JP5139071B2 - ガラスマイクロバブルおよび生製品の製造方法 - Google Patents
ガラスマイクロバブルおよび生製品の製造方法 Download PDFInfo
- Publication number
- JP5139071B2 JP5139071B2 JP2007544338A JP2007544338A JP5139071B2 JP 5139071 B2 JP5139071 B2 JP 5139071B2 JP 2007544338 A JP2007544338 A JP 2007544338A JP 2007544338 A JP2007544338 A JP 2007544338A JP 5139071 B2 JP5139071 B2 JP 5139071B2
- Authority
- JP
- Japan
- Prior art keywords
- glass microbubbles
- feed
- glass
- frit
- fsc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000011521 glass Substances 0.000 title claims description 69
- 238000004519 manufacturing process Methods 0.000 title description 3
- 238000009826 distribution Methods 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 20
- 238000010438 heat treatment Methods 0.000 claims description 11
- 239000002861 polymer material Substances 0.000 claims 1
- 239000002245 particle Substances 0.000 description 32
- 238000000227 grinding Methods 0.000 description 11
- 239000011324 bead Substances 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- 238000012545 processing Methods 0.000 description 9
- 239000011734 sodium Substances 0.000 description 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 239000011593 sulfur Substances 0.000 description 7
- 229910052717 sulfur Inorganic materials 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 229910004298 SiO 2 Inorganic materials 0.000 description 5
- 239000012530 fluid Substances 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 239000004604 Blowing Agent Substances 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 229910044991 metal oxide Inorganic materials 0.000 description 4
- 150000004706 metal oxides Chemical class 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 239000004005 microsphere Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000010298 pulverizing process Methods 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 241000203482 Polyscias Species 0.000 description 2
- 241001625808 Trona Species 0.000 description 2
- 229910021538 borax Inorganic materials 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000002706 hydrostatic effect Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000005368 silicate glass Substances 0.000 description 2
- 239000004328 sodium tetraborate Substances 0.000 description 2
- 235000010339 sodium tetraborate Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000005188 flotation Methods 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000006060 molten glass Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000005549 size reduction Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/10—Forming beads
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C11/00—Multi-cellular glass ; Porous or hollow glass or glass particles
- C03C11/002—Hollow glass particles
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/10—Forming beads
- C03B19/107—Forming hollow beads
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C12/00—Powdered glass; Bead compositions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/50—Glass production, e.g. reusing waste heat during processing or shaping
- Y02P40/57—Improving the yield, e-g- reduction of reject rates
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/004,385 US20060122049A1 (en) | 2004-12-03 | 2004-12-03 | Method of making glass microbubbles and raw product |
| US11/004,385 | 2004-12-03 | ||
| PCT/US2005/032887 WO2006062566A1 (en) | 2004-12-03 | 2005-09-15 | Method of making glass microbubbles and raw product |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2008521750A JP2008521750A (ja) | 2008-06-26 |
| JP2008521750A5 JP2008521750A5 (enExample) | 2008-10-16 |
| JP5139071B2 true JP5139071B2 (ja) | 2013-02-06 |
Family
ID=36575076
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007544338A Expired - Fee Related JP5139071B2 (ja) | 2004-12-03 | 2005-09-15 | ガラスマイクロバブルおよび生製品の製造方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20060122049A1 (enExample) |
| EP (1) | EP1833767B1 (enExample) |
| JP (1) | JP5139071B2 (enExample) |
| KR (1) | KR20070085613A (enExample) |
| CN (1) | CN101068753B (enExample) |
| BR (1) | BRPI0518722A2 (enExample) |
| MX (1) | MX2007006391A (enExample) |
| WO (1) | WO2006062566A1 (enExample) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006118901A1 (en) * | 2005-04-29 | 2006-11-09 | 3M Innovative Properties Company | Glass microbubble-containing syntactic foams, explosives, and method of making |
| US8701441B2 (en) * | 2006-08-21 | 2014-04-22 | 3M Innovative Properties Company | Method of making inorganic, metal oxide spheres using microstructured molds |
| US8522829B2 (en) * | 2006-11-29 | 2013-09-03 | 3M Innovative Properties Company | Microphere-containing insulation |
| US20080166558A1 (en) * | 2006-12-22 | 2008-07-10 | 3M Innovative Properties Company | Compositions of particles |
| US20080152913A1 (en) * | 2006-12-22 | 2008-06-26 | 3M Innovative Properties Company | Method of making compositions including particles |
| US20080153963A1 (en) * | 2006-12-22 | 2008-06-26 | 3M Innovative Properties Company | Method for making a dispersion |
| WO2008090235A2 (en) * | 2007-02-28 | 2008-07-31 | Solvay Advanced Polymers, L.L.C. | Thermoplastic compositions containing microspheres |
| US7900474B2 (en) * | 2008-08-14 | 2011-03-08 | Beck Warren R | Hollow glass microspheres comprising selenium oxide and method of making thereof |
| US20100330309A1 (en) * | 2009-06-30 | 2010-12-30 | Guardian Industries Corp. | Frit or solder glass compound including beads, and assemblies incorporating the same |
| US8261577B2 (en) | 2009-12-21 | 2012-09-11 | 3M Innovative Properties Company | Method for making hollow microspheres |
| EP2598600A1 (en) | 2010-07-29 | 2013-06-05 | 3M Innovative Properties Company | Elastomer-modified crosslinked epoxy vinyl ester particles and methods for making and using the same |
| DK2614039T3 (en) * | 2010-09-08 | 2019-04-08 | 3M Innovative Properties Co | GLASS BUBLES, COMPOSITION MATERIALS THEREOF AND PROCEDURE FOR THE PRODUCTION OF GLASS Bubbles |
| EP2655273A2 (en) * | 2010-12-20 | 2013-10-30 | 3M Innovative Properties Company | Hollow microspheres and method of making hollow microspheres |
| US11598031B2 (en) | 2011-07-07 | 2023-03-07 | 3M Innovative Properties Company | Article including multi-component fibers and hollow ceramic microspheres and methods of making and using the same |
| PT106237B (pt) * | 2012-03-30 | 2015-03-19 | Hovione Farmaci Ncia S A | Produção de partículas substancialmente monodispersas utilizando moagem e separação por membranas |
| AU2013272132B2 (en) | 2012-06-06 | 2015-11-05 | 3M Innovative Properties Company | Low density glass particles with low boron content |
| CN104662077B (zh) | 2012-06-25 | 2017-03-08 | 3M创新有限公司 | 母料组合物、使用方法，以及橡胶组合物 |
| BR112015000165A2 (pt) | 2012-07-03 | 2017-06-27 | 3M Innovative Properties Co | revestimento de tubos à base de siloxano |
| CN102910828B (zh) * | 2012-11-21 | 2015-07-15 | 贵州威顿晶磷电子材料股份有限公司 | 用于硅太阳能电池正面银浆无铅低熔点玻璃粉及制备方法 |
| KR20150099780A (ko) | 2012-12-20 | 2015-09-01 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 플루오로중합체를 포함하는 복합 입자, 제조 방법 및 그를 포함하는 물품 |
| US10053387B2 (en) | 2013-07-18 | 2018-08-21 | 3M Innovative Properties Company | Glass microbubbles, raw product, and methods of making the same |
| WO2015103099A1 (en) | 2013-12-30 | 2015-07-09 | 3M Innovative Properties Company | Polyolefin composition including hollow glass microspheres and method of using the same |
| WO2015103096A1 (en) | 2013-12-30 | 2015-07-09 | 3M Innovative Properties Company | Poly (methylpentene) composition including hollow glass microspheres and method of using the same |
| GB201415005D0 (en) * | 2014-08-22 | 2014-10-08 | Univ Nottingham | Porous and non-pourous bodies |
| KR20170123319A (ko) | 2015-02-27 | 2017-11-07 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 중공 유리 미소구체를 포함하는 폴리아미드 조성물 및 이와 관련된 물품 및 방법 |
| EP3130636A1 (en) | 2015-08-13 | 2017-02-15 | 3M Innovative Properties Company | Polyolefin composition comprising hollow glass microspheres |
| EP3344589A1 (en) * | 2015-09-04 | 2018-07-11 | 3M Innovative Properties Company | Method of making hollow glass microspheres |
| SI3184494T1 (en) * | 2015-12-21 | 2018-07-31 | Adf Materials Gmbh | Chemical composition for the production of hollow spherical glass particles with high compressive strength |
| BR112018017027A2 (pt) | 2016-02-26 | 2018-12-26 | 3M Innovative Properties Co | artigo de esfregamento e método para produção de um artigo de esfregamento |
| EP3826969B1 (en) * | 2018-07-26 | 2024-05-22 | Basf Se | Hollow spherical glass particles |
| WO2018118956A1 (en) | 2016-12-20 | 2018-06-28 | 3M Innovative Properties Company | Composition including fluoropolymer and inorganic filler and method of making a three-dimensional article |
| EP4308930A1 (en) * | 2021-03-19 | 2024-01-24 | Neogen Food Safety US HoldCo Corporation | Compositions and methods of detecting analytes |
| CN117916205A (zh) | 2021-07-16 | 2024-04-19 | 3M创新有限公司 | 玻璃泡以及由其制得的制品 |
| EP4197980A1 (en) | 2021-12-16 | 2023-06-21 | 3M Innovative Properties Company | Coated glass microspheres comprising a coating comprising hexagonal boron nitride particles |
| EP4638374A1 (en) | 2022-12-21 | 2025-10-29 | 3M Innovative Properties Company | Coated glass bubbles and methods of making coated glass bubbles by mechanical exfoliation |
| WO2025022197A1 (en) | 2023-07-21 | 2025-01-30 | 3M Innovative Properties Company | Castable composition comprising liquid silicone rubber and hollow glass microspheres |
| WO2025099515A1 (en) | 2023-11-09 | 2025-05-15 | 3M Innovative Properties Company | Composites containing graphene coated hollow particles useful in high frequency applications |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2797201A (en) * | 1953-05-11 | 1957-06-25 | Standard Oil Co | Process of producing hollow particles and resulting product |
| US2676892A (en) * | 1953-11-13 | 1954-04-27 | Kanium Corp | Method for making unicellular spherulized clay particles and articles and composition thereof |
| NL232500A (enExample) * | 1957-10-22 | |||
| US3230034A (en) * | 1960-09-29 | 1966-01-18 | Du Pont | Method of treating exhaust gases of internal combustion engines |
| US3365315A (en) * | 1963-08-23 | 1968-01-23 | Minnesota Mining & Mfg | Glass bubbles prepared by reheating solid glass partiles |
| US4017290A (en) * | 1974-04-15 | 1977-04-12 | Kms Fusion, Inc. | Method and apparatus for making uniform pellets for fusion reactors |
| US3961978A (en) * | 1974-09-20 | 1976-06-08 | General Refractories Company | Process for producing perlite microspheres |
| US4391646A (en) * | 1982-02-25 | 1983-07-05 | Minnesota Mining And Manufacturing Company | Glass bubbles of increased collapse strength |
| US4736527A (en) * | 1982-12-13 | 1988-04-12 | Konishiroku Photo Industry Co., Ltd. | Apparatus for the heat treatment of powdery material |
| FR2566384B1 (fr) * | 1984-06-21 | 1986-09-05 | Saint Gobain Vitrage | Perfectionnements aux techniques de production de microspheres en verre |
| US4767726A (en) * | 1987-01-12 | 1988-08-30 | Minnesota Mining And Manufacturing Company | Glass microbubbles |
| US4983550A (en) * | 1988-08-24 | 1991-01-08 | Potters Industries, Inc. | Hollow glass spheres |
| US5217928A (en) * | 1988-08-24 | 1993-06-08 | Potters Industries, Inc. | Hollow glass spheres |
| US4940497A (en) * | 1988-12-14 | 1990-07-10 | Atlas Powder Company | Emulsion explosive composition containing expanded perlite |
| JP2926164B2 (ja) * | 1989-04-18 | 1999-07-28 | 東海工業株式会社 | アルカリ溶出度の小さい新規なガラスバブル及びそのためのガラスフリット組成物 |
| FR2671072B1 (fr) * | 1990-11-14 | 1993-12-03 | Saint Gobain Vitrage Internal | Verre silico-sodo-calcique, microspheres obtenues a partir de ce verre et procede pour leur fabrication. |
| US5500287A (en) * | 1992-10-30 | 1996-03-19 | Innovation Associates, Inc. | Thermal insulating material and method of manufacturing same |
| US6531222B1 (en) * | 1999-06-30 | 2003-03-11 | Asahi Glass Company, Limited | Fine hollow glass sphere and method for preparing the same |
| AU3452501A (en) * | 2000-01-25 | 2001-08-07 | Lubrizol Corporation, The | Water in oil explosive emulsions |
| US6464770B1 (en) * | 2000-08-08 | 2002-10-15 | Advanced Minerals Corporation | Perlite products with controlled particle size distribution |
| US6906009B2 (en) * | 2002-08-14 | 2005-06-14 | 3M Innovative Properties Company | Drilling fluid containing microspheres and use thereof |
| WO2006118901A1 (en) * | 2005-04-29 | 2006-11-09 | 3M Innovative Properties Company | Glass microbubble-containing syntactic foams, explosives, and method of making |
-
2004
- 2004-12-03 US US11/004,385 patent/US20060122049A1/en not_active Abandoned
-
2005
- 2005-09-15 BR BRPI0518722-2A patent/BRPI0518722A2/pt not_active Application Discontinuation
- 2005-09-15 MX MX2007006391A patent/MX2007006391A/es unknown
- 2005-09-15 CN CN2005800412180A patent/CN101068753B/zh not_active Expired - Fee Related
- 2005-09-15 KR KR1020077012385A patent/KR20070085613A/ko not_active Withdrawn
- 2005-09-15 JP JP2007544338A patent/JP5139071B2/ja not_active Expired - Fee Related
- 2005-09-15 WO PCT/US2005/032887 patent/WO2006062566A1/en not_active Ceased
- 2005-09-15 EP EP05797410.7A patent/EP1833767B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP1833767A1 (en) | 2007-09-19 |
| US20060122049A1 (en) | 2006-06-08 |
| BRPI0518722A2 (pt) | 2008-12-02 |
| JP2008521750A (ja) | 2008-06-26 |
| EP1833767B1 (en) | 2019-08-14 |
| CN101068753B (zh) | 2012-02-29 |
| CN101068753A (zh) | 2007-11-07 |
| WO2006062566A1 (en) | 2006-06-15 |
| KR20070085613A (ko) | 2007-08-27 |
| MX2007006391A (es) | 2007-07-11 |
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