JP4970427B2 - ガスの精製方法 - Google Patents
ガスの精製方法 Download PDFInfo
- Publication number
- JP4970427B2 JP4970427B2 JP2008508864A JP2008508864A JP4970427B2 JP 4970427 B2 JP4970427 B2 JP 4970427B2 JP 2008508864 A JP2008508864 A JP 2008508864A JP 2008508864 A JP2008508864 A JP 2008508864A JP 4970427 B2 JP4970427 B2 JP 4970427B2
- Authority
- JP
- Japan
- Prior art keywords
- type zeolite
- adsorbent
- hydrogen
- zeolite powder
- adsorption
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
- B01J20/28004—Sorbent size or size distribution, e.g. particle size
- B01J20/28007—Sorbent size or size distribution, e.g. particle size with size in the range 1-100 nanometers, e.g. nanosized particles, nanofibers, nanotubes, nanowires or the like
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/30—Physical properties of adsorbents
- B01D2253/302—Dimensions
- B01D2253/304—Linear dimensions, e.g. particle shape, diameter
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/16—Hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/10—Single element gases other than halogens
- B01D2257/102—Nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/502—Carbon monoxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/702—Hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40013—Pressurization
- B01D2259/40015—Pressurization with two sub-steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40028—Depressurization
- B01D2259/40032—Depressurization with three sub-steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40058—Number of sequence steps, including sub-steps, per cycle
- B01D2259/40073—Ten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/406—Further details for adsorption processes and devices using more than four beds
- B01D2259/4067—Further details for adsorption processes and devices using more than four beds using ten beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/414—Further details for adsorption processes and devices using different types of adsorbents
- B01D2259/4141—Further details for adsorption processes and devices using different types of adsorbents within a single bed
- B01D2259/4145—Further details for adsorption processes and devices using different types of adsorbents within a single bed arranged in series
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/042—Purification by adsorption on solids
- C01B2203/043—Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/047—Composition of the impurity the impurity being carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/048—Composition of the impurity the impurity being an organic compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Separation Of Gases By Adsorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Separation By Low-Temperature Treatments (AREA)
Description
本発明は、一酸化炭素、それに加えて二酸化炭素、窒素、および、C1〜C8炭化水素から選択される少なくとも1種のその他の不純物などの様々な不純物によって汚染された水素ベースのガス混合物の精製方法に関する。
不純物としてCO、CO2、CH4、NH3、H2S、N2および水を含む水素ベースのガス混合物からの水素の製造に関して、US3,430,418は、二種の吸着剤の組み合わせを提供しており、第一の吸着剤は、CH4、CO2および水を除去する活性炭であり、第二の吸着剤は、窒素および一酸化炭素の除去を可能にする、カルシウムを含むA型ゼオライトである。
US3,078,639は、X型ゼオライトを用いて、水素が豊富なガス状混合物からCO2を除去する方法を開示している。
US6,773,694B1は、様々な分子篩の合成方法を開示しており、ここで、種結晶のスラリーは、骨格の栄養素(nutrients)または源、例えばアルミニウムおよびケイ素の添加によって成長させられている。栄養素の添加速度は、結晶成長速度と実質的に同じになるように、さらに、実質的に新しい結晶の核の形成が起こらないように制御される。
本発明は、水素の分離および精製方法、具体的にはPSA法において、特定の粒度分布を有するX型ゼオライト吸着剤を使用すると、水素の生産性と回収において予想外かつ有意な増加が生じるという発見に基づく。生産性という用語は、時間および体積あたりの、または、吸着剤の重量あたりの生産された水素の体積の比率を意味する。回収という用語は、生産された水素と、供給ガス中の水素との比率を意味する。
本発明の上記およびその他の目的、実施態様および詳細は、発明の詳細な説明から明確になるであろう。
本発明の一実施態様によれば、一酸化炭素によって汚染され、さらに二酸化炭素およびC1〜C8炭化水素からなる群より選択される少なくとも1種のその他の不純物を含むガス状の混合物に含まれる水素の分離は、ガス混合物を、二酸化炭素およびC1〜C8炭化水素の除去に選択的な少なくとも1種の第一の吸着剤、および、一酸化炭素および窒素の除去のためのX型ゼオライトを包含する第二の吸着剤、と接触させることを含み、ここで、X型ゼオライトの粒度分布は、15%〜30%の変動係数を有する。
図3に示したデータは、以下のようにして得られた。圧力スイング吸着(PSA)パイロットプラントを選択し、これを用いて、複数の吸着床を利用する大規模な工業的な水素精製システムを模擬した。このパイロットプラントは、単一の吸着器、および、複数の均等化タンク(異なるサイクル工程からのガスを保存するために使用される)からなる。円柱形の吸着床は、直径38mm、および、高さ3048mmを有していた。
Claims (10)
- 不純物によって汚染されたガス混合物に含まれる水素の分離および精製方法であって、精製しようとするガス混合物を、X型ゼオライトの粉末から形成された吸着剤凝集粒子を含む吸着領域に接触させることを含み、ここで、X型ゼオライトの粉末の粒度分布は、15%〜30%の変動係数を有する、前記方法。
- 前記精製しようとするガス混合物が、50パーセントより多いガス状の水素を含む、請求項1に記載の方法。
- 前記吸着領域が、790kPa〜7000kPaの圧力下で維持される、請求項1または2に記載の方法。
- 前記X型ゼオライトの粉末のシリカ/アルミナ比が、2.0〜2.5である、請求項1〜3のいずれか一項に記載の方法。
- 前記X型ゼオライト粉末の平均直径が、4〜12ミクロンの範囲である、請求項1〜4のいずれか一項に記載の方法。
- 前記X型ゼオライト粉末の平均直径が、6〜10ミクロンの範囲である、請求項1〜5のいずれか一項に記載の方法。
- 圧力スイング吸着システムが利用される、請求項1〜6のいずれか一項に記載の方法。
- 反応条件下で種結晶のスラリーを提供すること;種結晶を成長させるための種結晶の骨格の要素を提供するために、該スラリーに栄養素を添加すること;該添加を、実質的に結晶成長速度に等しい速度、および、X型ゼオライトの粉末が製造されるのに十分な時間で行うこと、によって、前記X型ゼオライトの粉末が合成される、請求項1〜7のいずれか一項に記載の方法。
- 前記圧力スイング吸着システムが、790kPa〜7000kPaの圧力下で維持される、請求項7に記載の方法。
- 前記吸着剤は、バルクで960kPaより大きい粉砕強さを有する、請求項1〜9のいずれか一項に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/114,285 | 2005-04-26 | ||
US11/114,285 US7399341B2 (en) | 2005-04-26 | 2005-04-26 | Gas purification process |
PCT/US2006/011409 WO2006115678A2 (en) | 2005-04-26 | 2006-03-29 | Gas purification process |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2008539158A JP2008539158A (ja) | 2008-11-13 |
JP4970427B2 true JP4970427B2 (ja) | 2012-07-04 |
Family
ID=37185494
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2008508864A Expired - Fee Related JP4970427B2 (ja) | 2005-04-26 | 2006-03-29 | ガスの精製方法 |
Country Status (11)
Country | Link |
---|---|
US (1) | US7399341B2 (ja) |
EP (1) | EP1874438B1 (ja) |
JP (1) | JP4970427B2 (ja) |
AT (1) | ATE543781T1 (ja) |
CA (1) | CA2602043C (ja) |
MX (1) | MX2007012900A (ja) |
NO (1) | NO20076048L (ja) |
PL (1) | PL1874438T3 (ja) |
RU (1) | RU2401799C2 (ja) |
TW (1) | TWI382956B (ja) |
WO (1) | WO2006115678A2 (ja) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101342773B1 (ko) | 2006-10-20 | 2013-12-19 | 에아.워타 가부시키가이샤 | 비열용융성 입상 페놀 수지 및 그 제조 방법, 그리고 열경화성 수지 조성물, 반도체용 밀봉재 및 반도체용 접착제 |
JP5496448B2 (ja) * | 2007-09-27 | 2014-05-21 | エア・ウォーター・ベルパール株式会社 | 分子ふるい炭素およびその製造方法、ならびに窒素発生装置 |
FR2936507B1 (fr) * | 2008-09-29 | 2011-04-08 | Inst Francais Du Petrole | Procede de production d'hydrogene avec captation totale du co2 et recyclage du methane non converti |
JP5487483B2 (ja) * | 2009-03-06 | 2014-05-07 | 国立大学法人横浜国立大学 | 吸着材 |
US8992884B2 (en) * | 2009-11-30 | 2015-03-31 | Chevron U.S.A. Inc. | Preparation of X zeolite |
US20110126709A1 (en) * | 2009-12-02 | 2011-06-02 | Uop Llc | Use of calcium exchanged x-type zeolite for improvement of refinery off-gas pressure swing adsorption |
US8853475B2 (en) | 2010-12-15 | 2014-10-07 | Uop Llc | Process for producing a renewable hydrocarbon fuel |
US8764855B2 (en) | 2010-12-15 | 2014-07-01 | Uop Llc | Process for producing a biofuel while minimizing fossil fuel derived carbon dioxide emissions |
US8435328B2 (en) | 2011-01-11 | 2013-05-07 | Praxair Technology, Inc. | Ten bed pressure swing adsorption process operating in normal and turndown modes |
US8551217B2 (en) | 2011-01-11 | 2013-10-08 | Praxair Technology, Inc. | Six bed pressure swing adsorption process operating in normal and turndown modes |
US8491704B2 (en) | 2011-01-11 | 2013-07-23 | Praxair Technology, Inc. | Six bed pressure swing adsorption process operating in normal and turndown modes |
US8496733B2 (en) | 2011-01-11 | 2013-07-30 | Praxair Technology, Inc. | Large scale pressure swing adsorption systems having process cycles operating in normal and turndown modes |
US8394171B2 (en) | 2011-03-17 | 2013-03-12 | Uop Llc | Methods for controlling impurity buildup on adsorbent for pressure swing adsorption processes |
FR2979253B1 (fr) * | 2011-08-26 | 2014-07-25 | IFP Energies Nouvelles | Procede et dispositif de separation par adsorption modulee en pression du dioxyde de carbone contenu dans le flux de sortie d'une unite de reformage a la vapeur |
US9533280B2 (en) * | 2012-06-22 | 2017-01-03 | Praxair Technology, Inc. | High rate compositions |
US9381460B2 (en) | 2014-09-11 | 2016-07-05 | Air Products And Chemicals, Inc. | Pressure swing adsorption process |
JP6697014B2 (ja) * | 2018-02-09 | 2020-05-20 | Jxtgエネルギー株式会社 | 圧力スイング吸着(psa)装置及び圧力スイング吸着方法 |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2882244A (en) * | 1953-12-24 | 1959-04-14 | Union Carbide Corp | Molecular sieve adsorbents |
US3078639A (en) * | 1960-01-06 | 1963-02-26 | Union Carbide Corp | Carbon dioxide removal from vapor mixtures |
US3430418A (en) * | 1967-08-09 | 1969-03-04 | Union Carbide Corp | Selective adsorption process |
JPS5324038B2 (ja) * | 1973-06-29 | 1978-07-18 | ||
US4194891A (en) * | 1978-12-27 | 1980-03-25 | Union Carbide Corporation | Multiple bed rapid pressure swing adsorption for oxygen |
US4381189A (en) * | 1981-10-27 | 1983-04-26 | Union Carbide Corporation | Pressure swing adsorption process and system |
DE3143993A1 (de) * | 1981-11-05 | 1983-05-11 | Bayer Ag, 5090 Leverkusen | Molekularsieb-zeolith fuer die gewinnung von wasserstoff mit der druckwechsel-adsorptions-technik |
US6180549B1 (en) * | 1998-09-10 | 2001-01-30 | The B. F. Goodrich Company | Modified zeolites and methods of making thereof |
US6656447B1 (en) * | 1998-12-29 | 2003-12-02 | Uop Llc | Process for synthesizing and controlling the particle size and particle size distribution of a molecular sieve |
CA2274388A1 (en) * | 1999-06-10 | 2000-12-10 | Bowie Keefer | Surge adsorber flow regulation for modular pressure swing adsorption |
US6340382B1 (en) * | 1999-08-13 | 2002-01-22 | Mohamed Safdar Allie Baksh | Pressure swing adsorption process for the production of hydrogen |
US6773694B1 (en) * | 1999-12-22 | 2004-08-10 | Uop Llc | Process for synthesizing molecular sieves |
DE60129626T2 (de) * | 2000-04-20 | 2008-05-21 | Tosoh Corp., Shinnanyo | Verfahren zum Reinigen von einem Wasserstoff enthaltenden Gasgemisch |
JP4686889B2 (ja) * | 2000-04-20 | 2011-05-25 | 東ソー株式会社 | 水素ガスの精製方法 |
US6409800B1 (en) * | 2000-08-28 | 2002-06-25 | The Boc Group, Inc. | Temperature swing adsorption process |
US6773693B2 (en) * | 2000-12-28 | 2004-08-10 | Kao Corporation | Fine zeolite particle |
TW541200B (en) * | 2001-04-04 | 2003-07-11 | Kuraray Chemical Kk | Filter element, process for producing it and filter using the element |
US6471744B1 (en) * | 2001-08-16 | 2002-10-29 | Sequal Technologies, Inc. | Vacuum-pressure swing absorption fractionator and method of using the same |
CN100581645C (zh) * | 2002-12-24 | 2010-01-20 | 普莱克斯技术有限公司 | 氢气提纯用工艺和装置 |
DE10333156A1 (de) * | 2003-07-22 | 2005-02-24 | H.C. Starck Gmbh | Verfahren zur Herstellung von Niobsuboxid |
DE10356184A1 (de) * | 2003-12-02 | 2005-07-07 | Basf Ag | Zeolithisches Material vom Pentasil-Strukturtyp, seine Herstellung und seine Verwendung |
-
2005
- 2005-04-26 US US11/114,285 patent/US7399341B2/en not_active Expired - Fee Related
-
2006
- 2006-03-29 CA CA2602043A patent/CA2602043C/en not_active Expired - Fee Related
- 2006-03-29 JP JP2008508864A patent/JP4970427B2/ja not_active Expired - Fee Related
- 2006-03-29 EP EP06758219A patent/EP1874438B1/en not_active Not-in-force
- 2006-03-29 AT AT06758219T patent/ATE543781T1/de active
- 2006-03-29 PL PL06758219T patent/PL1874438T3/pl unknown
- 2006-03-29 WO PCT/US2006/011409 patent/WO2006115678A2/en active Application Filing
- 2006-03-29 MX MX2007012900A patent/MX2007012900A/es active IP Right Grant
- 2006-03-29 RU RU2007143482/05A patent/RU2401799C2/ru not_active IP Right Cessation
- 2006-04-14 TW TW095113555A patent/TWI382956B/zh not_active IP Right Cessation
-
2007
- 2007-11-23 NO NO20076048A patent/NO20076048L/no not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
MX2007012900A (es) | 2007-12-11 |
RU2007143482A (ru) | 2009-06-10 |
CA2602043A1 (en) | 2006-11-02 |
JP2008539158A (ja) | 2008-11-13 |
WO2006115678A2 (en) | 2006-11-02 |
EP1874438A2 (en) | 2008-01-09 |
RU2401799C2 (ru) | 2010-10-20 |
EP1874438B1 (en) | 2012-02-01 |
PL1874438T3 (pl) | 2012-07-31 |
US20060236861A1 (en) | 2006-10-26 |
CA2602043C (en) | 2013-04-30 |
EP1874438A4 (en) | 2010-09-22 |
WO2006115678A3 (en) | 2009-04-16 |
ATE543781T1 (de) | 2012-02-15 |
TW200700311A (en) | 2007-01-01 |
US7399341B2 (en) | 2008-07-15 |
NO20076048L (no) | 2007-11-23 |
TWI382956B (zh) | 2013-01-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP4970427B2 (ja) | ガスの精製方法 | |
US6849106B2 (en) | Method for purifying hydrogen-based gas mixtures using a calcium x-zeolite | |
US5912422A (en) | Method for purifying hydrogen based gas mixture using a lithium- exchanged X zeolite | |
KR100966064B1 (ko) | 합성가스 정제 방법 | |
US6402813B2 (en) | Process for purifying a gas by adsorption of the impurities on several active carbons | |
KR100896455B1 (ko) | 압력변동흡착장치 및 이를 이용한 수소 정제 방법 | |
US6616732B1 (en) | Zeolite adsorbents, method for obtaining them and their use for removing carbonates from a gas stream | |
EP0489555A1 (en) | Hydrogen and carbon monoxide production by hydrocarbon steam reforming and pressure swing adsorption purification | |
US6478854B1 (en) | High purity, low silica X-type zeolite binderless shaped product and gas separation method employing it | |
PL206938B1 (pl) | Zmiennociśnieniowy adsorpcyjny sposób oddzielania azotu od jego mieszaniny z metanem | |
JPH046642B2 (ja) | ||
TWI629099B (zh) | 改性的菱沸石吸附劑組合物、其製造及使用方法 | |
AU784559B2 (en) | adsorption processes | |
TWI629235B (zh) | 改性的菱沸石吸附劑組合物、其製造及使用方法 | |
US6027549A (en) | Adjusted density carbon for hydrogen PSA | |
US3078638A (en) | Carbon dioxide removal from vapor mixtures | |
WO2002051524A1 (fr) | Procede de separation de gaz hydrogene | |
CA3095357C (en) | Rate/kinetic selective multiple bed adsorption process cycle | |
WO2022043789A1 (en) | Ethylene separations using small pore zeolite ssz-45 | |
JPS59179127A (ja) | 低温、低圧条件下での混合気体からの酸素及び窒素の分離方法 | |
US11465122B2 (en) | Potassium-merlinoite zeolite, its synthesis and use | |
KR20100085285A (ko) | 수소가스 정제방법(ⅰ) |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20081202 |
|
RD04 | Notification of resignation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7424 Effective date: 20110913 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20111027 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20111118 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20120209 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20120312 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20120404 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20150413 Year of fee payment: 3 |
|
R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
LAPS | Cancellation because of no payment of annual fees |