GB1164855A - Dimerisation of Olefins - Google Patents
Dimerisation of OlefinsInfo
- Publication number
- GB1164855A GB1164855A GB40242/67A GB4024267A GB1164855A GB 1164855 A GB1164855 A GB 1164855A GB 40242/67 A GB40242/67 A GB 40242/67A GB 4024267 A GB4024267 A GB 4024267A GB 1164855 A GB1164855 A GB 1164855A
- Authority
- GB
- United Kingdom
- Prior art keywords
- halophosphine
- napthenate
- propene
- dimerization
- lewis acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/1865—Phosphonites (RP(OR)2), their isomeric phosphinates (R2(RO)P=O) and RO-substitution derivatives thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/20—Olefin oligomerisation or telomerisation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
- C07C2527/126—Aluminium chloride
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/128—Compounds comprising a halogen and an iron group metal or a platinum group metal
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/22—Organic complexes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/24—Phosphines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24
- C07C2531/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24 of the platinum group metals, iron group metals or copper
- C07C2531/30—Halides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
1,164,855. Oligomerizing olefins. IMPERIAL CHEMICAL INDUSTRIES Ltd. 19 Aug., 1968 [4 Sept., 1967], No. 40242/67. Addition to 1,131,146. Heading C5E. Monoalkenes are oligomerized by contacting the monomer with a catalyst formed from (1) a nickel compound, (2) a substituted halophosphine of the formula PXR 2 or PX 2 R where X is halogen and R is a hydrocarbyl group, and (3) a Lewis acid. The Ni compound preferably contains at least one anionic ligand e.g. napthenate, acetylacetonate or halide. The halophosphine may be Ph 2 ClP or PhCl 2 P. The Lewis acid may be an aluminium trihalide, alkyl halide or trialkyl. Instead of compounds (1) and (2) a complex of nickel containing one or more halophosphine ligands may be used e.g. NiCl 2 (PCl- Ph 2 ) 2 or Ni(napthenate)2(PClPh 2 ) 2 . The oligomerization may be carried out in a solvent, e.g. chlorobenzene, at -25 to 200 C. and 1-300 atmospheres pressure. Examples describe the co-dimerization of butene and propene and the dimerization of propene.
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB40242/67A GB1164855A (en) | 1966-05-23 | 1967-09-04 | Dimerisation of Olefins |
CA028244A CA929172A (en) | 1966-05-23 | 1968-08-22 | Dimerisation of olefins |
US754740A US3642935A (en) | 1966-05-23 | 1968-08-22 | Dimerisation of olefins |
AU42622/68A AU4262268A (en) | 1967-09-04 | 1968-08-27 | Dimmerisation of olefins |
NL6812220.A NL158471B (en) | 1966-05-23 | 1968-08-28 | IMPROVEMENT OF A METHOD FOR THE CATALYTIC OLIGOMERIZATION OF MONOAL FRAMES. |
JP43063116A JPS5013763B1 (en) | 1966-05-23 | 1968-09-04 | |
FR165094A FR95584E (en) | 1966-05-23 | 1968-09-04 | Process for the oligomerization of monoalkenes. |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB22869/66A GB1131146A (en) | 1966-05-23 | 1966-05-23 | Oligomerisation process |
GB5712266 | 1966-12-21 | ||
GB40242/67A GB1164855A (en) | 1966-05-23 | 1967-09-04 | Dimerisation of Olefins |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1164855A true GB1164855A (en) | 1969-09-24 |
Family
ID=10413921
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB40242/67A Expired GB1164855A (en) | 1966-05-23 | 1967-09-04 | Dimerisation of Olefins |
Country Status (6)
Country | Link |
---|---|
US (1) | US3642935A (en) |
JP (1) | JPS5013763B1 (en) |
CA (1) | CA929172A (en) |
FR (1) | FR95584E (en) |
GB (1) | GB1164855A (en) |
NL (1) | NL158471B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4528416A (en) * | 1984-10-09 | 1985-07-09 | Shell Oil Company | Ethylene oligomerization process carried out in a monohydric/dihydric alcohol solvent mixture |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5162595A (en) * | 1991-12-18 | 1992-11-10 | Phillips Petroleum Company | Ethylene dimerization |
WO2004074223A1 (en) * | 1992-10-06 | 2004-09-02 | Keiichi Sato | Process for dimerizing lower olefin and process for producing alsohol from dinerized olefin |
WO1994008924A1 (en) * | 1992-10-16 | 1994-04-28 | Mitsubishi Kasei Corporation | Process for dimerizing butene, butene dimer composition, and process for producing alcohol therefrom |
US5550306A (en) * | 1993-09-22 | 1996-08-27 | Institut Francais Du Petrole | Catalytic process for the dimerization of olefins |
US9873648B2 (en) * | 2014-10-24 | 2018-01-23 | Lyondell Chemical Technology, L.P. | Oxidative methods of phosphorus removal from liquid hydrocarbons |
-
1967
- 1967-09-04 GB GB40242/67A patent/GB1164855A/en not_active Expired
-
1968
- 1968-08-22 CA CA028244A patent/CA929172A/en not_active Expired
- 1968-08-22 US US754740A patent/US3642935A/en not_active Expired - Lifetime
- 1968-08-28 NL NL6812220.A patent/NL158471B/en unknown
- 1968-09-04 FR FR165094A patent/FR95584E/en not_active Expired
- 1968-09-04 JP JP43063116A patent/JPS5013763B1/ja active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4528416A (en) * | 1984-10-09 | 1985-07-09 | Shell Oil Company | Ethylene oligomerization process carried out in a monohydric/dihydric alcohol solvent mixture |
Also Published As
Publication number | Publication date |
---|---|
FR95584E (en) | 1971-03-26 |
CA929172A (en) | 1973-06-26 |
JPS5013763B1 (en) | 1975-05-22 |
US3642935A (en) | 1972-02-15 |
NL6812220A (en) | 1969-03-06 |
NL158471B (en) | 1978-11-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PCNP | Patent ceased through non-payment of renewal fee |