JP5218422B2 - 水素化処理触媒用硫化剤ならびに現場および現場外での予備硫化のための該硫化剤の使用 - Google Patents
水素化処理触媒用硫化剤ならびに現場および現場外での予備硫化のための該硫化剤の使用 Download PDFInfo
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- JP5218422B2 JP5218422B2 JP2009542161A JP2009542161A JP5218422B2 JP 5218422 B2 JP5218422 B2 JP 5218422B2 JP 2009542161 A JP2009542161 A JP 2009542161A JP 2009542161 A JP2009542161 A JP 2009542161A JP 5218422 B2 JP5218422 B2 JP 5218422B2
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- catalyst
- sulfiding
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- sulfur
- sulfiding agent
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- 239000003054 catalyst Substances 0.000 title claims description 64
- 239000003795 chemical substances by application Substances 0.000 title claims description 60
- CETBSQOFQKLHHZ-UHFFFAOYSA-N Diethyl disulfide Chemical compound CCSSCC CETBSQOFQKLHHZ-UHFFFAOYSA-N 0.000 claims description 36
- 238000005486 sulfidation Methods 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 19
- 230000000873 masking effect Effects 0.000 claims description 10
- 239000012535 impurity Substances 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 238000011065 in-situ storage Methods 0.000 claims description 3
- 229910052752 metalloid Inorganic materials 0.000 claims description 3
- 150000002738 metalloids Chemical class 0.000 claims description 3
- WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 description 53
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 23
- 229910052717 sulfur Inorganic materials 0.000 description 23
- 239000011593 sulfur Substances 0.000 description 23
- ALVPFGSHPUPROW-UHFFFAOYSA-N dipropyl disulfide Chemical compound CCCSSCCC ALVPFGSHPUPROW-UHFFFAOYSA-N 0.000 description 18
- 229910052739 hydrogen Inorganic materials 0.000 description 17
- 239000001257 hydrogen Substances 0.000 description 16
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 15
- 239000003921 oil Substances 0.000 description 14
- 239000007789 gas Substances 0.000 description 13
- 239000007787 solid Substances 0.000 description 13
- 239000005077 polysulfide Substances 0.000 description 12
- 229920001021 polysulfide Polymers 0.000 description 12
- 150000008117 polysulfides Polymers 0.000 description 12
- 239000000203 mixture Substances 0.000 description 10
- 239000004215 Carbon black (E152) Substances 0.000 description 9
- CUDSBWGCGSUXDB-UHFFFAOYSA-N Dibutyl disulfide Chemical compound CCCCSSCCCC CUDSBWGCGSUXDB-UHFFFAOYSA-N 0.000 description 9
- 229930195733 hydrocarbon Natural products 0.000 description 9
- 150000002430 hydrocarbons Chemical class 0.000 description 9
- 230000008569 process Effects 0.000 description 8
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 150000003464 sulfur compounds Chemical class 0.000 description 7
- QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 description 6
- -1 carbon disulfide, thiophenes Chemical class 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- 150000008116 organic polysulfides Chemical class 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 238000006477 desulfuration reaction Methods 0.000 description 4
- 230000023556 desulfurization Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- CBOQJANXLMLOSS-UHFFFAOYSA-N ethyl vanillin Chemical group CCOC1=CC(C=O)=CC=C1O CBOQJANXLMLOSS-UHFFFAOYSA-N 0.000 description 4
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 4
- DDTIGTPWGISMKL-UHFFFAOYSA-N molybdenum nickel Chemical compound [Ni].[Mo] DDTIGTPWGISMKL-UHFFFAOYSA-N 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 230000004913 activation Effects 0.000 description 3
- 238000001994 activation Methods 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000005987 sulfurization reaction Methods 0.000 description 3
- 150000003568 thioethers Chemical class 0.000 description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 150000002019 disulfides Chemical class 0.000 description 2
- PXJJSXABGXMUSU-UHFFFAOYSA-N disulfur dichloride Chemical compound ClSSCl PXJJSXABGXMUSU-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 2
- 229940073505 ethyl vanillin Drugs 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- MLFHJEHSLIIPHL-UHFFFAOYSA-N isoamyl acetate Chemical compound CC(C)CCOC(C)=O MLFHJEHSLIIPHL-UHFFFAOYSA-N 0.000 description 2
- 239000003915 liquefied petroleum gas Substances 0.000 description 2
- 229910052976 metal sulfide Inorganic materials 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000011020 pilot scale process Methods 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 description 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- BKCNDTDWDGQHSD-UHFFFAOYSA-N 2-(tert-butyldisulfanyl)-2-methylpropane Chemical compound CC(C)(C)SSC(C)(C)C BKCNDTDWDGQHSD-UHFFFAOYSA-N 0.000 description 1
- ONJROLGQWMBXAP-UHFFFAOYSA-N 2-methyl-1-(2-methylpropyldisulfanyl)propane Chemical compound CC(C)CSSCC(C)C ONJROLGQWMBXAP-UHFFFAOYSA-N 0.000 description 1
- MBZKQDXXFMITAC-UHFFFAOYSA-N 2-methylbutyl butanoate Chemical compound CCCC(=O)OCC(C)CC MBZKQDXXFMITAC-UHFFFAOYSA-N 0.000 description 1
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 description 1
- LZAZXBXPKRULLB-UHFFFAOYSA-N Diisopropyl disulfide Chemical compound CC(C)SSC(C)C LZAZXBXPKRULLB-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 230000007059 acute toxicity Effects 0.000 description 1
- 231100000403 acute toxicity Toxicity 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229940007550 benzyl acetate Drugs 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- QGJOPFRUJISHPQ-NJFSPNSNSA-N carbon disulfide-14c Chemical compound S=[14C]=S QGJOPFRUJISHPQ-NJFSPNSNSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229940117955 isoamyl acetate Drugs 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- XLTBPTGNNLIKRW-UHFFFAOYSA-N methyldisulfanylethane Chemical compound CCSSC XLTBPTGNNLIKRW-UHFFFAOYSA-N 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 150000002897 organic nitrogen compounds Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- UJHLGDUCOCXGBW-UHFFFAOYSA-N oxocobalt trioxomolybdenum Chemical compound O=[Co].O=[Mo](=O)=O UJHLGDUCOCXGBW-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- FLKPEMZONWLCSK-UHFFFAOYSA-N phthalic acid di-n-ethyl ester Natural products CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 150000003388 sodium compounds Chemical class 0.000 description 1
- 239000003597 spicing agent Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 229940059867 sulfur containing product ectoparasiticides Drugs 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 150000003577 thiophenes Chemical class 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C321/00—Thiols, sulfides, hydropolysulfides or polysulfides
- C07C321/12—Sulfides, hydropolysulfides, or polysulfides having thio groups bound to acyclic carbon atoms
- C07C321/14—Sulfides, hydropolysulfides, or polysulfides having thio groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/20—Sulfiding
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G51/00—Compounds of cobalt
- C01G51/04—Oxides; Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/04—Oxides; Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
- C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/882—Molybdenum and cobalt
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Description
排気ガス中にH2Sの一定濃度を有するのに十分な時間、250から350℃、好ましくは290から330℃の範囲の温度で第二の硫化を実施する。
約63から68℃の沸点を有するヘキサンタイプのガソリン、
約100から160℃の沸点を有し、通常、芳香族炭化水素10から20%を含む、Fタイプのガソリン、
約150から250℃の沸点を有し、通常、芳香族炭化水素14から22%を含む、ホワイトスピリット型のガソリン、
前述したガソリンと同等の、任意の炭化水素または非炭化水素留分。
− 反応器から排気されるガス中のH2Sおよび他のメルカプタン類の含有量を連続的に監視する。
− 230℃での温度静止期を4時間維持する(3000ppmを超えるH2Sの急増の達成を可能にする。)。
− 25℃/時の速度で230℃から350℃に温度を上昇させる。
− 350℃での静止期を12時間。
− 硫化原料を停止し、試験原料に切り替える。
Claims (10)
- 触媒が、少なくとも1種の金属または半金属の酸化物をベースとする担体および少なくとも1種の活性金属を含む水素化処理触媒用硫化剤であって、硫化剤が、基本的にジエチルジスルフィド(DEDS)からなることを特徴とする、水素化処理触媒の硫化剤。
- 不純物を20000ppmまで含むことを特徴とする、請求項1に記載の硫化剤。
- 不純物を10000ppmまで含むことを特徴とする、請求項2に記載の硫化剤。
- 不純物を5000ppmまで含むことを特徴とする、請求項3に記載の硫化剤。
- 少なくとも1種の臭気マスキング剤および/または1種の臭気主成分を含むことを特徴とする、請求項1から4のいずれか一項に記載の硫化剤。
- 少なくとも1種の臭気マスキング剤および/または1種の臭気主成分を、硫化剤の全重量の1重量%まで含むことを特徴とする、請求項1から5のいずれか一項に記載の硫化剤。
- 少なくとも1種の臭気マスキング剤および/または1種の臭気主成分を、硫化剤の全重量の0.1から0.5重量%含むことを特徴とする、請求項6に記載の硫化剤。
- 少なくとも1種の金属または半金属の酸化物をベースとする担体および少なくとも1種の活性金属を含む触媒の予備硫化工程であって、硫化剤が、請求項1から7のいずれか一項において定義されるものであることを特徴とする触媒の予備硫化工程。
- 予備硫化が現場外手法で実施される、請求項8に記載の触媒の予備硫化工程。
- 予備硫化が現場手法で実施される、請求項8に記載の触媒の予備硫化工程。
Applications Claiming Priority (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0655884 | 2006-12-22 | ||
FR0655884A FR2910349A1 (fr) | 2006-12-22 | 2006-12-22 | Agent de sulfuration de catalyseur d'hydrotraitement et son utilisation pour la sulfuration in-situ et ex-situ |
US93915207P | 2007-05-21 | 2007-05-21 | |
US60/939,152 | 2007-05-21 | ||
FR0757330A FR2910348B1 (fr) | 2006-12-22 | 2007-09-03 | Agent de sulfuration de catalyseur d'hydrotraitement et son utilisation pour la presulfuration in-situ et ex-situ |
FR0757330 | 2007-09-03 | ||
PCT/FR2007/052579 WO2008087330A2 (fr) | 2006-12-22 | 2007-12-20 | Agent de sulfuration de catalyseur d'hydrotraitement et son utilisation pour la presulfuration in-situ et ex-situ |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2010513011A JP2010513011A (ja) | 2010-04-30 |
JP5218422B2 true JP5218422B2 (ja) | 2013-06-26 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP2009542161A Active JP5218422B2 (ja) | 2006-12-22 | 2007-12-20 | 水素化処理触媒用硫化剤ならびに現場および現場外での予備硫化のための該硫化剤の使用 |
Country Status (9)
Country | Link |
---|---|
US (2) | US20080312074A1 (ja) |
EP (1) | EP2094386B1 (ja) |
JP (1) | JP5218422B2 (ja) |
CA (1) | CA2672615C (ja) |
ES (1) | ES2715047T3 (ja) |
FR (1) | FR2910348B1 (ja) |
PL (1) | PL2094386T3 (ja) |
TR (1) | TR201903476T4 (ja) |
WO (1) | WO2008087330A2 (ja) |
Families Citing this family (1)
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WO2017079629A1 (en) | 2015-11-06 | 2017-05-11 | Uop Llc | Use of c4 absorber for stripping aldehydes |
Family Cites Families (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1049396A (fr) | 1953-06-24 | 1953-12-29 | Cfcmug | Compteur de gaz de type sec à coquilles |
US2993938A (en) * | 1958-06-18 | 1961-07-25 | Universal Oil Prod Co | Hydroisomerization process |
NL256096A (ja) * | 1959-09-21 | |||
US3140994A (en) * | 1961-07-12 | 1964-07-14 | Socony Mobil Oil Co Inc | Method of reducing nitrogen to not more than 1 p. p. m. in reformer feed |
US3530200A (en) * | 1969-01-13 | 1970-09-22 | Shell Oil Co | Ethylene oligomerization |
US3527839A (en) * | 1969-01-13 | 1970-09-08 | Shell Oil Co | Ethylene oligomerization |
GB1309457A (en) | 1970-06-16 | 1973-03-14 | Universal Oil Prod Co | Method of activating hydrocracking catalysts |
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-
2007
- 2007-09-03 FR FR0757330A patent/FR2910348B1/fr active Active
- 2007-12-20 EP EP07871990.3A patent/EP2094386B1/fr active Active
- 2007-12-20 CA CA2672615A patent/CA2672615C/fr active Active
- 2007-12-20 US US11/961,164 patent/US20080312074A1/en not_active Abandoned
- 2007-12-20 TR TR2019/03476T patent/TR201903476T4/tr unknown
- 2007-12-20 WO PCT/FR2007/052579 patent/WO2008087330A2/fr active Application Filing
- 2007-12-20 ES ES07871990T patent/ES2715047T3/es active Active
- 2007-12-20 PL PL07871990T patent/PL2094386T3/pl unknown
- 2007-12-20 JP JP2009542161A patent/JP5218422B2/ja active Active
-
2010
- 2010-08-18 US US12/858,647 patent/US9353054B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
ES2715047T3 (es) | 2019-05-31 |
FR2910348B1 (fr) | 2012-05-18 |
EP2094386B1 (fr) | 2019-01-30 |
CA2672615A1 (fr) | 2008-07-24 |
US20080312074A1 (en) | 2008-12-18 |
PL2094386T3 (pl) | 2019-07-31 |
EP2094386A2 (fr) | 2009-09-02 |
WO2008087330A3 (fr) | 2008-09-12 |
WO2008087330A2 (fr) | 2008-07-24 |
FR2910348A1 (fr) | 2008-06-27 |
JP2010513011A (ja) | 2010-04-30 |
CA2672615C (fr) | 2012-02-28 |
TR201903476T4 (tr) | 2019-04-22 |
US20110005974A1 (en) | 2011-01-13 |
US9353054B2 (en) | 2016-05-31 |
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