JP5358769B2 - 撥水撥油防汚性アパレル製品とその製造方法 - Google Patents
撥水撥油防汚性アパレル製品とその製造方法 Download PDFInfo
- Publication number
- JP5358769B2 JP5358769B2 JP2007285881A JP2007285881A JP5358769B2 JP 5358769 B2 JP5358769 B2 JP 5358769B2 JP 2007285881 A JP2007285881 A JP 2007285881A JP 2007285881 A JP2007285881 A JP 2007285881A JP 5358769 B2 JP5358769 B2 JP 5358769B2
- Authority
- JP
- Japan
- Prior art keywords
- water
- group
- oil
- repellent
- antifouling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000005871 repellent Substances 0.000 title claims abstract description 72
- 238000000034 method Methods 0.000 title claims abstract description 8
- 230000003373 anti-fouling effect Effects 0.000 title claims description 53
- 239000000126 substance Substances 0.000 claims abstract description 85
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 78
- 125000005370 alkoxysilyl group Chemical group 0.000 claims abstract description 53
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 36
- 125000001183 hydrocarbyl group Chemical class 0.000 claims abstract description 36
- 239000004094 surface-active agent Substances 0.000 claims abstract description 25
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 230000002940 repellent Effects 0.000 claims description 47
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical group FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 36
- 239000000835 fiber Substances 0.000 claims description 22
- 238000004519 manufacturing process Methods 0.000 claims description 19
- 239000002131 composite material Substances 0.000 claims description 15
- 239000007788 liquid Substances 0.000 claims description 15
- 125000000217 alkyl group Chemical group 0.000 claims description 11
- 239000011248 coating agent Substances 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 10
- 150000005621 tetraalkylammonium salts Chemical class 0.000 claims description 8
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 claims description 7
- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 6
- 239000011356 non-aqueous organic solvent Substances 0.000 abstract description 5
- 239000005046 Chlorosilane Substances 0.000 abstract description 4
- 239000003463 adsorbent Substances 0.000 abstract description 4
- KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical compound Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 abstract description 4
- QLOAVXSYZAJECW-UHFFFAOYSA-N methane;molecular fluorine Chemical group C.FF QLOAVXSYZAJECW-UHFFFAOYSA-N 0.000 abstract description 2
- 239000004753 textile Substances 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 44
- 239000004744 fabric Substances 0.000 description 17
- 239000000758 substrate Substances 0.000 description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 5
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- 229910020175 SiOH Inorganic materials 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000005299 abrasion Methods 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 210000002268 wool Anatomy 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- -1 chlorosilyl groups Chemical group 0.000 description 2
- 238000007033 dehydrochlorination reaction Methods 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000010985 leather Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Images
Landscapes
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007285881A JP5358769B2 (ja) | 2007-11-02 | 2007-11-02 | 撥水撥油防汚性アパレル製品とその製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007285881A JP5358769B2 (ja) | 2007-11-02 | 2007-11-02 | 撥水撥油防汚性アパレル製品とその製造方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2009114559A JP2009114559A (ja) | 2009-05-28 |
| JP2009114559A5 JP2009114559A5 (enrdf_load_stackoverflow) | 2010-12-16 |
| JP5358769B2 true JP5358769B2 (ja) | 2013-12-04 |
Family
ID=40782010
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007285881A Expired - Fee Related JP5358769B2 (ja) | 2007-11-02 | 2007-11-02 | 撥水撥油防汚性アパレル製品とその製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP5358769B2 (enrdf_load_stackoverflow) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009069183A1 (ja) * | 2007-11-30 | 2009-06-04 | Kazufumi Ogawa | 調湿材料 |
| JP5736606B2 (ja) * | 2010-02-25 | 2015-06-17 | 小川 一文 | 撥水離水防汚処理液およびそれを用いた撥水離水性防汚膜とその製造方法およびそれらを用いた製品 |
| CN105113258A (zh) * | 2015-08-14 | 2015-12-02 | 湖州市云巢染料化工厂 | 由2，2- 二羟甲基丁酸制得的水性含氟拒水拒油剂 |
| CN112552515B (zh) * | 2019-09-25 | 2022-07-26 | 山东东岳未来氢能材料股份有限公司 | 一种含氟氨基硅油及其制备方法和应用 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2555797B2 (ja) * | 1991-05-13 | 1996-11-20 | トヨタ自動車株式会社 | 撥水ガラス及びその製造方法 |
| JP2000282015A (ja) * | 1999-01-28 | 2000-10-10 | Asahi Glass Co Ltd | 撥水撥油剤組成物およびその製造方法 |
| JP2001335693A (ja) * | 2000-05-25 | 2001-12-04 | E I Du Pont De Nemours & Co | フルオロカーボンシラン加水分解物含有水性エマルジョンおよび耐油防汚性・耐熱撥水性の被覆物 |
| JP2004076231A (ja) * | 2002-08-21 | 2004-03-11 | Du Pont Kk | 撥水撥油防汚性に優れた高強力耐熱有機繊維と繊維製品及びそれらの製造方法 |
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2007
- 2007-11-02 JP JP2007285881A patent/JP5358769B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP2009114559A (ja) | 2009-05-28 |
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