JP5058283B2 - ナノカーボン生成用触媒の処理方法及びナノカーボンの製造方法 - Google Patents
ナノカーボン生成用触媒の処理方法及びナノカーボンの製造方法 Download PDFInfo
- Publication number
- JP5058283B2 JP5058283B2 JP2010058180A JP2010058180A JP5058283B2 JP 5058283 B2 JP5058283 B2 JP 5058283B2 JP 2010058180 A JP2010058180 A JP 2010058180A JP 2010058180 A JP2010058180 A JP 2010058180A JP 5058283 B2 JP5058283 B2 JP 5058283B2
- Authority
- JP
- Japan
- Prior art keywords
- nanocarbon
- catalyst material
- catalyst
- chemical
- surface treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003054 catalyst Substances 0.000 title claims description 94
- 229910021392 nanocarbon Inorganic materials 0.000 title claims description 90
- 238000004519 manufacturing process Methods 0.000 title claims description 40
- 238000000034 method Methods 0.000 title claims description 28
- 239000000463 material Substances 0.000 claims description 77
- 239000000126 substance Substances 0.000 claims description 64
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 28
- 239000007788 liquid Substances 0.000 claims description 24
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 20
- 229910052742 iron Inorganic materials 0.000 claims description 14
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 10
- 229910017604 nitric acid Inorganic materials 0.000 claims description 10
- 229910001374 Invar Inorganic materials 0.000 claims description 8
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 6
- 238000005229 chemical vapour deposition Methods 0.000 claims description 6
- 229910000833 kovar Inorganic materials 0.000 claims description 6
- 239000007769 metal material Substances 0.000 claims description 4
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- 239000000908 ammonium hydroxide Substances 0.000 claims description 3
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 3
- 238000003672 processing method Methods 0.000 claims description 3
- 239000010935 stainless steel Substances 0.000 claims description 2
- 229910001220 stainless steel Inorganic materials 0.000 claims description 2
- 238000004381 surface treatment Methods 0.000 description 47
- 239000000243 solution Substances 0.000 description 25
- 239000008155 medical solution Substances 0.000 description 10
- 238000001878 scanning electron micrograph Methods 0.000 description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- 238000000089 atomic force micrograph Methods 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 229910021393 carbon nanotube Inorganic materials 0.000 description 5
- 239000002041 carbon nanotube Substances 0.000 description 5
- 238000005530 etching Methods 0.000 description 5
- 239000011259 mixed solution Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 239000002861 polymer material Substances 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical compound C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 description 1
- 229910001006 Constantan Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000001241 arc-discharge method Methods 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 208000037998 chronic venous disease Diseases 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 229910003472 fullerene Inorganic materials 0.000 description 1
- 229910001293 incoloy Inorganic materials 0.000 description 1
- 239000002082 metal nanoparticle Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 238000005268 plasma chemical vapour deposition Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000002230 thermal chemical vapour deposition Methods 0.000 description 1
- 238000004506 ultrasonic cleaning Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/06—Washing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/745—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Nanotechnology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Composite Materials (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Carbon And Carbon Compounds (AREA)
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2010058180A JP5058283B2 (ja) | 2010-03-15 | 2010-03-15 | ナノカーボン生成用触媒の処理方法及びナノカーボンの製造方法 |
DE102011013507A DE102011013507A1 (de) | 2010-03-15 | 2011-03-10 | Verfahren zur Behandlung eines Katalysators zur Nanokohlenstoffproduktion und Verfahren zur Herstellung von Nanokohlenstoff |
US13/047,207 US20110223333A1 (en) | 2010-03-15 | 2011-03-14 | Method of treating catalyst for nanocarbon production and method of manufacturing nanocarbon |
CN201110062532.4A CN102189005B (zh) | 2010-03-15 | 2011-03-15 | 纳米碳生成用催化剂的处理方法及纳米碳的制造方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2010058180A JP5058283B2 (ja) | 2010-03-15 | 2010-03-15 | ナノカーボン生成用触媒の処理方法及びナノカーボンの製造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2011189292A JP2011189292A (ja) | 2011-09-29 |
JP5058283B2 true JP5058283B2 (ja) | 2012-10-24 |
Family
ID=44560248
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2010058180A Expired - Fee Related JP5058283B2 (ja) | 2010-03-15 | 2010-03-15 | ナノカーボン生成用触媒の処理方法及びナノカーボンの製造方法 |
Country Status (4)
Country | Link |
---|---|
US (1) | US20110223333A1 (zh) |
JP (1) | JP5058283B2 (zh) |
CN (1) | CN102189005B (zh) |
DE (1) | DE102011013507A1 (zh) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101350690B1 (ko) * | 2012-02-13 | 2014-01-14 | 금호석유화학 주식회사 | 초저밀도 특성을 지닌 번들 구조의 고전도성 탄소나노튜브 및 이의 제조방법 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3673094A (en) * | 1969-07-07 | 1972-06-27 | Armco Steel Corp | Chemical milling method and bath for steel |
JPH05103997A (ja) * | 1991-10-16 | 1993-04-27 | Tanaka Kikinzoku Kogyo Kk | 触媒用金属基体の表面処理方法 |
JP2001048512A (ja) * | 1999-08-04 | 2001-02-20 | Ulvac Japan Ltd | 垂直配向カーボンナノチューブの作製方法 |
CN1172846C (zh) * | 2000-10-26 | 2004-10-27 | 中国科学院大连化学物理研究所 | 一种纳米碳纤维储氢材料的制备方法 |
JP3443646B1 (ja) * | 2002-03-25 | 2003-09-08 | 名古屋大学長 | カーボンナノチューブの成長方法 |
FR2851737B1 (fr) * | 2003-02-28 | 2006-05-26 | Commissariat Energie Atomique | Catalyseur structure notamment pour la realisation d'ecrans plats a emission de champ |
US7157791B1 (en) * | 2004-06-11 | 2007-01-02 | Bridge Semiconductor Corporation | Semiconductor chip assembly with press-fit ground plane |
JP4516091B2 (ja) * | 2007-04-23 | 2010-08-04 | 株式会社東芝 | ナノカーボン生成装置 |
-
2010
- 2010-03-15 JP JP2010058180A patent/JP5058283B2/ja not_active Expired - Fee Related
-
2011
- 2011-03-10 DE DE102011013507A patent/DE102011013507A1/de not_active Withdrawn
- 2011-03-14 US US13/047,207 patent/US20110223333A1/en not_active Abandoned
- 2011-03-15 CN CN201110062532.4A patent/CN102189005B/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CN102189005B (zh) | 2014-12-31 |
US20110223333A1 (en) | 2011-09-15 |
CN102189005A (zh) | 2011-09-21 |
DE102011013507A1 (de) | 2012-01-12 |
JP2011189292A (ja) | 2011-09-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5306482B2 (ja) | 乱層構造を持つ黒鉛性構造体からのグラフェンシートの製造方法およびその方法により製造されたグラフェンシート | |
JP5542829B2 (ja) | カーボンナノチューブ、フラーレン及び/又はグラフェン含有コーティングの製造方法 | |
WO2009139331A1 (ja) | 炭素線および炭素膜からなるナノ構造体およびそれらの製造方法 | |
Baddour et al. | Direct and repetitive growth cycles of carbon nanotubes on stainless steel particles by chemical vapor deposition in a fluidized bed | |
KR20100022419A (ko) | 탄소나노튜브 복합체 | |
Kumar et al. | Chemical vapor deposition of carbon nanotubes on monolayer graphene substrates: reduced etching via suppressed catalytic hydrogenation using C2H4 | |
KR100996883B1 (ko) | 그라핀시트 제조방법 및 상기 방법으로 제조된 그라핀시트 | |
Lee et al. | Analysis of acoustical performance of Bi-layer graphene and graphene-foam-based thermoacoustic sound generating devices | |
Zhang et al. | Dendritic growth of monolayer ternary WS 2 (1− x) Se 2x flakes for enhanced hydrogen evolution reaction | |
Wang et al. | Highly efficient production of graphene by an ultrasound coupled with a shear mixer in supercritical CO2 | |
JP2009256204A (ja) | カーボンナノチューブの製造方法 | |
Hofmann et al. | A facile tool for the characterization of two-dimensional materials grown by chemical vapor deposition | |
Chang et al. | Electrophoresis of nanodiamond on the growth of ultrananocrystalline diamond films on silicon nanowires and the enhancement of the electron field emission properties | |
Hussain et al. | Growth and plasma functionalization of carbon nanotubes | |
Tsou et al. | K and Au bicatalyst assisted growth of carbon nanocoils from acetylene: Effect of deposition parameters on field emission properties | |
JP5058283B2 (ja) | ナノカーボン生成用触媒の処理方法及びナノカーボンの製造方法 | |
Huang et al. | Enhanced field emission from ultrananocrystalline diamond-decorated carbon nanowalls prepared by a self-assembly seeding technique | |
AuBuchon et al. | Control of carbon capping for regrowth of aligned carbon nanotubes | |
Lu et al. | Influence of carbon dioxide plasma treatment on the dry adhesion of vertical aligned carbon nanotube arrays | |
Lee et al. | Reliability enhancement of germanium nanowires using graphene as a protective layer: Aspect of thermal stability | |
Bu et al. | Industrial compatible re-growth of vertically aligned multiwall carbon nanotubes by ultrafast pure oxygen purification process | |
Hwang et al. | Nanoscale layer of a minimized defect area of graphene and hexagonal boron nitride on copper for excellent anti-corrosion activity | |
Achour et al. | Effect of nitrogen configuration on carbon nanowall surface: Towards the improvement of electrochemical transduction properties and the stabilization of gold nanoparticles | |
JP6287463B2 (ja) | 再利用基材の製造方法およびカーボンナノチューブ生成用触媒基材の製造方法 | |
Pham et al. | Effect of plasma–nitric acid treatment on the electrical conductivity of flexible transparent conductive films |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20120412 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20120424 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20120615 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20120703 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20120731 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20150810 Year of fee payment: 3 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20150810 Year of fee payment: 3 |
|
LAPS | Cancellation because of no payment of annual fees |