JP5393145B2 - 乾燥促進剤およびその使用方法 - Google Patents
乾燥促進剤およびその使用方法 Download PDFInfo
- Publication number
- JP5393145B2 JP5393145B2 JP2008504397A JP2008504397A JP5393145B2 JP 5393145 B2 JP5393145 B2 JP 5393145B2 JP 2008504397 A JP2008504397 A JP 2008504397A JP 2008504397 A JP2008504397 A JP 2008504397A JP 5393145 B2 JP5393145 B2 JP 5393145B2
- Authority
- JP
- Japan
- Prior art keywords
- dryer
- ink
- cobalt
- desiccant
- manganese
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000001035 drying Methods 0.000 title description 42
- 238000000034 method Methods 0.000 title description 34
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 56
- 229910017052 cobalt Inorganic materials 0.000 claims description 55
- 239000010941 cobalt Substances 0.000 claims description 55
- 239000002274 desiccant Substances 0.000 claims description 51
- 239000000203 mixture Substances 0.000 claims description 40
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 29
- 229910052748 manganese Inorganic materials 0.000 claims description 29
- 239000011572 manganese Substances 0.000 claims description 29
- 239000003973 paint Substances 0.000 claims description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- 239000002966 varnish Substances 0.000 claims description 19
- 238000004519 manufacturing process Methods 0.000 claims description 16
- 229930195733 hydrocarbon Natural products 0.000 claims description 13
- 150000002430 hydrocarbons Chemical class 0.000 claims description 13
- 230000009977 dual effect Effects 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 5
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 2
- 239000000976 ink Substances 0.000 description 135
- 238000007639 printing Methods 0.000 description 51
- 238000001723 curing Methods 0.000 description 22
- 238000002156 mixing Methods 0.000 description 21
- 230000008569 process Effects 0.000 description 19
- 239000003921 oil Substances 0.000 description 16
- 150000007942 carboxylates Chemical class 0.000 description 11
- 238000012546 transfer Methods 0.000 description 11
- 238000001459 lithography Methods 0.000 description 7
- 239000002383 tung oil Substances 0.000 description 7
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 6
- -1 carboxylate salt Chemical class 0.000 description 5
- 230000002209 hydrophobic effect Effects 0.000 description 5
- 239000003446 ligand Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- 150000001735 carboxylic acids Chemical class 0.000 description 4
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 230000005855 radiation Effects 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 229940011182 cobalt acetate Drugs 0.000 description 3
- 229910000428 cobalt oxide Inorganic materials 0.000 description 3
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000002572 peristaltic effect Effects 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 238000007650 screen-printing Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 241000282819 Giraffa Species 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000002738 chelating agent Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 238000007647 flexography Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 229960004488 linolenic acid Drugs 0.000 description 2
- 239000011344 liquid material Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- CUXYLFPMQMFGPL-UHFFFAOYSA-N (9Z,11E,13E)-9,11,13-Octadecatrienoic acid Natural products CCCCC=CC=CC=CCCCCCCCC(O)=O CUXYLFPMQMFGPL-UHFFFAOYSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 244000055346 Paulownia Species 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- RECCKCFXMJNLFO-ZVGUSBNCSA-L cobalt(2+);(2r,3r)-2,3-dihydroxybutanedioate Chemical compound [Co+2].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O RECCKCFXMJNLFO-ZVGUSBNCSA-L 0.000 description 1
- CTIHZTFULZJBGQ-UHFFFAOYSA-L cobalt(2+);decanoate Chemical compound [Co+2].CCCCCCCCCC([O-])=O.CCCCCCCCCC([O-])=O CTIHZTFULZJBGQ-UHFFFAOYSA-L 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000005595 deprotonation Effects 0.000 description 1
- 238000010537 deprotonation reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000001227 electron beam curing Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000001056 green pigment Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 238000007644 letterpress printing Methods 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- LPNBBFKOUUSUDB-UHFFFAOYSA-N p-toluic acid Chemical compound CC1=CC=C(C(O)=O)C=C1 LPNBBFKOUUSUDB-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000010424 printmaking Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000001029 thermal curing Methods 0.000 description 1
- 238000007651 thermal printing Methods 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 230000035899 viability Effects 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F9/00—Compounds to be used as driers, i.e. siccatives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Paints Or Removers (AREA)
Description
「プリンターはインクについて何を知るべきか(What the Printer Should Know About Ink)」 テリー・スカーレットおよびネルソン・R・エルドレッド著,the Graphics Arts Technical Foundation出版
Claims (8)
- (a)12重量%のコバルトを含むコバルトドライヤーと、
(b)マンガンドライヤーと、
(c)キリ油と、
(d)加圧下に水素処理された炭化水素から構成される水活性化ドライヤーと、
(e)コバルトおよびマンガンの両方を含んだ2元ドライヤーと、
(f)リソグラフィック・オーバープリントワニスと
を含んでなる乾燥剤。 - 前記乾燥剤は、
(a)1重量部の前記コバルトドライヤーと、
(b)1重量部の前記マンガンドライヤーと、
(c)1重量部の前記キリ油と、
(d)1重量部の前記水活性化ドライヤーと、
(e)1重量部の前記2元ドライヤーと、および
(f)1重量部の前記リソグラフィック・オーバープリントワニスと
を含んでなる請求項1に記載の乾燥剤。 - (a)容器中にマンガンドライヤーを供給する工程と、
(b)リソグラフィック・オーバープリントワニスを前記容器中に添加する工程と、
(c)12重量%のコバルトを含むコバルトドライヤーを前記容器中に添加する工程と、
(d)コバルトおよびマンガンの両方を含んだ2元ドライヤーを前記容器中に添加する工程と、
(e)加圧下に水素処理された炭化水素から構成される水活性化ドライヤーを前記容器中に添加する工程と
を順に備えてなる乾燥剤の製造方法。 - 前記乾燥剤の製造方法が、
(a)前記マンガンドライヤーと、前記リソグラフィック・オーバープリントワニスと、前記コバルトドライヤーと、前記2元ドライヤーと、前記水活性化ドライヤーとを、前記容器中で均一に分散された混合物を形成するまで、前記容器中で攪拌する工程と
(b)前記容器中にキリ油を添加する工程と
を更に備えてなる請求項3に記載の乾燥剤の製造方法。 - インク混合物であって、
(a)インク、
(b)12重量%のコバルトを含むコバルトドライヤー、マンガンドライヤー、キリ油、加圧下に水素処理された炭化水素から構成される水活性化ドライヤー、コバルトおよびマンガンの両方を含んだ2元ドライヤー、および、リソグラフィック・オーバープリントワニスを含む乾燥剤、並びに、
(c)前記乾燥剤が当該インク混合物の3から50重量%であること、
を備えてなるインク混合物。 - 前記乾燥剤が当該インク混合物の10から15重量%である、請求項5に記載のインク混合物。
- (a)塗料、並びに、
(b)12重量%のコバルトを含むコバルトドライヤー、マンガンドライヤー、キリ油、加圧下に水素処理された炭化水素から構成される水活性化ドライヤー、コバルトおよびマンガンの両方を含んだ2元ドライヤー、および、リソグラフィック・オーバープリントワニスを含む乾燥剤
を備えてなる塗料混合物。 - 前記乾燥剤は当該塗料混合物の15重量%である、請求項7に記載の塗料混合物。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US66614705P | 2005-03-29 | 2005-03-29 | |
US60/666,147 | 2005-03-29 | ||
US11/307,273 US7682440B2 (en) | 2005-03-29 | 2006-01-30 | Drying enhancement additive and method of using same |
US11/307,273 | 2006-01-30 | ||
PCT/US2006/011776 WO2006105348A2 (en) | 2005-03-29 | 2006-03-29 | Drying enhancement additive and method of using same |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2008537970A JP2008537970A (ja) | 2008-10-02 |
JP5393145B2 true JP5393145B2 (ja) | 2014-01-22 |
Family
ID=37054155
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2008504397A Expired - Fee Related JP5393145B2 (ja) | 2005-03-29 | 2006-03-29 | 乾燥促進剤およびその使用方法 |
Country Status (3)
Country | Link |
---|---|
US (2) | US7682440B2 (ja) |
JP (1) | JP5393145B2 (ja) |
WO (1) | WO2006105348A2 (ja) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8460448B2 (en) * | 2010-06-14 | 2013-06-11 | Dic Corporation | Printing ink dryer and printing ink using the same |
JP2014514367A (ja) | 2010-11-15 | 2014-06-19 | サン ケミカル コーポレイション | 印刷用インクの凝固特性および耐摩擦性を改善するための組成物および方法 |
JP7094229B2 (ja) | 2016-05-23 | 2022-07-01 | サン ケミカル コーポレイション | 平版印刷インキ用液体変性petポリエステル |
US20220010149A1 (en) * | 2020-07-08 | 2022-01-13 | Swimc Llc | Paint tinting adjuvant with siccative for powder colorant system |
US20220010148A1 (en) * | 2020-07-08 | 2022-01-13 | Swimc Llc | Paint tinting adjuvant with siccative for liquid colorant system |
WO2023152240A1 (en) | 2022-02-09 | 2023-08-17 | Sun Chemical Corporation | Sustainable radiation curable hybrid offset inks |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3005789A (en) * | 1955-10-11 | 1961-10-24 | Gen Aniline & Film Corp | Drier composition |
CA1190987A (en) | 1984-05-23 | 1985-07-23 | Eli Ganho | Process and compositions for printing in multiple layers |
US5141562A (en) * | 1991-06-21 | 1992-08-25 | Mooney Chemicals, Inc. | Drier promoter compositions |
US5759252A (en) * | 1996-04-19 | 1998-06-02 | Borchers Gmbh | Mixtures of carboxylic acid salts and carboxylic acid esters and their use as siccatives for oxidatively drying lacquers |
US6245136B1 (en) * | 1999-05-10 | 2001-06-12 | Victory Ink Company, Inc. | Matte ink composition and method of use |
US6626985B1 (en) * | 1999-05-10 | 2003-09-30 | Victory Ink Company, Inc. | Matte ink composition and method of use |
KR100596698B1 (ko) * | 1999-06-03 | 2006-07-03 | 다이니혼 잉키 가가쿠 고교 가부시키가이샤 | 경화 촉진제 및 수지 조성물 |
JP3890372B2 (ja) * | 2001-11-19 | 2007-03-07 | 独立行政法人 国立印刷局 | 印刷インキ用乾燥剤 |
-
2006
- 2006-01-30 US US11/307,273 patent/US7682440B2/en active Active
- 2006-03-29 JP JP2008504397A patent/JP5393145B2/ja not_active Expired - Fee Related
- 2006-03-29 WO PCT/US2006/011776 patent/WO2006105348A2/en active Application Filing
-
2010
- 2010-02-08 US US12/702,098 patent/US7811367B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
WO2006105348A3 (en) | 2009-04-09 |
JP2008537970A (ja) | 2008-10-02 |
WO2006105348A2 (en) | 2006-10-05 |
US20060219136A1 (en) | 2006-10-05 |
US7682440B2 (en) | 2010-03-23 |
US7811367B2 (en) | 2010-10-12 |
US20100147189A1 (en) | 2010-06-17 |
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