JP5232860B2 - テキスタイルを処理するためのカルボン酸ジエステルの使用及び配合物 - Google Patents
テキスタイルを処理するためのカルボン酸ジエステルの使用及び配合物 Download PDFInfo
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- JP5232860B2 JP5232860B2 JP2010517364A JP2010517364A JP5232860B2 JP 5232860 B2 JP5232860 B2 JP 5232860B2 JP 2010517364 A JP2010517364 A JP 2010517364A JP 2010517364 A JP2010517364 A JP 2010517364A JP 5232860 B2 JP5232860 B2 JP 5232860B2
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- dicarboxylic acid
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- branched
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- 239000000203 mixture Substances 0.000 title claims description 51
- -1 carboxylic acid diesters Chemical class 0.000 title claims description 40
- 239000004753 textile Substances 0.000 title claims description 19
- 238000009472 formulation Methods 0.000 title claims description 14
- 239000004094 surface-active agent Substances 0.000 claims description 34
- 150000003505 terpenes Chemical class 0.000 claims description 25
- 235000007586 terpenes Nutrition 0.000 claims description 25
- 239000001257 hydrogen Substances 0.000 claims description 21
- 229910052739 hydrogen Inorganic materials 0.000 claims description 21
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 20
- 239000003973 paint Substances 0.000 claims description 20
- 239000002736 nonionic surfactant Substances 0.000 claims description 18
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 16
- 239000002904 solvent Substances 0.000 claims description 14
- 229920006395 saturated elastomer Polymers 0.000 claims description 11
- 239000012669 liquid formulation Substances 0.000 claims description 10
- 125000004122 cyclic group Chemical group 0.000 claims description 8
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 7
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 5
- 239000002689 soil Substances 0.000 claims description 4
- 125000002947 alkylene group Chemical group 0.000 claims description 3
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 claims description 2
- 125000002015 acyclic group Chemical group 0.000 claims description 2
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 2
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 2
- 239000010794 food waste Substances 0.000 claims description 2
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
- 239000010688 mineral lubricating oil Substances 0.000 claims description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 239000003208 petroleum Substances 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 239000011269 tar Substances 0.000 claims description 2
- 239000010693 vegetable lubricating oil Substances 0.000 claims description 2
- 235000013311 vegetables Nutrition 0.000 claims description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 3
- 239000013543 active substance Substances 0.000 claims 1
- 150000005690 diesters Chemical class 0.000 description 55
- 150000001875 compounds Chemical class 0.000 description 33
- 238000006243 chemical reaction Methods 0.000 description 20
- 239000002253 acid Substances 0.000 description 12
- 238000000034 method Methods 0.000 description 11
- 239000003599 detergent Substances 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000003054 catalyst Substances 0.000 description 9
- 238000004140 cleaning Methods 0.000 description 8
- 150000002430 hydrocarbons Chemical group 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 238000004821 distillation Methods 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- UDSFAEKRVUSQDD-UHFFFAOYSA-N Dimethyl adipate Chemical compound COC(=O)CCCCC(=O)OC UDSFAEKRVUSQDD-UHFFFAOYSA-N 0.000 description 5
- MUXOBHXGJLMRAB-UHFFFAOYSA-N Dimethyl succinate Chemical compound COC(=O)CCC(=O)OC MUXOBHXGJLMRAB-UHFFFAOYSA-N 0.000 description 5
- 239000002585 base Substances 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- BTGRAWJCKBQKAO-UHFFFAOYSA-N adiponitrile Chemical compound N#CCCCCC#N BTGRAWJCKBQKAO-UHFFFAOYSA-N 0.000 description 4
- XTDYIOOONNVFMA-UHFFFAOYSA-N dimethyl pentanedioate Chemical compound COC(=O)CCCC(=O)OC XTDYIOOONNVFMA-UHFFFAOYSA-N 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- WNLRTRBMVRJNCN-UHFFFAOYSA-N hexanedioic acid Natural products OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000012429 reaction media Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- WVUYYXUATWMVIT-UHFFFAOYSA-N 1-bromo-4-ethoxybenzene Chemical compound CCOC1=CC=C(Br)C=C1 WVUYYXUATWMVIT-UHFFFAOYSA-N 0.000 description 2
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 2
- GDCJAPJJFZWILF-UHFFFAOYSA-N 2-ethylbutanedinitrile Chemical compound CCC(C#N)CC#N GDCJAPJJFZWILF-UHFFFAOYSA-N 0.000 description 2
- RVHOBHMAPRVOLO-UHFFFAOYSA-N 2-ethylbutanedioic acid Chemical compound CCC(C(O)=O)CC(O)=O RVHOBHMAPRVOLO-UHFFFAOYSA-N 0.000 description 2
- FPPLREPCQJZDAQ-UHFFFAOYSA-N 2-methylpentanedinitrile Chemical compound N#CC(C)CCC#N FPPLREPCQJZDAQ-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
- 239000011149 active material Substances 0.000 description 2
- 150000001263 acyl chlorides Chemical class 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 2
- 235000011130 ammonium sulphate Nutrition 0.000 description 2
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 238000007306 functionalization reaction Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 238000005669 hydrocyanation reaction Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229920000847 nonoxynol Polymers 0.000 description 2
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 2
- 239000012074 organic phase Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- MFRIHAYPQRLWNB-UHFFFAOYSA-N sodium tert-butoxide Chemical compound [Na+].CC(C)(C)[O-] MFRIHAYPQRLWNB-UHFFFAOYSA-N 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- 238000003482 Pinner synthesis reaction Methods 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052936 alkali metal sulfate Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 125000002619 bicyclic group Chemical group 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- ZWKKRUNHAVNSFW-UHFFFAOYSA-N dimethyl 2-methylpentanedioate Chemical compound COC(=O)CCC(C)C(=O)OC ZWKKRUNHAVNSFW-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000001177 diphosphate Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 238000006266 etherification reaction Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- 239000011499 joint compound Substances 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical group CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229910052756 noble gas Inorganic materials 0.000 description 1
- UYDLBVPAAFVANX-UHFFFAOYSA-N octylphenoxy polyethoxyethanol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(OCCOCCOCCOCCO)C=C1 UYDLBVPAAFVANX-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- RPDAUEIUDPHABB-UHFFFAOYSA-N potassium ethoxide Chemical compound [K+].CC[O-] RPDAUEIUDPHABB-UHFFFAOYSA-N 0.000 description 1
- BDAWXSQJJCIFIK-UHFFFAOYSA-N potassium methoxide Chemical compound [K+].[O-]C BDAWXSQJJCIFIK-UHFFFAOYSA-N 0.000 description 1
- LPNYRYFBWFDTMA-UHFFFAOYSA-N potassium tert-butoxide Chemical compound [K+].CC(C)(C)[O-] LPNYRYFBWFDTMA-UHFFFAOYSA-N 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- QDRKDTQENPPHOJ-UHFFFAOYSA-N sodium ethoxide Chemical compound [Na+].CC[O-] QDRKDTQENPPHOJ-UHFFFAOYSA-N 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 239000011973 solid acid Substances 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 235000019817 tetrapotassium diphosphate Nutrition 0.000 description 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/266—Esters or carbonates
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Description
・粘着性下塗り
・「ベースコート」(塗料+金属顔料)
・「クリアコート」(透明保護ワニス)。
・式−CH(CH3)−CH2−CH2−のAMG基(2−メチルグルタル酸に対応)、
・式−CH(C2H5)−CH2−のAES基(2−エチルコハク酸に対応)、及び
・それらの混合物。
(ここで、
AMGは式−CH(CH3)−CH2−CH2−の基であり、
AESは式−CH(C2H5)−CH2−の基である。)
・式(I')のジカルボン酸ジエステル(好ましくはジメチルエステル)70〜95重量%、
・式(I'')のジカルボン酸ジエステル(好ましくはジメチルエステル)5〜30重量%、及び
・式(II)のジカルボン酸ジエステル(好ましくはジメチルエステル)0〜10重量%。
Zはビシクロ[a.b.c]ヘプテニル又はビシクロ[a.b.c.]ヘプチル基を表わし、ここで、
a+b+cは5であり、
aは2、3又は4であり、
bは2又は1であり、
cは0又は1であり、
この基は、随意に1個以上のC1〜C6アルキル基で置換されていてもよく、下記のもの:
Xは−CH2−C(R3)(R4)−O−又は−O−CH(R'3)−CH(R'4)−O−を表わし、ここで、R3、R4、R'3及びR'4は同一であっても異なっていてもよく、水素又は飽和若しくは不飽和の直鎖状、分岐鎖状若しくは環状C1〜C22、好ましくはC1〜C6炭化水素基を表わし、
R5及びR6は同一であっても異なっていてもよく、水素又は飽和若しくは不飽和の直鎖状、分岐鎖状若しくは環状C1〜C22炭化水素基を表わし、但し、R5及びR6の少なくとも1つは水素以外であるものとし、
R7は水素又は飽和若しくは不飽和の直鎖状、分岐鎖状若しくは環状の芳香族若しくは非芳香族C1〜C22炭化水素基(随意に例えばOH基で置換されていてよい)を表わし、
n、p及びqは0以上の整数又は非整数であり、
n+p+qは1超、好ましくは2〜200、好ましくは5〜50である。}
・nが2〜10の範囲の整数又は非整数であり、
・pが3〜20の範囲の整数又は非整数であり、
・qが0〜30の範囲の整数又は非整数である
a.酸化防止剤、
b.腐食防止剤、
c.増粘剤、
d.着色料、
e.芳香剤、
f.安定剤、又は
g.上記成分の任意の組合せ。
・メチルグルタロニトリル86.9重量%
・エチルスクシノニトリル11.2重量%
・アジポニトリル1.9重量%。
・2−メチルグルタル酸のジメチルエステル 89%
・2−エチルコハク酸のジメチルエステル 9%
・アジピン酸のジメチルエステル 1%
・各種化合物 1%
・1リットルの液状配合物を60℃においてターゴメーター中に入れる。
・撹拌機を100±3サイクル/分に調節する。
・撹拌しながら1時間洗浄する。
・浴の比(布帛重量/浴重量):約1/32。
・1リットルの水道水を用いて手動ですすぐ:洗った布帛試験片上に水を注ぎ、次いで5分間撹拌を行う;このすすぎプロセスは3回実施する。
・直鎖状ジエステル:Rhodiasolv(登録商標)RPDE
・アルカリ性洗剤:NaOH又はKOHペレット1/3、メタケイ酸ナトリウム又はケイ酸ナトリウム1/3及び二リン酸四カリウム1/3を含む活性材料45%±2%から成るアルカリ性洗剤0.36%+ポリアルコキシル化テルペン界面活性剤3%。
・直鎖状ジエステル(Rhodiasolv(登録商標)RPDE)とエトキシル化/プロポキシル化テルペン界面活性剤であるRhodoclean(登録商標)MSC(Rhodia社より販売)3重量%との組合せ物、
・前記のアルカリ性洗剤。
Claims (17)
- 前記A基がC4基であることを特徴とする、請求項1に記載の使用。
- 前記A基が
・式−CH(CH3)−CH2−CH2−のAMG基、
・式−CH(C2H5)−CH2−のAES基、及び
・それらの混合物
を含む群から選択されることを特徴とする、請求項1又は2に記載の使用。 - 前記R1及びR2基が同一であっても異なっていてもよく、メチル、エチル、n−プロピル、イソプロピル、ベンジル、フェニル、n−ブチル、イソブチル、シクロヘキシル、ヘキシル、イソオクチル及び2−エチルヘキシル基を含む群から選択されることを特徴とする、請求項1〜3のいずれかに記載の使用。
- 前記ジカルボン酸ジエステルが式(I)の異なるジカルボン酸ジエステルの混合物の形で提供されることを特徴とする、請求項1〜5のいずれかに記載の使用。
- 前記R1及びR2基がメチル基であることを特徴とする、請求項7に記載の使用。
- 前記混合物が
・式(I')のジカルボン酸ジエステル70〜95重量%、
・式(I'')のジカルボン酸ジエステル5〜30重量%、及び
・式(II)のジカルボン酸ジエステル0〜10重量%
を含むことを特徴とする、請求項7又は8に記載の使用。 - 前記の式(I)のジカルボン酸ジエステルが液状配合物中で少なくとも1種の界面活性剤と組み合わされることを特徴とする、請求項1〜9のいずれかに記載の使用。
- 前記界面活性剤がポリアルコキシル化テルペンノニオン性界面活性剤であることを特徴とする、請求項10に記載の使用。
- 前記のポリアルコキシル化テルペンノニオン性界面活性剤が次式(III):
Zはビシクロ[a.b.c]ヘプテニル又はビシクロ[a.b.c.]ヘプチル基を表わし、ここで、
a+b+cは5であり、
aは2、3又は4であり、
bは2又は1であり、
cは0又は1であり、
この基は、随意に1個以上のC1〜C6アルキル基で置換されていてもよく、下記のもの:
Xは−CH2−C(R3)(R4)−O−又は−O−CH(R'3)−CH(R'4)−O−を表わし、ここで、R3、R4、R'3及びR'4は同一であっても異なっていてもよく、水素又は飽和若しくは不飽和の直鎖状、分岐鎖状若しくは環状C1〜C22炭化水素基を表わし、
R5及びR6は同一であっても異なっていてもよく、水素又は飽和若しくは不飽和の直鎖状、分岐鎖状若しくは環状C1〜C22炭化水素基を表わし、但し、R5及びR6の少なくとも1つは水素以外であるものとし、
R7は水素又は飽和若しくは不飽和の直鎖状、分岐鎖状若しくは環状の芳香族若しくは非芳香族C1〜C22炭化水素基を表わし、
n、p及びqは0以上の整数又は非整数であり、
n+p+qは1超である}
に相当することを特徴とする、請求項11に記載の使用。 - nが2〜10の範囲の整数又は非整数であり、
pが3〜20の範囲の整数又は非整数であり、
qが0〜30の範囲の整数又は非整数である
ことを特徴とする、請求項12に記載の使用。 - 前記のテキスタイルの処理が該テキスタイル上の汚れを取り除くための洗浄を含むことを特徴とする、請求項1〜13のいずれかに記載の使用。
- 前記汚れが水性若しくは溶剤性1成分型若しくは2成分型塗料、樹脂、植物性若しくは鉱物性潤滑油、タール若しくは石油から誘導された製品、泥、脂肪質物質又は食料品残留物の汚れであることを特徴とする、請求項14に記載の使用。
- 請求項1〜9のいずれかに記載の式(I)に相当する少なくとも1種のジカルボン酸ジエステル及び少なくとも1種の界面活性剤を含むこと、並びに前記界面活性剤がポリアルコキシル化テルペンノニオン性界面活性剤であることを特徴とする、テキスタイルの処理に用いるための液状配合物。
- 前記ノニオン性界面活性剤が請求項12に記載の式(III)に相当するポリアルコキシル化テルペンであることを特徴とする、請求項16に記載の配合物。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0756630A FR2918993B1 (fr) | 2007-07-20 | 2007-07-20 | Utilisation de diesters d'acide carboxylique pour le traitement de textiles et formulation. |
FR0756630 | 2007-07-20 | ||
PCT/EP2008/059328 WO2009013207A1 (fr) | 2007-07-20 | 2008-07-16 | Utilisation de diesters d'acide carboxylique pour le traitement de textiles et formulation |
Publications (2)
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JP2010533803A JP2010533803A (ja) | 2010-10-28 |
JP5232860B2 true JP5232860B2 (ja) | 2013-07-10 |
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JP2010517364A Expired - Fee Related JP5232860B2 (ja) | 2007-07-20 | 2008-07-16 | テキスタイルを処理するためのカルボン酸ジエステルの使用及び配合物 |
Country Status (7)
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US (1) | US7863232B2 (ja) |
EP (1) | EP2190959A1 (ja) |
JP (1) | JP5232860B2 (ja) |
CN (1) | CN101765654B (ja) |
BR (1) | BRPI0812677A2 (ja) |
FR (1) | FR2918993B1 (ja) |
WO (1) | WO2009013207A1 (ja) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
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FR2918994B1 (fr) * | 2007-07-20 | 2012-10-19 | Rhodia Operations | Formulations de diesters d'acide carboxylique et leur utilisation pour le traitement de materiaux. |
FR2929954B1 (fr) * | 2008-04-09 | 2010-04-30 | Rhodia Operations | Composition aqueuse de traitement inhibitrice de la corrosion et de l'attaque acide sur des surfaces metalliques |
EP2491102A2 (en) * | 2009-10-19 | 2012-08-29 | Rhodia Operations | Auto-emulsifying cleaning systems and methods for use |
KR101673589B1 (ko) * | 2009-10-30 | 2016-11-07 | 동우 화인켐 주식회사 | 평판표시장치의 유리기판용 세정제 조성물 |
WO2011094942A1 (en) * | 2010-02-04 | 2011-08-11 | Rhodia (China) Co., Ltd. | Cleaning composition for wool scouring and felting |
CN103038327A (zh) * | 2010-06-02 | 2013-04-10 | 罗地亚管理公司 | 生态友好型微乳液在清洁油应用中的用途 |
US20180147694A1 (en) * | 2016-11-26 | 2018-05-31 | Packaging Service Co., Inc. | Abrasive paint remover compositions and methods for making and using same |
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JPS56145998A (en) * | 1980-04-15 | 1981-11-13 | Ube Industries | Detergent |
US4304901A (en) * | 1980-04-28 | 1981-12-08 | Eastman Kodak Company | Water dissipatable polyesters |
FR2721921B1 (fr) * | 1994-07-01 | 1996-10-31 | Rhone Poulenc Chimie | Derives d'origine terpenique, composition tensioactive et/ou parfumante en contenant et formulation detergente a base de cette composition |
DE59610828D1 (de) * | 1995-05-18 | 2004-01-08 | Textil Color Ag Sevelen | Zusammensetzung zum Waschen und Reinigen von Textilmaterialien |
FR2794476B1 (fr) * | 1999-06-07 | 2001-11-16 | Rhodia Chimie Sa | Utilisation de derives terpeniques polyalcoxyles dans le traitement de fibres textiles |
MY128504A (en) * | 2001-09-25 | 2007-02-28 | Pennzoil Quaker State Co | Environmentally friendly lubricants |
US6699829B2 (en) * | 2002-06-07 | 2004-03-02 | Kyzen Corporation | Cleaning compositions containing dichloroethylene and six carbon alkoxy substituted perfluoro compounds |
US7351778B2 (en) * | 2004-04-30 | 2008-04-01 | China Petroleum & Chemical Corporation | Catalyst component for olefin polymerization and catalyst comprising the same |
DE102005056230A1 (de) * | 2005-11-25 | 2007-05-31 | Henkel Kgaa | Verfahren zur Verbesserung der mechanischen Eigenschaften textiler Fasern oder Flächengebilde |
FR2898356B1 (fr) * | 2006-03-07 | 2008-12-05 | Rhodia Recherches & Tech | Diesters d'acides carboxylique ramifies |
US20080200544A1 (en) * | 2007-02-09 | 2008-08-21 | Kokyu Alcohol Kogyo Co., Ltd. | Oil agent and lubricant agent, moisturizer and external preparation composition containing the same |
-
2007
- 2007-07-20 FR FR0756630A patent/FR2918993B1/fr not_active Expired - Fee Related
-
2008
- 2008-07-16 CN CN2008801010446A patent/CN101765654B/zh not_active Expired - Fee Related
- 2008-07-16 WO PCT/EP2008/059328 patent/WO2009013207A1/fr active Application Filing
- 2008-07-16 US US12/669,801 patent/US7863232B2/en not_active Expired - Fee Related
- 2008-07-16 BR BRPI0812677-1A2A patent/BRPI0812677A2/pt not_active IP Right Cessation
- 2008-07-16 EP EP08775148A patent/EP2190959A1/fr not_active Withdrawn
- 2008-07-16 JP JP2010517364A patent/JP5232860B2/ja not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
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FR2918993B1 (fr) | 2012-12-14 |
CN101765654A (zh) | 2010-06-30 |
US20100240567A1 (en) | 2010-09-23 |
WO2009013207A1 (fr) | 2009-01-29 |
CN101765654B (zh) | 2012-05-02 |
EP2190959A1 (fr) | 2010-06-02 |
US7863232B2 (en) | 2011-01-04 |
BRPI0812677A2 (pt) | 2014-12-23 |
JP2010533803A (ja) | 2010-10-28 |
FR2918993A1 (fr) | 2009-01-23 |
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