GB1282305A - Oligomerization and cooligomerization process - Google Patents

Oligomerization and cooligomerization process

Info

Publication number
GB1282305A
GB1282305A GB22299/69A GB2229969A GB1282305A GB 1282305 A GB1282305 A GB 1282305A GB 22299/69 A GB22299/69 A GB 22299/69A GB 2229969 A GB2229969 A GB 2229969A GB 1282305 A GB1282305 A GB 1282305A
Authority
GB
United Kingdom
Prior art keywords
aluminium
oligomerized
hydrocarbyl
temperature
olefins
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB22299/69A
Inventor
Yves Paul Lucien Mari Castille
Paul Thomas Parker
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Priority to GB22299/69A priority Critical patent/GB1282305A/en
Priority to NL7006328A priority patent/NL7006328A/xx
Priority to FR7016066A priority patent/FR2047213A5/fr
Priority to DE19702021524 priority patent/DE2021524A1/en
Publication of GB1282305A publication Critical patent/GB1282305A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines

Abstract

1282305 Oligomerizing olefins ESSO RESEARCH & ENG CO 30 April 1970 [1 May 1969] 22299/69 Heading C5E Olefins are oligomerized or co-oligomerized in the presence of a catalyst system comprising (1) a salt or chelate of a Group VIII transition metal, e.g. nickel acetylacetonate, (2) an electron donor of formula YR 3 or R 2 Y-(CH 2 ) m -YR 2 in which Y is a Group V element, R is H or hydrocarbyl and m is 0, 1 or 2, e.g. triphenyl phosphine or tricyclohexyl phosphine, and (3) an aluminium compound of formula AlR n X 3-n where X is halogen, R is hydrocarbyl or alkoxy and n is 1-3, e.g. aluminium ethyl dichloride or ethyl aluminium sesquichloride, the catalyst being activated in the presence of a solvent and a C 2-12 olefin for 1-15 minutes at a temperature of 0- 60‹ C., the activation temperature being higher than the reaction temperature which is itself below 20‹ C. Examples describe the dimerization of propylene.
GB22299/69A 1969-05-01 1969-05-01 Oligomerization and cooligomerization process Expired GB1282305A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
GB22299/69A GB1282305A (en) 1969-05-01 1969-05-01 Oligomerization and cooligomerization process
NL7006328A NL7006328A (en) 1969-05-01 1970-04-29
FR7016066A FR2047213A5 (en) 1969-05-01 1970-04-30
DE19702021524 DE2021524A1 (en) 1969-05-01 1970-05-02 Process for the oligomerization or co-oligomerization of olefins

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB22299/69A GB1282305A (en) 1969-05-01 1969-05-01 Oligomerization and cooligomerization process

Publications (1)

Publication Number Publication Date
GB1282305A true GB1282305A (en) 1972-07-19

Family

ID=10177140

Family Applications (1)

Application Number Title Priority Date Filing Date
GB22299/69A Expired GB1282305A (en) 1969-05-01 1969-05-01 Oligomerization and cooligomerization process

Country Status (4)

Country Link
DE (1) DE2021524A1 (en)
FR (1) FR2047213A5 (en)
GB (1) GB1282305A (en)
NL (1) NL7006328A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2205853A (en) * 1987-06-16 1988-12-21 Exxon Chemical Patents Inc A process for the production of octenes
WO2017017087A1 (en) 2015-07-29 2017-02-02 IFP Energies Nouvelles Novel catalytic composition comprising nickel and a phosphine-type ligand, and use thereof in an olefin oligomerisation method

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59500166A (en) * 1982-02-17 1984-02-02 コモンウェルス・サイエンティフィック・アンド・インダストリアル・リサ−チ・オ−ガニゼイション Catalysts for olefin oligomerization and isomerization

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2205853A (en) * 1987-06-16 1988-12-21 Exxon Chemical Patents Inc A process for the production of octenes
WO2017017087A1 (en) 2015-07-29 2017-02-02 IFP Energies Nouvelles Novel catalytic composition comprising nickel and a phosphine-type ligand, and use thereof in an olefin oligomerisation method
FR3039430A1 (en) * 2015-07-29 2017-02-03 Ifp Energies Now NOVEL NICKEL AND PHOSPHINE LIGAND CATALYST COMPOSITION AND USE THEREOF IN OLEFIN OLIGOMERIZATION PROCESS
US10633303B2 (en) 2015-07-29 2020-04-28 IFP Energies Nouvelles Catalytic composition comprising nickel and a phosphine-type ligand, and use thereof in an olefin oligomerisation method

Also Published As

Publication number Publication date
DE2021524A1 (en) 1971-01-07
FR2047213A5 (en) 1971-03-12
NL7006328A (en) 1970-11-03

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees