JP5801810B2 - 二元冷却流体 - Google Patents
二元冷却流体 Download PDFInfo
- Publication number
- JP5801810B2 JP5801810B2 JP2012528407A JP2012528407A JP5801810B2 JP 5801810 B2 JP5801810 B2 JP 5801810B2 JP 2012528407 A JP2012528407 A JP 2012528407A JP 2012528407 A JP2012528407 A JP 2012528407A JP 5801810 B2 JP5801810 B2 JP 5801810B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- difluoromethane
- tetrafluoropropene
- composition
- flow mode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
- C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/12—Hydrocarbons
- C09K2205/122—Halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/12—Hydrocarbons
- C09K2205/126—Unsaturated fluorinated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/22—All components of a mixture being fluoro compounds
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B9/00—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
- F25B9/002—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant
- F25B9/006—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant the refrigerant containing more than one component
Description
(1)二つの流体が平行に配置され、同じ方向に移動する:並流(アンチメソディック(antimethodic))モード、
(2)二つの流体が平行に配置され、逆方向に移動する:向流(メソディック(methodic))モード、
(3)二つの流体が直角に配置される交差流モード:この交差流モードは並流モードまたは向流モードの傾向にできる。
(4)二つの流体の一方が第2の流体が通る大径パイプ中でUターンする。この形状は長さの半分が向流交換器で他の半分が並流交換器であるものと等価:ピンヘッドモード。
計算ツール
密度、エンタルピー、エントロピーおよび混合物の液体/蒸気平衡データはRK-Soave式を用いて計算した。この式を使用するには該当混合物中の各純粋化合物の性質に関する知識と、各二成分混合物に対する相互作用係数とが必要である。
この化合物のデータは「ASHRAE Handbook 2005、第20章」に記載されており、また、Refrop(冷媒の性質を計算するためにNISTによって開発されたソフトウェア)から入手できる。
HFO-1234yfの温度-圧力曲線データは静的方法で測定できる。臨界温度および臨界圧力はSetaramから市販のC80カロリメータを使用して測定される。温度を関数とする飽和密度はパリのEcole des Mines研究所が開発した振動管デンシトメータ法を用いて測定される。
混合物中の各化合物の挙動を表すためにRK-Soave式では二元相互作用係数を使用する。この係数は液体−蒸気平衡の実験データの関数として計算される。
スクリュー圧縮機と膨張弁とを有する、向流凝縮器および蒸発器を備えた圧縮システムを考える。この圧縮システムを15℃の過熱および5℃の過冷却で運転する。二次流体と冷媒との間の最少温度差は約5℃とみなされる。
加熱モードでは、圧縮システムは蒸発器への冷媒の入口温度の-5℃と、凝縮器への冷媒の入口温度の50℃との間の温度で運転する。システムは45℃で熱を供給する。
冷却モードでは、冷媒システムを蒸発器への冷媒の入口温度の-5℃と、凝縮器への冷媒の入口温度の50℃との間で運転する。システムは0℃で冷蔵する。
冷却運転条件下の本発明組成物の性能を[表2]に示す。各組成物の各成分(HF0-1234yf、HFC-32)の値は重量百分率で与えられる。
Claims (10)
- 2,3,3,3-テトラフルオロプロペンとジフルオロメタンの二成分組成物の、逆流モードまたは逆流傾向を有する交差流モードの熱交換器を有する圧縮-タイプの冷凍システムでのR−404AまたはR−407Cを代替する熱伝達流体としての使用。
- 組成物が70〜90重量%の2,3,3,3-テトラフルオロプロペンと、10〜30重量%のジフルオロメタンとを含む請求項1に記載の使用。
- 組成物が78〜84重量%の2,3,3,3-テトラフルオロプロペンと、16〜22重量%のジフルオロメタンとを含む請求項1に記載の使用。
- 組成物が81〜83重量%の2,3,3,3-テトラフルオロプロペンと、17〜19重量%のジフルオロメタンとを含む請求項1に記載の使用。
- 二成分組成物を空調およびヒートポンプの熱伝達流体として使用する請求項1〜4のいずれか一項に記載の使用。
- 逆流モードまたは逆流傾向を有する交差流モードの熱交換器を有する圧縮システムでR−404AまたはR−407Cの代替して2,3,3,3-テトラフルオロプロペンとジフルオロメタンの二成分組成物を冷媒として使用することを特徴とする伝熱方法。
- 基本的に70〜90重量%の2,3,3,3-テトラフルオロプロペンと、10〜30重量%のジフルオロメタンとを含む請求項6に記載の方法。
- 基本的に78〜84重量%の2,3,3,3-テトラフルオロプロペンと、16〜22重量%のジフルオロメタンとを含む請求項6に記載の方法。
- 二成分組成物が安定である請求項6〜8のいずれか一項に記載の方法。
- 潤滑剤の存在下で実行される請求項6〜9のいずれか一項に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0956240A FR2950065B1 (fr) | 2009-09-11 | 2009-09-11 | Fluide refrigerant binaire |
FR0956240 | 2009-09-11 | ||
PCT/FR2010/051724 WO2011030026A1 (fr) | 2009-09-11 | 2010-08-17 | Fluide refrigerant binaire |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2015166474A Division JP2016026248A (ja) | 2009-09-11 | 2015-08-26 | 二元冷却流体 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2013504638A JP2013504638A (ja) | 2013-02-07 |
JP5801810B2 true JP5801810B2 (ja) | 2015-10-28 |
Family
ID=42078887
Family Applications (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2012528407A Active JP5801810B2 (ja) | 2009-09-11 | 2010-08-17 | 二元冷却流体 |
JP2015166474A Pending JP2016026248A (ja) | 2009-09-11 | 2015-08-26 | 二元冷却流体 |
JP2017083271A Pending JP2017193711A (ja) | 2009-09-11 | 2017-04-20 | 二元冷却流体 |
JP2019131811A Active JP6781308B2 (ja) | 2009-09-11 | 2019-07-17 | 二元冷却流体 |
Family Applications After (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2015166474A Pending JP2016026248A (ja) | 2009-09-11 | 2015-08-26 | 二元冷却流体 |
JP2017083271A Pending JP2017193711A (ja) | 2009-09-11 | 2017-04-20 | 二元冷却流体 |
JP2019131811A Active JP6781308B2 (ja) | 2009-09-11 | 2019-07-17 | 二元冷却流体 |
Country Status (10)
Country | Link |
---|---|
US (4) | US9133379B2 (ja) |
EP (1) | EP2475734B1 (ja) |
JP (4) | JP5801810B2 (ja) |
CN (2) | CN104388048A (ja) |
BR (1) | BR112012005251B1 (ja) |
ES (1) | ES2864828T3 (ja) |
FR (1) | FR2950065B1 (ja) |
PT (1) | PT2475734T (ja) |
RU (1) | RU2543191C2 (ja) |
WO (1) | WO2011030026A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016026248A (ja) * | 2009-09-11 | 2016-02-12 | アルケマ フランス | 二元冷却流体 |
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JP2016026248A (ja) * | 2009-09-11 | 2016-02-12 | アルケマ フランス | 二元冷却流体 |
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CN102482561A (zh) | 2012-05-30 |
CN102482561B (zh) | 2014-12-24 |
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US20180134936A1 (en) | 2018-05-17 |
JP6781308B2 (ja) | 2020-11-04 |
JP2016026248A (ja) | 2016-02-12 |
PT2475734T (pt) | 2021-04-26 |
US9133379B2 (en) | 2015-09-15 |
US10125296B2 (en) | 2018-11-13 |
EP2475734A1 (fr) | 2012-07-18 |
WO2011030026A1 (fr) | 2011-03-17 |
RU2012114109A (ru) | 2013-10-20 |
EP2475734B1 (fr) | 2021-04-07 |
FR2950065A1 (fr) | 2011-03-18 |
BR112012005251B1 (pt) | 2020-02-27 |
RU2543191C2 (ru) | 2015-02-27 |
US20150353802A1 (en) | 2015-12-10 |
FR2950065B1 (fr) | 2012-02-03 |
BR112012005251A2 (pt) | 2016-03-15 |
JP2013504638A (ja) | 2013-02-07 |
JP2017193711A (ja) | 2017-10-26 |
CN104388048A (zh) | 2015-03-04 |
US20190023957A1 (en) | 2019-01-24 |
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US9884984B2 (en) | 2018-02-06 |
US10858562B2 (en) | 2020-12-08 |
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