JP5301151B2 - オレフィン重合を制御する方法 - Google Patents
オレフィン重合を制御する方法 Download PDFInfo
- Publication number
- JP5301151B2 JP5301151B2 JP2007507432A JP2007507432A JP5301151B2 JP 5301151 B2 JP5301151 B2 JP 5301151B2 JP 2007507432 A JP2007507432 A JP 2007507432A JP 2007507432 A JP2007507432 A JP 2007507432A JP 5301151 B2 JP5301151 B2 JP 5301151B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- catalyst component
- molecular weight
- productivity
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US56023004P | 2004-04-07 | 2004-04-07 | |
| US60/560,230 | 2004-04-07 | ||
| PCT/US2005/011493 WO2005100414A1 (en) | 2004-04-07 | 2005-04-05 | Method of controlling olefin polymerization |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2007532719A JP2007532719A (ja) | 2007-11-15 |
| JP2007532719A5 JP2007532719A5 (https=) | 2008-05-15 |
| JP5301151B2 true JP5301151B2 (ja) | 2013-09-25 |
Family
ID=34964940
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007507432A Expired - Fee Related JP5301151B2 (ja) | 2004-04-07 | 2005-04-05 | オレフィン重合を制御する方法 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US7601783B2 (https=) |
| EP (1) | EP1732957B1 (https=) |
| JP (1) | JP5301151B2 (https=) |
| CN (1) | CN1938341B (https=) |
| AR (1) | AR053745A1 (https=) |
| AU (1) | AU2005233566B2 (https=) |
| BR (1) | BRPI0508789A (https=) |
| CA (1) | CA2560348C (https=) |
| ES (1) | ES2386357T3 (https=) |
| MY (1) | MY162605A (https=) |
| RU (1) | RU2006139079A (https=) |
| SG (1) | SG151339A1 (https=) |
| WO (1) | WO2005100414A1 (https=) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102005035477A1 (de) * | 2005-07-26 | 2007-02-01 | Basell Polyolefine Gmbh | Verfahren zur Steuerung der relativen Aktivität der unterschiedlichen aktiven Zentren von Hybridkatalysatoren |
| EP2231723B1 (en) * | 2007-11-20 | 2012-05-16 | Univation Technologies, LLC | Methods for making polyolefins |
| US8809220B2 (en) * | 2010-04-13 | 2014-08-19 | Union Carbide Chemicals & Plastics Technology Llc | Method of making Ziegler-Natta type catalysts |
| KR20140001993A (ko) * | 2010-12-31 | 2014-01-07 | 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크날러지 엘엘씨 | 중합체, 이의 제조 방법, 및 이로부터 만든 물품 |
| US8940842B2 (en) * | 2012-09-24 | 2015-01-27 | Chevron Phillips Chemical Company Lp | Methods for controlling dual catalyst olefin polymerizations |
| RU2689991C1 (ru) * | 2014-02-11 | 2019-05-30 | ЮНИВЕЙШН ТЕКНОЛОДЖИЗ, ЭлЭлСи | Способ получения полиэтилена и полиэтилен, полученный указанным способом |
| EP3504250A1 (en) * | 2016-08-23 | 2019-07-03 | ExxonMobil Chemical Patents Inc. | Olefin polymerization processes |
| WO2018111631A1 (en) | 2016-12-15 | 2018-06-21 | Univation Technologies, Llc | Rating polymerization processes |
| WO2018226787A1 (en) * | 2017-06-08 | 2018-12-13 | Univation Technologies, Llc | Method of maintaining a melt flow index of a polyethylene polymer product |
| WO2019046085A1 (en) * | 2017-08-28 | 2019-03-07 | Univation Technologies, Llc | BIMODAL POLYETHYLENE |
| US10654949B2 (en) * | 2018-02-22 | 2020-05-19 | Exxonmobil Chemical Patents Inc. | High molecular weight functionalized olefin copolymer quenching agent |
| WO2021050227A1 (en) | 2019-09-13 | 2021-03-18 | Exxonmobil Chemical Patents Inc. | Slurry loop reactor polymerization rate and quality controller |
Family Cites Families (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USB632416I5 (https=) | 1956-03-01 | 1976-03-09 | ||
| US3190862A (en) | 1961-05-24 | 1965-06-22 | Monsanto Co | Copolymers of ethylene and methyl substituted alpha, omega-diolefins |
| NL281221A (https=) | 1961-07-21 | |||
| DE1595665C3 (de) * | 1966-08-09 | 1975-08-14 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung von Äthylenpolymerisaten |
| CA849081A (en) | 1967-03-02 | 1970-08-11 | Du Pont Of Canada Limited | PRODUCTION OF ETHYLENE/.alpha.-OLEFIN COPOLYMERS OF IMPROVED PHYSICAL PROPERTIES |
| IT1113111B (it) | 1978-02-28 | 1986-01-20 | Snia Viscosa | Procedimento perfezionato per la preparazione di alfa,gamma diammine |
| IT1127222B (it) | 1979-11-14 | 1986-05-21 | Montedison Spa | Componenti di catalizzatori per la polimerizzazione di olefine |
| IT1141295B (it) | 1980-04-22 | 1986-10-01 | Montedison Spa | Componenti e catalizzatori per la polimerizzazione delle alfaolefine |
| US4481301A (en) | 1981-12-04 | 1984-11-06 | Mobil Oil Corporation | Highly active catalyst composition for polymerizing alpha-olefins |
| IT1190682B (it) | 1982-02-12 | 1988-02-24 | Montedison Spa | Catalizzatori per la polimerizzazione di olefine |
| US4461873A (en) * | 1982-06-22 | 1984-07-24 | Phillips Petroleum Company | Ethylene polymer blends |
| US4937299A (en) | 1983-06-06 | 1990-06-26 | Exxon Research & Engineering Company | Process and catalyst for producing reactor blend polyolefins |
| US4530914A (en) * | 1983-06-06 | 1985-07-23 | Exxon Research & Engineering Co. | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
| JPS6155104A (ja) | 1984-08-24 | 1986-03-19 | Toho Titanium Co Ltd | オレフィン類重合用触媒成分 |
| US5055438A (en) | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
| US4939217A (en) | 1987-04-03 | 1990-07-03 | Phillips Petroleum Company | Process for producing polyolefins and polyolefin catalysts |
| US4918038A (en) | 1987-10-29 | 1990-04-17 | Union Carbide Chemicals And Plastics Company Inc. | Process for the production of polyethylene with a broad and/or bimodal molecular weight distribution |
| US5330950A (en) * | 1987-12-29 | 1994-07-19 | Mobil Oil Corporation | Mixed Ziegler and chromium catalyst and process for preparing a broad molecular weight distribution HDPE |
| NZ235032A (en) | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
| US5026798A (en) | 1989-09-13 | 1991-06-25 | Exxon Chemical Patents Inc. | Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
| US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| US5237025A (en) | 1990-10-09 | 1993-08-17 | Phillips Petroleum Company | Process for making bimodal polyolefins using two independent particulate catalysts |
| US5372980A (en) | 1993-06-03 | 1994-12-13 | Polysar | Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers |
| ES2155095T5 (es) | 1993-10-21 | 2006-04-16 | Exxonmobil Oil Corporation | Mezclas de poliolefinas con distribucion bimodal de pesos moleculares. |
| US5614456A (en) | 1993-11-15 | 1997-03-25 | Mobil Oil Corporation | Catalyst for bimodal molecular weight distribution ethylene polymers and copolymers |
| US6461696B1 (en) * | 1993-11-16 | 2002-10-08 | Baxter International Inc. | Multi-layered polymer based moisture barrier structure for medical grade products |
| US5624877A (en) | 1994-02-25 | 1997-04-29 | Phillips Petroleum Company | Process for producing polyolefins |
| US5442018A (en) | 1994-04-01 | 1995-08-15 | Union Carbide Chemicals & Plastics Technology Corporation | Ethylene polymerization using a titanium and vanadium catalyst system in staged reactors |
| US5525678A (en) | 1994-09-22 | 1996-06-11 | Mobil Oil Corporation | Process for controlling the MWD of a broad/bimodal resin produced in a single reactor |
| US5882750A (en) | 1995-07-03 | 1999-03-16 | Mobil Oil Corporation | Single reactor bimodal HMW-HDPE film resin with improved bubble stability |
| JP3654318B2 (ja) * | 1995-11-24 | 2005-06-02 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分および触媒 |
| US6051525A (en) * | 1997-07-14 | 2000-04-18 | Mobil Corporation | Catalyst for the manufacture of polyethylene with a broad or bimodal molecular weight distribution |
| US6001766A (en) | 1997-12-24 | 1999-12-14 | Mobil Oil Corporation | Bimetallic catalysts for ethylene polymerization reactions activated with paraffin-soluble alkylalumoxanes |
| US6258903B1 (en) * | 1998-12-18 | 2001-07-10 | Univation Technologies | Mixed catalyst system |
| US6184299B1 (en) * | 1999-03-31 | 2001-02-06 | Union Carbide Chemicals & Plastics Technology Corporation | Staged reactor process |
| WO2001030862A1 (en) * | 1999-10-22 | 2001-05-03 | Univation Technologies, Llc | Start up methods for multiple catalyst systems |
| US6372868B1 (en) * | 1999-12-07 | 2002-04-16 | Univation Technologies, Llc | Start up methods for multiple catalyst systems |
| WO2003048213A1 (en) * | 2001-11-30 | 2003-06-12 | Exxonmobil Chemical Patents, Inc. | Ethylene/alpha-olefin copolymer made with a non-single-site/single-site catalyst combination, its preparation and use |
| US7238756B2 (en) * | 2003-10-15 | 2007-07-03 | Univation Technologies, Llc | Polymerization process and control of polymer composition properties |
| US6828395B1 (en) | 2003-10-15 | 2004-12-07 | Univation Technologies, Llc | Polymerization process and control of polymer composition properties |
-
2005
- 2005-04-05 RU RU2006139079/04A patent/RU2006139079A/ru not_active Application Discontinuation
- 2005-04-05 ES ES05732744T patent/ES2386357T3/es not_active Expired - Lifetime
- 2005-04-05 AU AU2005233566A patent/AU2005233566B2/en not_active Ceased
- 2005-04-05 US US11/099,328 patent/US7601783B2/en not_active Expired - Fee Related
- 2005-04-05 SG SG200902387-0A patent/SG151339A1/en unknown
- 2005-04-05 WO PCT/US2005/011493 patent/WO2005100414A1/en not_active Ceased
- 2005-04-05 EP EP05732744A patent/EP1732957B1/en not_active Expired - Lifetime
- 2005-04-05 CA CA2560348A patent/CA2560348C/en not_active Expired - Fee Related
- 2005-04-05 CN CN2005800107686A patent/CN1938341B/zh not_active Expired - Lifetime
- 2005-04-05 BR BRPI0508789-9A patent/BRPI0508789A/pt not_active IP Right Cessation
- 2005-04-05 MY MYPI20051528A patent/MY162605A/en unknown
- 2005-04-05 JP JP2007507432A patent/JP5301151B2/ja not_active Expired - Fee Related
- 2005-04-06 AR ARP050101354A patent/AR053745A1/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| SG151339A1 (en) | 2009-04-30 |
| RU2006139079A (ru) | 2008-05-20 |
| EP1732957A1 (en) | 2006-12-20 |
| JP2007532719A (ja) | 2007-11-15 |
| MY162605A (en) | 2017-06-30 |
| CN1938341B (zh) | 2011-08-10 |
| EP1732957B1 (en) | 2012-05-23 |
| ES2386357T3 (es) | 2012-08-17 |
| CA2560348A1 (en) | 2005-10-27 |
| AU2005233566A1 (en) | 2005-10-27 |
| US7601783B2 (en) | 2009-10-13 |
| AR053745A1 (es) | 2007-05-23 |
| BRPI0508789A (pt) | 2007-09-04 |
| AU2005233566B2 (en) | 2011-01-06 |
| CN1938341A (zh) | 2007-03-28 |
| CA2560348C (en) | 2013-05-28 |
| WO2005100414A1 (en) | 2005-10-27 |
| US20050228138A1 (en) | 2005-10-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US11332553B2 (en) | Catalyst composition for polymerizing polyolefin, method for producing polyolefin, and polyolefin resin | |
| JP4576049B2 (ja) | 二段階反応器エチレン重合法 | |
| EP2228394A1 (en) | Multi-stage process for producing multi-modal linear low density polyethylene | |
| JP5301151B2 (ja) | オレフィン重合を制御する方法 | |
| KR20110138254A (ko) | 개선된 에틸렌 중합 촉매 조성물 | |
| US20190194371A1 (en) | Process for the Preparation of Ethylene Polymers Using a Number of Reactors Arranged in Series | |
| EP2655445B1 (en) | Process for controlling the relative activity of active centers of catalyst systems comprising at least one late transition metal catalyst component and at least one ziegler catalyst component | |
| CA2523051C (en) | Process for preparing a polymerization catalyst comprising ti, mg, and al | |
| EP1913037B1 (en) | Method of controlling the relative activity of the different active centers of hybrid catalysts | |
| EP3339333B1 (en) | Ziegler-natta catalyst and preparation thereof | |
| US6462149B1 (en) | Control of resin split in single-reactor manufacture of bimodal polyolefins | |
| US6448348B1 (en) | Process for polymerizing olefins with supported Ziegler-Natta catalyst systems | |
| EP1231223B1 (en) | Process for the polymerization of olefins | |
| AU2001291152A1 (en) | Control of resin split in single-reactor manufacture of bimodal polyolefins | |
| EP2607391A1 (en) | Process for controlling the polymer composition of an ethylene copolymer obtained by a catalyst system comprising a transition metal catalyst component and a Ziegler catalyst component | |
| WO2017029579A1 (en) | Method for altering melt flow ratio of ethylene polymers | |
| Korkmaz | Evolution of Ultra High Molecular Weight Polyethylene Synthesis: A Comprehensive Review of Phenoxy-Imine Catalysts for Enhanced Material Properties and Industrial Perspective | |
| US20030045659A1 (en) | Process for polymerizing olefins with supported Ziegler-Natta catalyst systems | |
| EP1905785A1 (en) | Process for the preparation of ethylene polymers using a number of reactors arranged in series |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20080327 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20080327 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20111025 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20120124 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20120131 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20120308 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20120605 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20120905 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20120912 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20121106 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20130521 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20130619 |
|
| R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| LAPS | Cancellation because of no payment of annual fees |