JP5168637B2 - 金属磁性微粒子及びその製造方法、圧粉磁芯 - Google Patents
金属磁性微粒子及びその製造方法、圧粉磁芯 Download PDFInfo
- Publication number
- JP5168637B2 JP5168637B2 JP2008103449A JP2008103449A JP5168637B2 JP 5168637 B2 JP5168637 B2 JP 5168637B2 JP 2008103449 A JP2008103449 A JP 2008103449A JP 2008103449 A JP2008103449 A JP 2008103449A JP 5168637 B2 JP5168637 B2 JP 5168637B2
- Authority
- JP
- Japan
- Prior art keywords
- phase
- fine particles
- magnetic fine
- metal magnetic
- heat treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 230000005291 magnetic effect Effects 0.000 title claims description 117
- 239000010419 fine particle Substances 0.000 title claims description 69
- 239000002184 metal Substances 0.000 title claims description 64
- 229910052751 metal Inorganic materials 0.000 title claims description 64
- 238000004519 manufacturing process Methods 0.000 title claims description 12
- 239000000428 dust Substances 0.000 title claims description 5
- 239000000843 powder Substances 0.000 claims description 67
- 238000010438 heat treatment Methods 0.000 claims description 45
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 41
- 229910052799 carbon Inorganic materials 0.000 claims description 38
- 230000005415 magnetization Effects 0.000 claims description 37
- 239000007771 core particle Substances 0.000 claims description 34
- 239000002245 particle Substances 0.000 claims description 30
- 229910000859 α-Fe Inorganic materials 0.000 claims description 30
- 230000005294 ferromagnetic effect Effects 0.000 claims description 26
- 150000001875 compounds Chemical class 0.000 claims description 20
- 238000002156 mixing Methods 0.000 claims description 15
- 238000010828 elution Methods 0.000 claims description 11
- 229910052742 iron Inorganic materials 0.000 claims description 11
- 239000002994 raw material Substances 0.000 claims description 11
- 238000007885 magnetic separation Methods 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 238000004813 Moessbauer spectroscopy Methods 0.000 claims description 7
- 239000012298 atmosphere Substances 0.000 claims description 7
- 239000000872 buffer Substances 0.000 claims description 7
- 230000035699 permeability Effects 0.000 claims description 6
- 230000003196 chaotropic effect Effects 0.000 claims description 5
- 230000001590 oxidative effect Effects 0.000 claims description 5
- 238000004458 analytical method Methods 0.000 claims description 4
- 239000006249 magnetic particle Substances 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- 229910001111 Fine metal Inorganic materials 0.000 claims description 2
- 238000000465 moulding Methods 0.000 claims description 2
- 230000008569 process Effects 0.000 claims description 2
- 239000012266 salt solution Substances 0.000 claims 2
- 239000012071 phase Substances 0.000 description 71
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 69
- 239000006247 magnetic powder Substances 0.000 description 23
- 239000011248 coating agent Substances 0.000 description 16
- 238000000576 coating method Methods 0.000 description 16
- 238000005260 corrosion Methods 0.000 description 15
- 230000007797 corrosion Effects 0.000 description 15
- 229910001566 austenite Inorganic materials 0.000 description 14
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 12
- 239000007864 aqueous solution Substances 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- 229910017082 Fe-Si Inorganic materials 0.000 description 8
- 229910017133 Fe—Si Inorganic materials 0.000 description 8
- 239000011247 coating layer Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 238000006722 reduction reaction Methods 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 239000011324 bead Substances 0.000 description 6
- 229910001567 cementite Inorganic materials 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
- 239000002953 phosphate buffered saline Substances 0.000 description 6
- 238000000746 purification Methods 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 229910000905 alloy phase Inorganic materials 0.000 description 4
- 239000000696 magnetic material Substances 0.000 description 4
- 230000005298 paramagnetic effect Effects 0.000 description 4
- 238000001556 precipitation Methods 0.000 description 4
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000003822 epoxy resin Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229920000647 polyepoxide Polymers 0.000 description 3
- 230000001737 promoting effect Effects 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000007790 solid phase Substances 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 229910020599 Co 3 O 4 Inorganic materials 0.000 description 2
- 229910017112 Fe—C Inorganic materials 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000000635 electron micrograph Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 230000005389 magnetism Effects 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 239000011812 mixed powder Substances 0.000 description 2
- 230000001376 precipitating effect Effects 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- 238000001669 Mossbauer spectrum Methods 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 238000003917 TEM image Methods 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000000427 antigen Substances 0.000 description 1
- 102000036639 antigens Human genes 0.000 description 1
- 108091007433 antigens Proteins 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- STIAPHVBRDNOAJ-UHFFFAOYSA-N carbamimidoylazanium;carbonate Chemical compound NC(N)=N.NC(N)=N.OC(O)=O STIAPHVBRDNOAJ-UHFFFAOYSA-N 0.000 description 1
- 150000001722 carbon compounds Chemical class 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- LOKCTEFSRHRXRJ-UHFFFAOYSA-I dipotassium trisodium dihydrogen phosphate hydrogen phosphate dichloride Chemical compound P(=O)(O)(O)[O-].[K+].P(=O)(O)([O-])[O-].[Na+].[Na+].[Cl-].[K+].[Cl-].[Na+] LOKCTEFSRHRXRJ-UHFFFAOYSA-I 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000005087 graphitization Methods 0.000 description 1
- 229960000789 guanidine hydrochloride Drugs 0.000 description 1
- NDEMNVPZDAFUKN-UHFFFAOYSA-N guanidine;nitric acid Chemical compound NC(N)=N.O[N+]([O-])=O.O[N+]([O-])=O NDEMNVPZDAFUKN-UHFFFAOYSA-N 0.000 description 1
- PJJJBBJSCAKJQF-UHFFFAOYSA-N guanidinium chloride Chemical compound [Cl-].NC(N)=[NH2+] PJJJBBJSCAKJQF-UHFFFAOYSA-N 0.000 description 1
- ZJYYHGLJYGJLLN-UHFFFAOYSA-N guanidinium thiocyanate Chemical compound SC#N.NC(N)=N ZJYYHGLJYGJLLN-UHFFFAOYSA-N 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- KSOKAHYVTMZFBJ-UHFFFAOYSA-N iron;methane Chemical compound C.[Fe].[Fe].[Fe] KSOKAHYVTMZFBJ-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 239000011268 mixed slurry Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 229910021382 natural graphite Inorganic materials 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 102000039446 nucleic acids Human genes 0.000 description 1
- 108020004707 nucleic acids Proteins 0.000 description 1
- 150000007523 nucleic acids Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000010587 phase diagram Methods 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- -1 polyvinyl alcohol Chemical class 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000013076 target substance Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000013519 translation Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Powder Metallurgy (AREA)
- Hard Magnetic Materials (AREA)
- Soft Magnetic Materials (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2008103449A JP5168637B2 (ja) | 2008-04-11 | 2008-04-11 | 金属磁性微粒子及びその製造方法、圧粉磁芯 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2008103449A JP5168637B2 (ja) | 2008-04-11 | 2008-04-11 | 金属磁性微粒子及びその製造方法、圧粉磁芯 |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2009249739A JP2009249739A (ja) | 2009-10-29 |
JP2009249739A5 JP2009249739A5 (enrdf_load_stackoverflow) | 2012-03-22 |
JP5168637B2 true JP5168637B2 (ja) | 2013-03-21 |
Family
ID=41310705
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2008103449A Expired - Fee Related JP5168637B2 (ja) | 2008-04-11 | 2008-04-11 | 金属磁性微粒子及びその製造方法、圧粉磁芯 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP5168637B2 (enrdf_load_stackoverflow) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8657431B2 (en) * | 2011-03-17 | 2014-02-25 | Xerox Corporation | Phase change magnetic ink comprising carbon coated magnetic nanoparticles and process for preparing same |
US8801954B2 (en) * | 2011-03-17 | 2014-08-12 | Xerox Corporation | Curable inks comprising coated magnetic nanoparticles |
WO2013100346A1 (ko) * | 2011-12-29 | 2013-07-04 | 한국화학연구원 | 기공을 갖는 탄소가 코팅된 금속나노입자의 제조방법 및 이에 의해 제조되는 기공을 갖는 탄소가 코팅된 금속나노입자 |
KR101355125B1 (ko) * | 2012-07-03 | 2014-01-29 | 한국화학연구원 | 기공을 갖는 탄소가 코팅된 금속나노입자의 제조방법 및 이에 의해 제조되는 기공을 갖는 탄소가 코팅된 금속나노입자 |
JP5892421B2 (ja) * | 2012-02-16 | 2016-03-23 | 日立金属株式会社 | 金属粉末、その製造方法、及び圧粉磁心 |
JP6864498B2 (ja) * | 2017-02-28 | 2021-04-28 | 山陽特殊製鋼株式会社 | 高透磁率および高耐候性を有する軟磁性扁平粉末およびこれを含有する軟磁性樹脂組成物 |
JP7356270B2 (ja) * | 2019-07-01 | 2023-10-04 | 株式会社豊田中央研究所 | 圧粉磁心 |
CN119178877A (zh) * | 2024-10-12 | 2024-12-24 | 广州国际旅行卫生保健中心(广州海关口岸门诊部) | 一种应用于免疫检测的免疫磁珠及其制备方法 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004259807A (ja) * | 2003-02-25 | 2004-09-16 | Hitachi Metals Ltd | 圧粉磁芯用磁性粉末、および圧粉磁芯 |
JP4304668B2 (ja) * | 2004-02-18 | 2009-07-29 | 日立金属株式会社 | 金属微粒子および金属微粒子の製造方法 |
JP4895151B2 (ja) * | 2004-02-27 | 2012-03-14 | 日立金属株式会社 | 鉄系ナノサイズ粒子およびその製造方法 |
-
2008
- 2008-04-11 JP JP2008103449A patent/JP5168637B2/ja not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JP2009249739A (ja) | 2009-10-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5168637B2 (ja) | 金属磁性微粒子及びその製造方法、圧粉磁芯 | |
JP5710427B2 (ja) | 磁性材料、磁性材料の製造方法および磁性材料を用いたインダクタ素子 | |
EP1568427B1 (en) | Production method of fine composite metal particles | |
JP5058031B2 (ja) | コアシェル型磁性粒子、高周波磁性材料および磁性シート | |
JP5669389B2 (ja) | 高周波用磁性材料とその製造方法 | |
CN108885930B (zh) | 磁性材料及其制造方法 | |
CN110214355B (zh) | 磁性材料及其制造方法 | |
JP4560784B2 (ja) | 金属微粒子およびその製造方法ならびに磁気ビーズ | |
JP5359905B2 (ja) | 金属微粒子およびその製造方法ならびに磁気ビーズ | |
JP6942379B2 (ja) | 磁性材料とその製造法 | |
JP2008308711A (ja) | 磁性超微粒子及びその製造方法 | |
CN110506314B (zh) | 磁性材料及其制造法 | |
JP5556756B2 (ja) | 鉄系ナノサイズ粒子およびその製造方法 | |
JP4895151B2 (ja) | 鉄系ナノサイズ粒子およびその製造方法 | |
CN111816401A (zh) | 扁平状软磁性粉末的制造方法 | |
JP2008081818A (ja) | ニッケル―鉄合金ナノ粒子の前駆体粉末の製造方法およびニッケル―鉄合金ナノ粒子の前駆体粉末、ニッケル―鉄合金ナノ粒子の製造方法およびニッケル―鉄合金ナノ粒子 | |
JP2009249739A5 (enrdf_load_stackoverflow) | ||
JP2012204744A (ja) | 軟磁性金属粉末及びその製造方法、圧粉磁心及びその製造方法 | |
CN1913993A (zh) | 软磁性材料和压粉铁心 | |
JP2004281846A (ja) | 高周波磁性材料およびそれを用いた高周波磁性部品、並びに製造方法 | |
KR20190116267A (ko) | 연자성 편평 분말 | |
JP2011132581A (ja) | 高飽和磁化ニッケル−鉄合金ナノ粒子の製造方法及び高飽和磁化ニッケル−鉄合金ナノ粒子 | |
JP2007046074A5 (enrdf_load_stackoverflow) | ||
JP2007046074A (ja) | 金属微粒子およびその製造方法 | |
JP2009272615A (ja) | 圧粉磁心およびその製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20110322 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20120201 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20120203 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20120904 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20120914 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20121106 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20121130 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20121213 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5168637 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
LAPS | Cancellation because of no payment of annual fees |