JP5389159B2 - Ｇａ−Ｐ−Ｓ型のガラス組成物 - Google Patents
Ｇａ−Ｐ−Ｓ型のガラス組成物 Download PDFInfo
- Publication number
- JP5389159B2 JP5389159B2 JP2011507425A JP2011507425A JP5389159B2 JP 5389159 B2 JP5389159 B2 JP 5389159B2 JP 2011507425 A JP2011507425 A JP 2011507425A JP 2011507425 A JP2011507425 A JP 2011507425A JP 5389159 B2 JP5389159 B2 JP 5389159B2
- Authority
- JP
- Japan
- Prior art keywords
- atoms
- glass
- glass composition
- percent
- replaced
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000011521 glass Substances 0.000 title claims description 92
- 239000000203 mixture Substances 0.000 title claims description 61
- 229910052711 selenium Inorganic materials 0.000 claims description 57
- 229910052714 tellurium Inorganic materials 0.000 claims description 57
- 229910052717 sulfur Inorganic materials 0.000 claims description 52
- 125000004429 atom Chemical group 0.000 claims description 41
- 125000004434 sulfur atom Chemical group 0.000 claims description 20
- 229910052733 gallium Inorganic materials 0.000 claims description 17
- 229910052738 indium Inorganic materials 0.000 claims description 16
- 229910005839 GeS 2 Inorganic materials 0.000 claims description 11
- 229910052698 phosphorus Inorganic materials 0.000 claims description 9
- 229910052785 arsenic Inorganic materials 0.000 claims description 8
- 229910052732 germanium Inorganic materials 0.000 claims description 7
- 229910052787 antimony Inorganic materials 0.000 claims description 6
- 229910002056 binary alloy Inorganic materials 0.000 claims description 6
- 229910052797 bismuth Inorganic materials 0.000 claims description 3
- 229910052745 lead Inorganic materials 0.000 claims description 3
- 229910052716 thallium Inorganic materials 0.000 claims description 3
- 229910052718 tin Inorganic materials 0.000 claims description 3
- 239000002203 sulfidic glass Substances 0.000 description 16
- 230000005855 radiation Effects 0.000 description 12
- 229910052761 rare earth metal Inorganic materials 0.000 description 12
- 150000002910 rare earth metals Chemical class 0.000 description 11
- 238000001228 spectrum Methods 0.000 description 10
- 239000002019 doping agent Substances 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 6
- 239000011593 sulfur Substances 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 229910052747 lanthanoid Inorganic materials 0.000 description 5
- 150000002602 lanthanoids Chemical class 0.000 description 5
- 239000000146 host glass Substances 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000003708 ampul Substances 0.000 description 3
- CUGMJFZCCDSABL-UHFFFAOYSA-N arsenic(3+);trisulfide Chemical compound [S-2].[S-2].[S-2].[As+3].[As+3] CUGMJFZCCDSABL-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000009477 glass transition Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000075 oxide glass Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- 239000005291 arsenic sulfide based glass Substances 0.000 description 2
- 230000005670 electromagnetic radiation Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000007496 glass forming Methods 0.000 description 2
- 238000004433 infrared transmission spectrum Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- 238000004425 31P magic-angle spinning nuclear magnetic resonance (31P MAS NMR) spectrum Methods 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 229910052692 Dysprosium Inorganic materials 0.000 description 1
- 229910052691 Erbium Inorganic materials 0.000 description 1
- 229910052693 Europium Inorganic materials 0.000 description 1
- 229910052688 Gadolinium Inorganic materials 0.000 description 1
- 229910052689 Holmium Inorganic materials 0.000 description 1
- 229910052765 Lutetium Inorganic materials 0.000 description 1
- 229910052779 Neodymium Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910052777 Praseodymium Inorganic materials 0.000 description 1
- 229910052773 Promethium Inorganic materials 0.000 description 1
- 229910052772 Samarium Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 229910052771 Terbium Inorganic materials 0.000 description 1
- 229910052775 Thulium Inorganic materials 0.000 description 1
- 229910052769 Ytterbium Inorganic materials 0.000 description 1
- 239000005354 aluminosilicate glass Substances 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 description 1
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 description 1
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- -1 for example Chemical class 0.000 description 1
- 239000005350 fused silica glass Substances 0.000 description 1
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 1
- 239000000086 gallium sulfide glass Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000004803 parallel plate viscometry Methods 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000002002 phosphorus-31 magic angle spinning nuclear magnetic resonance spectrum Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
- VQMWBBYLQSCNPO-UHFFFAOYSA-N promethium atom Chemical compound [Pm] VQMWBBYLQSCNPO-UHFFFAOYSA-N 0.000 description 1
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 description 1
- 238000001845 vibrational spectrum Methods 0.000 description 1
- 238000001429 visible spectrum Methods 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/32—Non-oxide glass compositions, e.g. binary or ternary halides, sulfides or nitrides of germanium, selenium or tellurium
- C03C3/321—Chalcogenide glasses, e.g. containing S, Se, Te
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/10—Compositions for glass with special properties for infrared transmitting glass
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/111,620 US7767604B2 (en) | 2008-04-29 | 2008-04-29 | Ga—P—S glass compositions |
| US12/111,620 | 2008-04-29 | ||
| PCT/US2009/002577 WO2009134351A1 (en) | 2008-04-29 | 2009-04-28 | Ga-p-s glass compositions |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2011518758A JP2011518758A (ja) | 2011-06-30 |
| JP2011518758A5 JP2011518758A5 (enExample) | 2013-10-10 |
| JP5389159B2 true JP5389159B2 (ja) | 2014-01-15 |
Family
ID=40848668
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011507425A Expired - Fee Related JP5389159B2 (ja) | 2008-04-29 | 2009-04-28 | Ｇａ−Ｐ−Ｓ型のガラス組成物 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7767604B2 (enExample) |
| EP (1) | EP2294023B1 (enExample) |
| JP (1) | JP5389159B2 (enExample) |
| KR (1) | KR101515670B1 (enExample) |
| CN (1) | CN102066274B (enExample) |
| TW (1) | TWI391360B (enExample) |
| WO (1) | WO2009134351A1 (enExample) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5339720B2 (ja) * | 2007-12-28 | 2013-11-13 | 五鈴精工硝子株式会社 | モールド成型用赤外線透過ガラス |
| US9187360B2 (en) | 2012-04-20 | 2015-11-17 | Schott Corporation | Glasses for the correction of chromatic and thermal optical aberations for lenses transmitting in the near, mid, and far-infrared sprectrums |
| JP6505975B2 (ja) | 2013-03-15 | 2019-04-24 | スコット コーポレーションＳｃｈｏｔｔ Ｃｏｒｐｏｒａｔｉｏｎ | 赤外光学用の低軟化点光学ガラスを用いたオプティカルボンディング及び形成された製造物 |
| CN103864296B (zh) * | 2014-03-26 | 2016-08-24 | 南京信息工程大学 | 一种红外光纤用硫系玻璃及其制备方法 |
| CN103864297A (zh) * | 2014-03-26 | 2014-06-18 | 南京信息工程大学 | 一种精密模压成型用中红外光学玻璃 |
| CN104355538B (zh) * | 2014-10-20 | 2016-12-21 | 江苏师范大学 | 一种硫化物红外玻璃及制备方法 |
| CN104402220B (zh) * | 2014-11-10 | 2017-02-22 | 湖北新华光信息材料有限公司 | 一种硫系光学玻璃 |
| CN104402221B (zh) * | 2014-11-26 | 2017-03-29 | 江苏师范大学 | 一种硫卤玻璃及其制备方法 |
| WO2016159289A1 (ja) * | 2015-03-31 | 2016-10-06 | 国立大学法人京都工芸繊維大学 | モールド成型に適した赤外線透過ガラス |
| US10099957B2 (en) | 2015-06-17 | 2018-10-16 | Schott Corporation | Infrared transmission chalcogenide glasses |
| WO2017086227A1 (ja) * | 2015-11-20 | 2017-05-26 | 旭硝子株式会社 | 光学ガラス |
| US10519061B2 (en) * | 2016-07-18 | 2019-12-31 | Corning Incorporated | Use of arsenic-free chalcogenide glasses for hot-melt processing |
| US10889887B2 (en) | 2016-08-22 | 2021-01-12 | Honeywell International Inc. | Chalcogenide sputtering target and method of making the same |
| CN113035692B (zh) * | 2021-03-05 | 2023-11-17 | 河南师范大学 | 一种超宽禁带二维半导体GaPS4的制备方法 |
| CN114656143B (zh) * | 2022-04-02 | 2023-04-11 | 中国科学院西安光学精密机械研究所 | 一种稀土离子掺杂硫系增益玻璃及其低温合成制备方法 |
| KR20260108167A (ko) * | 2023-11-02 | 2026-07-07 | 코닝 인코포레이티드 | 사출 성형을 위한 초저농도의 도펀트를 갖는 비소-풍부 셀레늄계 칼코게나이드 유리 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5240885A (en) | 1992-09-21 | 1993-08-31 | Corning Incorporated | Rare earth-doped, stabilized cadmium halide glasses |
| US5389584A (en) * | 1994-04-11 | 1995-02-14 | Corning Incorporated | Ga- and/or In-containing AsGe sulfide glasses |
| US5392376A (en) | 1994-04-11 | 1995-02-21 | Corning Incorporated | Gallium sulfide glasses |
| WO2000043323A1 (en) * | 1999-01-21 | 2000-07-27 | Corning Incorporated | GeAs SULPHIDE GLASSES CONTAINING P |
| US6696157B1 (en) * | 2000-03-05 | 2004-02-24 | 3M Innovative Properties Company | Diamond-like glass thin films |
| US20030064293A1 (en) | 2001-09-07 | 2003-04-03 | Polight Technologies Ltd. | Holographic recording medium |
| US7184203B2 (en) * | 2003-02-21 | 2007-02-27 | Burgener Ii Robert H | Rare earth compounds having photo-luminescent properties and applications thereof |
| US7116888B1 (en) * | 2005-04-13 | 2006-10-03 | Corning, Incorporated | Chalcogenide glass for low viscosity extrusion and injection molding |
-
2008
- 2008-04-29 US US12/111,620 patent/US7767604B2/en not_active Expired - Fee Related
-
2009
- 2009-04-27 TW TW098113970A patent/TWI391360B/zh not_active IP Right Cessation
- 2009-04-28 JP JP2011507425A patent/JP5389159B2/ja not_active Expired - Fee Related
- 2009-04-28 CN CN2009801243845A patent/CN102066274B/zh not_active Expired - Fee Related
- 2009-04-28 KR KR1020107026540A patent/KR101515670B1/ko not_active Expired - Fee Related
- 2009-04-28 EP EP09739154.4A patent/EP2294023B1/en not_active Not-in-force
- 2009-04-28 WO PCT/US2009/002577 patent/WO2009134351A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| US7767604B2 (en) | 2010-08-03 |
| CN102066274B (zh) | 2013-07-24 |
| EP2294023B1 (en) | 2018-08-01 |
| TWI391360B (zh) | 2013-04-01 |
| CN102066274A (zh) | 2011-05-18 |
| TW201004889A (en) | 2010-02-01 |
| US20090270241A1 (en) | 2009-10-29 |
| KR20100134794A (ko) | 2010-12-23 |
| JP2011518758A (ja) | 2011-06-30 |
| KR101515670B1 (ko) | 2015-04-27 |
| WO2009134351A1 (en) | 2009-11-05 |
| EP2294023A1 (en) | 2011-03-16 |
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