JP5192944B2 - セリア及びステンレス鋼に基づく電極 - Google Patents
セリア及びステンレス鋼に基づく電極 Download PDFInfo
- Publication number
- JP5192944B2 JP5192944B2 JP2008219434A JP2008219434A JP5192944B2 JP 5192944 B2 JP5192944 B2 JP 5192944B2 JP 2008219434 A JP2008219434 A JP 2008219434A JP 2008219434 A JP2008219434 A JP 2008219434A JP 5192944 B2 JP5192944 B2 JP 5192944B2
- Authority
- JP
- Japan
- Prior art keywords
- conducting phase
- anode
- ceria
- precursor solution
- surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 title claims abstract description 41
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 239000010935 stainless steel Substances 0.000 title description 18
- 229910001220 stainless steel Inorganic materials 0.000 title description 18
- 239000004094 surface-active agent Substances 0.000 claims abstract description 31
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 30
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 25
- 239000000956 alloy Substances 0.000 claims abstract description 25
- 238000001354 calcination Methods 0.000 claims abstract description 21
- 239000002002 slurry Substances 0.000 claims abstract description 19
- 239000000203 mixture Substances 0.000 claims abstract description 18
- 239000011195 cermet Substances 0.000 claims abstract description 15
- 238000000034 method Methods 0.000 claims abstract description 15
- 239000002243 precursor Substances 0.000 claims abstract description 15
- 239000002904 solvent Substances 0.000 claims abstract description 15
- 229910052727 yttrium Inorganic materials 0.000 claims abstract description 13
- 239000000843 powder Substances 0.000 claims abstract description 11
- 239000006185 dispersion Substances 0.000 claims abstract description 9
- 239000011230 binding agent Substances 0.000 claims abstract description 8
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 7
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 7
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 5
- 229910052746 lanthanum Inorganic materials 0.000 claims abstract description 5
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 5
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 5
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 5
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 67
- 229910052751 metal Inorganic materials 0.000 claims description 60
- 239000002184 metal Substances 0.000 claims description 60
- 239000003792 electrolyte Substances 0.000 claims description 42
- 238000005470 impregnation Methods 0.000 claims description 37
- 239000001301 oxygen Substances 0.000 claims description 29
- 229910052760 oxygen Inorganic materials 0.000 claims description 29
- 239000000446 fuel Substances 0.000 claims description 25
- -1 oxygen ion Chemical class 0.000 claims description 21
- 239000007787 solid Substances 0.000 claims description 20
- 239000012693 ceria precursor Substances 0.000 claims description 15
- 239000002019 doping agent Substances 0.000 claims description 11
- 229910052688 Gadolinium Inorganic materials 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- VEALVRVVWBQVSL-UHFFFAOYSA-N strontium titanate Chemical compound [Sr+2].[O-][Ti]([O-])=O VEALVRVVWBQVSL-UHFFFAOYSA-N 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- 238000005245 sintering Methods 0.000 claims description 8
- 239000010955 niobium Substances 0.000 claims description 6
- 229910052772 Samarium Inorganic materials 0.000 claims description 5
- 238000005868 electrolysis reaction Methods 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 239000012528 membrane Substances 0.000 claims description 5
- 238000000926 separation method Methods 0.000 claims description 5
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 239000002736 nonionic surfactant Substances 0.000 claims description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 2
- 239000003945 anionic surfactant Substances 0.000 claims description 2
- 239000003093 cationic surfactant Substances 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 claims description 2
- 239000003546 flue gas Substances 0.000 claims description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 239000000243 solution Substances 0.000 description 56
- 239000002245 particle Substances 0.000 description 31
- 229910002490 Ce0.9Gd0.1O2–δ Inorganic materials 0.000 description 26
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 description 16
- 238000012360 testing method Methods 0.000 description 16
- 239000002131 composite material Substances 0.000 description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- 239000002105 nanoparticle Substances 0.000 description 12
- 230000015572 biosynthetic process Effects 0.000 description 10
- 239000000919 ceramic Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- 229910000604 Ferrochrome Inorganic materials 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 9
- 229920002415 Pluronic P-123 Polymers 0.000 description 8
- 239000012298 atmosphere Substances 0.000 description 8
- 238000000157 electrochemical-induced impedance spectroscopy Methods 0.000 description 8
- 230000010287 polarization Effects 0.000 description 8
- 239000011148 porous material Substances 0.000 description 8
- 229910002119 nickel–yttria stabilized zirconia Inorganic materials 0.000 description 7
- 229910002651 NO3 Inorganic materials 0.000 description 6
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 6
- MWFSXYMZCVAQCC-UHFFFAOYSA-N gadolinium(iii) nitrate Chemical compound [Gd+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O MWFSXYMZCVAQCC-UHFFFAOYSA-N 0.000 description 6
- 230000008595 infiltration Effects 0.000 description 6
- 238000001764 infiltration Methods 0.000 description 6
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 6
- 238000010345 tape casting Methods 0.000 description 6
- 229910001928 zirconium oxide Inorganic materials 0.000 description 6
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 230000015556 catabolic process Effects 0.000 description 4
- 239000011651 chromium Substances 0.000 description 4
- 238000011065 in-situ storage Methods 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 239000013504 Triton X-100 Substances 0.000 description 3
- 229920004890 Triton X-100 Polymers 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 229910000420 cerium oxide Inorganic materials 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000013507 mapping Methods 0.000 description 3
- 230000003204 osmotic effect Effects 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- 229910002367 SrTiO Inorganic materials 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- 229920004897 Triton X-45 Polymers 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000001453 impedance spectrum Methods 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 2
- 150000002823 nitrates Chemical class 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 229910000599 Cr alloy Inorganic materials 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910005191 Ga 2 O 3 Inorganic materials 0.000 description 1
- 229910017563 LaCrO Inorganic materials 0.000 description 1
- MOCSSSMOHPPNTG-UHFFFAOYSA-N [Sc].[Y] Chemical compound [Sc].[Y] MOCSSSMOHPPNTG-UHFFFAOYSA-N 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- DRVWBEJJZZTIGJ-UHFFFAOYSA-N cerium(3+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[Ce+3].[Ce+3] DRVWBEJJZZTIGJ-UHFFFAOYSA-N 0.000 description 1
- 239000013626 chemical specie Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000000788 chromium alloy Substances 0.000 description 1
- UPHIPHFJVNKLMR-UHFFFAOYSA-N chromium iron Chemical compound [Cr].[Fe] UPHIPHFJVNKLMR-UHFFFAOYSA-N 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 229910001938 gadolinium oxide Inorganic materials 0.000 description 1
- 229940075613 gadolinium oxide Drugs 0.000 description 1
- CMIHHWBVHJVIGI-UHFFFAOYSA-N gadolinium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[Gd+3].[Gd+3] CMIHHWBVHJVIGI-UHFFFAOYSA-N 0.000 description 1
- 229910021526 gadolinium-doped ceria Inorganic materials 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000013101 initial test Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000002905 metal composite material Substances 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 239000011533 mixed conductor Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9041—Metals or alloys
- H01M4/905—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC
- H01M4/9066—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC of metal-ceramic composites or mixtures, e.g. cermets
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
- H01M4/0416—Methods of deposition of the material involving impregnation with a solution, dispersion, paste or dry powder
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
- H01M4/9025—Oxides specially used in fuel cell operating at high temperature, e.g. SOFC
- H01M4/9033—Complex oxides, optionally doped, of the type M1MeO3, M1 being an alkaline earth metal or a rare earth, Me being a metal, e.g. perovskites
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Composite Materials (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Sustainable Energy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Inert Electrodes (AREA)
- Fuel Cell (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Catalysts (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Electrolytic Production Of Metals (AREA)
- Powder Metallurgy (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DKPA200701245 | 2007-08-31 | ||
| DKPA200701245 | 2007-08-31 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2009110934A JP2009110934A (ja) | 2009-05-21 |
| JP2009110934A5 JP2009110934A5 (https=) | 2012-09-13 |
| JP5192944B2 true JP5192944B2 (ja) | 2013-05-08 |
Family
ID=39816598
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008219434A Expired - Fee Related JP5192944B2 (ja) | 2007-08-31 | 2008-08-28 | セリア及びステンレス鋼に基づく電極 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8500842B2 (https=) |
| EP (1) | EP2031675B1 (https=) |
| JP (1) | JP5192944B2 (https=) |
| KR (1) | KR20090023255A (https=) |
| CN (1) | CN101383418B (https=) |
| AT (1) | ATE519241T1 (https=) |
| AU (1) | AU2008207645B2 (https=) |
| CA (1) | CA2639175A1 (https=) |
| DK (1) | DK2031675T3 (https=) |
| ES (1) | ES2367885T3 (https=) |
| RU (1) | RU2480863C2 (https=) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9209473B2 (en) * | 2009-03-16 | 2015-12-08 | Korea Institute Of Science And Technology | Anode-supported solid oxide fuel cell comprising a nanoporous layer having a pore gradient structure, and a production method therefor |
| US9240597B2 (en) * | 2010-10-13 | 2016-01-19 | University Of South Carolina | Ni modified ceramic anodes for direct-methane solid oxide fuel cells |
| PL2638587T3 (pl) | 2010-11-11 | 2015-10-30 | The Technical Univ Of Denmark | Sposób wytwarzania stosu stałotlenkowych ogniw |
| JP6313976B2 (ja) * | 2010-12-03 | 2018-04-18 | フェデラル−モーグル・リミテッド・ライアビリティ・カンパニーＦｅｄｅｒａｌ−Ｍｏｇｕｌ Ｌｌｃ | セリアおよび／またはイットリアで含浸された粉末金属部品と製造方法 |
| US20140287341A1 (en) * | 2011-10-24 | 2014-09-25 | Technical University Of Denmark | Modified anode/electrolyte structure for a solid oxide electrochemical cell and a method for making said structure |
| AU2012327278A1 (en) * | 2011-10-24 | 2014-05-15 | Technical University Of Denmark | High performance fuel electrode for a solid oxide electrochemical cell |
| EP2823079B1 (en) | 2012-02-23 | 2023-02-22 | Treadstone Technologies, Inc. | Corrosion resistant and electrically conductive surface of metal |
| EP2836625B1 (en) * | 2012-04-13 | 2017-12-06 | Danmarks Tekniske Universitet | High performance reversible electrochemical cell for h2o electrolysis or conversion of co2 and h2o to fuel |
| RU2510385C1 (ru) * | 2012-10-01 | 2014-03-27 | Федеральное государственное бюджетное учреждение науки Институт высокотемпературной электрохимии Уральского отделения Российской Академии наук | Твердооксидный композитный материал для мембран электрохимических устройств |
| TWI482660B (zh) * | 2012-12-11 | 2015-05-01 | Ind Tech Res Inst | 電極及其製備方法 |
| US9525179B2 (en) * | 2013-03-13 | 2016-12-20 | University Of Maryland, College Park | Ceramic anode materials for solid oxide fuel cells |
| CN103280339A (zh) * | 2013-04-12 | 2013-09-04 | 上海大学 | 一种用于超级电容器的氧化铈电极的制备方法 |
| US9181148B2 (en) * | 2013-05-22 | 2015-11-10 | Saudi Arabian Oil Company | Ni/CGO and Ni-Ru/CGO based pre-reforming catalysts formulation for methane rich gas production from diesel processing for fuel cell applications |
| EP2808932A1 (en) | 2013-05-31 | 2014-12-03 | Topsøe Fuel Cell A/S | Metal-supported solid oxide cell |
| GB2517927B (en) * | 2013-09-04 | 2018-05-16 | Ceres Ip Co Ltd | Process for forming a metal supported solid oxide fuel cell |
| CN104710845A (zh) * | 2013-12-13 | 2015-06-17 | 通用电气公司 | 组合物及其相应的装置、方法 |
| GB2524638B (en) * | 2015-02-06 | 2016-04-06 | Ceres Ip Co Ltd | Electrolyte forming process |
| US20180200695A1 (en) * | 2017-01-18 | 2018-07-19 | Saudi Arabian Oil Company | Structured catalysts for pre-reforming hydrocarbons |
| US10953388B1 (en) | 2019-12-27 | 2021-03-23 | Saudi Arabian Oil Company | Ni—Ru—CgO based pre-reforming catalyst for liquid hydrocarbons |
| US12322811B2 (en) * | 2021-07-29 | 2025-06-03 | Nissan North America, Inc. | Metal-supported anode for solid oxide fuel cell |
| CN114583226B (zh) * | 2022-03-31 | 2024-07-12 | 电堆科技(合肥)有限公司 | 一种金属支撑质子导体固体氧化物电池及其制备方法 |
| WO2023193062A1 (en) * | 2022-04-06 | 2023-10-12 | Commonwealth Scientific And Industrial Research Organisation | Electrode compositions |
| CN121360818B (zh) * | 2025-12-22 | 2026-03-24 | 崇义章源钨业股份有限公司 | 一种钨铈合金丝及其制备方法 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3377265A (en) * | 1964-11-16 | 1968-04-09 | Mobil Oil Corp | Electrochemical electrode |
| JPH01186561A (ja) * | 1988-01-14 | 1989-07-26 | Hitachi Ltd | 燃料電池 |
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| DK167163B1 (da) | 1991-02-13 | 1993-09-06 | Risoe Forskningscenter | Fastoxidbraendselscelle til oxidation af ch4 |
| US5312582A (en) * | 1993-02-04 | 1994-05-17 | Institute Of Gas Technology | Porous structures from solid solutions of reduced oxides |
| RU2125324C1 (ru) * | 1996-11-11 | 1999-01-20 | Горина Лилия Федоровна | Способ изготовления единичного высокотемпературного топливного элемента и его компонентов: катода, электролита, анода, токопрохода, интерфейсного и электроизолирующего слоев |
| US6682842B1 (en) * | 1999-07-31 | 2004-01-27 | The Regents Of The University Of California | Composite electrode/electrolyte structure |
| US6752979B1 (en) | 2000-11-21 | 2004-06-22 | Very Small Particle Company Pty Ltd | Production of metal oxide particles with nano-sized grains |
| CN1672283A (zh) * | 2002-06-06 | 2005-09-21 | 宾夕法尼亚州大学理事会 | 陶瓷阳极及其制造方法 |
| KR20050084337A (ko) * | 2002-12-16 | 2005-08-26 | 더 트러스티스 오브 더 유니버시티 오브 펜실바니아 | 고성능 세라믹 음극 및 이의 제조 방법 |
| RU2236722C1 (ru) * | 2003-06-10 | 2004-09-20 | Мятиев Ата Атаевич | Электрод-электролитная пара на основе двуокиси церия (варианты), способ ее изготовления (варианты) и органогель |
| US20090220829A1 (en) * | 2003-12-24 | 2009-09-03 | Anna Berta Lopes Correia Tavares | Solid Oxide Fuel Cell |
| US20050221163A1 (en) * | 2004-04-06 | 2005-10-06 | Quanmin Yang | Nickel foam and felt-based anode for solid oxide fuel cells |
| EP2259373A1 (en) * | 2004-06-10 | 2010-12-08 | Technical University of Denmark | Solid oxide fuel cell |
| ES2326601T3 (es) * | 2005-01-12 | 2009-10-15 | Technical University Of Denmark | Procedimiento de control de la contraccion y la porosidad durante la sinterizacion de estructuras multicapa. |
| AU2006210103B2 (en) * | 2005-02-02 | 2010-07-15 | Technical University Of Denmark | A method for producing a reversible solid oxide fuel cell |
| CA2606307A1 (en) | 2005-04-21 | 2006-11-02 | The Regents Of The University Of California | Precursor infiltration and coating method |
| ES2434442T3 (es) * | 2005-08-31 | 2013-12-16 | Technical University Of Denmark | Apilamiento sólido reversible de pilas de combustible de óxido y método para preparar el mismo |
-
2008
- 2008-08-21 EP EP08014830A patent/EP2031675B1/en not_active Not-in-force
- 2008-08-21 AT AT08014830T patent/ATE519241T1/de not_active IP Right Cessation
- 2008-08-21 DK DK08014830.7T patent/DK2031675T3/da active
- 2008-08-21 ES ES08014830T patent/ES2367885T3/es active Active
- 2008-08-27 US US12/199,571 patent/US8500842B2/en not_active Expired - Fee Related
- 2008-08-28 JP JP2008219434A patent/JP5192944B2/ja not_active Expired - Fee Related
- 2008-08-28 CA CA002639175A patent/CA2639175A1/en not_active Abandoned
- 2008-08-29 AU AU2008207645A patent/AU2008207645B2/en not_active Ceased
- 2008-08-29 CN CN200810130977.XA patent/CN101383418B/zh not_active Expired - Fee Related
- 2008-08-29 RU RU2008134998/07A patent/RU2480863C2/ru not_active IP Right Cessation
- 2008-08-29 KR KR1020080084905A patent/KR20090023255A/ko not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| CN101383418A (zh) | 2009-03-11 |
| DK2031675T3 (da) | 2011-11-14 |
| HK1130118A1 (en) | 2009-12-18 |
| RU2480863C2 (ru) | 2013-04-27 |
| KR20090023255A (ko) | 2009-03-04 |
| EP2031675A1 (en) | 2009-03-04 |
| AU2008207645A1 (en) | 2009-03-19 |
| ES2367885T3 (es) | 2011-11-10 |
| US8500842B2 (en) | 2013-08-06 |
| JP2009110934A (ja) | 2009-05-21 |
| RU2008134998A (ru) | 2010-03-10 |
| CA2639175A1 (en) | 2009-02-28 |
| US20090061272A1 (en) | 2009-03-05 |
| CN101383418B (zh) | 2014-06-25 |
| AU2008207645B2 (en) | 2012-04-19 |
| ATE519241T1 (de) | 2011-08-15 |
| EP2031675B1 (en) | 2011-08-03 |
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