material as the said electrolyte membrane. In the catalyst layer-electrolyte membrane laminate, the catalyst layer is formed on the electrolyte membrane except for the outer peripheral edge of the electrolyte membrane,
5. The catalyst layer-electrolyte film stack with a reinforcing film according to claim 1, wherein the welded layer is welded to an outer peripheral edge of the catalyst layer and an outer peripheral edge of the electrolyte membrane. body. In the catalyst layer-electrolyte membrane laminate, the catalyst layer is formed on both surfaces of the electrolyte membrane,
The weld layer is welded to both surfaces of the catalyst layer-electrolyte membrane laminate,
The reinforcing film is formed to be slightly larger than the catalyst layer-electrolyte membrane laminate, and the weld layers are welded to each other in a portion beyond the catalyst layer-electrolyte membrane laminate. The catalyst layer-electrolyte membrane laminated body with a reinforcement film in any one of -4. A solid polymer electrolyte membrane made of a perfluorocarbon sulfonic acid ion exchange resin; and
Catalyst layers respectively formed on both surfaces of the electrolyte membrane;
The ion exchange resin of perfluorocarbon sulfonic acid as a material, a catalyst layer made of the electrolyte membrane and the catalyst layer - the catalyst layer so as to cover the peripheral edge of the electrolyte membrane laminate - a frame shape on at least one surface of the electrolyte membrane laminate A reinforcing film having a weld layer of
With
In the catalyst layer-electrolyte membrane laminate, the catalyst layer is formed on the electrolyte membrane except for the outer peripheral edge of the electrolyte membrane,
The reinforcing membrane has a reinforcing layer-attached catalyst layer-electrolyte membrane laminate in which the weld layer is welded to the outer peripheral edge of the catalyst layer and the outer peripheral edge of the electrolyte membrane;
A gas diffusion layer formed only on the catalyst layer exposed from the opening of the reinforcing membrane;
An electrode-electrolyte membrane laminate with a reinforcing membrane, comprising: A solid polymer electrolyte membrane made of a perfluorocarbon sulfonic acid ion exchange resin; and
Catalyst layers respectively formed on both surfaces of the electrolyte membrane;
Using a perfluorocarbon sulfonic acid ion exchange resin as a material , frame- like welding on both sides of the catalyst layer-electrolyte membrane laminate so as to cover the outer periphery of the catalyst layer-electrolyte membrane laminate comprising the electrolyte membrane and the catalyst layer A reinforcing membrane having a layer;
With
In the catalyst layer-electrolyte membrane laminate, the catalyst layer is formed on both surfaces of the electrolyte membrane,
The reinforcing membrane is formed to be slightly larger than the catalyst layer-electrolyte membrane laminate, and the welded layers are welded to each other in a portion beyond the catalyst layer-electrolyte membrane laminate. A catalyst layer-electrolyte membrane laminate;
A gas diffusion layer formed only on the catalyst layer exposed from the opening of the reinforcing membrane;
An electrode-electrolyte membrane laminate with a reinforcing membrane, comprising: A catalyst layer-electrolyte membrane laminate with a reinforcing membrane according to any one of claims 1 to 6,
A gas diffusion layer formed on the catalyst layer exposed from the opening of the reinforcing membrane;
An electrode-electrolyte membrane laminate with a reinforcing membrane, comprising: An electrode-electrolyte membrane laminate with a reinforcing membrane according to any one of claims 7 to 9,
Gaskets respectively installed on the reinforcing membrane so as to surround each electrode composed of the catalyst layer and the gas diffusion layer;
Separators respectively installed on the electrodes and gaskets;
A solid polymer fuel cell comprising:

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