JP5697670B2 - 粘液性シリコーン流体 - Google Patents
粘液性シリコーン流体 Download PDFInfo
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- JP5697670B2 JP5697670B2 JP2012527999A JP2012527999A JP5697670B2 JP 5697670 B2 JP5697670 B2 JP 5697670B2 JP 2012527999 A JP2012527999 A JP 2012527999A JP 2012527999 A JP2012527999 A JP 2012527999A JP 5697670 B2 JP5697670 B2 JP 5697670B2
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- RDOFJDLLWVCMRU-UHFFFAOYSA-N Diisobutyl adipate Chemical compound CC(C)COC(=O)CCCCC(=O)OCC(C)C RDOFJDLLWVCMRU-UHFFFAOYSA-N 0.000 description 1
- IUMSDRXLFWAGNT-UHFFFAOYSA-N Dodecamethylcyclohexasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 IUMSDRXLFWAGNT-UHFFFAOYSA-N 0.000 description 1
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- ADANNTOYRVPQLJ-UHFFFAOYSA-N [dimethyl(trimethylsilyloxy)silyl]oxy-[[dimethyl(trimethylsilyloxy)silyl]oxy-dimethylsilyl]oxy-dimethylsilane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C ADANNTOYRVPQLJ-UHFFFAOYSA-N 0.000 description 1
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- 125000003493 decenyl group Chemical group [H]C([*])=C([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- KUVMKLCGXIYSNH-UHFFFAOYSA-N isopentadecane Natural products CCCCCCCCCCCCC(C)C KUVMKLCGXIYSNH-UHFFFAOYSA-N 0.000 description 1
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- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940048862 octyldodecyl neopentanoate Drugs 0.000 description 1
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- VNRWTCZXQWOWIG-UHFFFAOYSA-N tetrakis(trimethylsilyl) silicate Chemical compound C[Si](C)(C)O[Si](O[Si](C)(C)C)(O[Si](C)(C)C)O[Si](C)(C)C VNRWTCZXQWOWIG-UHFFFAOYSA-N 0.000 description 1
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- DHWLRNPWPABRBG-UHFFFAOYSA-N tridecyl 2,2-dimethylpropanoate Chemical compound CCCCCCCCCCCCCOC(=O)C(C)(C)C DHWLRNPWPABRBG-UHFFFAOYSA-N 0.000 description 1
- OTOIBUHBRMYFLY-UHFFFAOYSA-N trimethyl-[(2,4,4,6,6-pentamethyl-1,3,5,2,4,6-trioxatrisilinan-2-yl)oxy]silane Chemical compound C[Si](C)(C)O[Si]1(C)O[Si](C)(C)O[Si](C)(C)O1 OTOIBUHBRMYFLY-UHFFFAOYSA-N 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/14—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/895—Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/48—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
- C08G77/50—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms by carbon linkages
Description
本出願は、2009年9月3日に出願された、米国特許出願第61/239529号明細書及び米国特許出願第61/239533号明細書にかかる優先権の利益を主張する。
A)a)式[(CH 3 )HSiO]g(ここで、gは3〜8である)をもつオルガノ水素シクロシロキサンと、
b)式(R2R2SiO1/2)v(R2SiO2/2)x(ここで、v≧2、x≧50であり、Rは1〜6の炭素原子を含むアルキル基であり、R2は2〜12の炭素原子を含むアルケニル基であり、ヒドロシリル化触媒の存在下において、反応中のSiHに対するアルケニル基のモル比が0.9〜2.2の間である)のシロキシ単位を有するアルケニル基末端ポリジオルガノシロキサンと
の反応によって得られた、0.1〜50質量%の分岐状オルガノポリシロキサンと、B)50〜99.9質量%の担体流体と、を含み、
23℃で少なくとも100mPa・sの粘度を有し、粘液性レオロジー特性を示す流体組成物に関する。
A)a)式[(CH 3 )HSiO]g(ここで、gは3〜8である)をもつオルガノ水素シクロシロキサンと、
b)式(R2R2SiO1/2)v(R2SiO2/2)x(ここで、v≧2、x≧50であり、Rは1〜6の炭素原子を含むアルキル基であり、R2は2〜12の炭素原子を含むアルケニル基であり、ヒドロシリル化触媒の存在下において、反応中のSiHに対するアルケニル基のモル比が0.9〜2.2の間である)のシロキシ単位を有するアルケニル基末端ポリジオルガノシロキサンと
の反応によって得られた、0.1〜50質量%の分岐状オルガノポリシロキサンと、
B)50〜99.9質量%の担体流体と、を含み、
23℃で少なくとも100mPa・sの粘度を有し、粘液性レオロジー特性を示す流体組成物に関する。
前記分岐状オルガノポリシロキサンは、
a)式[(CH 3 )HSiO]g
(ここで、gは3〜8である)
をもつオルガノ水素シクロシロキサンと、
b)式(R2R2SiO1/2)v(R2SiO2/2)x
(ここで、v≧2、x≧50であり、Rは1〜6の炭素原子を含むアルキル基であり、R2は2〜12の炭素原子を含むアルケニル基であり、ヒドロシリル化触媒の存在下において、反応中のSiHに対するアルケニル基のモル比が0.9〜2.2の間である)
のシロキシ単位を有するアルケニル基末端ポリジオルガノシロキサンと
の反応によって得られる。
(R2R2SiO1/2)v(R2SiO2/2)x
ここで、v≧2で、x≧50選択的にはx≧50であり、Rは、1〜20の炭素原子を含むアルキル基、選択的には1〜12の炭素原子を含むアルキル基であり、選択的には1〜6の炭素原子を含むアルキル基、若しくは選択的にはメチル基、を含む炭化水素又はハロゲン置換された炭化水素である。1〜20の炭素原子を有する一価の炭化水素基Rは:メチル基、エチル基、プロピル基、ブチル基、ヘキシル基、オクチル基、及びデシル基;シクロヘキシル基のような脂環式基;フェニル基、トリル基、キシリル基のようなアリール基;並びに、ベンジル基及びフェニルエチル基のようなアラルキル基が例示される。R2は2〜12の炭素原子を含むアルケニル基である。構成成分b)のR2アルケニル基は、ビニル基、アリル基、3−ブテニル基、4−ペンテニル基、5−ヘキセニル基、6−ヘプテニル基、7−オクテニル基、8−ノネニル基、9−デセニル基、10−ウンデセニル基、4,7−オクタジエニル基、5,8−ノナジエニル基、5,9−デカジエニル基、6,11−ドデカジエニル基、及び4,8−ノナジエニル基、が例示される。
CH2=CH(Me)2SiO[Me2SiO]x'Si(Me)2CH=CH2
CH2=CH-(CH2)4-(Me)2SiO[Me2SiO]x'Si(Me)2-(CH2)4-CH=CH2
(ここで、Meはメチル基、x'≧50である。)
上述のオルガノポリシロキサンを、担体流体中に分散する。適した担体流体は、鎖状及び環状のいずれものシリコーン、オーガニックオイル、有機溶媒及びこれらの混合物を含む。溶媒の詳細な例としては、米国特許第6200581号明細書で挙げられ、本目的に照らすことで具体化を行う。
ビニル基末端ジメチルシロキサンポリマーとメチル水素環状シロキサンとを反応させ、高度に分岐した流体を生成することにより、粘液性シリコン流体のシリーズを用意した。これらの実施例では、高度に分岐したネットワークを生成するが未だゲル点(シロキサン鎖間の相互継手の数が弾性固体を得るのに十分なほど多い点)を下回るように、反応の化学量論を制御した。反応槽に、〜4800の平均重合度、及び、〜150ppmの%ビニル量(C2H3)を有する、イソパー(登録商標)L希釈剤に分散したジメチルビニル末端ジメチルシロキサンポリマー(A)を入れた。これに、2.2%の%ビニル量(C2H3)を有するジメチルビニル末端ジメチルシロキサンに希釈された白金触媒(C)に続いて、テトラメチルシクロテトラシロキサン(B)を加えた。次に、反応混合物を85℃まで18時間加熱し、著しい粘度上昇をもたらした。その後、反応混合物を冷却させ、反応槽から取り出した。以下の表は実施例1A、B、C、D及びEに用いた反応物質及び量についてまとめたものである。
反応槽に、〜160の平均重合度を有するトルエン希釈剤に分散したジメチルビニル末端ジメチルシロキサンポリマー(A)を入れた。これに、テトラメチルシクロテトラシロキサン(B)及び白金触媒(C)を加えた。反応混合物を100℃まで3.5時間加熱し、著しい粘度上昇をもたらした。この原材料の比率では、前記ビニル官能性は、完全反応の結果物のSiH官能性を超えている。その後、反応混合物を冷却させ、反応槽から取り出した。以下の表は本実施例に用いた反応物質及び量についてまとめたものである。
Claims (8)
- A)a)式[(CH3)HSiO]g(ここで、gは3〜8である)をもつオルガノ水素シクロシロキサンと、b)式(R2R2SiO1/2)v(R2SiO2/2)x(ここで、v≧2、x≧50であり、Rは1〜6の炭素原子を含むアルキル基であり、R2は2〜12の炭素原子を含むアルケニル基であり、ヒドロシリル化触媒の存在下において、反応中のSiHに対するアルケニル基のモル比が0.9〜2.2の間である)のシロキシ単位を有するアルケニル基末端ポリジオルガノシロキサンとの反応によって得られた、0.1〜20質量%の分岐状オルガノポリシロキサンと、
B)80〜99.9質量%の担体流体と、を含み、
23℃で少なくとも100mPa・sの粘度を有し、粘液性レオロジー特性を示す流体組成物。 - 前記流体組成物のレオロジー特性は、垂直せん断速度(sec-1)に対する法線力(Pa)のプロットから決定され、該プロットが3.6より大きい平均勾配を有する請求項1に記載の流体組成物。
- 前記アルケニル基末端ポリジオルガノシロキサンはビニル基末端ポリジメチルシロキサンである請求項1又は2に記載の流体組成物。
- 前記ビニル基末端ポリジメチルシロキサンはガムである請求項3に記載の流体組成物。
- 前記gが4である請求項1〜4のいずれかに記載の流体組成物。
- 前記担体流体が炭化水素系溶媒である請求項1〜5のいずれかに記載の流体組成物。
- A)a)式[(CH3)HSiO]g(ここで、gは3〜8である)をもつオルガノ水素シクロシロキサンと、b)式(R2R2SiO1/2)v(R2SiO2/2)x(ここで、v≧2、x≧50であり、Rは1〜6の炭素原子を含むアルキル基であり、R2は2〜12の炭素原子を含むアルケニル基であり、ヒドロシリル化触媒の存在下において、反応中のSiHに対するアルケニル基のモル比が0.9〜2.2の間である)のシロキシ単位を有するアルケニル基末端ポリジオルガノシロキサンとの反応によって得られた、0.1〜20質量%の分岐状オルガノポリシロキサンと、
B)80〜99.9質量%の担体流体と、からなり、
前記gが4であり、前記アルケニル基末端ポリジオルガノシロキサンはビニル基末端ポリジメチルシロキサンである請求項1に記載の流体組成物の流体組成物。 - 請求項1〜7のいずれか1項に記載の流体組成物を含むパーソナルケア組成物。
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KR101828999B1 (ko) * | 2009-09-03 | 2018-02-13 | 다우 코닝 코포레이션 | 점액성 실리콘 유체를 이용한 퍼스널 케어 조성물 |
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2010
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- 2010-09-01 JP JP2012527999A patent/JP5697670B2/ja active Active
- 2010-09-01 WO PCT/US2010/047479 patent/WO2011028770A1/en active Application Filing
- 2010-09-01 KR KR1020127008402A patent/KR20120059599A/ko not_active Application Discontinuation
- 2010-09-01 CN CN201080038657.7A patent/CN102639606B/zh active Active
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EP2473552B1 (en) | 2016-03-30 |
KR20120059599A (ko) | 2012-06-08 |
US9173832B2 (en) | 2015-11-03 |
US20120220549A1 (en) | 2012-08-30 |
JP2013503940A (ja) | 2013-02-04 |
US20140249106A1 (en) | 2014-09-04 |
WO2011028770A1 (en) | 2011-03-10 |
CN102639606B (zh) | 2014-12-10 |
CN102639606A (zh) | 2012-08-15 |
EP2473552A1 (en) | 2012-07-11 |
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