JP5453252B2 - 製剤 - Google Patents
製剤 Download PDFInfo
- Publication number
- JP5453252B2 JP5453252B2 JP2010514090A JP2010514090A JP5453252B2 JP 5453252 B2 JP5453252 B2 JP 5453252B2 JP 2010514090 A JP2010514090 A JP 2010514090A JP 2010514090 A JP2010514090 A JP 2010514090A JP 5453252 B2 JP5453252 B2 JP 5453252B2
- Authority
- JP
- Japan
- Prior art keywords
- organoclay
- alkyl
- oil
- stabilizer
- low
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title description 25
- 238000009472 formulation Methods 0.000 title description 18
- 239000004533 oil dispersion Substances 0.000 claims description 56
- 239000007788 liquid Substances 0.000 claims description 51
- 239000003381 stabilizer Substances 0.000 claims description 51
- 239000003995 emulsifying agent Substances 0.000 claims description 38
- 238000000034 method Methods 0.000 claims description 37
- 125000000217 alkyl group Chemical group 0.000 claims description 35
- 239000012190 activator Substances 0.000 claims description 19
- 239000007787 solid Substances 0.000 claims description 16
- 125000005210 alkyl ammonium group Chemical group 0.000 claims description 15
- 239000004359 castor oil Substances 0.000 claims description 15
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 15
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- 229910000278 bentonite Inorganic materials 0.000 claims description 14
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 14
- 125000005207 tetraalkylammonium group Chemical group 0.000 claims description 14
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 13
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- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 12
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- 125000002877 alkyl aryl group Chemical group 0.000 claims description 7
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 claims description 7
- 229910000271 hectorite Inorganic materials 0.000 claims description 7
- AIMMSOZBPYFASU-UHFFFAOYSA-N n-(4,6-dimethoxypyrimidin-2-yl)-n'-[3-(2,2,2-trifluoroethoxy)pyridin-1-ium-2-yl]sulfonylcarbamimidate Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CN=2)OCC(F)(F)F)=N1 AIMMSOZBPYFASU-UHFFFAOYSA-N 0.000 claims description 7
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- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
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- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 230000001965 increasing effect Effects 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- MAGPZHKLEZXLNU-UHFFFAOYSA-N mandelamide Chemical compound NC(=O)C(O)C1=CC=CC=C1 MAGPZHKLEZXLNU-UHFFFAOYSA-N 0.000 description 2
- RTCOGUMHFFWOJV-UHFFFAOYSA-N nicosulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CN=2)C(=O)N(C)C)=N1 RTCOGUMHFFWOJV-UHFFFAOYSA-N 0.000 description 2
- 239000012053 oil suspension Substances 0.000 description 2
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- 159000000000 sodium salts Chemical class 0.000 description 2
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- HOKKPVIRMVDYPB-UVTDQMKNSA-N (Z)-thiacloprid Chemical compound C1=NC(Cl)=CC=C1CN1C(=N/C#N)/SCC1 HOKKPVIRMVDYPB-UVTDQMKNSA-N 0.000 description 1
- RBSXHDIPCIWOMG-UHFFFAOYSA-N 1-(4,6-dimethoxypyrimidin-2-yl)-3-(2-ethylsulfonylimidazo[1,2-a]pyridin-3-yl)sulfonylurea Chemical compound CCS(=O)(=O)C=1N=C2C=CC=CN2C=1S(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 RBSXHDIPCIWOMG-UHFFFAOYSA-N 0.000 description 1
- WKBPZYKAUNRMKP-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)pentyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(CCC)CN1C=NC=N1 WKBPZYKAUNRMKP-UHFFFAOYSA-N 0.000 description 1
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- CAAMSDWKXXPUJR-UHFFFAOYSA-N 3,5-dihydro-4H-imidazol-4-one Chemical class O=C1CNC=N1 CAAMSDWKXXPUJR-UHFFFAOYSA-N 0.000 description 1
- AWRKZJMELLVWDI-UHFFFAOYSA-N 3-pyrimidin-2-yloxypyridine-2-carboxylic acid Chemical class OC(=O)C1=NC=CC=C1OC1=NC=CC=N1 AWRKZJMELLVWDI-UHFFFAOYSA-N 0.000 description 1
- RQDJADAKIFFEKQ-UHFFFAOYSA-N 4-(4-chlorophenyl)-2-phenyl-2-(1,2,4-triazol-1-ylmethyl)butanenitrile Chemical compound C1=CC(Cl)=CC=C1CCC(C=1C=CC=CC=1)(C#N)CN1N=CN=C1 RQDJADAKIFFEKQ-UHFFFAOYSA-N 0.000 description 1
- MBFHUWCOCCICOK-UHFFFAOYSA-N 4-iodo-2-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoylsulfamoyl]benzoic acid Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=C(I)C=2)C(O)=O)=N1 MBFHUWCOCCICOK-UHFFFAOYSA-N 0.000 description 1
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- 239000012530 fluid Substances 0.000 description 1
- PXDNXJSDGQBLKS-UHFFFAOYSA-N foramsulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=C(NC=O)C=2)C(=O)N(C)C)=N1 PXDNXJSDGQBLKS-UHFFFAOYSA-N 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 1
- 229940056881 imidacloprid Drugs 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- KPUREKXXPHOJQT-UHFFFAOYSA-N mesotrione Chemical compound [O-][N+](=O)C1=CC(S(=O)(=O)C)=CC=C1C(=O)C1C(=O)CCCC1=O KPUREKXXPHOJQT-UHFFFAOYSA-N 0.000 description 1
- NIFKBBMCXCMCAO-UHFFFAOYSA-N methyl 2-[(4,6-dimethoxypyrimidin-2-yl)carbamoylsulfamoyl]-4-(methanesulfonamidomethyl)benzoate Chemical group COC(=O)C1=CC=C(CNS(C)(=O)=O)C=C1S(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 NIFKBBMCXCMCAO-UHFFFAOYSA-N 0.000 description 1
- NPKIXUIJIVNVSU-UHFFFAOYSA-N methyl 2-[[4,6-bis(fluoromethoxy)pyrimidin-2-yl]carbamoylsulfamoyl]benzoate Chemical group COC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(OCF)=CC(OCF)=N1 NPKIXUIJIVNVSU-UHFFFAOYSA-N 0.000 description 1
- VWGAYSCWLXQJBQ-UHFFFAOYSA-N methyl 4-iodo-2-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoylsulfamoyl]benzoate Chemical group COC(=O)C1=CC=C(I)C=C1S(=O)(=O)NC(=O)NC1=NC(C)=NC(OC)=N1 VWGAYSCWLXQJBQ-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- RSMUVYRMZCOLBH-UHFFFAOYSA-N metsulfuron methyl Chemical group COC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(C)=NC(OC)=N1 RSMUVYRMZCOLBH-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- FTQWRYSLUYAIRQ-UHFFFAOYSA-N n-[(octadecanoylamino)methyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCNC(=O)CCCCCCCCCCCCCCCCC FTQWRYSLUYAIRQ-UHFFFAOYSA-N 0.000 description 1
- 239000005645 nematicide Substances 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 239000012457 nonaqueous media Substances 0.000 description 1
- 235000014571 nuts Nutrition 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- IOXAXYHXMLCCJJ-UHFFFAOYSA-N oxetan-3-yl 2-[(4,6-dimethylpyrimidin-2-yl)carbamoylsulfamoyl]benzoate Chemical compound CC1=CC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(=O)OC2COC2)=N1 IOXAXYHXMLCCJJ-UHFFFAOYSA-N 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000005648 plant growth regulator Substances 0.000 description 1
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 239000006254 rheological additive Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- MEFOUWRMVYJCQC-UHFFFAOYSA-N rimsulfuron Chemical compound CCS(=O)(=O)C1=CC=CN=C1S(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 MEFOUWRMVYJCQC-UHFFFAOYSA-N 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000011232 storage material Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- ZDXMLEQEMNLCQG-UHFFFAOYSA-N sulfometuron methyl Chemical group COC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(C)=CC(C)=N1 ZDXMLEQEMNLCQG-UHFFFAOYSA-N 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 150000003456 sulfonamides Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- IUQAXCIUEPFPSF-UHFFFAOYSA-N tembotrione Chemical compound ClC1=C(COCC(F)(F)F)C(S(=O)(=O)C)=CC=C1C(=O)C1C(=O)CCCC1=O IUQAXCIUEPFPSF-UHFFFAOYSA-N 0.000 description 1
- PZTAGFCBNDBBFZ-UHFFFAOYSA-N tert-butyl 2-(hydroxymethyl)piperidine-1-carboxylate Chemical compound CC(C)(C)OC(=O)N1CCCCC1CO PZTAGFCBNDBBFZ-UHFFFAOYSA-N 0.000 description 1
- ZFXYFBGIUFBOJW-UHFFFAOYSA-N theophylline Chemical compound O=C1N(C)C(=O)N(C)C2=C1NC=N2 ZFXYFBGIUFBOJW-UHFFFAOYSA-N 0.000 description 1
- 229960000278 theophylline Drugs 0.000 description 1
- NWWZPOKUUAIXIW-FLIBITNWSA-N thiamethoxam Chemical compound [O-][N+](=O)\N=C/1N(C)COCN\1CC1=CN=C(Cl)S1 NWWZPOKUUAIXIW-FLIBITNWSA-N 0.000 description 1
- AHTPATJNIAFOLR-UHFFFAOYSA-N thifensulfuron-methyl Chemical group S1C=CC(S(=O)(=O)NC(=O)NC=2N=C(OC)N=C(C)N=2)=C1C(=O)OC AHTPATJNIAFOLR-UHFFFAOYSA-N 0.000 description 1
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical compound COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- IYMLUHWAJFXAQP-UHFFFAOYSA-N topramezone Chemical compound CC1=C(C(=O)C2=C(N(C)N=C2)O)C=CC(S(C)(=O)=O)=C1C1=NOCC1 IYMLUHWAJFXAQP-UHFFFAOYSA-N 0.000 description 1
- XOPFESVZMSQIKC-UHFFFAOYSA-N triasulfuron Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)OCCCl)=N1 XOPFESVZMSQIKC-UHFFFAOYSA-N 0.000 description 1
- AKTQJCBOGPBERP-UHFFFAOYSA-N triflusulfuron Chemical compound FC(F)(F)COC1=NC(N(C)C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2C)C(O)=O)=N1 AKTQJCBOGPBERP-UHFFFAOYSA-N 0.000 description 1
- KVEQCVKVIFQSGC-UHFFFAOYSA-N tritosulfuron Chemical compound FC(F)(F)C1=NC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(F)(F)F)=N1 KVEQCVKVIFQSGC-UHFFFAOYSA-N 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Zoology (AREA)
- Dentistry (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Colloid Chemistry (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Fertilizers (AREA)
Description
低極性液体(57.4g)を室温にて温度を制御した容器に入れ、5000rpmで動作している回転子−固定子ミキサー(例えば、Silverson製のL4Rモデル)を使用して高せん断下で混合した。オルガノクレー(1.0g)を、高せん断を保っている間に添加し、その後、所望によるプロピレンカーボネート(使用する場合0.1g)、乳化剤(7.5g)、及び所望によるグリコールエーテル(使用する場合2.0g)を、その順番で添加した。分散体の温度を20〜25℃に保持して、高せん断混合を7500rpmまで増加させて、この温度において15分間この速度で保持した。沈降防止系の分離の割合は、室温にて約1ヶ月間の貯蔵後に視覚的に評価した。この方法で調製した沈降防止系製剤1A〜1AIを表1に列挙する。
沈降防止系の濃縮物2A〜2Fを、表2に示すように、Bentone 38(商標)の最終濃縮物を得るようにミネラルオイルの減少した量を用いた以外は、沈降防止系製剤1Dと同じ方法で調製した。
油分散体3.1
沈降防止系の製剤1Dを、温度制御した容器に入れ、良好なバルク混合を達成するための条件を用いて25℃にて攪拌した。攪拌を維持しながら、プロピレングリコールモノブチルエーテル(2.0g)を添加した。別途調製した、細かく粉砕した(約1〜約10μmの粒径まで)Sunspray(商標)11N中のトリフロキシスルフロン(ナトリウム塩として)の40%w/wの懸濁液を添加して、100g/lの最終濃度を得て、調製物が視覚的に均質になるまでバルク混合を維持した。この製剤は25℃にて1年間の貯蔵後、または40℃にて8週間後、または54℃にて2週間後に、5%未満の分離を示すことが分かった。これらの結果は、得られた油分散体が長期間の物理的安定性を有することを示している。
例3.1と同様の油分散体を、沈降防止系濃縮物2A−2Fのそれぞれから調製した。それぞれの場合において、目標のトリフロキシスルフロン濃縮物を得るために必要とされる平衡化したミネラルオイルを容器に最初に入れて、その後に、沈降防止系濃縮物を入れ、その後に、混合物が視覚的に均質になるまでバルク混合を維持しながら、細かく粉砕した(約1〜約10μmの粒径まで)Sunspray(商標)11N中のトリフロキシスルフロン(ナトリウム塩として)の40%w/wの懸濁液を入れた(グリコールエーテルが沈降防止系濃縮物に既に含まれているので、この例には追加のグリコールエーテルは添加しなかった)。これらの製剤は全て、54℃にて2週間後に、5%未満の分離を示すことが分かった。これらの結果は、高濃度のオルガノクレー安定剤を用いて作られた油分散体を用いても、長期間の物理的安定性がまたみられることを示している。
例3.1と同様の油分散体を、様々なグリコールエーテルを用いて調製した。得られた安定性のデータを表3に示す。
例3.1と同様の油分散体を、グリコールエーテル(プロピレングリコールモノブチルエーテル)及び乳化剤(Emulsogen M)の存在する量を変えて調製した。得られた安定性のデータを表4に示す。
例3.1と同様の油分散体を、沈降防止系1Dの代わりに、1B、1E、及び1Fを用いて調製した。それぞれの場合に、コーンプレート形状を備えたUDS200レオメーター(Paar Physica)を用いて、油分散体の低せん断のレオロジー挙動を測定した。これらの試料について測定された弾性率(G’)及び凝集エネルギー(Em)を表5にまとめた。
オルガノクレーを分散させるように鋸歯状ミキサーを用いて、例1Dで使用したものと同様のレシピにしたがって一連の沈降防止系を調製した。一連の沈降防止系にわたって調製を行った温度を変化させた。分離データを表6に示す。
本発明はまた、以下の内容を包含する。
(1)
低極性液体での使用に適したオルガノクレー安定剤を活性化する方法であって、低極性液体の存在下における高せん断条件下で、アルキルエトキシレート、アルキルエトキシレートホスフェートエステル、アルキルサルフェート、アルキルアンモニウム塩、及びキャスターオイルエトシキレートからなる群から選択される乳化剤と混合することを含む、オルガノクレー安定剤の活性化方法。
(2)
該オルガノクレー安定剤に対して、最大20%w/wの量で極性活性化剤を添加することをさらに含む、項目1に記載の方法。
(3)
グリコールエーテルを添加することをさらに含む、項目1または2に記載の方法。
(4)
該オルガノクレーの活性化が、15℃を超える温度にて起こる、項目1〜3のいずれか一項に記載の方法。
(5)
該オルガノクレー安定剤が、テトラアルキルアンモニウムベントナイト、テトラアルキルアンモニウムヘクトライト、及びテトラ(アルキル/アリール)アンモニウムベントナイトからなる群から選択される、項目1〜4のいずれか一項に記載の方法。
(6)
該低極性液体が、パラフィンオイルまたはミネラルオイルである、項目1〜5のいずれか一項に記載の方法。
(7)
a)低極性液体での使用に適したオルガノクレー安定剤、
b)アルキルエトキシレート、アルキルエトキシレートホスフェートエステル、アルキルサルフェート、アルキルアンモニウム塩、及びキャスターオイルエトキシレートからなる群から選択される乳化剤、
c)低極性液体、並びに
d)該低極性液体に実質的に不溶性である固体成分、
を含む、物理的に安定な油分散体であって、
該オルガノクレー安定剤が項目1〜6のいずれか一項に記載の方法によって活性化されたものである、油分散体。
(8)
該オルガノクレー安定剤に対して、最大20%w/wの量で存在する極性活性化剤をさらに含む、項目7に記載の物理的に安定な油分散体。
(9)
a)低極性液体での使用に適したオルガノクレー安定剤、
b)アルキルエトキシレート、アルキルエトキシレートホスフェートエステル、アルキルサルフェート、アルキルアンモニウム塩、及びキャスターオイルエトキシレートからなる群から選択される乳化剤、
c)低極性液体、並びに
d)該低極性液体に実質的に不溶性である固体成分、
を含む、物理的に安定な油分散体であって、
該油分散体が、該オルガノクレー安定剤に対して、20%w/w未満の極性活性化剤を含む、油分散体。
(10)
グリコールエーテルをさらに含む、項目7〜9のいずれか一項に記載の物理的に安定な油分散体。
(11)
該オルガノクレーが、テトラアルキルアンモニウムベントナイト、テトラアルキルアンモニウムヘクトライト、及びテトラ(アルキル/アリール)アンモニウムベントナイトからなる群から選択される、項目7〜10のいずれか一項に記載の物理的に安定な油分散体。
(12)
該低極性液体が、パラフィンオイルまたはミネラルオイルである、項目7〜10のいずれか一項に記載の物理的に安定な油分散体。
(13)
該固体成分が、油不溶性の農薬、肥料、またはアジュバントである、項目7〜12のいずれか一項に記載の物理的に安定な油分散体。
(14)
油不溶性の農薬が、ALS阻害剤、HPPD阻害剤、ネオニコチノイド、カルバメート、アベルメクチン、ピレスロイド、ビスアマイド、トリアゾール、マンデルアミド、及びストロビルリンからなる群から選択される、項目13に記載の物理的に安定な油分散体。
(15)
該油不溶性の農薬がスルホニル尿素である、項目14に記載の物理的に安定な油分散体。
(16)
該油不溶性の農薬がトリフロキシスルフロンである、項目15に記載の物理的に安定な油分散体。
(17)
a)低極性液体での使用に適したオルガノクレー安定剤、
b)低極性液体、
c)アルキルエトキシレート、アルキルエトキシレートホスフェートエステル、アルキルサルフェート、アルキルアンモニウム塩、及びキャスターオイルエトキシレートからなる群から選択される乳化剤、並びに
d)該低極性液体に実質的に不溶性である固体成分、
を準備すること、並びに
高せん断条件下において該成分を混合すること、
を含む、物理的に安定な油分散体の形成方法。
(18)
該オルガノクレー安定剤に対して、最大20%w/wの量で極性活性化剤を添加することをさらに含む、項目17に記載の方法。
(19)
グリコールエーテルを添加することをさらに含む、項目17または18に記載の方法。
(20)
該乳化剤を添加する前に、該オルガノクレー安定剤を該低極性液体に添加する、項目17〜19のいずれか一項に記載の方法。
(21)
該方法が、15℃を超える温度にて行われる、項目17〜19のいずれか一項に記載の方法。
(22)
該オルガノクレー安定剤が、テトラアルキルアンモニウムベントナイト、テトラアルキルアンモニウムヘクトライト、及びテトラ(アルキル/アリール)アンモニウムベントナイトからなる群から選択される、項目17〜19のいずれか一項に記載の方法。
(23)
該低極性液体が、パラフィンオイルまたはミネラルオイルである、項目17〜19のいずれか一項に記載の方法。
(24)
アルキルエトキシレート、アルキルエトキシレートホスフェートエステル、アルキルサルフェート、アルキルアンモニウム塩、及びキャスターオイルエトキシレートからなる群から選択される乳化剤を使用して、低極性液体での使用に適したオルガノクレー安定剤を活性化させる方法。
(25)
ある場所の不所望の雑草を抑制する方法であって、項目15または16に記載の物理的に安定な油分散体またはその希釈物の除草に効果的な量を、該雑草または該場所に適用することを含む、雑草の抑制方法。
Claims (7)
- a)低極性液体での使用に適したオルガノクレー安定剤、
b)低極性液体、
c)アルキルエトキシレート、アルキルエトキシレートホスフェートエステル、アルキルサルフェート、アルキルアンモニウム塩、及びキャスターオイルエトキシレートからなる群から選択される乳化剤、並びに
d)トリフロキシスルフロンを含む、該低極性液体に実質的に不溶性である固体成分、
を準備すること、並びに
高せん断条件下において該成分を混合すること、
を含む、物理的に安定な油分散体の形成方法。 - 該オルガノクレー安定剤に対して、最大20%w/wの量で極性活性化剤を添加することをさらに含む、請求項1に記載の方法。
- グリコールエーテルを添加することをさらに含む、請求項1または2に記載の方法。
- 該乳化剤を添加する前に、該オルガノクレー安定剤を該低極性液体に添加する、請求項1〜3のいずれか一項に記載の方法。
- 該方法が、15℃を超える温度にて行われる、請求項1〜3のいずれか一項に記載の方法。
- 該オルガノクレー安定剤が、テトラアルキルアンモニウムベントナイト、テトラアルキルアンモニウムヘクトライト、及びテトラ(アルキル/アリール)アンモニウムベントナイトからなる群から選択される、請求項1〜3のいずれか一項に記載の方法。
- 該低極性液体が、パラフィンオイルまたはミネラルオイルである、請求項1〜3のいずれか一項に記載の方法。
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GBGB0712884.6A GB0712884D0 (en) | 2007-07-03 | 2007-07-03 | Formulations |
PCT/GB2008/001983 WO2009004281A2 (en) | 2007-07-03 | 2008-06-09 | Formulations |
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EP (1) | EP2175720A2 (ja) |
JP (1) | JP5453252B2 (ja) |
KR (1) | KR101534473B1 (ja) |
CN (1) | CN101808512B (ja) |
AR (1) | AR067380A1 (ja) |
AU (1) | AU2008270070B2 (ja) |
BR (1) | BRPI0814188A2 (ja) |
CA (1) | CA2691183A1 (ja) |
GB (1) | GB0712884D0 (ja) |
SG (1) | SG195618A1 (ja) |
TW (1) | TWI473565B (ja) |
WO (1) | WO2009004281A2 (ja) |
ZA (1) | ZA200908969B (ja) |
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EP2067752A1 (en) * | 2007-12-06 | 2009-06-10 | Nederlandse Organisatie voor toegepast- natuurwetenschappelijk onderzoek TNO | Construction material |
ES2954135T3 (es) * | 2010-10-15 | 2023-11-20 | Bayer Cropscience Lp | Mutantes de Beta vulgaris tolerantes a herbicidas inhibidores de ALS |
IT1403174B1 (it) | 2010-12-14 | 2013-10-04 | Lamberti Spa | Dispersione agrochimica in olio |
WO2012108873A1 (en) * | 2011-02-11 | 2012-08-16 | Dow Agrosciences Llc | Stable agrochemical oil dispersions |
BR102013009504A2 (pt) | 2013-04-18 | 2015-03-17 | Oxiteno S A Indústria E Comércio | Formulação agroquímica do tipo dispersão em óleo, uso das formulações agroquímicas do tipo dispersão em óleo e processo de obtenção de formulação agroquímica do tipo dispersão em óleo |
BR112017013448B1 (pt) * | 2014-12-22 | 2021-09-28 | Battelle Uk Limited | Composições líquidas de herbicidas contendo sulfonilureia |
WO2016142518A1 (en) * | 2015-03-12 | 2016-09-15 | Rhodia Operations | Concentrate formulations, agricultural oil dispersions, methods and uses thereof |
CA2995900A1 (en) * | 2015-08-21 | 2017-03-02 | Bayer Cropscience Aktiengesellschaft | An agrochemical oil-based suspension concentrate comprising low-density particles with low gravitational separation and low viscosity |
JP2016145188A (ja) * | 2015-12-28 | 2016-08-12 | ダウ アグロサイエンシィズ エルエルシー | 安定な農薬油分散体 |
BR102017010745A2 (pt) | 2016-05-24 | 2018-02-27 | Adama Makhteshim Ltd. | Formulação líquida de óleo fungicida, suspoemulsão fungicida e uso da formulação líquida de óleo fungicida |
CN109714964A (zh) * | 2016-07-06 | 2019-05-03 | 农作物增强公司 | 用于农业用途的无毒覆层浓缩液 |
CN110099565A (zh) | 2016-12-29 | 2019-08-06 | 阿克苏诺贝尔化学品国际有限公司 | 具有聚合物流变改性剂的增稠有机液体组合物 |
US10793737B2 (en) * | 2017-12-29 | 2020-10-06 | Behr Process Corporation | Fast dry stain formula |
IT201800003500A1 (it) | 2018-03-13 | 2019-09-13 | Lamberti Spa | Dispersioni agrochimiche in olio |
KR20220077924A (ko) * | 2019-10-10 | 2022-06-09 | 바이엘 악티엔게젤샤프트 | 프로필렌 카르보네이트를 포함하는 살곤충제 제제 |
TW202128014A (zh) * | 2019-10-10 | 2021-08-01 | 德商拜耳廠股份有限公司 | 含二醇醚溶劑之殺蟲劑調配物 |
TW202128015A (zh) * | 2019-10-10 | 2021-08-01 | 德商拜耳廠股份有限公司 | 包含乙二醇醚溶劑之殺昆蟲混合物調配物 |
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RO66706A2 (ro) * | 1977-10-01 | 1982-03-24 | Centrala Industriala De Produse Anorganice,Ro | Compozitie fungicida cu volum ultraredus |
GB2067407B (en) * | 1980-01-18 | 1983-07-27 | Fbc Ltd | Pesticidal composition and use |
GB2082913B (en) * | 1980-09-03 | 1983-07-13 | Dow Chemical Co | Emulsifiable non-aqueous solvent-flowable compositions containing an insoluble pesticide |
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ATE40506T1 (de) * | 1983-09-19 | 1989-02-15 | Monsanto Co | Lagerstabile fliessfaehige formuliering in form einer emulsion die eine mischung aus alachlor/atrazin als wirkstoff enthaelt. |
IT1173066B (it) * | 1984-01-18 | 1987-06-18 | Sipcam Spa | Sospensione fluida stabilizzata di antiparassitari in solventi organici non clorurati e procedimento di preparazione e di impiego della stessa |
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DE102004025220A1 (de) * | 2004-05-22 | 2005-12-08 | Bayer Cropscience Gmbh | Ölsuspensionskonzentrat |
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WO2009004281A2 (en) | 2009-01-08 |
SG195618A1 (en) | 2013-12-30 |
CN101808512B (zh) | 2014-04-23 |
BRPI0814188A2 (pt) | 2014-10-14 |
WO2009004281A3 (en) | 2009-11-26 |
AR067380A1 (es) | 2009-10-07 |
TWI473565B (zh) | 2015-02-21 |
KR101534473B1 (ko) | 2015-07-07 |
CA2691183A1 (en) | 2009-01-08 |
ZA200908969B (en) | 2011-05-25 |
KR20100037063A (ko) | 2010-04-08 |
EP2175720A2 (en) | 2010-04-21 |
US8623389B2 (en) | 2014-01-07 |
US20100331187A1 (en) | 2010-12-30 |
TW200906297A (en) | 2009-02-16 |
JP2010531864A (ja) | 2010-09-30 |
GB0712884D0 (en) | 2007-08-15 |
CN101808512A (zh) | 2010-08-18 |
AU2008270070A1 (en) | 2009-01-08 |
AU2008270070B2 (en) | 2014-07-17 |
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