JP4993921B2 - 環形動物の忌避剤 - Google Patents
環形動物の忌避剤 Download PDFInfo
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- JP4993921B2 JP4993921B2 JP2006049551A JP2006049551A JP4993921B2 JP 4993921 B2 JP4993921 B2 JP 4993921B2 JP 2006049551 A JP2006049551 A JP 2006049551A JP 2006049551 A JP2006049551 A JP 2006049551A JP 4993921 B2 JP4993921 B2 JP 4993921B2
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- JP
- Japan
- Prior art keywords
- repellent
- annelids
- annelid
- ricinoleic acid
- active ingredient
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000005871 repellent Substances 0.000 title claims description 62
- 230000002940 repellent Effects 0.000 title claims description 62
- 241000243818 Annelida Species 0.000 title claims description 37
- 239000004480 active ingredient Substances 0.000 claims description 22
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 claims description 17
- 229960003656 ricinoleic acid Drugs 0.000 claims description 17
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 15
- 239000002202 Polyethylene glycol Substances 0.000 claims description 12
- 229920001223 polyethylene glycol Polymers 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 9
- 239000011347 resin Substances 0.000 claims description 9
- 229920005989 resin Polymers 0.000 claims description 9
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 9
- 239000010695 polyglycol Substances 0.000 claims description 6
- 229920000151 polyglycol Polymers 0.000 claims description 6
- 239000000443 aerosol Substances 0.000 claims description 5
- 230000001846 repelling effect Effects 0.000 claims description 5
- IJRHDFLHUATAOS-DPMBMXLASA-M sodium ricinoleate Chemical compound [Na+].CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O IJRHDFLHUATAOS-DPMBMXLASA-M 0.000 claims description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 125000004436 sodium atom Chemical group 0.000 claims description 3
- 230000000694 effects Effects 0.000 description 20
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 16
- 230000000052 comparative effect Effects 0.000 description 12
- 239000007921 spray Substances 0.000 description 11
- 239000000203 mixture Substances 0.000 description 8
- VAKMIIPDYZXBEV-DPMBMXLASA-M potassium;(z,12r)-12-hydroxyoctadec-9-enoate Chemical compound [K+].CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O VAKMIIPDYZXBEV-DPMBMXLASA-M 0.000 description 8
- 235000015112 vegetable and seed oil Nutrition 0.000 description 8
- 239000008158 vegetable oil Substances 0.000 description 8
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 7
- 239000008280 blood Substances 0.000 description 7
- 210000004369 blood Anatomy 0.000 description 7
- 239000003995 emulsifying agent Substances 0.000 description 7
- 229940066675 ricinoleate Drugs 0.000 description 7
- WBHHMMIMDMUBKC-QJWNTBNXSA-M ricinoleate Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O WBHHMMIMDMUBKC-QJWNTBNXSA-M 0.000 description 7
- 239000003945 anionic surfactant Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 235000005911 diet Nutrition 0.000 description 5
- 230000037213 diet Effects 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 5
- 241001465754 Metazoa Species 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 229930014626 natural product Natural products 0.000 description 3
- -1 polyethylene Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 241000251468 Actinopterygii Species 0.000 description 2
- 241000282817 Bovidae Species 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 235000009046 Convallaria majalis Nutrition 0.000 description 2
- 244000068485 Convallaria majalis Species 0.000 description 2
- 241000545744 Hirudinea Species 0.000 description 2
- 102000007625 Hirudins Human genes 0.000 description 2
- 108010007267 Hirudins Proteins 0.000 description 2
- 241000282412 Homo Species 0.000 description 2
- 241000237852 Mollusca Species 0.000 description 2
- MMOXZBCLCQITDF-UHFFFAOYSA-N N,N-diethyl-m-toluamide Chemical compound CCN(CC)C(=O)C1=CC=CC(C)=C1 MMOXZBCLCQITDF-UHFFFAOYSA-N 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 229960001673 diethyltoluamide Drugs 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- WQPDUTSPKFMPDP-OUMQNGNKSA-N hirudin Chemical compound C([C@@H](C(=O)N[C@@H](CCC(O)=O)C(=O)N[C@@H](CCC(O)=O)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N1[C@@H](CCC1)C(=O)N[C@@H](CCC(O)=O)C(=O)N[C@@H](CCC(O)=O)C(=O)N[C@@H](CC=1C=CC(OS(O)(=O)=O)=CC=1)C(=O)N[C@@H](CC(C)C)C(=O)N[C@@H](CCC(N)=O)C(O)=O)NC(=O)[C@H](CC(O)=O)NC(=O)CNC(=O)[C@H](CC(O)=O)NC(=O)[C@H](CC(N)=O)NC(=O)[C@H](CC=1NC=NC=1)NC(=O)[C@H](CO)NC(=O)[C@H](CCC(N)=O)NC(=O)[C@H]1N(CCC1)C(=O)[C@H](CCCCN)NC(=O)[C@H]1N(CCC1)C(=O)[C@@H](NC(=O)CNC(=O)[C@H](CCC(O)=O)NC(=O)CNC(=O)[C@@H](NC(=O)[C@@H](NC(=O)[C@H]1NC(=O)[C@H](CCC(N)=O)NC(=O)[C@H](CC(N)=O)NC(=O)[C@H](CCCCN)NC(=O)[C@H](CCC(O)=O)NC(=O)CNC(=O)[C@H](CC(O)=O)NC(=O)[C@H](CO)NC(=O)CNC(=O)[C@H](CC(C)C)NC(=O)[C@H]([C@@H](C)CC)NC(=O)[C@@H]2CSSC[C@@H](C(=O)N[C@@H](CCC(O)=O)C(=O)NCC(=O)N[C@@H](CO)C(=O)N[C@@H](CC(N)=O)C(=O)N[C@H](C(=O)N[C@H](C(NCC(=O)N[C@@H](CCC(N)=O)C(=O)NCC(=O)N[C@@H](CC(N)=O)C(=O)N[C@@H](CCCCN)C(=O)N2)=O)CSSC1)C(C)C)NC(=O)[C@H](CC(C)C)NC(=O)[C@H]1NC(=O)[C@H](CC(C)C)NC(=O)[C@H](CC(N)=O)NC(=O)[C@H](CCC(N)=O)NC(=O)CNC(=O)[C@H](CO)NC(=O)[C@H](CCC(O)=O)NC(=O)[C@H]([C@@H](C)O)NC(=O)[C@@H](NC(=O)[C@H](CC(O)=O)NC(=O)[C@@H](NC(=O)[C@H](CC=2C=CC(O)=CC=2)NC(=O)[C@@H](NC(=O)[C@@H](N)C(C)C)C(C)C)[C@@H](C)O)CSSC1)C(C)C)[C@@H](C)O)[C@@H](C)O)C1=CC=CC=C1 WQPDUTSPKFMPDP-OUMQNGNKSA-N 0.000 description 2
- 229940006607 hirudin Drugs 0.000 description 2
- 230000000749 insecticidal effect Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 210000001519 tissue Anatomy 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 241001083548 Anemone Species 0.000 description 1
- 208000035985 Body Odor Diseases 0.000 description 1
- 206010012735 Diarrhoea Diseases 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241001149911 Isopoda Species 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 206010040904 Skin odour abnormal Diseases 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 230000023555 blood coagulation Effects 0.000 description 1
- 230000036760 body temperature Effects 0.000 description 1
- 230000037396 body weight Effects 0.000 description 1
- MYFXBBAEXORJNB-UHFFFAOYSA-N calcium cyanamide Chemical compound [Ca+2].[N-]=C=[N-] MYFXBBAEXORJNB-UHFFFAOYSA-N 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000010495 camellia oil Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 210000000936 intestine Anatomy 0.000 description 1
- 239000008141 laxative Substances 0.000 description 1
- 230000002475 laxative effect Effects 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 230000002572 peristaltic effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 229960002668 sodium chloride Drugs 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 229920005792 styrene-acrylic resin Polymers 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 230000035900 sweating Effects 0.000 description 1
- 206010042772 syncope Diseases 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 230000000699 topical effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Landscapes
- Catching Or Destruction (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
リシノール酸カリウム:花王(株)製 FR−25(リシノール酸カリウム33%水溶液)
ポリエチレングリコール♯4000:関東化学(株)製
ポリアクリル酸ナトリウム:純正化学(株)製
塩化ナトリウム:純正化学(株)製
ポリエチレングリコール♯4000を10部、ポリアクリル酸ナトリウム2部、エタノール88部を販乳化機「コンビミックス」(PRIMIX(株)製)で攪拌し均一に混合し、これをスプレーボトルに入れて目的物とした。
塩化ナトリウム10部、精製水90部を市販乳化機「コンビミックス」(PRIMIX(株)製)で攪拌し均一に混合し、これをスプレーボトルに入れて目的物とした。
一般的な食塩水である。
市販忌避剤「ヒルノック」スプレー剤、アミノエタノール系薬剤。エタノールで希釈されている。
直径9cmのシャーレ上に直径7cmの濾紙を載せ、その濾紙中心部に供試薬剤1mlをマイクロピペットを使って滴下した。そしてこの液滴が濾紙全体に拡展するまで放置した。液が濾紙全体に拡展したのを確認後、乾燥機に入れて濾紙を乾燥させた。次にこの濾紙の中心部に直径3cmに切り取った円状の濾紙を載せ、その上に体長約2cmのヤマビルを1匹載せた。このヤマビルが直径3cmの濾紙外に出て、下に敷いた直径7cmの濾紙の上を徘徊するかどうかを観察した。結果を[表2]に示す。
供試薬剤を長靴から10cm離してスプレーし吹付けた。長靴は高さ32cmの市販品で、各剤均一な速度で一方の靴片面に10秒程度吹付けた。これを風乾後に履き、ヤマビルが生息する山中を1時間歩き、その後靴に付着しているヤマビルの数を数えた。この実験を晴天時の乾燥した状態と、雨天後の路面が湿っている状態で行った。結果を[表3]に示す。
Claims (10)
- 環形動物の忌避剤が、ポリグリコール類および樹脂の中から選択される1種または2種以上を含有することを特徴とする、請求項1記載の環形動物の忌避剤。
- 前記したポリグリコール類がポリエチレングリコールであり、前記した樹脂がポリアクリル酸ナトリウムである、請求項2記載の環形動物の忌避剤。
- 環形動物の忌避剤が、有機溶媒および/または水を含有するエアゾル剤である、請求項1〜請求項3のいずれかの項に記載の環形動物の忌避剤。
- 前記した環形動物がヤマビルである、請求項1〜請求項4のいずれかの項に記載の環形動物の忌避剤。
- 環形動物の忌避剤が、ポリグリコール類および樹脂の中から選択される1種または2種以上を含有することを特徴とする、請求項6記載の環形動物の忌避方法。
- 前記したポリグリコール類がポリエチレングリコールであり、前記した樹脂がポリアクリル酸ナトリウムである、請求項7記載の環形動物の忌避方法。
- 環形動物の忌避剤が、有機溶媒および/または水を含有するエアゾル剤として使用されることを特徴とする、請求項6〜請求項8のいずれかの項に記載の環形動物の忌避方法。
- 前記した環形動物がヤマビルである、請求項6〜請求項9のいずれかの項に記載の環形動物の忌避方法。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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JP2006049551A JP4993921B2 (ja) | 2006-02-27 | 2006-02-27 | 環形動物の忌避剤 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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JP2006049551A JP4993921B2 (ja) | 2006-02-27 | 2006-02-27 | 環形動物の忌避剤 |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2007223984A JP2007223984A (ja) | 2007-09-06 |
JP2007223984A5 JP2007223984A5 (ja) | 2009-04-16 |
JP4993921B2 true JP4993921B2 (ja) | 2012-08-08 |
Family
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JP2006049551A Active JP4993921B2 (ja) | 2006-02-27 | 2006-02-27 | 環形動物の忌避剤 |
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JP (1) | JP4993921B2 (ja) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5516846B2 (ja) * | 2009-03-03 | 2014-06-11 | 住化グリーン株式会社 | ヤマビル及び不快害虫忌避剤とその忌避方法 |
JP2012072083A (ja) * | 2010-09-28 | 2012-04-12 | Akita Univ | 有害生物忌避材 |
JP5735699B1 (ja) * | 2014-12-09 | 2015-06-17 | 都美恵 花田 | ヒル防御用塩パック |
JP7144040B2 (ja) * | 2018-08-27 | 2022-09-29 | 敏明 山口 | 環形動物門、扁形動物門、刺胞動物門に属する動物の駆除剤 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07196407A (ja) * | 1993-12-28 | 1995-08-01 | Yashima Sangyo Kk | ヤマビルの忌避剤及び忌避剤組成物 |
JP4256105B2 (ja) * | 2001-02-23 | 2009-04-22 | 保土谷化学工業株式会社 | 摂食性害虫駆除組成物 |
-
2006
- 2006-02-27 JP JP2006049551A patent/JP4993921B2/ja active Active
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JP2007223984A (ja) | 2007-09-06 |
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