JP5824069B2 - 中空微小球及び中空微小球を作製する方法 - Google Patents
中空微小球及び中空微小球を作製する方法 Download PDFInfo
- Publication number
- JP5824069B2 JP5824069B2 JP2013546204A JP2013546204A JP5824069B2 JP 5824069 B2 JP5824069 B2 JP 5824069B2 JP 2013546204 A JP2013546204 A JP 2013546204A JP 2013546204 A JP2013546204 A JP 2013546204A JP 5824069 B2 JP5824069 B2 JP 5824069B2
- Authority
- JP
- Japan
- Prior art keywords
- feedstock
- hollow
- hollow microspheres
- microspheres
- heating system
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000004005 microsphere Substances 0.000 title claims description 108
- 238000000034 method Methods 0.000 title claims description 59
- 238000010438 heat treatment Methods 0.000 claims description 72
- 229910044991 metal oxide Inorganic materials 0.000 claims description 22
- 150000004706 metal oxides Chemical class 0.000 claims description 22
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 16
- 238000009826 distribution Methods 0.000 claims description 14
- 239000012159 carrier gas Substances 0.000 claims description 12
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 11
- 229910052717 sulfur Inorganic materials 0.000 claims description 10
- 239000011593 sulfur Substances 0.000 claims description 10
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 7
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims description 7
- 239000011737 fluorine Substances 0.000 claims description 7
- 229910052731 fluorine Inorganic materials 0.000 claims description 7
- 239000011521 glass Substances 0.000 description 42
- 239000002245 particle Substances 0.000 description 19
- 239000000463 material Substances 0.000 description 18
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- 239000004604 Blowing Agent Substances 0.000 description 14
- 239000003570 air Substances 0.000 description 13
- 210000003739 neck Anatomy 0.000 description 9
- 239000007789 gas Substances 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 239000004568 cement Substances 0.000 description 6
- 239000012530 fluid Substances 0.000 description 6
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- 239000002131 composite material Substances 0.000 description 5
- 239000000945 filler Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 239000010451 perlite Substances 0.000 description 5
- 235000019362 perlite Nutrition 0.000 description 5
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- 229920000642 polymer Polymers 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- 239000012080 ambient air Substances 0.000 description 4
- 239000004567 concrete Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000010309 melting process Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000003607 modifier Substances 0.000 description 4
- 238000002604 ultrasonography Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
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- 239000002360 explosive Substances 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 239000005368 silicate glass Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- 241000294754 Macroptilium atropurpureum Species 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 238000005553 drilling Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 241000283216 Phocidae Species 0.000 description 1
- 239000011398 Portland cement Substances 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000005524 ceramic coating Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 239000011231 conductive filler Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000002059 diagnostic imaging Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
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- 238000001125 extrusion Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011094 fiberboard Substances 0.000 description 1
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- 238000007496 glass forming Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910001872 inorganic gas Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000003129 oil well Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 150000002927 oxygen compounds Chemical class 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000005549 size reduction Methods 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
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- 229910052682 stishovite Inorganic materials 0.000 description 1
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- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/10—Forming beads
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/10—Forming beads
- C03B19/107—Forming hollow beads
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C11/00—Multi-cellular glass ; Porous or hollow glass or glass particles
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C11/00—Multi-cellular glass ; Porous or hollow glass or glass particles
- C03C11/002—Hollow glass particles
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C12/00—Powdered glass; Bead compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacturing & Machinery (AREA)
- Glass Compositions (AREA)
- Manufacturing Of Micro-Capsules (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201061424960P | 2010-12-20 | 2010-12-20 | |
| US61/424,960 | 2010-12-20 | ||
| PCT/US2011/064581 WO2012087656A2 (en) | 2010-12-20 | 2011-12-13 | Hollow microspheres and method of making hollow microspheres |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2014501693A JP2014501693A (ja) | 2014-01-23 |
| JP2014501693A5 JP2014501693A5 (enExample) | 2015-02-05 |
| JP5824069B2 true JP5824069B2 (ja) | 2015-11-25 |
Family
ID=45476605
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013546204A Expired - Fee Related JP5824069B2 (ja) | 2010-12-20 | 2011-12-13 | 中空微小球及び中空微小球を作製する方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9266764B2 (enExample) |
| EP (1) | EP2655273A2 (enExample) |
| JP (1) | JP5824069B2 (enExample) |
| KR (1) | KR20140000302A (enExample) |
| CN (1) | CN103249684B (enExample) |
| BR (1) | BR112013013237A2 (enExample) |
| EA (1) | EA028106B1 (enExample) |
| WO (1) | WO2012087656A2 (enExample) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015009461A2 (en) * | 2013-07-18 | 2015-01-22 | 3M Innovative Properties Company | Glass microbubbles, raw product, and methods of making the same |
| CN103755146A (zh) * | 2013-12-14 | 2014-04-30 | 蚌埠玻璃工业设计研究院 | 一种固体浮体材料空心玻璃微珠及其制备方法 |
| CN104276745B (zh) * | 2014-10-30 | 2022-09-09 | 中国建材国际工程集团有限公司 | 空心玻璃微珠的强化方法 |
| US9809493B2 (en) * | 2015-04-27 | 2017-11-07 | Ford Global Technologies, Llc | Surface treatment of glass bubbles |
| CN105036555A (zh) * | 2015-07-13 | 2015-11-11 | 安徽天堂唯高塑业科技有限公司 | 一种用于汽车车牌级反光膜的玻璃微珠及其制备方法 |
| WO2017040900A1 (en) * | 2015-09-04 | 2017-03-09 | 3M Innovative Properties Company | Method of making hollow glass microspheres |
| KR101715180B1 (ko) * | 2015-10-22 | 2017-03-10 | 주식회사 케이알 | 화장품 용기 |
| CN108191250A (zh) * | 2018-03-30 | 2018-06-22 | 山东德润机电设备制造有限公司 | 空心玻璃微珠及其制备方法 |
| CA3105264A1 (en) * | 2018-07-26 | 2020-01-30 | Basf Se | Hollow spherical glass particles |
| CN111362582B (zh) * | 2020-04-09 | 2021-01-19 | 浙江大学 | 真空发泡低温泡沫玻璃材料及其制备方法和应用 |
| RU2749769C1 (ru) * | 2020-12-25 | 2021-06-16 | Автономная некоммерческая организация высшего образования «Белгородский университет кооперации, экономики и права» | Способ получения стеклянных светоотражающих сферических материалов |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE521556A (enExample) * | 1953-07-18 | |||
| NL232500A (enExample) | 1957-10-22 | |||
| US3230064A (en) | 1960-10-21 | 1966-01-18 | Standard Oil Co | Apparatus for spherulization of fusible particles |
| US3365315A (en) | 1963-08-23 | 1968-01-23 | Minnesota Mining & Mfg | Glass bubbles prepared by reheating solid glass partiles |
| US3838998A (en) * | 1971-01-07 | 1974-10-01 | R Carson | Process for forming hollow glass micro-spheres from admixed high and low temperature glass formers |
| US4133854A (en) * | 1977-06-16 | 1979-01-09 | The United States Of America As Represented By The United States Department Of Energy | Method for producing small hollow spheres |
| US4257798A (en) * | 1979-07-26 | 1981-03-24 | The United States Of America As Represented By The United States Department Of Energy | Method for introduction of gases into microspheres |
| US4391646A (en) | 1982-02-25 | 1983-07-05 | Minnesota Mining And Manufacturing Company | Glass bubbles of increased collapse strength |
| ZA831343B (en) | 1982-04-08 | 1983-11-30 | Pq Corp | Hollow microspheres with organosilicon-silicate surfaces |
| FR2566384B1 (fr) * | 1984-06-21 | 1986-09-05 | Saint Gobain Vitrage | Perfectionnements aux techniques de production de microspheres en verre |
| US4767726A (en) | 1987-01-12 | 1988-08-30 | Minnesota Mining And Manufacturing Company | Glass microbubbles |
| US4935387A (en) * | 1988-10-24 | 1990-06-19 | Corning Incorporated | Fiber-reinforced composite comprising mica matrix or interlayer |
| JP3633091B2 (ja) * | 1996-04-09 | 2005-03-30 | 旭硝子株式会社 | 微小無機質球状中実体の製造方法 |
| EP1156021A1 (en) | 2000-05-19 | 2001-11-21 | Asahi Glass Co., Ltd. | Hollow aluminosilicate glass microspheres and process for their production |
| JP2002037636A (ja) * | 2000-07-26 | 2002-02-06 | Toshiba Eng Co Ltd | 微小中空球体の製造方法、その製造装置および廃棄物リサイクル方法 |
| US20060122049A1 (en) | 2004-12-03 | 2006-06-08 | 3M Innovative Properties Company | Method of making glass microbubbles and raw product |
| WO2007050062A1 (en) | 2005-10-26 | 2007-05-03 | University Of North Dakota | Methods for the production of low-density microspheres |
| GB0609409D0 (en) * | 2006-05-12 | 2006-06-21 | Ici Plc | Plaster levelling compositions |
| CN101439935B (zh) * | 2008-12-22 | 2011-04-13 | 北京航空航天大学 | 一种中空玻璃微球/铁氧体复合材料的制备方法 |
| US8261577B2 (en) * | 2009-12-21 | 2012-09-11 | 3M Innovative Properties Company | Method for making hollow microspheres |
| US20110152057A1 (en) * | 2009-12-21 | 2011-06-23 | Gang Qi | Hollow microspheres |
| BR112013022871A2 (pt) * | 2011-03-07 | 2016-12-06 | 3M Innovative Properties Co | microesferas ocas |
-
2011
- 2011-12-13 US US13/996,182 patent/US9266764B2/en not_active Expired - Fee Related
- 2011-12-13 WO PCT/US2011/064581 patent/WO2012087656A2/en not_active Ceased
- 2011-12-13 BR BR112013013237A patent/BR112013013237A2/pt not_active Application Discontinuation
- 2011-12-13 JP JP2013546204A patent/JP5824069B2/ja not_active Expired - Fee Related
- 2011-12-13 CN CN201180058604.6A patent/CN103249684B/zh not_active Expired - Fee Related
- 2011-12-13 EA EA201300432A patent/EA028106B1/ru not_active IP Right Cessation
- 2011-12-13 EP EP11808033.2A patent/EP2655273A2/en not_active Withdrawn
- 2011-12-13 KR KR1020137018570A patent/KR20140000302A/ko not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| EA028106B1 (ru) | 2017-10-31 |
| US9266764B2 (en) | 2016-02-23 |
| KR20140000302A (ko) | 2014-01-02 |
| JP2014501693A (ja) | 2014-01-23 |
| BR112013013237A2 (pt) | 2016-09-06 |
| CN103249684A (zh) | 2013-08-14 |
| EP2655273A2 (en) | 2013-10-30 |
| WO2012087656A3 (en) | 2012-11-15 |
| US20130291590A1 (en) | 2013-11-07 |
| WO2012087656A2 (en) | 2012-06-28 |
| EA201300432A1 (ru) | 2013-09-30 |
| CN103249684B (zh) | 2016-03-30 |
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