JP4977537B2 - オレフィンの二量化用触媒組成物およびオレフィンの二量化方法 - Google Patents
オレフィンの二量化用触媒組成物およびオレフィンの二量化方法 Download PDFInfo
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- JP4977537B2 JP4977537B2 JP2007168354A JP2007168354A JP4977537B2 JP 4977537 B2 JP4977537 B2 JP 4977537B2 JP 2007168354 A JP2007168354 A JP 2007168354A JP 2007168354 A JP2007168354 A JP 2007168354A JP 4977537 B2 JP4977537 B2 JP 4977537B2
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- catalyst composition
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- chloride
- halide
- dimerization
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/125—Halogens; Compounds thereof with scandium, yttrium, aluminium, gallium, indium or thallium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
- B01J31/0278—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre
- B01J31/0281—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member
- B01J31/0284—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member of an aromatic ring, e.g. pyridinium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
- B01J31/0287—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing atoms other than nitrogen as cationic centre
- B01J31/0288—Phosphorus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/20—Olefin oligomerisation or telomerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/22—Organic complexes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/24—Phosphines
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Description
<イオン溶媒の調製>周囲温度で塩化ブチルメチルイミダゾリウム17.5 g(0.1モル)、昇華塩化アルミニウム16.3 g(0.122モル)、ジクロロエチルアルミニウム0.26 g(0.002モル)およびイソズレン4.02 g(0.03 モル)を混合した。このようにして澄んだ黄色の液体を得た。
<イオン溶媒の調製>芳香族炭化水素が添加されなかったことを除けば、先の実施例の条件と同一の条件でイオン溶媒を調製した。この場合液体はほとんど無色であった。
<プロピレンの二量化>錯体NiCl2 ,2P(iPr)3 45 mg の代わりに、錯体NiCl2 ,2P(シクロヘキシル)3 を69 mg(0.1 ミリモル)を導入したことを除いて、実施例1のように操作を行った。3回の抜き取りを行ったが、これは導入されたプロピレン210 g に相当する。三つのフラクションは、二量体78%、三量体18%および四量体4%の割合で構成されていた。各二量体は、2,3-ジメチルブテンを84%、n-ヘキセンを1%および2-メチルペンテンを15%含んでいた。各二量体は特にジメチルブテンに富んでいた。
<イオン溶媒の調製>イソズレンがa- メチルナフタリン4.26 gに代えられたことを除いて、実施例1のように操作を行った。
<イオン溶媒の調製>イソズレンが、ペンタメチルベンゼン4.4 g により代えられたことを除いて、実施例1のように操作が行われた。
本実施例は、ここではトルエンである芳香族炭化水素が極性相およびオリゴマーよりなる相の間で分けられる場合を例証している。各抜き取りの後、芳香族炭化水素(トルエン)が導入された。
Claims (14)
- 少なくとも一つのハロゲン化アルミニウム(B) を、少なくとも一つのハロゲン化第四級アンモニウムおよび/または少なくとも一つのハロゲン化第四級ホスホニウム(A) と、少なくとも一つの芳香族炭化水素(C) と接触させた結果生じるイオン特性を持つ非水性媒質中に少なくとも一部溶解した、少なくとも一つの第三級ホスフィンと混合されたまたは錯化された少なくとも一つのニッケル化合物を含む、オレフィンの二量化、共二量化またはオリゴマー化用触媒組成物。
- ハロゲン化第四級アンモニウムは、塩化N−ブチルピリジニウム、臭化エチルピリジニウム、塩化3-ブチル-1- メチルイミダゾリウム、塩化ジエチルピラゾリウムおよび塩化N−ブチルピリジニウムからなる群より選ばれる、請求項1による触媒組成物。
- ハロゲン化第四級ホスホニウムは塩化テトラブチルホスホニウムである、請求項1または2項による触媒組成物。
- ハロゲン化アルミニウムは塩化アルミニウムである、請求項1〜3のうちの1項による触媒組成物。
- 芳香族炭化水素は、ベンゼン、一般式C6 HX R6-X (式中、Rはアルキル、シクロアルキル、アリール、アルキルアリール基であり、xは1〜5である)の置換ベンゼン、ナフタリン、一般式C10HX R8-X (式中、Rは先に定義されたRであり、xは0〜7)の置換ナフタリン、アントラセン、一般式C14HX R8-X (式中、Rは先に定義されたRであり、xは0〜7)の置換アントラセンからなる群より選ばれる、請求項1〜4のうちの1項による触媒組成物。
- 芳香族炭化水素は、トルエン、キシレン、ズレン、イソズレン、ペンタメチルベンゼン、a-メチルナフタリン、2,6-ジメチルアントラセンからなる群より選ばれる、請求項5による触媒組成物。
- A:Bモル比は1:0.5 〜1:3であり、B:Cモル比は1:1〜1:100 である、請求項1〜6のうちの1項による触媒組成物。
- A:Bモル比は1:1〜1:2であり、B:Cモル比は1:1〜1:10である、請求項1〜7のうちの1項による触媒組成物。
- ニッケル化合物は、ニッケルの塩化物、臭化物、硫酸塩、アセチルアセトン酸塩、カルボン酸塩、フェノラートからなる群より選ばれる、請求項1〜8のうちの1項による触媒組成物。
- ホスフィンは、トリイソプロピルホスフィン、トリシクロヘキシルホスフィン、トリベンジルホスフィンおよびテトラシクロヘキシルメチレンジホスフィンからなる群より選ばれる、請求項1〜9のうちの1項による触媒組成物。
- オレフィンは、少なくとも一つの第三級ホスフィンと混合されたまたは錯化された少なくとも一つのニッケル化合物と接触させられ、前記化合物は少なくとも一部、イオン特性を持つ非水性媒質中に溶解されている、少なくとも一つのオレフィンの二量化、共二量化およびオリゴマー化のための方法において、前記媒質は少なくとも一つのハロゲン化アルミニウムを、少なくとも一つのハロゲン化第四級アンモニウムおよび/または少なくとも一つのハロゲン化第四級ホスホニウムと、少なくとも一つの芳香族炭化水素と接触させた結果生じるものであることを特徴とする方法。
- 反応温度は-40 〜+70 ℃であり、圧力は0.1 〜20MPa である、請求項11による方法。
- オレフィンとの反応温度は-20 〜+50 ℃である、請求項11または12による方法。
- 芳香族炭化水素はオレフィンとの反応中に導入される、請求項11〜13のうちの1項による方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9311381A FR2710280B1 (fr) | 1993-09-22 | 1993-09-22 | Composition catalytique et procédé pour la dimérisation des oléfines. |
FR9311381 | 1993-09-22 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP22748694A Division JP4168098B2 (ja) | 1993-09-22 | 1994-09-22 | オレフィンの二量化用触媒組成物およびオレフィンの二量化方法 |
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JP2007268533A JP2007268533A (ja) | 2007-10-18 |
JP4977537B2 true JP4977537B2 (ja) | 2012-07-18 |
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JP2007168354A Expired - Lifetime JP4977537B2 (ja) | 1993-09-22 | 2007-06-27 | オレフィンの二量化用触媒組成物およびオレフィンの二量化方法 |
Country Status (2)
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US (1) | US5550306A (ja) |
JP (1) | JP4977537B2 (ja) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5877372A (en) * | 1997-11-21 | 1999-03-02 | Arco Chemical Technology, L.P. | Isobutylene oligomerization using isooctane diluent |
FR2794038B1 (fr) * | 1999-05-27 | 2001-06-29 | Inst Francais Du Petrole | Composition catalytique amelioree et son application a l'oligomerisation des olefines |
FR2804678B1 (fr) * | 2000-02-04 | 2002-04-05 | Inst Francais Du Petrole | Procede pour la dimerisation selective du propylene principalement en dimeres ramifies |
FR2804622B1 (fr) * | 2000-02-04 | 2002-04-05 | Inst Francais Du Petrole | Composition catalytique pour la dimerisation, la codimerisation et l'oligomerisation des olefines |
GB0217499D0 (en) | 2002-07-29 | 2002-09-04 | Novartis Ag | Analytical process |
GB0525251D0 (en) * | 2005-12-12 | 2006-01-18 | Univ Belfast | Oligomerisation |
US8084715B2 (en) * | 2006-04-10 | 2011-12-27 | Quad Cities Automatic Pools, Inc. | Method and means for heating and controlling the temperatures in a sauna |
JP2011505490A (ja) | 2007-12-03 | 2011-02-24 | ジーヴォ,インコーポレイテッド | 再生可能組成物 |
US8193402B2 (en) * | 2007-12-03 | 2012-06-05 | Gevo, Inc. | Renewable compositions |
EP2521705A4 (en) | 2010-01-08 | 2014-06-18 | Gevo Inc | INTEGRATED METHODS OF MANUFACTURING RENEWABLE CHEMICALS |
WO2011140560A1 (en) | 2010-05-07 | 2011-11-10 | Gevo, Inc. | Renewable jet fuel blendstock from isobutanol |
ES2409707T3 (es) * | 2011-02-16 | 2013-06-27 | Linde Ag | Procedimiento de preparación de una composición catalítica para oligomerización de etileno y unidad de preformación de composición de catalizador respectiva |
RU2452567C1 (ru) * | 2011-03-25 | 2012-06-10 | Общество с ограниченной ответственностью "Научно-производственное предприятие КВАЛИТЕТ" (ООО "НПП КВАЛИТЕТ") | Катализатор и способ олигомеризации альфа-олефинов |
EP2699618A4 (en) | 2011-04-19 | 2014-12-17 | Gevo Inc | VARIATIONS OF A PRINS REACTION FOR THE PREPARATION OF 2,5-DIMETHYLHEXADIENE FROM ISOBUTANOL |
WO2018122703A1 (en) | 2016-12-30 | 2018-07-05 | Sabic Global Technologies B.V. | Method for preparation of homogenous catalyst for selective 1-hexene production |
ES2868123T3 (es) | 2016-12-30 | 2021-10-21 | Sabic Global Technologies Bv | Método de preparación de una solución de catalizador para la producción selectiva de 1-hexeno |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IL27721A (en) * | 1966-04-15 | 1971-03-24 | Sentralinst For Ind Forskning | Process for dimerization,codimerization,polymerization and copolymerization of mono-olefins |
GB1164855A (en) * | 1966-05-23 | 1969-09-24 | Ici Ltd | Dimerisation of Olefins |
US3482001A (en) * | 1966-05-23 | 1969-12-02 | Sun Oil Co | Dimerization of propylene to dimethylbutenes |
BE796441A (fr) * | 1973-03-08 | 1973-07-02 | Labofina Sa | Nouveau systeme catalytique et procede d'oligomerisation d'olefines |
JPS6191138A (ja) * | 1984-10-08 | 1986-05-09 | Mitsubishi Yuka Fine Chem Co Ltd | エチレンとスチレン類との共二量体の製造法 |
JP2550641B2 (ja) * | 1988-02-29 | 1996-11-06 | 住友化学工業株式会社 | 低級α−オレフィンの二量化方法 |
FR2659871B1 (fr) * | 1990-03-20 | 1992-06-05 | Inst Francais Du Petrole | Composition liquide non aqueuse a caractere ionique et son utilisation comme solvant. invention de mm. yves chauvin, dominique commereuc, isabelle guibard, andre hirschauer, helene olivier, lucien saussine. |
JPH0441440A (ja) * | 1990-06-06 | 1992-02-12 | Mitsui Toatsu Chem Inc | 低級オレフィンの二量化方法 |
JPH06254402A (ja) * | 1991-09-05 | 1994-09-13 | Mitsui Petrochem Ind Ltd | α−オレフィンのオリゴメリゼーション触媒およびα−オレフィンのオリゴメリゼーション法 |
-
1995
- 1995-06-01 US US08/456,820 patent/US5550306A/en not_active Expired - Lifetime
-
2007
- 2007-06-27 JP JP2007168354A patent/JP4977537B2/ja not_active Expired - Lifetime
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Publication number | Publication date |
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US5550306A (en) | 1996-08-27 |
JP2007268533A (ja) | 2007-10-18 |
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