JP5520509B2

JP5520509B2 - 硬化性樹脂組成物

硬化性樹脂組成物 Download PDF

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Publication number: JP5520509B2
Authority: JP; Japan
Prior art keywords: compound; carboxyl group; group; resin; reacting
Prior art date: 2009-03-31
Legal status : Active

Application number

JP2009087371A

Other languages

English (en)

Japanese (ja)

Other versions

JP2010237575A (ja

Inventor

信人伊藤

聖夫有馬

Current Assignee

Taiyo Holdings Co Ltd

Original Assignee

Taiyo Holdings Co Ltd

Priority date

2009-03-31

Filing date

2009-03-31

Publication date

2014-06-11

2009-03-31 Application filed by Taiyo Holdings Co Ltd filed Critical Taiyo Holdings Co Ltd

2009-03-31 Priority to JP2009087371A priority Critical patent/JP5520509B2/ja

2010-03-23 Priority to CN2010101405365A priority patent/CN101851411B/zh

2010-03-29 Priority to TW099109421A priority patent/TWI500640B/zh

2010-03-30 Priority to KR1020100028255A priority patent/KR101174983B1/ko

2010-10-21 Publication of JP2010237575A publication Critical patent/JP2010237575A/ja

2014-06-11 Application granted granted Critical

2014-06-11 Publication of JP5520509B2 publication Critical patent/JP5520509B2/ja

Status Active legal-status Critical Current

2029-03-31 Anticipated expiration legal-status Critical

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239000011342 resin composition Substances 0.000 title claims description 46
229920005989 resin Polymers 0.000 claims description 156
239000011347 resin Substances 0.000 claims description 156
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 124
-1 cyclic carbonate compound Chemical class 0.000 claims description 122
150000001875 compounds Chemical class 0.000 claims description 94
229920000647 polyepoxide Polymers 0.000 claims description 58
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 57
239000003822 epoxy resin Substances 0.000 claims description 54
238000006243 chemical reaction Methods 0.000 claims description 35
ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 34
239000000758 substrate Substances 0.000 claims description 34
150000008065 acid anhydrides Chemical class 0.000 claims description 30
239000000047 product Substances 0.000 claims description 28
239000007795 chemical reaction product Substances 0.000 claims description 26
229920001187 thermosetting polymer Polymers 0.000 claims description 24
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 23
229920002803 thermoplastic polyurethane Polymers 0.000 claims description 23
239000003999 initiator Substances 0.000 claims description 20
IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 18
125000002947 alkylene group Chemical group 0.000 claims description 16
230000015572 biosynthetic process Effects 0.000 claims description 15
150000004292 cyclic ethers Chemical group 0.000 claims description 15
238000003786 synthesis reaction Methods 0.000 claims description 15
150000007519 polyprotic acids Polymers 0.000 claims description 13
238000001035 drying Methods 0.000 claims description 12
239000003086 colorant Substances 0.000 claims description 11
125000005442 diisocyanate group Chemical group 0.000 claims description 10
125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims description 8
239000007858 starting material Substances 0.000 claims description 8
238000010438 heat treatment Methods 0.000 claims description 7
125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 claims description 6
150000002763 monocarboxylic acids Chemical class 0.000 claims description 5
NCAVPEPBIJTYSO-UHFFFAOYSA-N 4-hydroxybutyl prop-2-enoate;2-(oxiran-2-ylmethoxymethyl)oxirane Chemical compound C1OC1COCC1CO1.OCCCCOC(=O)C=C NCAVPEPBIJTYSO-UHFFFAOYSA-N 0.000 claims description 3
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 2
239000000049 pigment Substances 0.000 description 91
239000010408 film Substances 0.000 description 57
239000000203 mixture Substances 0.000 description 40
239000000126 substance Substances 0.000 description 36
239000000243 solution Substances 0.000 description 35
238000000576 coating method Methods 0.000 description 33
239000011248 coating agent Substances 0.000 description 30
125000000217 alkyl group Chemical group 0.000 description 29
125000004432 carbon atom Chemical group C* 0.000 description 29
229910000679 solder Inorganic materials 0.000 description 24
239000004593 Epoxy Substances 0.000 description 23
RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 20
239000002253 acid Substances 0.000 description 16
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 16
239000012948 isocyanate Substances 0.000 description 16
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 15
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
238000011156 evaluation Methods 0.000 description 15
238000000034 method Methods 0.000 description 15
239000002981 blocking agent Substances 0.000 description 14
239000003054 catalyst Substances 0.000 description 14
RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 14
229920003986 novolac Polymers 0.000 description 14
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 14
239000005056 polyisocyanate Substances 0.000 description 14
229920001228 polyisocyanate Polymers 0.000 description 14
239000007787 solid Substances 0.000 description 14
229910052757 nitrogen Inorganic materials 0.000 description 13
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 12
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 12
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 12
125000003118 aryl group Chemical group 0.000 description 12
150000001732 carboxylic acid derivatives Chemical class 0.000 description 12
229920000642 polymer Polymers 0.000 description 12
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 11
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 11
238000011161 development Methods 0.000 description 11
230000018109 developmental process Effects 0.000 description 11
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 10
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 10
239000003963 antioxidant agent Substances 0.000 description 10
239000007864 aqueous solution Substances 0.000 description 10
239000003795 chemical substances by application Substances 0.000 description 10
238000013329 compounding Methods 0.000 description 10
238000009413 insulation Methods 0.000 description 10
150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 10
238000007747 plating Methods 0.000 description 10
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 9
230000000052 comparative effect Effects 0.000 description 9
229910052802 copper Inorganic materials 0.000 description 9
239000010949 copper Substances 0.000 description 9
LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 9
239000012535 impurity Substances 0.000 description 9
239000002904 solvent Substances 0.000 description 9
238000012360 testing method Methods 0.000 description 9
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
239000003513 alkali Substances 0.000 description 8
PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 8
125000004122 cyclic group Chemical group 0.000 description 8
GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 8
229920001971 elastomer Polymers 0.000 description 8
LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
QWVGKYWNOKOFNN-UHFFFAOYSA-N o-cresol Chemical compound CC1=CC=CC=C1O QWVGKYWNOKOFNN-UHFFFAOYSA-N 0.000 description 8
239000004065 semiconductor Substances 0.000 description 8
230000035945 sensitivity Effects 0.000 description 8
YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 7
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 7
230000003078 antioxidant effect Effects 0.000 description 7
230000007423 decrease Effects 0.000 description 7
238000004090 dissolution Methods 0.000 description 7
239000000806 elastomer Substances 0.000 description 7
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
239000000945 filler Substances 0.000 description 7
238000002156 mixing Methods 0.000 description 7
PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 7
239000003960 organic solvent Substances 0.000 description 7
239000012321 sodium triacetoxyborohydride Substances 0.000 description 7
XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical group S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 7
KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 6
FPZWZCWUIYYYBU-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl acetate Chemical compound CCOCCOCCOC(C)=O FPZWZCWUIYYYBU-UHFFFAOYSA-N 0.000 description 6
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 6
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
239000007983 Tris buffer Substances 0.000 description 6
150000001252 acrylic acid derivatives Chemical class 0.000 description 6
238000007259 addition reaction Methods 0.000 description 6
125000002723 alicyclic group Chemical group 0.000 description 6
125000001931 aliphatic group Chemical group 0.000 description 6
150000004056 anthraquinones Chemical class 0.000 description 6
PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 6
XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 6
239000003085 diluting agent Substances 0.000 description 6
125000003700 epoxy group Chemical group 0.000 description 6
125000005843 halogen group Chemical group 0.000 description 6
ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 6
239000000463 material Substances 0.000 description 6
229910052751 metal Inorganic materials 0.000 description 6
239000002184 metal Substances 0.000 description 6
NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 description 6
125000004430 oxygen atom Chemical group O* 0.000 description 6
KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 6
238000007650 screen-printing Methods 0.000 description 6
229910000029 sodium carbonate Inorganic materials 0.000 description 6
238000003756 stirring Methods 0.000 description 6
CWERGRDVMFNCDR-UHFFFAOYSA-M thioglycolate(1-) Chemical compound [O-]C(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-M 0.000 description 6
QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 5
FVCSARBUZVPSQF-UHFFFAOYSA-N 5-(2,4-dioxooxolan-3-yl)-7-methyl-3a,4,5,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C(C(OC2=O)=O)C2C(C)=CC1C1C(=O)COC1=O FVCSARBUZVPSQF-UHFFFAOYSA-N 0.000 description 5
239000004925 Acrylic resin Substances 0.000 description 5
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
229920000877 Melamine resin Polymers 0.000 description 5
238000010521 absorption reaction Methods 0.000 description 5
125000002252 acyl group Chemical group 0.000 description 5
150000004945 aromatic hydrocarbons Chemical class 0.000 description 5
125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 5
229930003836 cresol Natural products 0.000 description 5
239000011521 glass Substances 0.000 description 5
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 5
229910052737 gold Inorganic materials 0.000 description 5
239000010931 gold Substances 0.000 description 5
125000004435 hydrogen atom Chemical group [H]* 0.000 description 5
239000003112 inhibitor Substances 0.000 description 5
150000002513 isocyanates Chemical class 0.000 description 5
JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine powder Natural products NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 5
229910052759 nickel Inorganic materials 0.000 description 5
NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 5
230000035515 penetration Effects 0.000 description 5
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 5
239000003208 petroleum Substances 0.000 description 5
239000005011 phenolic resin Substances 0.000 description 5
IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical class N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 5
229920005862 polyol Polymers 0.000 description 5
230000035939 shock Effects 0.000 description 5
FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 4
BTJPUDCSZVCXFQ-UHFFFAOYSA-N 2,4-diethylthioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC(CC)=CC(CC)=C3SC2=C1 BTJPUDCSZVCXFQ-UHFFFAOYSA-N 0.000 description 4
JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 4
GZVHEAJQGPRDLQ-UHFFFAOYSA-N 6-phenyl-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 GZVHEAJQGPRDLQ-UHFFFAOYSA-N 0.000 description 4
BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 4
KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 4
ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 4
GTDPSWPPOUPBNX-UHFFFAOYSA-N ac1mqpva Chemical compound CC12C(=O)OC(=O)C1(C)C1(C)C2(C)C(=O)OC1=O GTDPSWPPOUPBNX-UHFFFAOYSA-N 0.000 description 4
150000001412 amines Chemical class 0.000 description 4
125000000751 azo group Chemical group [*]N=N[*] 0.000 description 4
239000002585 base Substances 0.000 description 4
ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical class C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 4
239000012965 benzophenone Substances 0.000 description 4
WQAQPCDUOCURKW-UHFFFAOYSA-N butanethiol Chemical compound CCCCS WQAQPCDUOCURKW-UHFFFAOYSA-N 0.000 description 4
239000011889 copper foil Substances 0.000 description 4
150000004294 cyclic thioethers Chemical group 0.000 description 4
125000000753 cycloalkyl group Chemical group 0.000 description 4
125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 4
239000004744 fabric Substances 0.000 description 4
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RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 4
WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 4
230000009257 reactivity Effects 0.000 description 4
239000007921 spray Substances 0.000 description 4
230000008961 swelling Effects 0.000 description 4
238000012719 thermal polymerization Methods 0.000 description 4
150000003553 thiiranes Chemical class 0.000 description 4
CNHDIAIOKMXOLK-UHFFFAOYSA-N toluquinol Chemical compound CC1=CC(O)=CC=C1O CNHDIAIOKMXOLK-UHFFFAOYSA-N 0.000 description 4
238000012546 transfer Methods 0.000 description 4
POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical class C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 3
WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 description 3
FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 3
TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 3
KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Natural products CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 3
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
239000005058 Isophorone diisocyanate Substances 0.000 description 3
SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
239000002202 Polyethylene glycol Substances 0.000 description 3
BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 description 3
239000006096 absorbing agent Substances 0.000 description 3
BAPJBEWLBFYGME-UHFFFAOYSA-N acrylic acid methyl ester Natural products COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 3
230000001476 alcoholic effect Effects 0.000 description 3
150000008064 anhydrides Chemical class 0.000 description 3
MYONAGGJKCJOBT-UHFFFAOYSA-N benzimidazol-2-one Chemical compound C1=CC=CC2=NC(=O)N=C21 MYONAGGJKCJOBT-UHFFFAOYSA-N 0.000 description 3
150000008366 benzophenones Chemical class 0.000 description 3
IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 3
230000001588 bifunctional effect Effects 0.000 description 3
239000011230 binding agent Substances 0.000 description 3
239000012986 chain transfer agent Substances 0.000 description 3
230000008859 change Effects 0.000 description 3
229910052804 chromium Inorganic materials 0.000 description 3
229920001577 copolymer Polymers 0.000 description 3
238000007334 copolymerization reaction Methods 0.000 description 3
125000004663 dialkyl amino group Chemical group 0.000 description 3
238000002845 discoloration Methods 0.000 description 3
239000000975 dye Substances 0.000 description 3
238000010292 electrical insulation Methods 0.000 description 3
238000007772 electroless plating Methods 0.000 description 3
DNJIEGIFACGWOD-UHFFFAOYSA-N ethyl mercaptane Natural products CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 3
125000000524 functional group Chemical group 0.000 description 3
VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 3
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