JP5203623B2 - 水中油型乳化化粧料 - Google Patents
水中油型乳化化粧料 Download PDFInfo
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- JP5203623B2 JP5203623B2 JP2007094197A JP2007094197A JP5203623B2 JP 5203623 B2 JP5203623 B2 JP 5203623B2 JP 2007094197 A JP2007094197 A JP 2007094197A JP 2007094197 A JP2007094197 A JP 2007094197A JP 5203623 B2 JP5203623 B2 JP 5203623B2
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- Prior art keywords
- oil
- acid
- component
- water
- mpa
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- 239000002537 cosmetic Substances 0.000 title claims description 48
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- -1 water (d) polysaccharide Chemical class 0.000 claims description 14
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- 235000012907 honey Nutrition 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 1
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Description
一方、種々の美容効果や付加価値向上のため、アミノ酸やアルコルビン酸などの酸性物質を含有する化粧料も数多く開発されている(前記特許文献3参照)。
(a)ポリオキシエチレン(20)モノステアリン酸ソルビタン
(b)炭素数16〜22の高級アルコール
(c)水
(d)多糖類系水溶性高分子
(e)酸性物質
を含有し、かつ、成分(a)と成分(b)の含有質量比(a)/(b)が0.05〜10で、25℃におけるpHが3以上4.5以下、粘度が1000mPa・s以上7500mPa・s以下であることを特徴とする水中油型乳化化粧料を提供するものである。
具体的には、α−ヒドロキシ酸(AHA)には、乳酸、グリコール酸、フルーツ酸(例えば、リンゴ酸、クエン酸、酒石酸、AHAを含む天然化合物の抽出物(例えば、リンゴ抽出物、アンズ抽出物等)、蜂蜜抽出物、2−ヒドロキシオクタン酸、グリセリン酸(ジヒドロキシプロピオン酸)、タルトロン酸(ジヒドロキシプロパン二酸)、グルコン酸、マンデル酸、ベンジル酸、アゼライン酸、α−リポ酸、サリチル酸、α−ヒドロキシ酪酸、α−ヒドロキシイソ酪酸、α−ヒドロキシイソカプロン酸、α−ヒドロキシイソバレリアン酸、アトロ乳酸(atrolactic
acid)等が挙げられ得るが、これらに制限はされない。
表1及び表2示す組成および以下に示す製造方法に従って水中油型乳化化粧料を調製した。得られた水中油型乳化化粧料に関して、使用時のみずみずしい感触、pH値、経時安定性、粘度の評価を下記の方法に従って行った。その結果を併せて表1及び表2示す。
A.成分(1)〜(12)を70℃にて、均一に混合分散する。
B.成分(13)〜(19)を70℃にて、均一に混合分散する。
C.AにBを加え乳化し、冷却する。
D.Cに成分(20)〜(23)を加え、水中油型化粧料を得た。
表1、表2の各試料について、専門パネル10名により、使用時の感触については使用時のみずみずしさについて、以下の(イ)絶対評価基準を用いて7段階評価をしてもらった。その後、各資料の評点の平均値を(ロ)4段階判定基準を用いて判定した。
(評点) (評価)
6 : 非常にみずみずしく感じる
5 : みずみずしく感じる
4 : やや良い
3 : 普通
2 : ややのびが重い
1 : 非常にのびが重い
(ロ)4段階判定基準
(評価) (判定)
5.0を超えるもの :◎
3.5を超えて5.0迄のもの :○
1.5を超えて3.5迄もの :△
1.5以下のもの :×
表1の各試料を5℃、40℃にて24時間保管し、B型回転粘度計(芝浦システム株式会社)を用いて、3号ローターで6回転、1分後の粘度値を測定した。以下の(ハ)4段階判定基準を用いて判定した。
(ハ)4段階評価基準(評点) :(評価)
1000以上2500mPa・s以下 :◎
2501以上7500mPa・s以下 :○
7501以上10000mPa・s以下 :△
10001mPa・s以上 :×
表1の各試料を50℃の恒温槽に1ヶ月保管し、調整直後の状態を基準として、外観の変化を以下の4段階判定基準を用いて判定した。
(評価) (判定)
変化無し :◎
外観に軽微な変化があるが問題ない :○
わずかな分離が見られる :△
分離している :×
(成分) (%)
1.ポリオキシエチレン(20)モノステアリン酸ソルビタン 1
2.1,3−ブチレングリコール 7
3.グリセリン 3
4.ε―アミノカプロン酸 8
5.メチルパラベン 0.1
6.精製水 残量
7.パラメトキシ皮酸2−エチルヘキシル 6
8.4−tert−ブチルー4´―メトキシジベンゾイルメタン 1
9.メチルポリシロキサン 1.5
10.ベヘニルアルコール 1.5
11.セトステアリルアルコール 1.9
12.新油型モノステアリン酸グリセリン 0.4
13.水素添加大豆リン脂質 0.2
14.微粒子酸化チタン 10
15.香料 適量
16.キサンタンガム 0.15
17.ヒドロキシエチルセルロース 0.15
18.エタノール 5
A.成分(1)〜(6)を70℃にて、均一に混合する。
B.成分(7)〜(15)を70℃にて、均一に混合する。
C.AにBを加え乳化し、冷却する。
D.C成分に成分(16)〜(18)を加え、日焼け止め料を得た。
(成分) (%)
1.ポリオキシエチレン(20)モノステアリン酸ソルビタン 0.3
2.セトステアリルアルコール 0.3
3.ベヘニルアルコール 0.5
4.新油型モノステアリン酸グリセリン 0.5
5.トリエタノールアミン 0.01
6.スクワラン 3.5
7.メチルパラベン 0・1
8.デカメチルシクロペンタシロキサン 1
9.2−エチルヘキサン酸セチル 2
10.1,3−ブチレングリコール 15
11.アスコルビン酸 0.5
12.精製水 残量
13.水素添加大豆リン脂質 0.2
14.キサンタンガム 0.12
15.クイーンシードエキス 0.12
16.香料 適量
A.成分(1)〜(9)を75℃にて、均一に混合分散する。
B.成分(10)〜(12)を75℃にて、均一に混合分散する。
C.AにBを加え乳化し、冷却する。
D.Cに成分(13)〜(16)を加え、美容液を得る。
(成分) (%)
1.精製水 残量
2.1,3−ブチレングリコール 7.5
3.リンゴ酸 0.02
4.ポリオキシエチレン(20)モノステアリン酸ソルビタン 1.5
5.トリエタノールアミン 0.4
6.ベヘニルアルコール 0.5
7.セトステアリルアルコール 0.5
8.新油性モノステアリン酸グリセリン 0.8
9.水素添加大豆リン脂質 0.3
10.パラメトキシケイ皮酸2−エチルヘキシル 7.5
11.2−エチルヘキサン酸セチル 3
12.顔料級酸化チタン 2.2
13.ベンガラ 適量
14.黄酸化鉄 適量
15.黒酸化鉄 適量
16.1,3−ブチレングリコール 4.5
17.キサンタンガム 0.12
18.ヒドロキシエチルセルロース 0.06
19.香料 適量
A.成分(1)〜(5)を70℃にて、均一に混合分散する。
B.成分(6)〜(11)を70℃にて、均一に混合分散する。
C.AにBを加え乳化し、冷却する。
D.Cに成分(12)〜(19)を加え、リキッドファンデーションを得る。
(成分) (%)
1.ポリオキシエチレン(20)モノステアリン酸ソルビタン 1.5
2.1,3−ブチレングリコール 18
3.グリセリン 5
4.フィチンサン酸 0.05
5.メチルパラベン 0.1
6.精製水 残量
7.水酸化ナトリウム 0.001
8.セトステアリルアルコール 0.5
9.ベヘニルアルコール 0.5
10.新油性モノステアリン酸グリセリン 0.8
11.水素添加大豆リン脂質 0.3
12.流動パラフィン 20
13.キサンタンガム 0.15
14.ヒドロキシエチルセルロース 0.15
A.成分(1)〜(7)70℃にて、均一に混合分散する。
B.成分(8)〜(11)70℃にて、均一に混合分散する。
C.AにBを加え乳化し、冷却する。
D.Cに成分(12)〜(14)を加え、クレンジングミルクを得た。
Claims (3)
- 次の成分(a)〜(e);
(a)ポリオキシエチレン(20)モノステアリン酸ソルビタン
(b)炭素数16〜22の高級アルコール
(c)水
(d)多糖類系水溶性高分子
(e)酸性物質
を含有し、かつ、成分(a)と成分(b)の含有質量比(a)/(b)が0.05〜10であり、25℃におけるpHが3以上4.5以下、粘度が1000mPa・s以上7500mPa・s以下であることを特徴とし、
前記成分(a)の含有量が、0.05〜3質量%、
前記成分(d)の含有量が、0.05〜2質量%、
前記成分(e)の含有量が、0.001〜20質量%である、水中油型乳化化粧料。 - 前記成分(d)がキサンタンガムであることを特徴とする請求項1記載の水中油型乳化化粧料。
- 油剤を含有し、その含有量が、5〜20質量%であることを特徴とする請求項1または2記載の水中油型乳化化粧料。
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