JP5113748B2 - 車両燃料電池に水素を提供する分圧スイング吸着システム - Google Patents

車両燃料電池に水素を提供する分圧スイング吸着システム Download PDF

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JP5113748B2
JP5113748B2 JP2008524021A JP2008524021A JP5113748B2 JP 5113748 B2 JP5113748 B2 JP 5113748B2 JP 2008524021 A JP2008524021 A JP 2008524021A JP 2008524021 A JP2008524021 A JP 2008524021A JP 5113748 B2 JP5113748 B2 JP 5113748B2
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supply
fuel
purge
stream
hydrogen
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JP2009503788A (ja
JP2009503788A5 (enExample
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ジェームズ マッケルロイ
ジョン フィン
エム ダグラス レバン
スワミナサン ヴェンカタラマン
フレッド ミトリトスキー
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ブルーム エナジー コーポレーション
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    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
    • B01D53/053—Pressure swing adsorption with storage or buffer vessel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • C01B3/48—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
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    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/16—Hydrogen
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
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    • B01D2257/108—Hydrogen
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01D—SEPARATION
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/402—Further details for adsorption processes and devices using two beds
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    • B01D2259/45—Gas separation or purification devices adapted for specific applications
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    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
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    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
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  • Organic Chemistry (AREA)
  • Sustainable Development (AREA)
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  • Sustainable Energy (AREA)
  • Manufacturing & Machinery (AREA)
  • Electrochemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Fuel Cell (AREA)
JP2008524021A 2005-07-25 2006-07-24 車両燃料電池に水素を提供する分圧スイング吸着システム Expired - Fee Related JP5113748B2 (ja)

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US11/188,123 2005-07-25
US11/188,123 US7520916B2 (en) 2005-07-25 2005-07-25 Partial pressure swing adsorption system for providing hydrogen to a vehicle fuel cell
PCT/US2006/028612 WO2007014126A2 (en) 2005-07-25 2006-07-24 Partial pressure swing adsorption system for providing hydrogen to a vehicle fuel cell

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JP2009503788A JP2009503788A (ja) 2009-01-29
JP2009503788A5 JP2009503788A5 (enExample) 2009-09-10
JP5113748B2 true JP5113748B2 (ja) 2013-01-09

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US (1) US7520916B2 (enExample)
EP (1) EP1912722A4 (enExample)
JP (1) JP5113748B2 (enExample)
WO (1) WO2007014126A2 (enExample)

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US8101307B2 (en) * 2005-07-25 2012-01-24 Bloom Energy Corporation Fuel cell system with electrochemical anode exhaust recycling
JP5542332B2 (ja) * 2005-07-25 2014-07-09 ブルーム エナジー コーポレーション アノード排気を部分的にリサイクルする燃料電池システム
DE102005041747B4 (de) * 2005-09-02 2020-03-12 Bayerische Motoren Werke Aktiengesellschaft Verfahren zur Reduzierung von Emissionen durch gasförmige Zersetzungsprodukte eines Elektrolyten in Kraftfahrzeugen und Vorrichtung zur Durchführung des Verfahrens
US7883803B2 (en) * 2007-03-30 2011-02-08 Bloom Energy Corporation SOFC system producing reduced atmospheric carbon dioxide using a molten carbonated carbon dioxide pump
US7833668B2 (en) * 2007-03-30 2010-11-16 Bloom Energy Corporation Fuel cell system with greater than 95% fuel utilization
WO2008150524A2 (en) 2007-06-04 2008-12-11 Bloom Energy Corporation Structure for high temperature fuel cell system start up and shutdown
DE102007026652A1 (de) * 2007-06-08 2008-12-11 Forschungszentrum Jülich GmbH Hochtemperatur-Polymerelektrolyt-Brennstoffzellensystem sowie Verfahren zum Betreiben desselben
WO2009059571A1 (de) * 2007-11-10 2009-05-14 Horst-Eckart Vollmar Hochtemperaturbrennstoffzellensystem mit teilweisem kreislauf des anodenabgases und ausschleusung von gaskomponenten
CN101946351B (zh) 2008-02-19 2014-04-02 博隆能源股份有限公司 用于给电动交通工具充电的燃料电池系统
US9287571B2 (en) * 2008-07-23 2016-03-15 Bloom Energy Corporation Operation of fuel cell systems with reduced carbon formation and anode leading edge damage
CN102470750B (zh) * 2009-07-21 2015-11-25 丰田自动车株式会社 燃料系统及车辆
US20110017153A1 (en) 2009-07-22 2011-01-27 Green On Demand, LLP (G.O.D.) System for on demand hydrogen production and delivery of hydrogen to an internal combustion engine
TWI458172B (zh) * 2009-09-02 2014-10-21 Bloom Energy Corp 燃料電池系統之多流熱交換器
US9856769B2 (en) * 2010-09-13 2018-01-02 Membrane Technology And Research, Inc. Gas separation process using membranes with permeate sweep to remove CO2 from combustion exhaust
EP2661782B1 (en) 2011-01-06 2018-10-03 Bloom Energy Corporation Sofc hot box components
US8945368B2 (en) 2012-01-23 2015-02-03 Battelle Memorial Institute Separation and/or sequestration apparatus and methods
WO2014151214A1 (en) 2013-03-15 2014-09-25 Exxonmobil Research And Engineering Company Integration of molten carbonate fuel cells in fischer-tropsch synthesis
US9774053B2 (en) 2013-03-15 2017-09-26 Exxonmobil Research And Engineering Company Integrated power generation and carbon capture using fuel cells
US9077007B2 (en) 2013-03-15 2015-07-07 Exxonmobil Research And Engineering Company Integrated power generation and chemical production using fuel cells
US9755258B2 (en) 2013-09-30 2017-09-05 Exxonmobil Research And Engineering Company Integrated power generation and chemical production using solid oxide fuel cells
US9556753B2 (en) 2013-09-30 2017-01-31 Exxonmobil Research And Engineering Company Power generation and CO2 capture with turbines in series
US9287572B2 (en) 2013-10-23 2016-03-15 Bloom Energy Corporation Pre-reformer for selective reformation of higher hydrocarbons
EP3073559B1 (en) * 2013-11-20 2018-01-03 Panasonic Intellectual Property Management Co., Ltd. Fuel-cell system
US9461320B2 (en) 2014-02-12 2016-10-04 Bloom Energy Corporation Structure and method for fuel cell system where multiple fuel cells and power electronics feed loads in parallel allowing for integrated electrochemical impedance spectroscopy (EIS)
US10320017B2 (en) * 2015-10-06 2019-06-11 Bloom Energy Corporation Sorbent bed assembly and fuel cell system including same
KR102212137B1 (ko) 2016-04-21 2021-02-03 퓨얼 셀 에너지, 인크 이산화탄소 포획을 위해 용융 탄산염 연료 전지 애노드 배기를 후가공처리하는 방법
CN109314261B (zh) 2016-04-29 2023-01-31 燃料电池能有限公司 甲烷化阳极废气以提高二氧化碳捕获
US11398634B2 (en) 2018-03-27 2022-07-26 Bloom Energy Corporation Solid oxide fuel cell system and method of operating the same using peak shaving gas
WO2020112812A1 (en) 2018-11-30 2020-06-04 Exxonmobil Research And Engineering Company Operation of molten carbonate fuel cells with enhanced co 2 utilization
US11742508B2 (en) 2018-11-30 2023-08-29 ExxonMobil Technology and Engineering Company Reforming catalyst pattern for fuel cell operated with enhanced CO2 utilization
US11695122B2 (en) 2018-11-30 2023-07-04 ExxonMobil Technology and Engineering Company Layered cathode for molten carbonate fuel cell
WO2020112770A1 (en) 2018-11-30 2020-06-04 Exxonmobil Research And Engineering Company Regeneration of molten carbonate fuel cells for deep co 2 capture
US12355085B2 (en) 2018-11-30 2025-07-08 ExxonMobil Technology and Engineering Company Cathode collector structures for molten carbonate fuel cell
KR102610184B1 (ko) 2018-11-30 2023-12-04 퓨얼셀 에너지, 인크 용융 탄산염 연료 전지를 위한 연료 전지 스테이징
AU2019388977B2 (en) 2018-11-30 2025-01-30 ExxonMobil Technology and Engineering Company Flow field baffle for molten carbonate fuel cell cathode
US11424469B2 (en) 2018-11-30 2022-08-23 ExxonMobil Technology and Engineering Company Elevated pressure operation of molten carbonate fuel cells with enhanced CO2 utilization
US11616249B2 (en) 2019-03-22 2023-03-28 Bloom Energy Corporation Solid oxide fuel cell system with hydrogen pumping cell with carbon monoxide tolerant anodes and integrated shift reactor
JP7480174B2 (ja) 2019-04-12 2024-05-09 ブルーム エネルギー コーポレイション 一酸化炭素耐性アノードを備えた水素ポンピングセルと統合されたシフト反応器とを有する固体酸化物形燃料電池システム
EP4000118A4 (en) 2019-07-19 2024-08-28 Bloom Energy Corporation INTEGRATED POWER GENERATION, CARBON DIOXIDE SEPARATION AND POST-PROCESSING SYSTEM AND PROCESS
JP7370792B2 (ja) * 2019-09-30 2023-10-30 東京瓦斯株式会社 燃料電池システム、及び燃料電池システムの運転方法
CA3162614C (en) 2019-11-26 2024-03-26 Exxonmobile Research And Engineering Company Fuel cell module assembly and systems using same
WO2021107935A1 (en) 2019-11-26 2021-06-03 Exxonmobil Research And Engineering Company Operation of molten carbonate fuel cells with high electrolyte fill level
EP4066303A1 (en) 2019-11-26 2022-10-05 ExxonMobil Technology and Engineering Company Fuel cell assembly with external manifold for parallel flow
WO2021181249A1 (en) 2020-03-11 2021-09-16 Fuelcell Energy, Inc. Steam methane reforming unit for carbon capture
JP7298541B2 (ja) * 2020-05-19 2023-06-27 トヨタ自動車株式会社 燃料電池システム
EP4288185A4 (en) * 2021-02-04 2025-12-03 Indian Inst Scient HYDROGEN SEPARATION SYSTEM FOR A FEED GAS
US11978931B2 (en) 2021-02-11 2024-05-07 ExxonMobil Technology and Engineering Company Flow baffle for molten carbonate fuel cell
US12603315B2 (en) 2021-04-08 2026-04-14 Bloom Energy Corporation Hydrogen pumping proton exchange membrane electrochemical cell with carbon monoxide tolerant anode and method of making thereof
EP4113675A3 (en) 2021-06-25 2024-06-26 Bloom Energy Corporation Handling of variable and unpredictable gas composition changes to maximize health and performance of fuel cell systems
EP4381030A4 (en) * 2021-09-09 2025-09-03 Coldstream Energy Ip Llc PORTABLE PRESSURE SWING ADSORPTION PROCESS AND SYSTEM FOR FUEL GAS CONDITIONING
CN119497764A (zh) * 2022-07-12 2025-02-21 托普索公司 用于进行固体氧化物电解的soe设备和方法
CN116093368B (zh) * 2023-01-13 2025-11-11 江苏徐工工程机械研究院有限公司 燃料电池低温停机吹扫控制方法、系统、燃料电池及汽车

Family Cites Families (59)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3488266A (en) * 1967-12-12 1970-01-06 Continental Oil Co Electrochemical reduction of benzene using a carbon anode
US4041210A (en) * 1976-08-30 1977-08-09 United Technologies Corporation Pressurized high temperature fuel cell power plant with bottoming cycle
US4182795A (en) * 1978-07-10 1980-01-08 Energy Research Corporation Fuel cell thermal control and reforming of process gas hydrocarbons
US4532192A (en) * 1984-11-06 1985-07-30 Energy Research Corporation Fuel cell system
US4792502A (en) * 1986-11-14 1988-12-20 International Fuel Cells Corporation Apparatus for producing nitrogen
US4898792A (en) * 1988-12-07 1990-02-06 Westinghouse Electric Corp. Electrochemical generator apparatus containing modified high temperature insulation and coated surfaces for use with hydrocarbon fuels
US4917971A (en) * 1989-03-03 1990-04-17 Energy Research Corporation Internal reforming fuel cell system requiring no recirculated cooling and providing a high fuel process gas utilization
US5302470A (en) * 1989-05-16 1994-04-12 Osaka Gas Co., Ltd. Fuel cell power generation system
US4983471A (en) * 1989-12-28 1991-01-08 Westinghouse Electric Corp. Electrochemical cell apparatus having axially distributed entry of a fuel-spent fuel mixture transverse to the cell lengths
US5034287A (en) * 1990-04-23 1991-07-23 International Fuel Cells Corporation Fuel cell cooling using heat of reaction
CA2018639A1 (en) * 1990-06-08 1991-12-08 James D. Blair Method and apparatus for comparing fuel cell voltage
US5143800A (en) * 1990-07-25 1992-09-01 Westinghouse Electric Corp. Electrochemical cell apparatus having combusted exhaust gas heat exchange and valving to control the reformable feed fuel composition
US5047299A (en) * 1990-07-25 1991-09-10 Westinghouse Electric Corp. Electrochemical cell apparatus having an integrated reformer-mixer nozzle-mixer diffuser
US5169730A (en) * 1990-07-25 1992-12-08 Westinghouse Electric Corp. Electrochemical cell apparatus having an exterior fuel mixer nozzle
US5084362A (en) * 1990-08-29 1992-01-28 Energy Research Corporation Internal reforming molten carbonate fuel cell system with methane feed
JP3064167B2 (ja) * 1993-09-01 2000-07-12 三菱重工業株式会社 固体電解質燃料電池
TW299345B (enExample) * 1994-02-18 1997-03-01 Westinghouse Electric Corp
JPH07275631A (ja) * 1994-04-11 1995-10-24 Nippon Steel Corp 圧力スイング吸着法における製品不純物の置換低減方法
US5498487A (en) * 1994-08-11 1996-03-12 Westinghouse Electric Corporation Oxygen sensor for monitoring gas mixtures containing hydrocarbons
US5441821A (en) * 1994-12-23 1995-08-15 Ballard Power Systems Inc. Electrochemical fuel cell system with a regulated vacuum ejector for recirculation of the fluid fuel stream
US5505824A (en) * 1995-01-06 1996-04-09 United Technologies Corporation Propellant generator and method of generating propellants
US5601937A (en) * 1995-01-25 1997-02-11 Westinghouse Electric Corporation Hydrocarbon reformer for electrochemical cells
US5733675A (en) * 1995-08-23 1998-03-31 Westinghouse Electric Corporation Electrochemical fuel cell generator having an internal and leak tight hydrocarbon fuel reformer
US5573867A (en) * 1996-01-31 1996-11-12 Westinghouse Electric Corporation Purge gas protected transportable pressurized fuel cell modules and their operation in a power plant
US5741605A (en) * 1996-03-08 1998-04-21 Westinghouse Electric Corporation Solid oxide fuel cell generator with removable modular fuel cell stack configurations
US5686196A (en) * 1996-10-09 1997-11-11 Westinghouse Electric Corporation System for operating solid oxide fuel cell generator on diesel fuel
US5955039A (en) * 1996-12-19 1999-09-21 Siemens Westinghouse Power Corporation Coal gasification and hydrogen production system and method
CA2242176C (en) * 1997-06-30 2009-01-27 Ballard Power Systems Inc. Solid polymer fuel cell system and method for humidifying and adjusting the temperature of a reactant stream
US6013385A (en) * 1997-07-25 2000-01-11 Emprise Corporation Fuel cell gas management system
WO2000016423A2 (de) * 1998-09-14 2000-03-23 Forschungszentrum Jülich GmbH Festoxidbrennstoffzelle betrieben mit brennstoffüberschuss
US6051125A (en) * 1998-09-21 2000-04-18 The Regents Of The University Of California Natural gas-assisted steam electrolyzer
US6403245B1 (en) * 1999-05-21 2002-06-11 Microcoating Technologies, Inc. Materials and processes for providing fuel cells and active membranes
US6329090B1 (en) * 1999-09-03 2001-12-11 Plug Power Llc Enthalpy recovery fuel cell system
US6280865B1 (en) * 1999-09-24 2001-08-28 Plug Power Inc. Fuel cell system with hydrogen purification subsystem
JP2001102076A (ja) * 1999-09-29 2001-04-13 Daihatsu Motor Co Ltd 燃料電池装置
US6627338B2 (en) * 1999-12-22 2003-09-30 Ballard Power Systems Inc. Integrated fuel cell and pressure swing adsorption system
US6451466B1 (en) * 2000-04-06 2002-09-17 Utc Fuel Cells, Llc Functional integration of multiple components for a fuel cell power plant
US6630264B2 (en) * 2000-05-01 2003-10-07 Delphi Technologies, Inc. Solid oxide fuel cell process gas sampling for analysis
JP2001347125A (ja) * 2000-06-12 2001-12-18 Mitsubishi Kakoki Kaisha Ltd 圧力変動吸着装置による高純度ガスの製造方法
US7051801B1 (en) * 2000-07-28 2006-05-30 Hydrogenics Corporation Method and apparatus for humidification and temperature control of incoming fuel cell process gas
EP1328984A2 (en) * 2000-09-01 2003-07-23 Global Thermoelectric Inc. Anode oxidation protection in a high-temperature fuel cell
US6811913B2 (en) * 2000-11-15 2004-11-02 Technology Management, Inc. Multipurpose reversible electrochemical system
US7294421B2 (en) * 2001-02-07 2007-11-13 Delphi Technologies, Inc. Solid oxide auxiliary power unit reformate control
US6623880B1 (en) * 2001-05-29 2003-09-23 The United States Of America As Represented By The Department Of Energy Fuel cell-fuel cell hybrid system
US7067208B2 (en) * 2002-02-20 2006-06-27 Ion America Corporation Load matched power generation system including a solid oxide fuel cell and a heat pump and an optional turbine
JP2006505095A (ja) * 2002-03-14 2006-02-09 クエストエアー テクノロジーズ インコーポレイテッド 固体酸化物燃料電池用の水素リサイクル
US20030196893A1 (en) * 2002-04-23 2003-10-23 Mcelroy James Frederick High-temperature low-hydration ion exchange membrane electrochemical cell
US6854688B2 (en) * 2002-05-03 2005-02-15 Ion America Corporation Solid oxide regenerative fuel cell for airplane power generation and storage
US7179313B2 (en) 2002-08-02 2007-02-20 Catacel Corp. Regenerative autothermal catalytic steam reformer
US6821663B2 (en) * 2002-10-23 2004-11-23 Ion America Corporation Solid oxide regenerative fuel cell
JP2004247290A (ja) * 2003-01-21 2004-09-02 Honda Motor Co Ltd 水素供給装置
WO2004076017A2 (en) * 2003-02-26 2004-09-10 Questair Technologies Inc. Hydrogen recycle for high temperature fuel cells
US6924053B2 (en) * 2003-03-24 2005-08-02 Ion America Corporation Solid oxide regenerative fuel cell with selective anode tail gas circulation
US7045238B2 (en) * 2003-03-24 2006-05-16 Ion America Corporation SORFC power and oxygen generation method and system
US7482078B2 (en) 2003-04-09 2009-01-27 Bloom Energy Corporation Co-production of hydrogen and electricity in a high temperature electrochemical system
US7575822B2 (en) * 2003-04-09 2009-08-18 Bloom Energy Corporation Method of optimizing operating efficiency of fuel cells
US7364810B2 (en) * 2003-09-03 2008-04-29 Bloom Energy Corporation Combined energy storage and fuel generation with reversible fuel cells
US7060382B2 (en) * 2003-05-15 2006-06-13 Fuelcell Energy, Inc. Fuel cell system with recycle of anode exhaust gas
US7422810B2 (en) * 2004-01-22 2008-09-09 Bloom Energy Corporation High temperature fuel cell system and method of operating same

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