JP5594004B2 - ガラスの接着方法 - Google Patents
ガラスの接着方法 Download PDFInfo
- Publication number
- JP5594004B2 JP5594004B2 JP2010206058A JP2010206058A JP5594004B2 JP 5594004 B2 JP5594004 B2 JP 5594004B2 JP 2010206058 A JP2010206058 A JP 2010206058A JP 2010206058 A JP2010206058 A JP 2010206058A JP 5594004 B2 JP5594004 B2 JP 5594004B2
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- JP
- Japan
- Prior art keywords
- glass
- solution
- mass
- cleaning
- adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000011521 glass Substances 0.000 title claims description 124
- 238000000034 method Methods 0.000 title claims description 41
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 54
- 239000000853 adhesive Substances 0.000 claims description 35
- 230000001070 adhesive effect Effects 0.000 claims description 35
- 238000004140 cleaning Methods 0.000 claims description 35
- 150000001875 compounds Chemical class 0.000 claims description 29
- 239000002904 solvent Substances 0.000 claims description 29
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 claims description 27
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 claims description 27
- 239000000919 ceramic Substances 0.000 claims description 15
- 125000003277 amino group Chemical group 0.000 claims description 7
- REQXNMOSXYEQLM-UHFFFAOYSA-N methoxy-dimethyl-phenylsilane Chemical compound CO[Si](C)(C)C1=CC=CC=C1 REQXNMOSXYEQLM-UHFFFAOYSA-N 0.000 claims description 6
- 125000001841 imino group Chemical group [H]N=* 0.000 claims description 5
- 125000003396 thiol group Chemical group [H]S* 0.000 claims description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 33
- -1 sulfonic acid compound Chemical class 0.000 description 22
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 21
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- 238000011156 evaluation Methods 0.000 description 10
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- 229920001228 polyisocyanate Polymers 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
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- 238000010410 dusting Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
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- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 4
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- 230000000052 comparative effect Effects 0.000 description 4
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- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 4
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical class C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
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- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 3
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- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- KBJFYLLAMSZSOG-UHFFFAOYSA-N n-(3-trimethoxysilylpropyl)aniline Chemical compound CO[Si](OC)(OC)CCCNC1=CC=CC=C1 KBJFYLLAMSZSOG-UHFFFAOYSA-N 0.000 description 3
- 150000003460 sulfonic acids Chemical class 0.000 description 3
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 2
- WBUSESIMOZDSHU-UHFFFAOYSA-N 3-(4,5-dihydroimidazol-1-yl)propyl-triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN1CCN=C1 WBUSESIMOZDSHU-UHFFFAOYSA-N 0.000 description 2
- IKYAJDOSWUATPI-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propane-1-thiol Chemical compound CO[Si](C)(OC)CCCS IKYAJDOSWUATPI-UHFFFAOYSA-N 0.000 description 2
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 2
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 239000006087 Silane Coupling Agent Substances 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000002274 desiccant Substances 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 description 2
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 2
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 2
- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 229920005749 polyurethane resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- NBXZNTLFQLUFES-UHFFFAOYSA-N triethoxy(propyl)silane Chemical compound CCC[Si](OCC)(OCC)OCC NBXZNTLFQLUFES-UHFFFAOYSA-N 0.000 description 2
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
- 239000008096 xylene Chemical class 0.000 description 2
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- LFSYUSUFCBOHGU-UHFFFAOYSA-N 1-isocyanato-2-[(4-isocyanatophenyl)methyl]benzene Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=CC=C1N=C=O LFSYUSUFCBOHGU-UHFFFAOYSA-N 0.000 description 1
- GPUKMTQLSWHBLZ-UHFFFAOYSA-N 1-phenyltridecane-1-sulfonic acid Chemical compound CCCCCCCCCCCCC(S(O)(=O)=O)C1=CC=CC=C1 GPUKMTQLSWHBLZ-UHFFFAOYSA-N 0.000 description 1
- DIZBQMTZXOUFTD-UHFFFAOYSA-N 2-(furan-2-yl)-3h-benzimidazole-5-carboxylic acid Chemical compound N1C2=CC(C(=O)O)=CC=C2N=C1C1=CC=CO1 DIZBQMTZXOUFTD-UHFFFAOYSA-N 0.000 description 1
- WXMOOUVVULRKOQ-UHFFFAOYSA-N 2-[diethoxy(phenyl)silyl]oxyethanethiol Chemical compound SCCO[Si](OCC)(OCC)C1=CC=CC=C1 WXMOOUVVULRKOQ-UHFFFAOYSA-N 0.000 description 1
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 1
- PVXSFEGIHWMAOD-UHFFFAOYSA-N 2-tridecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O PVXSFEGIHWMAOD-UHFFFAOYSA-N 0.000 description 1
- GSVMCEUQHZAFKG-UHFFFAOYSA-N 2-triethoxysilylaniline Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1N GSVMCEUQHZAFKG-UHFFFAOYSA-N 0.000 description 1
- DVNPFNZTPMWRAX-UHFFFAOYSA-N 2-triethoxysilylethanethiol Chemical compound CCO[Si](CCS)(OCC)OCC DVNPFNZTPMWRAX-UHFFFAOYSA-N 0.000 description 1
- LOSLJXKHQKRRFN-UHFFFAOYSA-N 2-trimethoxysilylethanethiol Chemical compound CO[Si](OC)(OC)CCS LOSLJXKHQKRRFN-UHFFFAOYSA-N 0.000 description 1
- IHDMWJVVHWITIM-UHFFFAOYSA-N 3-(4,5-dihydroimidazol-1-yl)propyl-trimethoxysilane Chemical compound CO[Si](OC)(OC)CCCN1CCN=C1 IHDMWJVVHWITIM-UHFFFAOYSA-N 0.000 description 1
- ZZNRMMYTKJBVPD-UHFFFAOYSA-N 3-[diethoxy(methyl)silyl]-n,n-dimethylpropan-1-amine Chemical compound CCO[Si](C)(OCC)CCCN(C)C ZZNRMMYTKJBVPD-UHFFFAOYSA-N 0.000 description 1
- MBNRBJNIYVXSQV-UHFFFAOYSA-N 3-[diethoxy(methyl)silyl]propane-1-thiol Chemical compound CCO[Si](C)(OCC)CCCS MBNRBJNIYVXSQV-UHFFFAOYSA-N 0.000 description 1
- FMRSVUHIKQTOFR-UHFFFAOYSA-N 3-[ethoxy(dimethyl)silyl]propane-1-thiol Chemical compound CCO[Si](C)(C)CCCS FMRSVUHIKQTOFR-UHFFFAOYSA-N 0.000 description 1
- OXYZDRAJMHGSMW-UHFFFAOYSA-N 3-chloropropyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)CCCCl OXYZDRAJMHGSMW-UHFFFAOYSA-N 0.000 description 1
- BZOVBIIWPDQIHF-UHFFFAOYSA-N 3-hydroxy-2-methylbenzenesulfonic acid Chemical compound CC1=C(O)C=CC=C1S(O)(=O)=O BZOVBIIWPDQIHF-UHFFFAOYSA-N 0.000 description 1
- UDTHXSLCACXSKA-UHFFFAOYSA-N 3-tetradecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCCCC1=CC=CC(S(O)(=O)=O)=C1 UDTHXSLCACXSKA-UHFFFAOYSA-N 0.000 description 1
- DCQBZYNUSLHVJC-UHFFFAOYSA-N 3-triethoxysilylpropane-1-thiol Chemical compound CCO[Si](OCC)(OCC)CCCS DCQBZYNUSLHVJC-UHFFFAOYSA-N 0.000 description 1
- LVNLBBGBASVLLI-UHFFFAOYSA-N 3-triethoxysilylpropylurea Chemical compound CCO[Si](OCC)(OCC)CCCNC(N)=O LVNLBBGBASVLLI-UHFFFAOYSA-N 0.000 description 1
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- CNBZTHQYUOSCDJ-UHFFFAOYSA-N n-(3-triethoxysilylpropyl)butan-2-imine Chemical compound CCO[Si](OCC)(OCC)CCCN=C(C)CC CNBZTHQYUOSCDJ-UHFFFAOYSA-N 0.000 description 1
- SULYJYHNLMOZIP-UHFFFAOYSA-N n-(3-triethoxysilylpropyl)cyclohexanimine Chemical compound CCO[Si](OCC)(OCC)CCCN=C1CCCCC1 SULYJYHNLMOZIP-UHFFFAOYSA-N 0.000 description 1
- PHYRCSSYBSJTMI-UHFFFAOYSA-N n-(3-triethoxysilylpropyl)ethanimine Chemical compound CCO[Si](OCC)(OCC)CCCN=CC PHYRCSSYBSJTMI-UHFFFAOYSA-N 0.000 description 1
- MPKNGASSKGJBSA-UHFFFAOYSA-N n-(3-triethoxysilylpropyl)propan-2-imine Chemical compound CCO[Si](OCC)(OCC)CCCN=C(C)C MPKNGASSKGJBSA-UHFFFAOYSA-N 0.000 description 1
- DLAUQJZKDAKQGO-UHFFFAOYSA-N n-butyl-n-(3-triethoxysilylpropyl)butan-1-amine Chemical compound CCCCN(CCCC)CCC[Si](OCC)(OCC)OCC DLAUQJZKDAKQGO-UHFFFAOYSA-N 0.000 description 1
- DVYVMJLSUSGYMH-UHFFFAOYSA-N n-methyl-3-trimethoxysilylpropan-1-amine Chemical compound CNCCC[Si](OC)(OC)OC DVYVMJLSUSGYMH-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000006187 pill Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000012974 tin catalyst Substances 0.000 description 1
- 235000010215 titanium dioxide Nutrition 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- GQIUQDDJKHLHTB-UHFFFAOYSA-N trichloro(ethenyl)silane Chemical compound Cl[Si](Cl)(Cl)C=C GQIUQDDJKHLHTB-UHFFFAOYSA-N 0.000 description 1
- LENYMJLFWIMHEP-UHFFFAOYSA-N triethoxy(3-pyrrolidin-1-ylpropyl)silane Chemical compound CCO[Si](OCC)(OCC)CCCN1CCCC1 LENYMJLFWIMHEP-UHFFFAOYSA-N 0.000 description 1
- SCONUHVNGPLTMV-UHFFFAOYSA-N triethoxy-[10-(2h-1,3-oxazol-3-yl)decyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCCCCCCCCN1COC=C1 SCONUHVNGPLTMV-UHFFFAOYSA-N 0.000 description 1
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 description 1
- NGLLPRYTJGRGEU-UHFFFAOYSA-N trimethoxy(3-pyrrolidin-1-ylpropyl)silane Chemical compound CO[Si](OC)(OC)CCCN1CCCC1 NGLLPRYTJGRGEU-UHFFFAOYSA-N 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- 239000005050 vinyl trichlorosilane Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3405—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of organic materials
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C23/00—Other surface treatment of glass not in the form of fibres or filaments
- C03C23/0075—Cleaning of glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/30—Aspects of methods for coating glass not covered above
- C03C2218/31—Pre-treatment
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10T156/10—Methods of surface bonding and/or assembly therefor
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Surface Treatment Of Glass (AREA)
- Joining Of Glass To Other Materials (AREA)
- Paints Or Removers (AREA)
Description
(1) セラミックプリントされたガラスを、ドデシルベンゼンスルフォン酸とp−トルエンスルフォン酸と溶剤とを含む第1の溶液によって洗浄する第1の洗浄工程と、
前記第1の溶液によって洗浄されたガラスを、アルコキシシラン化合物を含む第2の溶液によって洗浄する第2の洗浄工程と、
第1の溶液及び第2の溶液により洗浄されたガラスに、ガラスプライマーを塗布するガラスプライマー塗布工程と、
ガラスプライマー塗布後のガラスに接着剤を塗布し、接着剤を塗布したガラスを被着体と貼り合わせるガラス接着工程と
を含み、
前記第1の溶液は、溶剤100質量%に対して、前記ドデシルベンゼンスルフォン酸を0.1質量%以上10質量%以下含み、前記p−トルエンスルフォン酸を0.01質量%以上5質量%以下含む、ガラスの接着方法。
(2) 前記アルコキシシラン化合物は、イミノ基、アミノ基、及びメルカプト基の少なくとも1つを含む上記(1)に記載のガラスの接着方法。
(3) 前記アルコキシシラン化合物は、ジメチルフェニルメトキシシランである上記(1)に記載のガラスの接着方法。
以下に示す3種類のセラガラス(セラガラスA、B、C)を、各々、第1の溶液(洗浄剤1)及び第2の溶液(洗浄剤2)によって順次洗浄した。洗浄後、各セラガラスにガラスプライマーを塗布し、さらに接着剤を塗布した後、接着剤を3mm厚に圧締し硬化させて手剥離試験片を得た。低温接着性試験用の手剥離試験片は、5℃、10日の条件で接着剤を硬化させた。耐温水接着性試験用の剥離試験片ては、20℃、7日の条件で接着剤を硬化させ、さらに、各セラガラスを40℃の温水に2週間浸漬させた。
・セラガラスA:通常のガラス
・セラガラスB:通常のガラスに紙を4週間圧着させて強制紙焼けさせたガラス
・セラガラスC:通常のガラスにシリコンゴムを1週間圧着させた後に4週間強制紙焼けさせたガラス
・N−2−(アミノエチル)3−アミノプロピルトリメトキシシラン:商品名「A−1110」、日本ユニカ社製
・実施例6で用いたNH基を含むもの(N−フェニル−3−アミノプロピルトリメトキシシラン):商品名「KBM−573」、信越化学社製
・実施例7で用いたSH基を含むもの(3−メルカプトプロピルメチルジメトキシシラン):商品名「KBM−802」、信越化学社製
セラガラス上で硬化させた接着剤の接着性と、ガラス表面のべたつき又は粉ふきと、痕跡の有無とに関する各々の評価1〜3の結果を表1に示す。
(評価1:接着性)
各手剥離試験片について、ナイフカットしながら、手剥離を行なった。
表1中、○、×は、各々以下の状態を示す。
○:完全に接着剤で凝集破壊した場合
×:完全に接着剤で凝集破壊せず、界面破壊が発生した場合
洗浄剤1による洗浄後、ガラス表面のべたつき又は粉ふきの有無を触指及び目視で評価した。その結果を表1に示す。
洗浄剤2による洗浄後、洗浄剤1、2によって濡らした痕跡の有無を目視にて評価した。その結果を表1に示す。
表1から明らかなように、洗浄剤1としてDBSAとPTSAとIPAとを本発明の範囲内の割合(IPA100質量%に対して、DBSAを0.1質量%以上10質量%以下、PTSAを0.01質量%以上5質量%以下)で含む溶液を用いて洗浄し、次いで洗浄剤2としてアルコキシシラン化合物を含む溶液を用いて洗浄した、実施例1〜7の接着方法については、いずれも、低温接着性試験(評価1)について、完全に接着剤で凝集破壊しており、接着性の向上が確認された。また、実施例1〜7の接着方法については、いずれも、ガラス表面のべたつき又は粉ふきの有無(評価2)及び痕跡の有無(評価3)についても、良好な結果が確認された。
Claims (3)
- セラミックプリントされたガラスを、ドデシルベンゼンスルフォン酸とp−トルエンスルフォン酸と溶剤とを含む第1の溶液によって洗浄する第1の洗浄工程と、
前記第1の溶液によって洗浄されたガラスを、アルコキシシラン化合物を含む第2の溶液によって洗浄する第2の洗浄工程と、
第1の溶液及び第2の溶液により洗浄されたガラスに、ガラスプライマーを塗布するガラスプライマー塗布工程と、
ガラスプライマー塗布後のガラスに接着剤を塗布し、接着剤を塗布したガラスを被着体と貼り合わせるガラス接着工程と
を含み、
前記第1の溶液は、溶剤100質量%に対して、前記ドデシルベンゼンスルフォン酸を0.1質量%以上10質量%以下含み、前記p−トルエンスルフォン酸を0.01質量%以上5質量%以下含むことを特徴とするガラスの接着方法。 - 前記アルコキシシラン化合物は、イミノ基、アミノ基、及びメルカプト基の少なくとも1つを含む請求項1に記載のガラスの接着方法。
- 前記アルコキシシラン化合物は、ジメチルフェニルメトキシシランである請求項1に記載のガラスの接着方法。
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JP2010206058A JP5594004B2 (ja) | 2010-09-14 | 2010-09-14 | ガラスの接着方法 |
US13/230,598 US8784600B2 (en) | 2010-09-14 | 2011-09-12 | Method for adhering glass |
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JP2010206058A JP5594004B2 (ja) | 2010-09-14 | 2010-09-14 | ガラスの接着方法 |
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TWI757257B (zh) * | 2015-11-19 | 2022-03-11 | 美商康寧公司 | 玻璃物件以及黏合玻璃片與載體之方法 |
CN111205908B (zh) * | 2020-01-17 | 2021-11-23 | 广州市华惠材料科技有限公司 | 一种智能调光贴膜安装液、制备方法及其应用 |
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US4857366A (en) * | 1988-03-11 | 1989-08-15 | Minnesota Mining And Manufacturing Company | Method for obtaining adhesion of urethane sealant to a painted or glass surface |
JP3171109B2 (ja) | 1996-05-21 | 2001-05-28 | 信越化学工業株式会社 | 撥水型洗浄剤 |
JP3938414B2 (ja) | 1996-06-13 | 2007-06-27 | 横浜ゴム株式会社 | 電着型材用プライマー組成物 |
EP1042419B2 (en) * | 1997-12-18 | 2007-08-01 | Essex Specialty Products, Inc. | Method to adhere urethane adhesive to a painted surface with a pre-wipe composition |
US6041976A (en) * | 1998-05-14 | 2000-03-28 | Robertson; Roger C. | Adhesive dispensing tool for use with a rotary power tool |
US7494540B2 (en) | 2004-12-15 | 2009-02-24 | Dow Global Technologies, Inc. | System for bonding glass into a structure |
US7931773B2 (en) | 2006-10-05 | 2011-04-26 | Dow Global Technologies Llc | Primer composition for glass bonding |
US20090061633A1 (en) * | 2007-08-31 | 2009-03-05 | Fujitsu Limited | Method of manufacturing semiconductor device |
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