JP4870839B2 - ブロックコポリマー修飾型の植物油とポリマーの混合物、ならびにその製造方法 - Google Patents
ブロックコポリマー修飾型の植物油とポリマーの混合物、ならびにその製造方法 Download PDFInfo
- Publication number
- JP4870839B2 JP4870839B2 JP2010539634A JP2010539634A JP4870839B2 JP 4870839 B2 JP4870839 B2 JP 4870839B2 JP 2010539634 A JP2010539634 A JP 2010539634A JP 2010539634 A JP2010539634 A JP 2010539634A JP 4870839 B2 JP4870839 B2 JP 4870839B2
- Authority
- JP
- Japan
- Prior art keywords
- polylactide
- vegetable oil
- composition
- block copolymer
- homopolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 235000015112 vegetable and seed oil Nutrition 0.000 title claims description 51
- 239000008158 vegetable oil Substances 0.000 title claims description 51
- 229920001400 block copolymer Polymers 0.000 title claims description 37
- 238000000034 method Methods 0.000 title claims description 11
- 229920002959 polymer blend Polymers 0.000 title 1
- 239000000203 mixture Substances 0.000 claims description 60
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 57
- 229920001519 homopolymer Polymers 0.000 claims description 26
- 229920001432 poly(L-lactide) Polymers 0.000 claims description 21
- 239000006185 dispersion Substances 0.000 claims description 13
- 229920000642 polymer Polymers 0.000 claims description 12
- 239000000839 emulsion Substances 0.000 claims description 9
- 235000012424 soybean oil Nutrition 0.000 claims description 8
- 239000003549 soybean oil Substances 0.000 claims description 8
- 239000011159 matrix material Substances 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 229920003232 aliphatic polyester Polymers 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- JJTUDXZGHPGLLC-IMJSIDKUSA-N 4511-42-6 Chemical compound C[C@@H]1OC(=O)[C@H](C)OC1=O JJTUDXZGHPGLLC-IMJSIDKUSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- 239000003708 ampul Substances 0.000 description 1
- 230000002051 biphasic effect Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000006735 epoxidation reaction Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- -1 lamellar structures Substances 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- XBGNERSKEKDZDS-UHFFFAOYSA-N n-[2-(dimethylamino)ethyl]acridine-4-carboxamide Chemical compound C1=CC=C2N=C3C(C(=O)NCCN(C)C)=CC=CC3=CC2=C1 XBGNERSKEKDZDS-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0016—Plasticisers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
- C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Biological Depolymerization Polymers (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Colloid Chemistry (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/957,559 | 2007-12-17 | ||
| US11/957,559 US7888418B2 (en) | 2007-12-17 | 2007-12-17 | Block copolymer modified vegetable oil and polymer blends and methods of making same |
| PCT/US2008/086320 WO2009079313A1 (en) | 2007-12-17 | 2008-12-11 | Block copolymer modified vegetable oil and polymer blends and methods of making same |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2011506752A JP2011506752A (ja) | 2011-03-03 |
| JP2011506752A5 JP2011506752A5 (enExample) | 2011-06-30 |
| JP4870839B2 true JP4870839B2 (ja) | 2012-02-08 |
Family
ID=40754106
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010539634A Expired - Fee Related JP4870839B2 (ja) | 2007-12-17 | 2008-12-11 | ブロックコポリマー修飾型の植物油とポリマーの混合物、ならびにその製造方法 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US7888418B2 (enExample) |
| EP (1) | EP2227320B1 (enExample) |
| JP (1) | JP4870839B2 (enExample) |
| WO (1) | WO2009079313A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10160857B2 (en) | 2014-11-05 | 2018-12-25 | Samsung Electronics Co., Ltd. | Thermoplastic resin composition and molded article made therefrom |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8231804B2 (en) | 2008-12-10 | 2012-07-31 | Syntroleum Corporation | Even carbon number paraffin composition and method of manufacturing same |
| CN103454100A (zh) * | 2012-06-04 | 2013-12-18 | 北京宇航系统工程研究所 | 蒙皮加筋圆柱壳结构弯曲等效刚度获取方法 |
| US20150005551A1 (en) * | 2013-07-01 | 2015-01-01 | Syntroleum Corporation | Method of processing adulterated biomass feedstocks |
| CN106280165B (zh) * | 2016-08-31 | 2021-07-13 | 黑龙江省森林保护研究所 | 高分子阻火灭火凝胶及其制备方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5922832A (en) * | 1995-01-19 | 1999-07-13 | Cargill, Incorporated | Impact modified melt-stable lactide polymer compositions and processes for manufacture thereof |
| US20030216496A1 (en) * | 2002-05-10 | 2003-11-20 | Mohanty Amar Kumar | Environmentally friendly polylactide-based composite formulations |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4369284A (en) | 1977-03-17 | 1983-01-18 | Applied Elastomerics, Incorporated | Thermoplastic elastomer gelatinous compositions |
| US5557037A (en) | 1989-12-05 | 1996-09-17 | Iowa State University Research Foundation, Inc. | Soybeans having elevated contents of saturated fatty acids |
| DE69125965T2 (de) | 1990-02-28 | 1997-09-25 | Agency Ind Science Techn | Verfahren zur Herstellung eines bioabbaubaren, formbaren Materials |
| JPH04132796A (ja) | 1990-09-26 | 1992-05-07 | Mitsubishi Kakoki Kaisha Ltd | 植物油の製造方法 |
| US5407715A (en) | 1990-11-28 | 1995-04-18 | Tactyl Technologies, Inc. | Elastomeric triblock copolymer compositions and articles made therewith |
| US5359026A (en) | 1993-07-30 | 1994-10-25 | Cargill, Incorporated | Poly(lactide) copolymer and process for manufacture thereof |
| SE504664C2 (sv) | 1995-09-22 | 1997-03-24 | Scotia Lipidteknik Ab | Sätt att framställa fraktionerad olja, oljan, dess användning samt emulsionskomposition innehållande oljan |
| US5869164A (en) | 1995-11-08 | 1999-02-09 | Rik Medical Llc | Pressure-compensating compositions and pads made therefrom |
| ZA973565B (en) | 1996-04-26 | 1998-10-26 | Du Pont | Soybean oil having high oxidative stability |
| US5858934A (en) | 1996-05-08 | 1999-01-12 | The Lubrizol Corporation | Enhanced biodegradable vegetable oil grease |
| US5756651A (en) | 1996-07-17 | 1998-05-26 | Chronopol, Inc. | Impact modified polylactide |
| US5916950A (en) | 1996-07-26 | 1999-06-29 | Mitsui Chemicals, Inc. | Resin composition and molded articles thereof |
| US6103834A (en) | 1998-10-13 | 2000-08-15 | Espinoza; Abel M. | Polymer composition derived from unsaturated vegetable oils |
| US20030088003A1 (en) | 2000-06-16 | 2003-05-08 | The Procter & Gamble Company | Thermoplastic hydrophilic polymeric compositions with high water solubility component |
| US20030049320A1 (en) | 2000-12-18 | 2003-03-13 | Wockhardt Limited | Novel in-situ forming controlled release microcarrier delivery system |
| JP3742842B2 (ja) | 2002-06-17 | 2006-02-08 | 独立行政法人産業技術総合研究所 | 生分解性ポリ乳酸樹脂組成物 |
| US7256223B2 (en) | 2002-11-26 | 2007-08-14 | Michigan State University, Board Of Trustees | Environmentally friendly polylactide-based composite formulations |
| CA2509087C (en) | 2003-01-08 | 2013-03-12 | Texas Tech University | Castor oil/epoxidized soybean oil based elastomeric compositions |
| MX2007000022A (es) | 2004-06-25 | 2007-05-23 | Pittsburg State University | Polioles basados en aceite vegetal modificado. |
| US20060036107A1 (en) | 2004-08-13 | 2006-02-16 | Casper David M | Method for producing soy bean oil diols |
| US20060121170A1 (en) | 2004-12-06 | 2006-06-08 | Howard David L | Rubbery gels made from vegetable oils |
| WO2006074815A1 (de) | 2005-01-12 | 2006-07-20 | Basf Aktiengesellschaft | Biologisch abbaubare polyestermischung |
| US7662753B2 (en) | 2005-05-12 | 2010-02-16 | Halliburton Energy Services, Inc. | Degradable surfactants and methods for use |
| US7691946B2 (en) | 2005-09-30 | 2010-04-06 | The United States Of America As Represented By The Secretary Of Agriculture | Soy-based thermosensitive hydrogels for controlled release systems |
-
2007
- 2007-12-17 US US11/957,559 patent/US7888418B2/en not_active Expired - Fee Related
-
2008
- 2008-12-11 JP JP2010539634A patent/JP4870839B2/ja not_active Expired - Fee Related
- 2008-12-11 EP EP08861655A patent/EP2227320B1/en not_active Not-in-force
- 2008-12-11 WO PCT/US2008/086320 patent/WO2009079313A1/en not_active Ceased
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5922832A (en) * | 1995-01-19 | 1999-07-13 | Cargill, Incorporated | Impact modified melt-stable lactide polymer compositions and processes for manufacture thereof |
| US20030216496A1 (en) * | 2002-05-10 | 2003-11-20 | Mohanty Amar Kumar | Environmentally friendly polylactide-based composite formulations |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10160857B2 (en) | 2014-11-05 | 2018-12-25 | Samsung Electronics Co., Ltd. | Thermoplastic resin composition and molded article made therefrom |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2227320B1 (en) | 2012-08-29 |
| WO2009079313A1 (en) | 2009-06-25 |
| JP2011506752A (ja) | 2011-03-03 |
| EP2227320A4 (en) | 2011-05-04 |
| US7888418B2 (en) | 2011-02-15 |
| US20090156746A1 (en) | 2009-06-18 |
| EP2227320A1 (en) | 2010-09-15 |
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