JP5719353B2 - 発泡性フルオロポリマー組成物 - Google Patents
発泡性フルオロポリマー組成物 Download PDFInfo
- Publication number
- JP5719353B2 JP5719353B2 JP2012510899A JP2012510899A JP5719353B2 JP 5719353 B2 JP5719353 B2 JP 5719353B2 JP 2012510899 A JP2012510899 A JP 2012510899A JP 2012510899 A JP2012510899 A JP 2012510899A JP 5719353 B2 JP5719353 B2 JP 5719353B2
- Authority
- JP
- Japan
- Prior art keywords
- copolymer
- tetrafluoroethylene
- composition
- tfe
- mfr
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims description 121
- 229920002313 fluoropolymer Polymers 0.000 title description 31
- 239000004811 fluoropolymer Substances 0.000 title description 30
- 229920001577 copolymer Polymers 0.000 claims description 210
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 143
- -1 perfluoro Chemical group 0.000 claims description 60
- 239000012212 insulator Substances 0.000 claims description 53
- 239000004020 conductor Substances 0.000 claims description 51
- 239000006260 foam Substances 0.000 claims description 46
- 238000002844 melting Methods 0.000 claims description 42
- 230000008018 melting Effects 0.000 claims description 42
- 238000001125 extrusion Methods 0.000 claims description 40
- 238000005187 foaming Methods 0.000 claims description 33
- 239000000155 melt Substances 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 27
- 239000002667 nucleating agent Substances 0.000 claims description 26
- 229920000642 polymer Polymers 0.000 claims description 23
- 125000004432 carbon atom Chemical group C* 0.000 claims description 21
- 210000000497 foam cell Anatomy 0.000 claims description 19
- 239000004604 Blowing Agent Substances 0.000 claims description 13
- 125000000217 alkyl group Chemical group 0.000 claims description 11
- 230000015572 biosynthetic process Effects 0.000 claims description 9
- 238000009413 insulation Methods 0.000 description 51
- 210000004027 cell Anatomy 0.000 description 22
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical compound FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 15
- 150000003839 salts Chemical class 0.000 description 15
- 230000008569 process Effects 0.000 description 14
- KHXKESCWFMPTFT-UHFFFAOYSA-N 1,1,1,2,2,3,3-heptafluoro-3-(1,2,2-trifluoroethenoxy)propane Chemical compound FC(F)=C(F)OC(F)(F)C(F)(F)C(F)(F)F KHXKESCWFMPTFT-UHFFFAOYSA-N 0.000 description 11
- 238000003682 fluorination reaction Methods 0.000 description 9
- 230000008054 signal transmission Effects 0.000 description 9
- 239000011800 void material Substances 0.000 description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 7
- 229910052802 copper Inorganic materials 0.000 description 7
- 239000010949 copper Substances 0.000 description 7
- 238000005259 measurement Methods 0.000 description 7
- 239000000178 monomer Substances 0.000 description 7
- 239000008188 pellet Substances 0.000 description 7
- BLTXWCKMNMYXEA-UHFFFAOYSA-N 1,1,2-trifluoro-2-(trifluoromethoxy)ethene Chemical compound FC(F)=C(F)OC(F)(F)F BLTXWCKMNMYXEA-UHFFFAOYSA-N 0.000 description 6
- 230000006872 improvement Effects 0.000 description 6
- 229910052582 BN Inorganic materials 0.000 description 5
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 5
- 239000012141 concentrate Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 230000005540 biological transmission Effects 0.000 description 4
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 230000003111 delayed effect Effects 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000004299 exfoliation Methods 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 150000007524 organic acids Chemical class 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 150000003460 sulfonic acids Chemical class 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 230000004323 axial length Effects 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000002666 chemical blowing agent Substances 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000032798 delamination Effects 0.000 description 2
- 238000000113 differential scanning calorimetry Methods 0.000 description 2
- 239000004088 foaming agent Substances 0.000 description 2
- KKKYJLNWARAYSD-UHFFFAOYSA-N hexacalcium;tetraborate Chemical group [Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] KKKYJLNWARAYSD-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- GDTSJMKGXGJFGQ-UHFFFAOYSA-N 3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound O1B([O-])OB2OB([O-])OB1O2 GDTSJMKGXGJFGQ-UHFFFAOYSA-N 0.000 description 1
- 238000012935 Averaging Methods 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 238000009954 braiding Methods 0.000 description 1
- 230000009172 bursting Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 229920001973 fluoroelastomer Polymers 0.000 description 1
- 238000010097 foam moulding Methods 0.000 description 1
- 238000013012 foaming technology Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052754 neon Inorganic materials 0.000 description 1
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000000615 nonconductor Substances 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/122—Hydrogen, oxygen, CO2, nitrogen or noble gases
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/18—Homopolymers or copolymers or tetrafluoroethene
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/443—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
- H01B3/445—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds from vinylfluorides or other fluoroethylenic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
- C08J2201/03—Extrusion of the foamable blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2207/00—Foams characterised by their intended use
- C08J2207/06—Electrical wire insulation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08J2327/18—Homopolymers or copolymers of tetrafluoroethylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US17858409P | 2009-05-15 | 2009-05-15 | |
| US61/178,584 | 2009-05-15 | ||
| PCT/US2010/034215 WO2010132350A1 (en) | 2009-05-15 | 2010-05-10 | Foamable fluoropolymer composition |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012526902A JP2012526902A (ja) | 2012-11-01 |
| JP2012526902A5 JP2012526902A5 (enExample) | 2013-06-20 |
| JP5719353B2 true JP5719353B2 (ja) | 2015-05-20 |
Family
ID=42735576
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012510899A Expired - Fee Related JP5719353B2 (ja) | 2009-05-15 | 2010-05-10 | 発泡性フルオロポリマー組成物 |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US8178592B2 (enExample) |
| EP (1) | EP2430085B1 (enExample) |
| JP (1) | JP5719353B2 (enExample) |
| CN (1) | CN102428128B (enExample) |
| WO (1) | WO2010132350A1 (enExample) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080153936A1 (en) * | 2006-12-21 | 2008-06-26 | E. I. Du Pont De Nemours And Company | Foamed Fluoropolymer Article |
| US8178592B2 (en) | 2009-05-15 | 2012-05-15 | E.I. Du Pont De Nemours And Company | Foamable fluoropolymer composition |
| US20150027747A1 (en) * | 2012-01-27 | 2015-01-29 | E I Du Pont De Nemours And Company | Foam insulated conductors |
| JP5757348B2 (ja) | 2013-01-24 | 2015-07-29 | ダイキン工業株式会社 | 組成物、並びに、発泡成形体及び電線の製造方法 |
| JP5757347B2 (ja) | 2013-01-24 | 2015-07-29 | ダイキン工業株式会社 | 組成物、並びに、発泡成形体及び電線の製造方法 |
| GB201308559D0 (en) * | 2013-05-13 | 2013-06-19 | Colorant Chromatics Ag | Thermoplastic Polymers |
| CN104451934A (zh) * | 2013-09-22 | 2015-03-25 | 杭州费尔过滤技术有限公司 | 一种可熔性含氟树脂单丝及其制造方法 |
| US20150175757A1 (en) | 2013-12-20 | 2015-06-25 | E I Du Pont De Nemours And Company | Oriented fluoropolymer film |
| US11021556B2 (en) * | 2014-02-05 | 2021-06-01 | Daikin Industries, Ltd. | Tetrafluoroethylene/hexafluoropropylene copolymer, and electric wire |
| US10730980B2 (en) | 2015-02-12 | 2020-08-04 | 3M Innovative Properties Company | Tetrafluoroethylene/hexafluoropropylene copolymers including perfluoroalkoxyalkyl pendant groups |
| DK3256501T3 (en) | 2015-02-12 | 2019-03-18 | 3M Innovative Properties Co | TETRAFLUORETHYLEN / HEXAFLUORPROPYLEN COPOLYMERS INCLUDING PERFLUORAL COXYALKYL GROUPS AS PREPARATIONS AND METHODS OF PRODUCTION AND USE PROCEDURES |
| CN107406550A (zh) | 2015-02-12 | 2017-11-28 | 3M创新有限公司 | 具有磺酰基基团的四氟乙烯共聚物 |
| TW201712694A (zh) | 2015-07-22 | 2017-04-01 | 科慕Ｆｃ有限責任公司 | 用於超高速資料傳輸之ｕｓｂ電纜 |
| KR102589718B1 (ko) | 2016-09-13 | 2023-10-18 | 다우 글로벌 테크놀로지스 엘엘씨 | 발포성 케이블 절연재용 핵제 |
| IT201700058974A1 (it) * | 2017-05-30 | 2018-11-30 | Guarniflon S P A | Appoggio strutturale, procedimento di fabbricazione |
| CN107216584B (zh) * | 2017-07-26 | 2019-03-05 | 立昌科技（赣州）有限公司 | 一种氟树脂合金及其制备方法 |
| JP7335685B2 (ja) | 2018-06-07 | 2023-08-30 | 三井・ケマーズ フロロプロダクツ株式会社 | 熱溶融性フッ素樹脂組成物及びこれから成る射出成形品 |
| KR20210146971A (ko) * | 2019-04-05 | 2021-12-06 | 다이킨 고교 가부시키가이샤 | 전기 화학 디바이스용 피압축 부재 |
| EP3960794A4 (en) * | 2019-04-26 | 2022-12-14 | Daikin Industries, Ltd. | Magnet wire and coil |
| FR3113677B1 (fr) | 2020-09-03 | 2023-07-14 | Commissariat Energie Atomique | Fabrication d’un aérogel conducteur |
| CN112409528B (zh) * | 2020-10-21 | 2021-11-16 | 浙江巨化技术中心有限公司 | 一种核壳结构ptfe分散树脂的制备方法 |
| EP4299615B1 (en) * | 2021-02-26 | 2026-04-08 | Daikin Industries, Ltd. | Fluorine-containing copolymer |
| JP7773446B2 (ja) * | 2022-08-26 | 2025-11-19 | 古河電気工業株式会社 | フッ素樹脂組成物、及びこれを用いた微細発泡フッ素樹脂フィルム |
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|---|---|---|---|---|
| JPS58174407A (ja) | 1982-03-08 | 1983-10-13 | Daikin Ind Ltd | 押出性の改良された含フツ素共重合体 |
| US4560829A (en) * | 1983-07-12 | 1985-12-24 | Reed Donald A | Foamed fluoropolymer articles having low loss at microwave frequencies and a process for their manufacture |
| US4743658A (en) * | 1985-10-21 | 1988-05-10 | E. I. Du Pont De Nemours And Company | Stable tetrafluoroethylene copolymers |
| US4764538A (en) * | 1987-12-16 | 1988-08-16 | E. I. Du Pont De Nemours And Company | Foam nucleation system for fluoropolymers |
| JPH02102247A (ja) | 1988-10-07 | 1990-04-13 | Daikin Ind Ltd | 溶融型フッ素樹脂組成物 |
| US4877815A (en) * | 1989-02-17 | 1989-10-31 | E. I. Du Pont De Nemours And Company | Nucleating agents for thermoplastic resins |
| EP0423995B1 (en) | 1989-10-06 | 1998-03-11 | E.I. Du Pont De Nemours And Company | Low dissipation-factor fluorocarbon resins and cables prepared therefrom |
| JP3276665B2 (ja) * | 1991-05-17 | 2002-04-22 | 古河電気工業株式会社 | 発泡絶縁電線の製造方法 |
| US5677404A (en) * | 1996-02-23 | 1997-10-14 | E. I. Du Pont De Nemours And Company | Tetrafluoroethylene terpolymer |
| JP4458658B2 (ja) * | 2000-12-06 | 2010-04-28 | 三井・デュポンフロロケミカル株式会社 | 熱溶融性フッ素樹脂組成物 |
| US6583226B1 (en) | 2001-06-28 | 2003-06-24 | 3M Innovative Properties Company | FEP with increased flexural fatigue strength and a low level of die deposits |
| US6838545B2 (en) * | 2002-11-08 | 2005-01-04 | E. I. Du Pont De Nemours And Company | Reaction of fluoropolymer melts |
| ITMI20030642A1 (it) * | 2003-04-01 | 2004-10-02 | Solvay Solexis Spa | Composizioni termoprocessabili a base di ctfe |
| US20040242819A1 (en) * | 2003-05-14 | 2004-12-02 | Earnest Thomas Robert | High melt flow fluoropolymer |
| US7638709B2 (en) * | 2007-05-15 | 2009-12-29 | E. I. Du Pont De Nemours And Company | Fluoropolymer wire insulation |
| US8178592B2 (en) | 2009-05-15 | 2012-05-15 | E.I. Du Pont De Nemours And Company | Foamable fluoropolymer composition |
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- 2010-05-10 WO PCT/US2010/034215 patent/WO2010132350A1/en not_active Ceased
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| US8404756B2 (en) | 2013-03-26 |
| JP2012526902A (ja) | 2012-11-01 |
| CN102428128A (zh) | 2012-04-25 |
| EP2430085A1 (en) | 2012-03-21 |
| CN102428128B (zh) | 2013-11-27 |
| EP2430085B1 (en) | 2015-09-16 |
| US8178592B2 (en) | 2012-05-15 |
| US20100288533A1 (en) | 2010-11-18 |
| WO2010132350A1 (en) | 2010-11-18 |
| US20120199377A1 (en) | 2012-08-09 |
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