JP4776766B2 - Method for manufacturing semiconductor device - Google Patents

Description

[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a semiconductor device having a circuit formed of a thin film transistor (hereinafter referred to as TFT) and a method for manufacturing the semiconductor device. For example, the present invention relates to an electro-optical device typified by a liquid crystal display panel and an electronic apparatus in which such an electro-optical device is mounted as a component.
[0002]
Note that in this specification, a semiconductor device refers to all devices that can function by utilizing semiconductor characteristics, and an electro-optical device, a semiconductor circuit, and an electronic device are all semiconductor devices.
[0003]
[Prior art]
Thin film transistors (hereinafter referred to as thin film transistors) in which an amorphous semiconductor film is formed on a light-transmitting insulating substrate such as glass and the active layer is a crystalline semiconductor film crystallized by laser annealing or thermal annealing. , Written as TFT). As the insulating substrate, a glass substrate such as barium borosilicate glass or alumino borosilicate glass is often used. Although such a glass substrate is inferior in heat resistance to a quartz substrate, but has a low commercial price, it has an advantage that a large-area substrate can be easily manufactured.
[0004]
The laser annealing method is known as a crystallization technique that does not raise the temperature of a glass substrate so much and can crystallize only an amorphous semiconductor film by applying high energy. In particular, an excimer laser capable of obtaining a large output in a short wavelength region is considered most suitable for this application. In the laser annealing method using an excimer laser, a laser beam is processed by an optical system so as to be spot-like or linear on the irradiated surface, and the irradiated surface is scanned with the processed laser light (laser light irradiation). The irradiation position is moved relative to the irradiated surface). For example, the excimer laser annealing method using linear laser light can also perform laser annealing of the entire irradiated surface by scanning only in the direction perpendicular to the longitudinal direction, and is excellent in productivity. It is becoming mainstream as a display device manufacturing technology.
[0005]
Laser annealing can be applied to crystallization of various semiconductor materials. However, so far, a high field effect mobility has been realized by using a crystalline silicon film for the active layer of the TFT. The technology is a monolithic device in which a pixel TFT for forming a pixel portion on a single glass substrate and a TFT for a drive circuit provided around the pixel portion are formed. Rishi A liquid crystal display device of the same type was made possible.
[0006]
However, the crystalline silicon film produced by the laser annealing method is formed in a form in which a plurality of crystal grains are aggregated, and the position and size of the crystal grains are random. Therefore, it has not been possible to specify the position and size of the crystal grains. At the crystal grain interface (grain boundary), carrier current transport characteristics due to recombination centers, trap centers, and potential levels at the grain boundaries due to amorphous structures and crystal defects. The There was a cause to reduce. However, it has been almost impossible to form a channel formation region in which the properties of the crystal have a significant influence on the characteristics of the TFT with a single crystal grain, excluding the influence of the grain boundary. For this reason, TFTs having a crystalline silicon film as an active layer have not been obtained to date with characteristics equivalent to those of MOS transistors fabricated on a single crystal silicon substrate.
[0007]
As a method for solving such a problem, it can be considered as an effective means to eliminate the crystal grain boundary from the channel formation region by increasing the crystal grain and controlling the position of the crystal grain. For example, "" Location Control of Large Grain Flowing Excimer-Laser Melting of Si Thin-Films ", R. Ishihara and A. Burtsev, Japan p. 3A. Boursev, Japan. . 1071-1075,19 9 No. 8 "discloses a method for controlling the position of crystals and increasing the grain size by controlling the temperature distribution of the silicon film three-dimensionally. According to the method, a refractory metal film is formed on a glass substrate, a silicon oxide film having a different thickness is partially formed thereon, and both surfaces of the substrate on which an amorphous silicon film is formed are formed. It is reported that the crystal grain size can be increased to several μm by irradiating excimer laser light.
[0008]
[Problems to be solved by the invention]
The method of Ishihara et al. Is characterized in that the thermal characteristics of the underlying material of the amorphous silicon film are locally changed to control the flow of heat to the substrate so as to have a temperature gradient. However, for this purpose, a three-layer structure of a refractory metal layer / silicon oxide layer / semiconductor film is formed on a glass substrate. Although it is structurally possible to form a top gate TFT using this semiconductor film as an active layer, a parasitic capacitance is generated by the silicon oxide film provided between the semiconductor film and the refractory metal layer. As a result, power consumption increases and it is difficult to realize high-speed operation of the TFT.
[0009]
On the other hand, it is considered that the method of Ishihara et al. Can be effectively applied to a bottom gate type or an inverted stagger type TFT by using a refractory metal layer as a gate electrode. However, in the three-layer structure, even if the thickness of the semiconductor film is excluded, the film thickness of the refractory metal layer and the silicon oxide layer is suitable for the film thickness suitable for the crystallization process and the characteristics as the TFT element. Since the film thickness does not always match, both the optimum design in the crystallization process and the optimum design of the element structure cannot be satisfied at the same time.
[0010]
Further, when a refractory metal layer having no translucency is formed on the entire surface of the glass substrate, it is impossible to manufacture a transmissive liquid crystal display device. Although the refractory metal layer is useful in terms of high thermal conductivity, the chromium (Cr) film and the titanium (Ti) film used as the refractory metal material have high internal stress, so the adhesion to the glass substrate There is a high possibility of problems. Further, the influence of the internal stress extends to the semiconductor film formed in the upper layer, and there is a high possibility that it acts as a force that distorts the formed crystalline semiconductor film.
[0011]
On the other hand, in order to control the threshold voltage (hereinafter referred to as Vth), which is an important characteristic parameter in the TFT, within a predetermined range, in addition to controlling the valence electrons in the channel formation region, It was necessary to reduce the charge defect density of the base film and gate insulating film formed of the insulating film and to consider the balance of internal stress. In response to such a demand, a material containing silicon as a constituent element, such as a silicon oxide film or a silicon oxynitride film, was suitable. Therefore, there is a concern that the provision of the refractory metal layer to give a temperature gradient will break the balance.
[0012]
The present invention is a technique for solving such problems. A crystalline semiconductor film in which the position and size of crystal grains are controlled is produced, and the crystalline semiconductor film is used as a channel formation region of a TFT. As a result, a TFT capable of high-speed operation is realized. It is another object of the present invention to provide a technique that can apply such a TFT to various semiconductor devices such as a transmissive liquid crystal display device and an EL display device.
[0013]
[Means for Solving the Problems]
The configuration of the invention disclosed in this specification is as follows.
An organic resin film having a predetermined shape in contact with the light-transmitting substrate;
An inorganic insulating film covering the organic resin film;
A crystalline semiconductor film in contact with the inorganic insulating film;
The semiconductor device is characterized in that the crystalline semiconductor film exists above the organic resin film through the inorganic insulating film.
[0014]
The inorganic insulating film is a single layer film selected from a silicon oxide film, a silicon nitride film, and a silicon oxynitride film, or a laminated film thereof, and has a thickness of 50 nm to 200 nm.
[0015]
As another configuration of the invention, a base insulating film may be provided between the substrate and the organic resin film.
[0016]
The organic resin film is made of BCB (benzocyclobutene) resin, polyimide resin (fluorine-added polyimide), acrylic resin, siloxane resin, fluorine-added paraxylene, fluorine-added parylene, Teflon, fluoropolyallyl ether, PFCB. , A single layer film selected from polysilazane, or a laminated film thereof, and the thermal conductivity of the organic resin film is 1.0 Wm ^-1 K ^-1 It is characterized by the following.
[0017]
Further, it is preferable that the organic resin film has photosensitivity because patterning can be easily performed.
[0018]
The configuration of the invention for realizing the above structure is as follows.
After forming an organic resin film on a substrate having translucency, the organic resin film is patterned into a predetermined shape,
Forming an inorganic insulating film covering the organic resin film having the predetermined shape;
Forming an amorphous semiconductor film in contact with the inorganic insulating film;
By irradiating the amorphous semiconductor film with laser light, a crystalline semiconductor film having a first region and a second region having a crystal grain size different from that of the first region is formed. It is a manufacturing method of an apparatus.
[0019]
The crystal grain size in the first region is larger than the crystal grain size in the second region.
[0020]
The first region is a region having the organic resin film below the crystalline semiconductor film with the inorganic insulating film interposed therebetween. The second region is a region of the crystalline semiconductor film that does not have the organic resin film below the inorganic insulating film with the inorganic insulating film interposed therebetween.
[0021]
If the first region is used as a channel formation region of a TFT, a TFT having excellent TFT characteristics can be obtained.
[0022]
In addition, the configuration of other inventions is as follows:
Form an organic resin film in contact with the substrate having translucency,
Forming an inorganic insulating film covering the organic resin film;
Forming an amorphous semiconductor film in contact with the inorganic insulating film;
A method for manufacturing a semiconductor device is characterized in that a crystalline semiconductor film is formed by crystallizing the amorphous semiconductor film by laser irradiation.
[0023]
In the above manufacturing method, the inorganic insulating film and the amorphous semiconductor film may be continuously formed without being exposed to the air.
[0024]
Moreover, in the said manufacturing method, the said laser beam may be irradiated from the surface side of the said board | substrate, and may be irradiated simultaneously from the surface side and the back surface side of the said board | substrate.
[0025]
DETAILED DESCRIPTION OF THE INVENTION
Embodiments of the present invention will be described below.
[0026]
In the conventional formation of a polysilicon film by laser crystallization, the inventors of the present invention have the reason that the crystal grain size is small because the cooling rate of the silicon layer after melting is high, the nucleation density increases, and one crystal nucleus It was thought that this was because sufficient crystal growth was inhibited. Therefore, the present inventors suppress the thermal diffusion from the upper silicon layer to the lower silicon oxide layer and the substrate when changing to the solid phase, and reduce the cooling rate of the silicon layer after melting to reduce the particle size. I thought it was possible to form large crystals.
[0027]
In the present invention, as shown in FIG. 1, an organic resin film 2 is selectively formed on a substrate 1 having an insulating surface, an inorganic insulating film 3 containing silicon is formed in contact with the organic resin film 2, and After obtaining a state in which an amorphous semiconductor film is formed, crystallization is performed by a laser annealing method.
[0028]
In the laser annealing method, the semiconductor film is heated and melted by optimizing the condition of the laser beam (or laser beam) to be irradiated, and the generation density of crystal nuclei and the crystal growth from the crystal nuclei are controlled.
[0029]
In FIG. 1, a region A distinguished by a broken line indicates a region having the organic resin film 2 between the substrate 1 and the inorganic insulating film 3, and a semiconductor film located in the region A is called a first region 4a. The region B refers to a region that does not have the organic resin film 2 between the substrate 1 and the inorganic insulating film 3, and a semiconductor film located in the region B is referred to as a second region 4b.
[0030]
FIG. 18 is a diagram showing an example of the configuration of a laser annealing apparatus. An excimer laser, an argon laser, a YAG laser, or the like is applied to the laser light generator 801. However, the second harmonic may be used in the YAG laser. The laser beam emitted from the laser beam generator 801 is spread in one direction by beam expanders 802 and 803, and the laser beam reflected by the mirror 804 is divided by the cylindrical lens array 805, and the cylindrical lenses 806 and 807 A linear beam having a line width of 100 to 1000 μm is irradiated so as to form an irradiation region 810 on the sample surface. substrate 8 08 is held on a stage 809 operable in the X direction, Y direction, and Θ direction. Then, laser annealing can be performed over the entire surface of the substrate 808 by moving the stage 809 with respect to the irradiation region 810. At this time, the substrate 808 may be held in an air atmosphere, or may be crystallized under a reduced pressure or in an inert gas atmosphere.
[0031]
In the laser annealing method, in particular, an excimer laser that emits laser light having a wavelength of 400 nm or less is used as a light source because the semiconductor film can be preferentially heated, which is suitable. Since the pulse width of the excimer laser is several nsec to several tens of nsec, for example, 30 nsec, when irradiated with a pulse oscillation frequency of 30 Hz, the semiconductor film is instantaneously heated by the pulse laser beam and cooled for a time much longer than the heating time. Will be. Immediately after the end of laser light irradiation, heat diffuses through the inorganic insulating film 2, so that the cooling of the region B starts more rapidly and changes to the solid state, whereas the organic resin film 3 exists in the region A. Therefore, compared with the region B, thermal diffusion from the semiconductor film to the substrate is suppressed, and the cooling rate is reduced.
[0032]
It is estimated that crystal nuclei are formed and formed in the cooling process from the molten state to the solid state, but the nucleation density correlates with the temperature of the molten state and the cooling rate, and is rapidly cooled from a high temperature. The tendency to increase the nucleation density has been obtained as empirical knowledge. Therefore, in the second region 4b (semiconductor film located in the region B) that is rapidly cooled from the molten state, the generation density of crystal nuclei is higher than that in the first region 4a (semiconductor film located in the region A), and randomly. The generation of crystal nuclei forms a plurality of crystal grains, and the grain size is relatively smaller than the crystal grains generated in the first region 4a. On the other hand, in the first region 4a, it is possible to control the temperature of the molten state and its cooling rate by optimizing the laser light irradiation conditions and the organic resin film 2 and the inorganic insulating film 3, and crystal nuclei. It is possible to grow a crystal having a large grain size by suppressing the number of occurrences of.
[0033]
As the substrate 1 having an insulating surface, a glass substrate such as barium borosilicate glass or alumino borosilicate glass, a quartz substrate, or the like can be used. However, the substrate 1 has translucency, is inexpensive, It is desirable to use a glass substrate in that an area substrate can be easily manufactured.
[0034]
The organic resin film 2 is similarly divided into islands or stripes in accordance with the arrangement of the TFT active layers (semiconductor film in which the channel formation region, the source region, the drain region, and the LDD region are formed) on the substrate. Form. The size is 0.35 × 0.35 μm according to the size of the TFT, for example. ² Submicron size (channel length x channel width) or 8 x 8 μm ² 8 × 200μm ² Or 12 × 400μm ² And so on. By forming the organic resin film 2 in accordance with at least the position and size of the channel formation region of the TFT, it is possible to form the channel formation region with a crystalline semiconductor film having a large crystal grain size formed thereon. Become.
[0035]
The organic resin film 2 has a thermal conductivity of 1.0 Wm. ^-1 K ^-1 Or less, preferably 0.3 Wm ^-1 K ^-1 If it is the following, it will not specifically limit. This organic resin film 2 has a thermal conductivity of a substrate (quartz glass: 1.4 Wm ^-1 K ^-1 ) And an inorganic insulating film containing silicon in contact with the organic resin film (1-2 Wm) ^-1 K ^-1 ), The thermal diffusion from the semiconductor film to the substrate is sufficiently suppressed.
[0036]
For example, as the organic resin film 2, BCB (benzocyclobutene) resin, polyimide resin (fluorine-added polyimide), acrylic resin, siloxane resin, fluorine-added paraxylene, fluorine-added parylene, Teflon, fluoropolyallyl ether, Examples thereof include PFCB and polysilazane. Among them, BCB (benzocyclobutene) resin having high heat resistance of about 450 ° C., plasma resistance and flatness is most preferable in the present invention.
[0037]
In addition, since the inorganic insulating film 3 and the amorphous semiconductor film are stacked on the organic resin film 2, it is desirable to form the organic resin film 2 by a spin coat method in which the surface is flat, and the end of the patterned organic resin film is tapered. As a shape, it is desirable to have good coverage. In addition, if an organic resin film is formed using a coating method typified by a spin coating method, the cost is much lower than that of an inorganic insulating film using a CVD apparatus, and it is advantageous because a complicated film forming process is not required. is there. In addition, if a photosensitive organic resin film is used also in terms of pattern processing, photolithography using a photoresist is not necessary, and the number of steps can be reduced. Further, even when the photosensitive organic resin film is not used, it is advantageous because the etching rate with the substrate and the base insulating film is easily secured and the controllability is high as compared with the etching of the inorganic insulating film.
[0038]
The film thickness of the organic resin film is preferably 100 nm to 500 nm. By adjusting this film thickness, the cooling rate in the crystallization step can be controlled. In addition, when it is set as a film thickness thinner than 100 nm, flatness will deteriorate. Further, when the film thickness is greater than 500 nm, it is difficult to form a laminated film because the step is too large.
[0039]
As the inorganic insulating film containing silicon, a single layer film selected from a silicon oxide film, a silicon nitride film, and a silicon oxynitride film by a PCVD method, an LPCVD method, or a sputtering method, or a stacked film thereof is appropriately used. be able to. This inorganic insulating film plays a role of preventing impurity diffusion from the substrate and the organic resin film and a function of improving the adhesion between the laminated semiconductor films. A substrate covered with a silicon oxide film using BCB resin (450 ° C.) as the organic resin film can withstand heat treatment at about 550 ° C. Thus, the inorganic insulating film plays the role of protecting the organic resin film and also has the effect of improving the heat resistance of the organic resin film.
[0040]
The film thickness of the inorganic insulating film containing silicon is 50 nm to 200 nm. When the thickness of the inorganic insulating film is greater than 200 nm, there is a high possibility that thermal diffusion from the semiconductor film to the substrate cannot be suppressed. Further, when the thickness of the inorganic insulating film is less than 50 nm, the coverage may be deteriorated and the organic resin film may not be covered.
[0041]
Further, as an amorphous semiconductor film formed over an inorganic insulating film containing silicon, there are an amorphous semiconductor film and a microcrystalline semiconductor film, and a compound semiconductor film having an amorphous structure such as an amorphous silicon germanium film. May be applied. As a method for forming the amorphous semiconductor film, a known method such as a PCVD method, an LPCVD method, or a sputtering method may be used.
[0042]
In the present invention, the crystal grain size can be controlled by adjusting the cooling rate according to the material and film thickness of the inorganic insulating film 3 or the material and film thickness of the organic resin film 2. The position of the crystal having a large grain size can be controlled by the arrangement.
[0043]
An example of manufacturing an island-shaped crystalline semiconductor film is briefly shown as an example of an embodiment of a manufacturing method of the present invention with reference to FIGS.
[0044]
First, an organic resin film is formed on a substrate 1 made of an alkali-free glass substrate or the like, and patterned to form an organic resin film 2 having a desired shape (island shape or stripe shape). (Fig. 2 (A))
[0045]
Next, an inorganic insulating film 3 that covers the organic resin film 2 is formed. Subsequently, an amorphous semiconductor film 4 is formed on the inorganic insulating film 3. (FIG. 2B) Further, the inorganic insulating film 3 and the amorphous semiconductor film 4 may be continuously formed without being exposed to the air to reduce the contamination of impurities.
[0046]
Next, the amorphous semiconductor film is crystallized by irradiating the laser beam 5 to form crystalline semiconductor films 4a and 4b. (Fig. 2 (C))
[0047]
Next, the crystalline semiconductor film is patterned to complete island-shaped crystalline semiconductor films 6 and 7 including the first region 4a. (Fig. 2 (D))
[0048]
Hereinafter, the island-shaped crystalline semiconductor film formed by the process shown in FIG. 2 is used for an active layer of TFT (a semiconductor film in which a channel formation region, a source region, a drain region, and an LDD region are formed), and is known. If a TFT is manufactured according to the method, a semiconductor device having excellent electrical characteristics can be obtained.
[0049]
As shown in FIG. 3C, an organic resin film 902 is formed over the entire surface of a substrate 901 having an insulating surface, and an inorganic insulating film 903 containing silicon is provided in contact with the organic resin film 902. After obtaining the state in which the amorphous semiconductor film 904 is formed, laser crystallization may be performed. However, in this case, the cooling rate can be adjusted by the material and film thickness of the organic resin film 902, but it is difficult to control the position of crystals having a large grain size. When compared with the case where an amorphous semiconductor film is formed on a plastic substrate and laser crystallization is performed, the cooling rate of crystallization is reduced, but it is impossible to adjust the cooling rate.
[0050]
In addition, a base insulating film 405 may be provided as illustrated in FIG. The base insulating film 405 can prevent impurity diffusion from the substrate 401 and can improve the adhesion between the substrate 401 and the organic resin film 402.
[0051]
The “cooling rate” in this specification refers to the cooling rate of the semiconductor film after being melted by laser light.
[0052]
Further, as shown in FIG. 5, the crystallization process is not limited to the ordinary laser annealing method, and laser light may be irradiated simultaneously from the front surface side and the back surface side of the substrate. Further, the laser light may be a pulse oscillation type or a continuous emission type. The laser beam can be a linear beam, a spot beam, a planar beam, or the like in the optical system, and is not limited to the shape.
[0053]
Further, the laser annealing method may be performed while heating the substrate. Further, a thermal annealing method and a laser annealing method may be combined. Further, a crystallization method using a catalytic element may be applied.
[0054]
The present invention having the above-described configuration will be described in more detail with the following examples.
[0055]
【Example】
[Example 1]
A process of manufacturing a crystalline semiconductor film (crystalline silicon film in this embodiment) patterned into an island shape using the present invention will be described. Hereinafter, this embodiment will be described with reference to FIG.
[0056]
First, an organic resin film (film thickness: 100 nm to 500 nm) is applied on a light-transmitting substrate 1 by a spin coat method or the like and baked. In this example, a benzocyclobutene film (hereinafter referred to as a BCB film) was applied as an organic resin film by a spin coating method, followed by baking (300 ° C., 1 hour) to obtain a film thickness of 200 nm. Note that the thickness of the BCB film used in this embodiment can be easily controlled by the number of spin rotations. Further, when not used for a transmissive display element (such as a liquid crystal panel), the light-transmitting substrate 1 does not need to be transparent, and can withstand heat resistance and resistance to subsequent processes using a CVD apparatus. It goes without saying that the organic resin film is not limited to the BCB film as long as it has plasma properties.
[0057]
Next, the BCB film is patterned by a known photolithography method, and an island-shaped organic resin film 2 is formed by dry etching. (FIG. 2A) In this embodiment, O ₂ And CF _Four Etching was performed using a mixed gas. However, the position of the island-shaped organic resin film 2 is formed in accordance with the island-shaped crystalline silicon film formed in a later step. Further, if a photosensitive material is used as the organic resin film, patterning can be performed without using a resist, and the manufacturing process can be shortened.
[0058]
Next, an inorganic insulating film 3 having a thickness of 50 nm to 200 nm is formed by a known method so as to cover the island-shaped organic resin film 2. As the inorganic insulating film 3, a single layer film selected from a silicon oxide film, a silicon nitride film, and a silicon oxynitride film or a laminated film thereof using a known method such as a PCVD method, an LPCVD method, or a sputtering method is used. Can do. However, when using a silicon nitride film or a silicon oxynitride film, it is necessary to consider the balance of internal stress. The inorganic insulating film 3 is used for the purpose of preventing impurity diffusion from the substrate, the purpose of improving the adhesion with a semiconductor film to be formed later, and the purpose of ensuring a selection ratio with a semiconductor film to be etched later. Is formed. In this embodiment, a silicon oxide film having a thickness of 50 nm is formed by PCVD.
[0059]
Next, an amorphous semiconductor film 4 is formed on the inorganic insulating film 3. In this embodiment, an amorphous silicon film (amorphous silicon film) having a thickness of 55 nm is formed by the PCVD method. (FIG. 2B) In addition, the semiconductor film is not limited to an amorphous silicon film as long as the semiconductor film includes an amorphous structure. For example, the semiconductor film includes an amorphous structure such as a microcrystalline semiconductor film or an amorphous silicon germanium film. A compound semiconductor film may be used. Alternatively, the inorganic insulating film 3 and the amorphous semiconductor film 4 may be continuously formed without being exposed to the atmosphere.
[0060]
Next, the amorphous semiconductor film 4 is crystallized by a laser annealing method. As the laser beam, a linear beam having a width of 100 to 1000 μm is used and irradiated from the substrate surface side as shown in FIG. In this embodiment, a laser irradiation apparatus using a pulse oscillation type excimer laser as a light source is used. (Fig. 2 (C))
[0061]
In this laser light crystallization process, when the pulsed laser light is irradiated, the amorphous silicon film is instantaneously heated to be in a molten state. Thereafter, in region A, heat is sequentially conducted from the lower surface of the molten silicon film through the inorganic insulating film 3 to the organic resin film 2 and the substrate 1, so that the molten silicon film is gradually cooled. To go.
[0062]
On the other hand, in the region B, heat is sequentially conducted from the lower surface of the molten silicon film through the inorganic insulating film 3 to the substrate 1, and the molten silicon film is rapidly cooled.
[0063]
Accordingly, in the region B where the organic resin film 2 does not exist, the silicon is rapidly cooled after laser irradiation, so that the crystal grain size becomes small. However, in the region A where the organic resin film 2 is present, since it is gradually cooled, the crystallization speed becomes slow, and a polycrystalline silicon film (polysilicon film) having a large crystal grain size can be formed. Since the thermal conductivity of the organic resin film 2 is very low compared to the thermal conductivity of the inorganic insulating film 3, the cooling rate after laser irradiation can be suppressed. This cooling rate can be controlled by the material and film thickness of the organic resin film 2.
[0064]
Next, the crystallized crystalline semiconductor film is patterned by a known photolithography method to form island-shaped crystalline semiconductor films 6 and 7. In this embodiment, O ₂ And CF _Four Patterning was performed by a dry etching method using a mixed gas of
[0065]
As described above, the island-shaped organic resin film 2 controls the cooling rate after laser irradiation to obtain an island-shaped crystalline silicon film having a very small lattice defect density and a large crystal grain size at a desired position. I was able to. When these island-like crystalline semiconductor films 6 and 7 are used for the active layer of the TFT, excellent characteristics can be obtained.
[0066]
[Example 2]
In Example 1, the example in which the organic resin film was patterned was shown, but in this example, an example in which the organic resin film is not patterned is shown in FIG.
[0067]
First, in the same manner as in Example 1, an organic resin film 902 (film thickness: 100 nm to 500 nm) is applied on a light-transmitting substrate 901 by a spin coating method and is baked. In this example, a BCB film was applied as the organic resin film 902 by spin coating, and then baked (300 ° C., 1 hour) to obtain a film thickness of 200 nm. Note that the film thickness of the BCB film used in this example can be easily controlled by the spin rotation speed. Further, when not used for a transmissive display element (such as a liquid crystal panel), the light-transmitting substrate 901 does not need to be transparent, and can withstand heat resistance and resistance to subsequent processes using a CVD apparatus. It goes without saying that the organic resin film is not limited to the BCB film as long as it has plasma properties.
[0068]
Next, an inorganic insulating film 903 having a thickness of 50 nm to 200 nm is formed by a known method so as to cover the organic resin film 902. As the inorganic insulating film 903, a single layer film selected from a silicon oxide film, a silicon nitride film, and a silicon oxynitride film or a stacked film thereof using a known method such as a PCVD method, an LPCVD method, or a sputtering method is used. Can do. This inorganic insulating film 903 is used for the purpose of preventing impurity diffusion from the substrate, the purpose of improving the adhesion with a semiconductor film to be formed later, and the purpose of ensuring the selection ratio with a semiconductor film to be etched later. Is formed. In this embodiment, a silicon oxide film having a thickness of 50 nm is formed by PCVD.
[0069]
Next, an amorphous semiconductor film 904 is formed over the inorganic insulating film 903. In this embodiment, an amorphous silicon film (amorphous silicon film) 903 having a film thickness of 55 nm is formed by PCVD. (FIG. 3B) In addition, the semiconductor film is not limited to an amorphous silicon film as long as it includes an amorphous structure, and includes an amorphous structure such as a microcrystalline semiconductor film or an amorphous silicon germanium film. A compound semiconductor film may be used. Alternatively, the inorganic insulating film 903 and the amorphous semiconductor film 904 may be continuously formed without being exposed to the air.
[0070]
Next, the amorphous semiconductor film 904 is crystallized by a laser annealing method. As the laser beam, a linear beam having a width of 100 to 1000 μm is used, and irradiation is performed from the substrate surface side as shown in FIG. In this embodiment, a laser irradiation apparatus using a pulse oscillation type excimer laser as a light source is used. (Fig. 3 (C))
[0071]
In this laser light crystallization step, when pulsed laser light is irradiated, the amorphous silicon film 904 is instantaneously heated to be in a molten state. Thereafter, heat is sequentially conducted from the lower surface of the molten silicon film to the organic resin film 902 and the substrate 901 through the inorganic insulating film 903, whereby the molten silicon film is gradually cooled. In this embodiment, since the BCB film, which is an organic resin film, is present on the entire surface of the substrate, the crystallization speed is slow and a polycrystalline silicon film (polysilicon film) having a large crystal grain size can be formed uniformly. Since the thermal conductivity of the organic resin film 902 is much lower than that of the inorganic insulating film 903, the cooling rate after laser irradiation can be suppressed. This cooling rate can be controlled by the material and film thickness of the organic resin film 902.
[0072]
Next, the crystallized crystalline semiconductor film is patterned by a known photolithography method to form island-shaped crystalline semiconductor films 906 and 907. In this embodiment, O ₂ And CF _Four Patterning was performed by a dry etching method using a mixed gas of
[0073]
As described above, the cooling rate after laser irradiation was controlled by the organic resin film 902 to obtain an island-like crystalline silicon film having a very small lattice defect density and a large crystal grain size. When these island-like crystalline semiconductor films 906 and 907 are used for the active layer of the TFT, excellent characteristics can be obtained.
[0074]
[Example 3]
In this embodiment, an example in which a base insulating film is provided between a substrate and an organic resin film is shown in FIG.
[0075]
First, a base insulating film 405 having a thickness of 50 nm to 400 nm is formed over the glass substrate 401 by a known method. As the base insulating film 405, a single layer film selected from a silicon oxide film, a silicon nitride film, and a silicon oxynitride film or a stacked film thereof using a known method such as a PCVD method, an LPCVD method, or a sputtering method is used. Can do. However, when using a silicon nitride film or a silicon oxynitride film, it is necessary to consider the balance of internal stress. The base insulating film 405 is formed for the purpose of preventing impurity diffusion from the substrate. In this embodiment, a silicon oxide film having a thickness of 50 nm is formed by PCVD.
[0076]
Next, an organic resin film (with a film thickness of 100 nm to 500 nm) is applied over the base insulating film 405 by a spin coating method or the like, and is baked. In this example, a benzocyclobutene film (hereinafter referred to as a BCB film) was applied as an organic resin film by a spin coating method, followed by baking (300 ° C., 1 hour) to obtain a film thickness of 200 nm. Further, when not used for a transmissive display element (such as a liquid crystal panel), the light-transmitting substrate 1 does not need to be transparent, and can withstand heat resistance and resistance to subsequent processes using a CVD apparatus. It goes without saying that the organic resin film is not limited to the BCB film as long as it has plasma properties.
[0077]
Next, the BCB film is patterned by a known photolithography method according to Example 1, and an island-shaped organic resin film 402 is formed by dry etching. Here, the base insulating film 405 protects the glass substrate surface from dry etching.
[0078]
In the subsequent steps, the inorganic insulating film 403 and the amorphous semiconductor film are formed by a known method so as to cover the island-shaped organic resin film 402 in accordance with Embodiment 1, laser crystallization is performed, and cooling after laser irradiation is performed. By controlling the speed, a crystalline silicon film having a very small lattice defect density and a large crystal grain size was obtained at a desired position (region A). Note that the crystal grain size of the crystalline semiconductor film 404b located in the region B is small. When this crystalline semiconductor film 404a is used for an active layer of a TFT, excellent characteristics can be obtained.
[0079]
In addition, this embodiment can be combined with Embodiment 2 as appropriate.
[0080]
[Example 4]
In this embodiment, an example in which crystallization is performed by a laser irradiation method different from that in Embodiment 1 is shown in FIG. In addition, since Example 1 is the same except for the laser irradiation method, a detailed description is omitted.
[0081]
In accordance with Embodiment 1, an island-shaped organic resin film 502 is formed on the substrate 501. Next, an inorganic insulating film 503 that covers the island-shaped organic resin film 502 is formed in the same manner as in Example 1, and an amorphous semiconductor film is formed over the inorganic insulating film 503. However, in this embodiment, the substrate 501 and the island-shaped organic resin film 502 are required to have translucency.
[0082]
Next, as shown in FIG. 5, laser light is simultaneously irradiated from the front surface side and the back surface side of the substrate. Here, the ratio of the energy of the laser beam that irradiates the substrate from the front surface side of the substrate to the energy of the laser beam that irradiates the substrate from the back surface side of the substrate is between 6: 4 and 8: 2. This is preferable because the crystal grain size of the crystalline semiconductor film can be further increased.
[0083]
Through the above steps, the cooling rate after laser irradiation was controlled to obtain a crystalline silicon film having a very small lattice defect density and a large crystal grain size at a desired position (region A). Note that the crystal grain size of the crystalline semiconductor film 504b located in the region B is as small as 0.3 μm or less. When this crystalline semiconductor film 504a is used for an active layer of a TFT, excellent characteristics can be obtained.
[0084]
In addition, this embodiment can be freely combined with Embodiment 2 or Embodiment 3 as appropriate.
[0085]
[Example 5]
In this embodiment, a manufacturing process of a CMOS circuit including an n-channel TFT and a p-channel TFT will be described with reference to FIGS.
[0086]
First, island-shaped organic resin films 103 and 104, an inorganic insulating film 105, and island-shaped semiconductor films 107 and 108a are formed on a substrate 101 by the method described in Embodiment 1. Next, a mask layer 109 made of a silicon oxide film having a thickness of 50 to 100 nm is formed by plasma CVD, low pressure CVD, or sputtering. (Fig. 6 (A))
[0087]
FIG. 8A shows a top view of FIG. The island-shaped semiconductor films 107 and 108b are provided so as to overlap with the organic resin films 103 and 104 patterned in an island shape, respectively. In FIG. 8A, the AA ′ cross section corresponds to the cross sectional structure in FIG.
[0088]
Then, as shown in FIG. 6B, a photoresist mask 110 is provided, and the island-shaped semiconductor film 108a for forming the n-channel TFT is controlled to have a threshold voltage of 1 × 10. ¹⁶ ~ 5x10 ¹⁷ atoms / cm ^Three An impurity element imparting p-type is added at a moderate concentration. As an impurity element imparting p-type to a semiconductor, elements of Group 13 of the periodic table such as boron (B), aluminum (Al), and gallium (Ga) are known. Here, diborane (B ₂ H ₆ ) And boron (B) was added. Addition of boron (B) is not always necessary and may be omitted, but the semiconductor layer 108b to which boron (B) is added is formed in order to keep the threshold voltage of the n-channel TFT within a predetermined range. Can do.
[0089]
In order to form the LDD region of the n-channel TFT, an impurity element imparting n-type conductivity is selectively added to the island-shaped semiconductor film 108b. As an impurity element imparting n-type to a semiconductor, elements of Group 15 of the periodic table such as phosphorus (P), arsenic (As), and antimony (Sb) are known. A photoresist mask 111 is formed, and phosphine (PH) is added here to add phosphorus (P). _Three ) Was applied. The phosphorus (P) concentration in the impurity region 112 to be formed is 2 × 10 ¹⁶ ~ 5x10 ¹⁹ atoms / cm ^Three (FIG. 6C). In this specification, the concentration of an impurity element imparting n-type contained in the impurity region 112 is defined as (n ^- ).
[0090]
Next, the mask layer 109 was removed with an etching solution such as hydrofluoric acid diluted with pure water. Then, a step of activating the impurity element added to the island-shaped semiconductor film 108b in FIGS. 6B and 6C is performed. The activation can be performed by a method such as thermal annealing or laser annealing at 500 to 600 ° C. for 1 to 4 hours in a nitrogen atmosphere. Moreover, you may carry out using both methods together. In this example, a laser activation method is used, an excimer laser beam is used to form a linear beam, an oscillation frequency of 5 to 50 Hz, and an energy density of 100 to 500 mJ / cm. ² As a result, the entire surface of the substrate on which the island-shaped semiconductor film was formed was processed by scanning the linear beam with an overlap ratio of 80 to 98%. Note that there are no particular limitations on the irradiation conditions of the laser beam, and the practitioner may make an appropriate decision.
[0091]
The gate insulating film 113 is formed of an insulating film containing silicon with a thickness of 40 to 150 nm by using a plasma CVD method or a sputtering method. For example, a silicon oxynitride film is preferably formed with a thickness of 120 nm. SiH _Four And N ₂ O to O ₂ The silicon oxynitride film manufactured by adding is preferable because the fixed charge density in the film is reduced. The gate insulating film is not limited to such a silicon oxynitride film, and another insulating film containing silicon may be used as a single layer or a stacked structure (FIG. 6D).
[0092]
As shown in FIG. 6E, a conductive layer is formed to form a gate electrode over the gate insulating film. Although this conductive layer may be formed as a single layer, it may have a laminated structure of two layers or three layers as required. In the present embodiment, a conductive layer (A) 114 made of a conductive nitride metal film and a conductive layer (B) 115 made of a metal film are stacked. The conductive layer (B) 115 is an element selected from tantalum (Ta), titanium (Ti), molybdenum (Mo), and tungsten (W), an alloy containing the element as a main component, or an alloy film in which the elements are combined. (Typically, the conductive layer (A) 114 may be formed of tantalum nitride (TaN), tungsten nitride (WN), titanium nitride (TiN) film, nitride). It is made of molybdenum (MoN) or the like. Alternatively, tungsten silicide, titanium silicide, or molybdenum silicide may be used for the conductive layer (A) 114.
[0093]
The conductive layer (A) 114 may be 10 to 50 nm (preferably 20 to 30 nm), and the conductive layer (B) 115 may be 200 to 400 nm (preferably 250 to 350 nm). In this example, a 30 nm thick WN film was used for the conductive layer (A) 114 and a 350 nm W film was used for the conductive layer (B) 115, both of which were formed by sputtering. Although not shown, it is effective to form a silicon film doped with phosphorus (P) with a thickness of about 2 to 20 nm under the conductive layer (A) 111. This improves adhesion and prevents oxidation of the conductive film formed thereon, and at the same time, an alkali metal element contained in a trace amount in the conductive layer (A) or the conductive layer (B) diffuses into the gate insulating film 113. Can be prevented. In any case, the conductive layer (B) preferably has a resistivity in the range of 10 to 500 μΩcm.
[0094]
Next, a photoresist mask having a predetermined pattern is formed, and the conductive layers (A) 114 and (B) 115 are collectively etched to form gate electrodes 116 and 117. The gate electrodes 116 and 117 are integrally formed of 116a and 117a made of a conductive layer (A) and 116b and 117b made of a conductive layer (B). At this time, the gate electrode 117 provided in the n-channel TFT is formed so as to overlap with part of the impurity region 112 with the gate insulating film 113 interposed therebetween (FIG. 7A). Alternatively, the gate electrode can be formed using only the conductive layer (B).
[0095]
FIG. 8B shows a top view of FIG. Gate electrodes 116 and 117 provided on the island-shaped semiconductor films 107 and 108b with a gate insulating film interposed therebetween are connected to the gate wiring 128. In FIG. 8B, the AA ′ cross section corresponds to the cross sectional structure in FIG.
[0096]
Next, impurity regions 119 serving as a source region and a drain region are formed in the island-shaped semiconductor film 107 that forms the p-channel TFT. Here, an impurity element imparting p-type is added using the gate electrode 116 as a mask, and an impurity region is formed in a self-aligning manner. At this time, the island-shaped semiconductor film 108b forming the n-channel TFT is covered with the photoresist mask 118. The impurity region 119 is diborane (B ₂ H ₆ ) Using an ion doping method. The boron (B) concentration in this region is 3 × 10 ²⁰ ~ 3x10 ²¹ atoms / cm ³ (FIG. 7B). In this specification, the impurity region 1 formed here 19 The concentration of the impurity element imparting p-type contained in (p ⁺ ).
[0097]
Next, an impurity region 121 for forming a source region or a drain region was formed in the island-shaped semiconductor film 108b for forming the n-channel TFT. Here, phosphine (PH _Three ), And the phosphorus (P) concentration in this region is 1 × 10 ²⁰ ~ 1x10 ^{twenty one} atoms / cm ^Three (FIG. 7C). In this specification, the concentration of the impurity element imparting n-type contained in the impurity region 121 formed here is defined as (n ⁺ ). Phosphorus (P) is also added to the impurity region 119 at the same time, but the phosphorus (P) concentration added to the impurity region 117 is half that of the boron (B) concentration already added in the previous step. Since it is about １ ／, p-type conductivity is ensured and the TFT characteristics are not affected at all.
[0098]
Thereafter, a step of activating the impurity element imparting n-type or p-type added at each concentration is performed by laser annealing. A furnace annealing furnace may be used for this step. In addition, a thermal annealing method or a rapid thermal annealing method (RTA method) can be used. Here, a laser activation method is used, a linear beam is formed using KrF excimer laser light (wavelength 248 nm), an oscillation frequency of 5 to 50 Hz, and an energy density of 100 to 500 mJ / cm. ² The entire substrate on which the island-shaped semiconductor film was formed was processed. Further, before the annealing treatment, the protective insulating layer 122 with a thickness of 50 to 200 nm is preferably formed using a silicon oxynitride film, a silicon oxide film, or the like. (FIG. 7 (D)).
[0099]
After the activation step, a heat treatment was performed at 300 to 450 ° C. for 1 to 12 hours in an atmosphere containing 3 to 100% hydrogen to perform a step of hydrogenating the island-shaped semiconductor film. This process is performed on the island-like semiconductor film 10 by thermally excited hydrogen. ¹⁶ -10 ¹⁸ /cm ^Three This is a step of terminating the dangling bond. As another means of hydrogenation, plasma hydrogenation (using hydrogen excited by plasma) may be performed.
[0100]
After the activation and hydrogenation steps are completed, a silicon oxynitride film or a silicon oxide film is further stacked over the protective insulating layer to form an interlayer insulating layer 123. The silicon oxynitride film is the protective insulating layer 1 22 SiH ₄ 27 SCCM, N ₂ O is 900 SCCM, the reaction pressure is 160 Pa, the substrate temperature is 325 ° C., and the discharge power density is 0.15 W / cm. ² As a thickness of 500-1500 nm (preferably 600-800 nm). Then, the interlayer insulating layer 123 and the protective insulating layer 122 In Contact holes reaching the source region or the drain region of the TFT are formed, and source wirings 124 and 125 and a drain wiring 126 are formed. Although not shown, in this embodiment, this electrode is a laminated film having a three-layer structure in which a Ti film is 100 nm, an aluminum film containing Ti is 300 nm, and a Ti film is 150 nm continuously formed by sputtering.
[0101]
Next, a silicon nitride film or a silicon oxynitride film is formed as the passivation film 127 with a thickness of 50 to 500 nm (typically 100 to 300 nm). Furthermore, when the hydrogenation treatment was performed in this state, a favorable result was obtained for improving the characteristics of the TFT. For example, heat treatment may be performed at 300 to 450 ° C. for 1 to 12 hours in an atmosphere containing 3 to 100% hydrogen, or the same effect can be obtained by using a plasma hydrogenation method. Further, by such heat treatment, hydrogen existing in the interlayer insulating layer 123 and the protective insulating layer 122 can be diffused into the island-shaped semiconductor films 107 and 108b to be hydrogenated.
[0102]
Thus, as shown in FIG. 7E, an n-channel TFT 151 and a p-channel TFT 150 were completed on the substrate 101. The p-channel TFT 150 includes a channel formation region 152, a source region 153, and a drain region 154 in the island-shaped semiconductor film 107. The n-channel TFT 151 includes a channel formation region 155, an LDD region 156 (hereinafter, such an LDD region is referred to as Lov) overlapping the island formation semiconductor film 108 and the gate electrode 117, a source region 157, and a drain region 158. ing. The length of the Lov region in the channel length direction was 0.5 to 3.0 μm (preferably 1.0 to 1.5 μm) with respect to the channel length of 3 to 8 μm. In this embodiment, each TFT has a single gate structure, but a double gate structure or a multi-gate structure in which a plurality of gate electrodes are provided may be used.
[0103]
FIG. 8C shows a top view of FIG. The source wirings 124 and 125 are in contact with the island-shaped semiconductor films 107 and 108b through contact holes provided in the interlayer insulating layer 123 and the protective insulating layer 122 (not shown). 8C, the AA ′ cross section corresponds to the cross sectional structure in FIG.
[0104]
In the p-channel TFT 150 and the n-channel TFT 151 thus manufactured, the channel formation region is formed of a polycrystalline silicon film having a large crystal grain size. In addition, a shift register circuit, a buffer circuit, a D / A converter circuit, a level shifter circuit, a multiplexer circuit, and the like can be formed using such TFTs. By appropriately combining these circuits, a semiconductor device manufactured on a glass substrate such as a liquid crystal display device, an EL display device, and a contact image sensor can be formed.
[0105]
However, in all of the above heat treatments, it is necessary to pay sufficient attention to the temperature of the heat treatment so that the temperature is within the temperature range that the organic resin films 103 and 104 can withstand.
[0106]
[Example 6]
An embodiment of the present invention will be described with reference to FIGS. Here, a method for manufacturing the pixel TFT of the pixel portion and the TFT of the driver circuit provided around the pixel portion over the same substrate will be described in detail according to the process. However, in order to simplify the description, a CMOS circuit that is a basic circuit such as a shift register circuit and a buffer circuit is shown in the control circuit, and an n-channel TFT that forms a sampling circuit.
[0107]
First, island-shaped organic resin films 203 to 206, an inorganic insulating film 207, and an amorphous semiconductor film 208a are formed on a substrate 201 by the method described in Embodiment 1. (Fig. 9 (A))
[0108]
Next, the amorphous semiconductor film 208a is laser crystallized by the method described in Embodiment 1 to form a crystalline semiconductor film 208b. (FIG. 9B) Here, in the crystalline semiconductor film 208b, the crystal grain size of the region having the organic resin film below the inorganic insulating film is the region not having the organic resin film. Larger than that but not shown.
[0109]
Next, the crystalline semiconductor film 208b is etched and divided into islands, and island-like semiconductor films 209 and 210a to 212a are formed as active layers. Thereafter, a mask layer 213 made of a silicon oxide film having a thickness of 50 to 100 nm is formed by plasma CVD, low pressure CVD, or sputtering. (Figure 9 (C))
[0110]
In the channel doping process, a photoresist mask 214 is provided, and the entire surface of the island-shaped semiconductor films 210a to 212a forming the n-channel TFT is controlled by 1 × 10 ¹⁶ ~ 5x10 ¹⁷ atoms / cm ^Three Boron (B) was added as an impurity element imparting p-type at a moderate concentration. Boron (B) may be added by an ion doping method, or may be added simultaneously with the formation of an amorphous silicon film. Although boron (B) is not necessarily added here, the semiconductor layers 210b to 212b to which boron (B) is added are preferably formed in order to keep the threshold voltage of the n-channel TFT within a predetermined range. It was good (FIG. 9D).
[0111]
In order to form the LDD region of the n-channel TFT of the driver circuit, an impurity element imparting n-type conductivity is selectively added to the island-shaped semiconductor films 210b and 211b. Photoresist masks 215 to 218 were formed in advance. Here, phosphine (PH) is added to add phosphorus (P). _Three ) Was applied. Impurity region (n ^- ) The phosphorus (P) concentration of 219, 220 is 1 × 10 ¹⁷ ~ 5x10 ¹⁹ atoms / cm ^Three (FIG. 10A). The impurity region 221 is a semiconductor layer for forming a storage capacitor of the pixel portion, and phosphorus (P) is added to this region at the same concentration.
[0112]
Next, the mask layer 213 is removed with hydrofluoric acid or the like, and a step of activating the impurity element added in FIGS. 9D and 10A is performed. Activation can be performed by a method of thermal annealing or laser annealing at 500 to 600 ° C. for 1 to 4 hours in a nitrogen atmosphere. Moreover, you may carry out using both together. In this embodiment, a laser activation method is used, a KrF excimer laser beam (wavelength 248 nm) is used to form a linear beam, an oscillation frequency of 5 to 50 Hz, and an energy density of 100 to 500 mJ / cm. ² As a result, the entire surface of the substrate on which the island-shaped semiconductor film was formed was processed by scanning the linear beam with an overlap ratio of 80 to 98%. Note that there are no particular limitations on the irradiation conditions of the laser beam, and the practitioner may make an appropriate decision.
[0113]
Then, the gate insulating film 222 is formed with an insulating film containing silicon with a thickness of 40 to 150 nm by plasma CVD or sputtering. For example, SiH _Four , N ₂ O, O ₂ Is formed of a silicon oxynitride film manufactured by a plasma CVD method. (Fig. 10 (B))
[0114]
Next, a first conductive layer is formed to form a gate electrode. In this embodiment, a conductive layer (A) 223 made of a conductive nitride metal film and a conductive layer (B) 224 made of a metal film are laminated. Here, the conductive layer (B) 224 is formed with tungsten (W) to a thickness of 250 nm by sputtering using W as a target, and the conductive layer (A) 223 is formed with tungsten (WN) to a thickness of 50 nm. (FIG. 10C).
[0115]
Next, photoresist masks 225 to 229 are formed, and the conductive layer (A) 223 and the conductive layer (B) 224 are etched together to form gate electrodes 230 to 233 and a capacitor wiring 234. The gate electrodes 230 to 233 and the capacitor wiring 234 are integrally formed of 230a to 234a made of a conductive layer (A) and 230b to 234b made of a conductive layer (B). At this time, the gate electrodes 231 and 232 formed in the driver circuit are formed so as to overlap with part of the impurity regions 219 and 220 with the gate insulating film 222 interposed therebetween (FIG. 10D).
[0116]
Next, in order to form a source region and a drain region of the p-channel TFT of the driver circuit, a step of adding an impurity element imparting p-type is performed. Here, the impurity region is formed in a self-aligning manner using the gate electrode 230 as a mask. The region where the n-channel TFT is formed is covered with a photoresist mask 235. And diborane (B ₂ H ₆ The impurity region (p ⁺ 23) 6 1 × 10 ²¹ atoms / cm ³ (FIG. 11A).
[0117]
Next, in the n-channel TFT, an impurity region functioning as a source region or a drain region was formed. Resist masks 237 to 239 are formed, and an impurity element imparting n-type conductivity is added to form impurity regions 241 to 244. This is the phosphine (PH _Three The impurity region (n ⁺ ) (P) concentration of 241 to 244 is 5 × 10 ²⁰ atoms / cm ^Three (FIG. 11B). The impurity region 240 already contains boron (B) added in the previous step, but phosphorus (P) is added at a concentration of 1/2 to 1/3 as compared with it. The influence of phosphorus (P) is not considered, and the TFT characteristics were not affected at all.
[0118]
Then, in order to form an LDD region of the n-channel TFT in the pixel portion, an impurity addition step for imparting n-type was performed. Here, an impurity element imparting n-type in a self-aligning manner is added by ion doping using the gate electrode 233 as a mask. The concentration of phosphorus (P) to be added is 5 × 10 ¹⁶ atoms / cm ^Three 9A, FIG. 10A, and FIG. 10B, the impurity region (n ^- Only 245 and 246 are formed (FIG. 11C).
[0119]
Thereafter, a heat treatment step (400 to 700 ° C.) is performed in a nitrogen atmosphere in order to activate the impurity element imparting n-type or p-type added at each concentration. This step can be performed by a thermal annealing method using a furnace annealing furnace, a laser annealing method, or a rapid thermal annealing method (RTA method).
[0120]
In this thermal annealing, the conductive films (C) 230c to 234c made of WN are formed with a thickness of 5 to 80 nm from the surface of the W films 230b to 234b formed on the gate electrodes 230 to 233 and the capacitor wiring 234. In addition, when the conductive layers (B) 230b to 234b are made of titanium (Ti), titanium nitride (TiN) can be formed. Alternatively, the gate electrodes 230 to 234 can be similarly formed by exposing them to a plasma atmosphere containing nitrogen using nitrogen or ammonia. Further, thermal annealing was performed at 300 to 450 ° C. for 1 to 12 hours in an atmosphere containing 3 to 100% hydrogen to perform a step of hydrogenating the island-shaped semiconductor film. This process is performed by 1 × 10 6 in the island-like semiconductor film by thermally excited hydrogen. ¹⁶ ~ 1x10 ¹⁸ /cm ^Three This is a step of terminating the dangling bond. As another means of hydrogenation, plasma hydrogenation (using hydrogen excited by plasma) may be performed. (Fig. 11 (D))
[0121]
FIG. 14A is a top view of the TFT in FIG. 11D, and the AA ′ cross section corresponds to AA ′ in FIG. 11D.
[0122]
When the activation and hydrogenation steps are completed, a second conductive layer serving as a gate wiring is formed. The second conductive layer is formed of a conductive layer (D) mainly composed of aluminum (Al) or copper (Cu) which is a low resistance material. In any case, the resistivity of the second conductive layer is about 0.1 to 10 μΩcm. Further, a conductive layer (E) made of titanium (Ti), tantalum (Ta), tungsten (W), or molybdenum (Mo) is preferably stacked. In this example, an aluminum (Al) film containing 0.1 to 2% by weight of titanium (Ti) was formed as the conductive layer (D) 247, and a titanium (Ti) film was formed as the conductive layer (E) 248. The conductive layer (D) 247 may be 200 to 400 nm (preferably 250 to 350 nm), and the conductive layer (E) 248 may be formed to be 50 to 200 nm (preferably 100 to 150 nm) (FIG. 12A). ).
[0123]
Then, in order to form a gate wiring connected to the gate electrode, the conductive layer (E) 248 and the conductive layer (D) 247 were etched to form gate wirings 249 and 250 and a capacitor wiring 251.
[0124]
FIG. 14B shows a top view of this state, and the AA ′ cross section corresponds to AA ′ in FIG.
[0125]
Next, the first interlayer insulating film 252 is formed with a thickness of 500 to 1500 nm using a silicon oxide film or a silicon oxynitride film. In this example, SiH _Four 27SCCM, N ₂ O is 900 SCCM, reaction pressure is 160 Pa, substrate temperature is 325 ° C., discharge power density is 0.15 W / cm ² Formed with. Thereafter, contact holes reaching the source region or the drain region formed in each island-shaped semiconductor film are formed, and source wirings 253 to 256 and drain wirings 257 to 260 are formed. Although not shown, in this embodiment, this electrode is a laminated film having a three-layer structure in which a Ti film is 100 nm, an aluminum film containing Ti is 300 nm, and a Ti film is 150 nm continuously formed by sputtering.
[0126]
Next, a silicon nitride film, a silicon oxide film, or a silicon oxynitride film is formed as the passivation film 261 with a thickness of 50 to 500 nm (typically 100 to 300 nm). When the hydrogenation treatment was performed in this state, favorable results were obtained with respect to the improvement of TFT characteristics. For example, heat treatment may be performed at 300 to 450 ° C. for 1 to 12 hours in an atmosphere containing 3 to 100% hydrogen, or the same effect can be obtained by using a plasma hydrogenation method. Further, by such heat treatment, hydrogen existing in the first interlayer insulating film 252 can be diffused into the island-shaped semiconductor films 209 and 210b to 212b to be hydrogenated. (FIG. 12C). Note that an opening may be formed in the passivation film 261 at a position where a contact hole for connecting the pixel electrode and the drain wiring is formed later.
[0127]
FIG. 14C shows a top view of this state, and the AA ′ cross section corresponds to AA ′ of FIG.
[0128]
Thereafter, a second interlayer insulating film 262 made of an organic resin is formed to a thickness of 1.0 to 1.5 μm. As the organic resin, polyimide, acrylic, polyamide, polyimide amide, BCB (benzocyclobutene), or the like can be used. Here, it was formed by baking at 300 ° C. using a type of polyimide that is thermally polymerized after being applied to the substrate. Then, a contact hole reaching the drain wiring 260 is formed in the second interlayer insulating film 262, and pixel electrodes 263 and 264 are formed. The pixel electrode may be a transparent conductive film in the case of a transmissive liquid crystal display device, and may be a metal film in the case of a reflective liquid crystal display device. In this example, an indium tin oxide (ITO) film having a thickness of 100 nm was formed by sputtering to obtain a transmissive liquid crystal display device (FIG. 13).
[0129]
In this way, a substrate having the TFT of the driving circuit and the pixel TFT of the pixel portion on the same substrate was completed. A p-channel TFT 301, a first n-channel TFT 302, and a second n-channel TFT 303 are formed in the driver circuit, and a pixel TFT 304 and a storage capacitor 305 are formed in the pixel portion. In this specification, such a substrate is referred to as an active matrix substrate for convenience.
[0130]
However, in all the heat treatments of the active matrix substrate, it is necessary to pay sufficient attention to the temperature of the heat treatment so that the organic resin films 203 to 206 are within a temperature range that can be tolerated.
[0131]
The p-channel TFT 301 of the driver circuit includes a channel formation region 306, source regions 307a and 307b, and drain regions 308a and 308b in an island-shaped semiconductor film 209. The first n-channel TFT 302 includes a channel formation region 309, an LDD region (Lov) 310 that overlaps with the gate electrode 231, a source region 311, and a drain region 312 on the island-shaped semiconductor film 210. The length of the Lov region in the channel length direction is 0.5 to 3.0 μm, preferably 1.0 to 1.5 μm. In the second n-channel TFT 303, a channel formation region 313, a Lov region and an Loff region (an LDD region that does not overlap with the gate electrode, hereinafter referred to as an Loff region) are formed in the island-shaped semiconductor film 211. The length of the region in the channel length direction is 0.3 to 2.0 μm, preferably 0.5 to 1.5 μm. The pixel TFT 304 has channel formation regions 318 and 319, Loff regions 320 to 323, and source or drain regions 324 to 326 in the island-shaped semiconductor film 212. The length of the Loff region in the channel length direction is 0.5 to 3.0 μm, preferably 1.5 to 2.5 μm. Further, the storage capacitor 305 includes the capacitor wirings 234 and 251, an insulating film made of the same material as the gate insulating film, and a semiconductor layer 327 connected to the drain region 326 of the pixel TFT 304 and doped with an impurity element imparting n-type conductivity. Is formed. Although the pixel TFT 304 has a double gate structure in FIG. 12, it may have a single gate structure or a multi-gate structure provided with a plurality of gate electrodes.
[0132]
The configuration as described above makes it possible to optimize the structure of the TFT constituting each circuit according to the specifications required by the pixel TFT and the drive circuit, and to improve the operation performance and reliability of the semiconductor device. Furthermore, the LDD region, the source region, and the drain region can be easily activated by forming the gate electrode from a heat-resistant conductive material, and the wiring resistance can be sufficiently reduced by forming the gate electrode from a low-resistance material. Therefore, the present invention can be applied to a display device having a display area (screen size) of 4 inches class or more. And by using the crystalline semiconductor film selectively formed on the organic resin layers 203 to 206 forming the base layer, extremely excellent characteristics can be realized in the completed TFT.
[0133]
[Example 7]
In this embodiment, a process of manufacturing an active matrix liquid crystal display device from the active matrix substrate manufactured in Embodiment 6 will be described. As shown in FIG. 15, an alignment film 601 is formed on the active matrix substrate in the state shown in FIG. Usually, a polyimide resin is often used for the alignment film of the liquid crystal display element. A light shielding film 603, a transparent conductive film 604, and an alignment film 605 were formed on the counter substrate 602 on the counter side. After the alignment film was formed, rubbing treatment was performed so that the liquid crystal molecules were aligned with a certain pretilt angle. Then, the pixel portion, the active matrix substrate on which the CMOS circuit is formed, and the counter substrate are bonded to each other through a sealing material, a spacer (both not shown), and the like by a known cell assembling process. Thereafter, a liquid crystal material 606 was injected between both substrates and completely sealed with a sealant (not shown). A known liquid crystal material may be used as the liquid crystal material. Thus, the active matrix liquid crystal display device shown in FIG. 15 was completed.
[0134]
Next, the structure of the active matrix liquid crystal display device will be described with reference to the perspective view of FIG. 16 and the top view of FIG. 16 and 17 use the same reference numerals in order to correspond to the sectional structure diagrams of FIGS. 9 to 13 and FIG. Further, the cross-sectional structure along the line EE ′ shown in FIG. 17 corresponds to the cross-sectional view of the pixel matrix circuit shown in FIG.
[0135]
In FIG. 16, the active matrix substrate includes a pixel portion 706, a scanning signal driving circuit 704, and an image signal driving circuit formed on the glass substrate 201. 7 05. A pixel TFT 304 is provided in the display area, and a driving circuit provided in the periphery is configured based on a CMOS circuit. The scanning signal driving circuit 704 and the image signal driving circuit 705 are connected to the pixel TFT 304 by a gate wiring 250 and a source wiring 256, respectively. Further, an FPC (Flexible Print Circuit) 731 is connected to the external input terminal 734, and the input wiring 7 02, 7 03 is connected to each drive circuit.
[0136]
FIG. 17 is a top view showing almost one pixel in the display area 706. The gate wiring 250 intersects the underlying semiconductor layer 212 through a gate insulating film (not shown). Although not shown, the semiconductor layer includes a source region, a drain region, and n ^- A Loff region formed of a region is formed. Reference numeral 265 denotes a contact portion between the source wiring 256 and the source region 324, 266 denotes a contact portion between the drain wiring 260 and the drain region 326, and 267 denotes a contact portion between the drain wiring 260 and the pixel electrode 263. The storage capacitor 305 is formed in a region where the capacitor wirings 234 and 251 overlap with a semiconductor layer 327 extending from the drain region 326 of the pixel TFT 304 and a gate insulating film.
[0137]
Note that the active matrix liquid crystal display device of this example has been described with reference to the structure described in Example 6, but is not limited to the configuration of Example 6 and is described in Embodiments 1 to 5. An active matrix substrate completed by applying the configuration to the sixth embodiment may be used. In any case, an active matrix liquid crystal display device can be manufactured by freely combining the active matrix substrates provided with the organic resin film described in the embodiment mode.
[0138]
[Example 8]
In this example, an example in which an EL (electroluminescence) module (also referred to as an EL display device) is manufactured using the present invention will be described.
[0139]
FIG. 19A is a top view of an EL display panel using the present invention. In FIG. 19A, 10 is a substrate, 11 is a pixel portion, 12 is a source side driving circuit, 13 is a gate side driving circuit, and each driving circuit reaches the FPC 17 via wirings 14 to 16 to an external device. Connected.
[0140]
At this time, the substrate 82 is provided so as to cover at least the pixel portion, preferably the driver circuit and the pixel portion. The substrate 82 may be a glass plate or a plastic plate, or an ultraviolet curable resin. When the substrate 82 is used, the substrate 82 is fixed to the substrate 10 with the adhesive 81, and the resin 20 is filled between the substrate 82. At this time, the EL element is completely enclosed in the resin 20 and is completely shielded from the outside air.
[0141]
Further, a sealed space may be provided between the substrate 82 and the substrate 10 and filled with an inert gas (argon, helium, nitrogen, etc.), or a drying agent such as barium oxide may be provided. Thereby, it is possible to suppress deterioration of the EL element due to moisture or the like.
[0142]
FIG. 19B shows a cross-sectional structure of the EL display panel of this embodiment. A driving circuit TFT (however, here a CMOS circuit combining NTFT and PTFT is illustrated on the substrate 10 and the inorganic insulating film 21 is shown. And a pixel portion TFT 23 (here, only the TFT for controlling the current to the EL element is shown). As the driving circuit TFT 22, the NTFT and PTFT shown in FIG. 7 may be used. The pixel portion TFT 23 may be the NTFT or PTFT shown in FIG.
[0143]
When the driving circuit TFT 22 and the pixel portion TFT 23 are completed using the present invention, a transparent conductive film electrically connected to the drain of the pixel portion TFT 23 is formed on the interlayer insulating film (planarization film) 26 made of a resin material. A pixel electrode 27 is formed. As the transparent conductive film, a compound of indium oxide and tin oxide (referred to as ITO) or a compound of indium oxide and zinc oxide can be used. Then, after the pixel electrode 27 is formed, an insulating film 28 is formed, and an opening is formed on the pixel electrode 27.
[0144]
Next, the EL layer 29 is formed. The EL layer 29 may have a laminated structure or a single layer structure by freely combining known EL materials (a hole injection layer, a hole transport layer, a light emitting layer, an electron transport layer, or an electron injection layer). A known technique may be used to determine the structure. EL materials include low-molecular materials and high-molecular (polymer) materials. When a low molecular material is used, a vapor deposition method is used. When a high molecular material is used, a simple method such as a spin coating method, a printing method, or an ink jet method can be used.
[0145]
In this embodiment, the EL layer is formed by vapor deposition using a shadow mask. Color display is possible by forming a light emitting layer (a red light emitting layer, a green light emitting layer, and a blue light emitting layer) capable of emitting light having different wavelengths for each pixel using a shadow mask. In addition, there are a method in which a color conversion layer (CCM) and a color filter are combined, and a method in which a white light emitting layer and a color filter are combined, but either method may be used. Needless to say, an EL display device emitting monochromatic light can also be used.
[0146]
After the EL layer 29 is formed, the cathode 30 is formed thereon. It is desirable to remove moisture and oxygen present at the interface between the cathode 30 and the EL layer 29 as much as possible. Therefore, it is necessary to devise such that the EL layer 29 and the cathode 30 are continuously formed in a vacuum, or the EL layer 29 is formed in an inert atmosphere and the cathode 30 is formed without being released to the atmosphere. In this embodiment, the above-described film formation is possible by using a multi-chamber type (cluster tool type) film formation apparatus.
[0147]
In this embodiment, a laminated structure of a LiF (lithium fluoride) film and an Al (aluminum) film is used as the cathode 30. Specifically, an LiF (lithium fluoride) film having a thickness of 1 nm is formed on the EL layer 29 by vapor deposition, and an aluminum film having a thickness of 300 nm is formed thereon. Of course, you may use the MgAg electrode which is a well-known cathode material. The cathode 30 is connected to the wiring 16 in a region indicated by 31. The wiring 16 is a power supply line for applying a predetermined voltage to the cathode 30, and is connected to the FPC 17 through a conductive paste material 32. Further, the connecting portion is covered with the resin 80 to protect the connecting portion.
[0148]
In order to electrically connect the cathode 30 and the wiring 16 in the region indicated by 31, it is necessary to form contact holes in the interlayer insulating film 26 and the insulating film 28. These may be formed when the interlayer insulating film 26 is etched (when the pixel electrode contact hole is formed) or when the insulating film 28 is etched (when the opening before the EL layer is formed). Further, when the insulating film 28 is etched, the interlayer insulating film 26 may be etched all at once. In this case, if the interlayer insulating film 26 and the insulating film 28 are the same resin material, the shape of the contact hole can be improved.
[0149]
In addition, the wiring 16 is electrically connected to the FPC 17 through a gap (but closed with an adhesive 81) between the substrate 82 and the substrate 10. Although the wiring 16 has been described here, the other wirings 14 and 15 are also electrically connected to the FPC 17 under the substrate 82 in the same manner.
[0150]
The present invention can be used in an EL display panel having the above-described configuration. Here, a more detailed cross-sectional structure of the pixel portion is shown in FIG. 20, a top structure is shown in FIG. 21A, and a circuit diagram is shown in FIG. In FIG. 20, FIG. 21 (A) and FIG.
[0151]
In FIG. 21, a switching TFT 1002 provided on a substrate 1001 is formed using the NTFT of the present invention. In this embodiment, a double gate structure is used. However, there is no significant difference in structure and manufacturing process, and thus description thereof is omitted. However, the double gate structure substantially has a structure in which two TFTs are connected in series, and there is an advantage that the off-current value can be reduced. Although the double gate structure is used in this embodiment, a single gate structure may be used, and a triple gate structure or a multi-gate structure having more gates may be used. Moreover, you may form using PTFT of this invention.
[0152]
The current control TFT 1003 is formed using the NTFT of the present invention. At this time, the drain wiring 35 of the switching TFT 1002 is electrically connected to the gate electrode 37 of the current control TFT by the wiring 36. A wiring indicated by 38 is a gate wiring that electrically connects the gate electrodes 39a and 39b of the switching TFT 1002.
[0153]
At this time, it is very important that the current control TFT 1003 has the structure of the present invention. Since the current control TFT is an element for controlling the amount of current flowing through the EL element, a large amount of current flows, and it is also an element with a high risk of deterioration due to heat or hot carriers. Therefore, the structure of the present invention in which the LDD region is provided on the drain side of the current control TFT so as to overlap the gate electrode through the gate insulating film is extremely effective.
[0154]
In this embodiment, the current control TFT 1003 is shown as a single gate structure, but a multi-gate structure in which a plurality of TFTs are connected in series may be used. Further, a structure may be employed in which a plurality of TFTs are connected in parallel to substantially divide the channel formation region into a plurality of portions so that heat can be emitted with high efficiency. Such a structure is effective as a countermeasure against deterioration due to heat.
[0155]
Further, as shown in FIG. 21A, the wiring that becomes the gate electrode 37 of the current control TFT 1003 overlaps the drain wiring 40 of the current control TFT 1003 with an insulating film in the region indicated by 1004. At this time, a capacitor is formed in a region indicated by 1004. This capacitor 1004 functions as a capacitor for holding the voltage applied to the gate of the current control TFT 1003. The drain wiring 40 is connected to a current supply line (power supply line) 1101, and a constant voltage is always applied.
[0156]
A first passivation film 41 is provided on the switching TFT 1002 and the current control TFT 1003, and a planarizing film 42 made of a resin insulating film is formed thereon. It is very important to flatten the step due to the TFT using the flattening film 42. Since an EL layer to be formed later is very thin, a light emission defect may occur due to the presence of a step. Therefore, it is desirable to planarize the pixel electrode before forming the pixel electrode so that the EL layer can be formed as flat as possible.
[0157]
Reference numeral 43 denotes a pixel electrode (EL element cathode) made of a highly reflective conductive film, which is electrically connected to the drain of the current control TFT 1003. As the pixel electrode 43, it is preferable to use a low-resistance conductive film such as an aluminum alloy film, a copper alloy film, or a silver alloy film, or a laminated film thereof. Of course, a laminated structure with another conductive film may be used.
[0158]
A light emitting layer 45 is formed in a groove (corresponding to a pixel) formed by banks 44a and 44b formed of an insulating film (preferably resin). Although only one pixel is shown here, a light emitting layer corresponding to each color of R (red), G (green), and B (blue) may be formed separately. A π-conjugated polymer material is used as the organic EL material for the light emitting layer. Typical polymer materials include polyparaphenylene vinylene (PPV), polyvinyl carbazole (PVK), and polyfluorene.
[0159]
There are various types of PPV organic EL materials such as “H. Shenk, H. Becker, O. Gelsen, E. Kluge, W. Kreuder, and H. Spreitzer,“ Polymers for Light Emitting ”. Materials such as those described in “Diodes”, Euro Display, Proceedings, 1999, p. 33-37 ”and Japanese Patent Laid-Open No. 10-92576 may be used.
[0160]
As a specific light emitting layer, cyanopolyphenylene vinylene may be used for a light emitting layer that emits red light, polyphenylene vinylene may be used for a light emitting layer that emits green light, and polyphenylene vinylene or polyalkylphenylene may be used for a light emitting layer that emits blue light. The film thickness may be 30 to 150 nm (preferably 40 to 100 nm).
[0161]
However, the above example is an example of an organic EL material that can be used as a light emitting layer, and is not necessarily limited to this. An EL layer (a layer for emitting light and moving carriers therefor) may be formed by freely combining a light-emitting layer, a charge transport layer, or a charge injection layer. As the EL layer, a thin film made of a light emitting material (singlet compound) that emits light (fluorescence) by singlet excitation, or a thin film made of a light emitting material (phosphorescence) that emits light (phosphorescence) by triplet excitation can be used.
[0162]
For example, in this embodiment, an example in which a polymer material is used as the light emitting layer is shown, but a low molecular weight organic EL material may be used. It is also possible to use an inorganic material such as silicon carbide for the charge transport layer or the charge injection layer. As these organic EL materials and inorganic materials, known materials can be used.
[0163]
In this embodiment, the EL layer has a laminated structure in which a hole injection layer 46 made of PEDOT (polythiophene) or PAni (polyaniline) is provided on the light emitting layer 45. An anode 47 made of a transparent conductive film is provided on the hole injection layer 46. In the case of the present embodiment, since the light generated in the light emitting layer 45 is emitted toward the upper surface side (upward of the TFT), the anode must be translucent. As the transparent conductive film, a compound of indium oxide and tin oxide or a compound of indium oxide and zinc oxide can be used, but it is possible to form after forming a light-emitting layer or hole injection layer with low heat resistance. What can form into a film at low temperature as much as possible is preferable.
[0164]
When the anode 47 is formed, the EL element 2405 is completed. Here, the EL element 1005 refers to a capacitor formed by the pixel electrode (cathode) 43, the light emitting layer 45, the hole injection layer 46, and the anode 47. As shown in FIG. 21A, since the pixel electrode 43 substantially matches the area of the pixel, the entire pixel functions as an EL element. Therefore, the use efficiency of light emission is very high, and a bright image display is possible.
[0165]
By the way, in the present embodiment, a second passivation film 48 is further provided on the anode 47. The second passivation film 48 is preferably a silicon nitride film or a silicon nitride oxide film. This purpose is to cut off the EL element from the outside, and has both the meaning of preventing deterioration due to oxidation of the organic EL material and the meaning of suppressing degassing from the organic EL material. This increases the reliability of the EL display device.
[0166]
As described above, the EL display panel of the present invention has a pixel portion composed of pixels having a structure as shown in FIG. 20, and includes a switching TFT having a sufficiently low off-current value and a current control TFT resistant to hot carrier injection. Have. Therefore, an EL display panel having high reliability and capable of displaying a good image can be obtained.
[0167]
In addition, the structure of a present Example can be implemented in combination freely with the structure of Examples 1-7.
[0168]
[Example 9]
In this embodiment, a structure in which the structure of the EL element 1005 is inverted in the pixel portion described in Embodiment 8 will be described. The explanation is shown in FIG. 2 Is used. Note that the only difference from the structure of FIG. 21A is the EL element portion and the current control TFT, and thus other descriptions are omitted.
[0169]
In FIG. 22, the current control TFT 12 01 is formed using the PTFT of the present invention. For the manufacturing process, Example 1 may be referred to.
[0170]
In this embodiment, a transparent conductive film is used as the pixel electrode (anode) 50. Specifically, a conductive film made of a compound of indium oxide and zinc oxide is used. Of course, a conductive film made of a compound of indium oxide and tin oxide may be used.
[0171]
Then, after banks 51a and 51b made of insulating films are formed, a light emitting layer 52 made of polyvinylcarbazole is formed by solution coating. An electron injection layer 53 made of potassium acetylacetonate (denoted as acacK) and a cathode 54 made of an aluminum alloy are formed thereon. In this case, the cathode 54 also functions as a passivation film. Thus EL element 12 02 is formed.
[0172]
In the case of the present embodiment, the light generated in the light emitting layer 53 is emitted toward the substrate on which the TFT is formed as indicated by an arrow. In the case of the structure as in this embodiment, the current control TFT 1201 is preferably formed of PTFT.
[0173]
In addition, the structure of a present Example can be implemented in combination freely with the structure of Examples 1-7.
[0174]
Example 10
In this embodiment, an example of a pixel having a structure different from the circuit diagram shown in FIG. 21B is shown in FIG. In this embodiment, 1301 is a source wiring of the switching TFT 1302, 1303 is a gate wiring of the switching TFT 1302, 1304 is a current control TFT, 1305 is a capacitor, 1306 and 1308 are current supply lines, and 1307 is an EL element. .
[0175]
FIG. 23A shows an example in which the current supply line 1306 is shared between two pixels. That is, there is a feature in that two pixels are formed so as to be symmetrical with respect to the current supply line 1306. In this case, since the number of power supply lines can be reduced, the pixel portion can be further refined.
[0176]
FIG. 23B illustrates an example in which the current supply line 1308 is provided in parallel with the gate wiring 1303. Note that in FIG. 23B, the current supply line 1308 and the gate wiring 1303 are provided so as not to overlap with each other. However, if the wirings are formed in different layers, they overlap with each other through an insulating film. It can also be provided. In this case, since the exclusive area can be shared by the power supply line 1308 and the gate wiring 1303, the pixel portion can be further refined.
[0177]
In FIG. 23C, a current supply line 1308 is provided in parallel with the gate wiring 1303 as in the structure of FIG. 23B, and two pixels are symmetrical about the current supply line 1308. It is characterized in that it is formed. It is also effective to provide the current supply line 1308 so as to overlap any one of the gate wirings 1303. In this case, since the number of power supply lines can be reduced, the pixel portion can be further refined.
[0178]
It should be noted that the configuration of this embodiment can be implemented by freely combining with the configuration of Embodiment 8 or Embodiment 9.
[0179]
Example 11
In FIGS. 21A and 21B shown in Embodiment 8, the capacitor 1004 is provided to hold the voltage applied to the gate of the current control TFT 1003. However, the capacitor 1004 can be omitted. is there.
[0180]
In the case of Example 8, since the NTFT of the present invention as shown in FIG. 20 is used as the current control TFT 1003, it has an LDD region provided so as to overlap the gate electrode through the gate insulating film. A parasitic capacitance generally referred to as a gate capacitance is formed in the overlapping region, but this embodiment is characterized in that this parasitic capacitance is actively used in place of the capacitor 1004.
[0181]
Since the capacitance of the parasitic capacitance varies depending on the area where the gate electrode and the LDD region overlap, it is determined by the length of the LDD region included in the overlapping region.
[0182]
Similarly, the capacitor 1305 can be omitted in the structures of FIGS. 23A, 23B, and 23C shown in the tenth embodiment.
[0183]
It should be noted that the configuration of this embodiment can be implemented by freely combining with the configuration of Embodiment 8 or Embodiment 9.
[0184]
[Example 12]
The CMOS circuit and the pixel portion formed by implementing the present invention can be used for various electro-optical devices (active matrix liquid crystal display, EL module, active matrix EC display). That is, the present invention can be implemented in all electronic devices in which these electro-optical devices are incorporated in the display unit.
[0185]
Such electronic devices include video cameras, digital cameras, projectors (rear type or front type), head mounted displays (goggles type displays), car navigation systems, car stereos, personal computers, personal digital assistants (mobile computers, mobile phones) Or an electronic book). Examples of these are shown in FIGS. 24, 25 and 26. FIG.
[0186]
FIG. 24A illustrates a personal computer, which includes a main body 2001, an image input portion 2002, a display portion 2003, a keyboard 2004, and the like. The present invention can be applied to the image input unit 2002, the display unit 2003, and other driving circuits.
[0187]
FIG. 24B illustrates a video camera, which includes a main body 2101, a display portion 2102, an audio input portion 2103, operation switches 2104, a battery 2105, an image receiving portion 2106, and the like. The present invention can be applied to the display portion 2102 and other driver circuits.
[0188]
FIG. 24C illustrates a mobile computer, which includes a main body 2201, a camera unit 2202, an image receiving unit 2203, operation switches 2204, a display unit 2205, and the like. The present invention can be applied to the display portion 2205 and other driving circuits.
[0189]
FIG. 24D illustrates a goggle type display including a main body 2301, a display portion 2302, an arm portion 2303, and the like. The present invention can be applied to the display portion 2302 and other driving circuits.
[0190]
FIG. 24E shows a player using a recording medium (hereinafter referred to as a recording medium) on which a program is recorded, and includes a main body 2401, a display portion 2402, a speaker portion 2403, a recording medium 2404, an operation switch 2405, and the like. This player uses a DVD (Digital Versatile Disc), CD, or the like as a recording medium, and can perform music appreciation, movie appreciation, games, and the Internet. The present invention can be applied to the display portion 2402 and other driving circuits.
[0191]
FIG. 24F illustrates a digital camera, which includes a main body 2501, a display portion 2502, an eyepiece portion 2503, operation switches 2504, an image receiving portion (not shown), and the like. The present invention can be applied to the display portion 2502 and other driving circuits.
[0192]
FIG. 25A illustrates a front type projector, which includes a projection device 2601, a screen 2602, and the like. The present invention can be applied to the liquid crystal display device 2808 constituting a part of the projection device 2601 and other driving circuits.
[0193]
FIG. 25B shows a rear projector, which includes a main body 2701, a projection device 2702, a mirror 2703, a screen 2704, and the like. The present invention can be applied to the liquid crystal display device 2808 constituting a part of the projection device 2702 and other driving circuits.
[0194]
Note that FIG. 25C illustrates an example of the structure of the projection devices 2601 and 2702 in FIGS. 25A and 25B. The projection devices 2601 and 2702 include a light source optical system 2801, mirrors 2802 and 2804 to 2806, a dichroic mirror 2803, a prism 2807, a liquid crystal display device 2808, a phase difference plate 2809, and a projection optical system 2810. Projection optical system 2810 includes an optical system including a projection lens. Although the present embodiment shows a three-plate type example, it is not particularly limited, and for example, a single-plate type may be used. In addition, the practitioner may appropriately provide an optical system such as an optical lens, a film having a polarization function, a film for adjusting a phase difference, or an IR film in the optical path indicated by an arrow in FIG. Good.
[0195]
FIG. 25D illustrates an example of the structure of the light source optical system 2801 in FIG. In this embodiment, the light source optical system 2801 includes a reflector 2811, a light source 2812, lens arrays 2813 and 2814, a polarization conversion element 2815, and a condenser lens 2816. Note that the light source optical system illustrated in FIG. 25D is an example and is not particularly limited. For example, the practitioner may appropriately provide an optical system such as an optical lens, a film having a polarization function, a film for adjusting a phase difference, or an IR film in the light source optical system.
[0196]
However, the projector shown in FIG. 25 shows a case where a transmissive electro-optical device is used, and an application example in a reflective electro-optical device and an EL display device is not shown.
[0197]
FIG. 26A shows a cellular phone, which includes a main body 2901, an audio output portion 2902, an audio input portion 2903, a display portion 2904, operation switches 2905, an antenna 2906, and the like. The present invention can be applied to the audio output unit 2902, the audio input unit 2903, the display unit 2904, and other driving circuits.
[0198]
FIG. 26B illustrates a portable book (electronic book) which includes a main body 3001, display portions 3002 and 3003, a storage medium 3004, operation switches 3005, an antenna 3006, and the like. The present invention can be applied to the display portions 3002 and 3003 and other driving circuits.
[0199]
FIG. 26C illustrates a display which includes a main body 3101, a support base 3102, a display portion 3103, and the like. The present invention can be applied to the display portion 3103. The display of the present invention is particularly advantageous when the screen is enlarged, and is advantageous for displays having a diagonal of 10 inches or more (particularly 30 inches or more).
[0200]
As described above, the application range of the present invention is extremely wide and can be applied to electronic devices in various fields. Moreover, the electronic device of a present Example is realizable even if it uses the structure which consists of what combination of Examples 1-11.
[0201]
[Example 13]
In this example, the following experiment was performed. The experimental procedure shown in this example is shown below.
[0202]
First, after forming a BCB film having a thickness of 200 nm on a glass substrate 1400, patterning was performed using the same mask as a semiconductor layer to be formed later, and then a BCB film 1401 was formed.
[0203]
Next, using plasma CVD, SiH _Four And N ₂ A silicon oxynitride film (composition ratio Si = 32%, O = 59%, N = 7%, H = 2%) formed using O as a reactive gas is stacked to a thickness of 200 nm.
[0204]
Next, in this example, a 54 nm amorphous silicon film 1403 was formed by plasma CVD. (Fig. 27 (A))
[0205]
This amorphous silicon film was dehydrogenated (500 ° C., 1 hour) and then patterned. (Fig. 27 (B))
[0206]
Next, the natural oxide film was removed with buffer hydrofluoric acid, and the laser annealing process of this example was performed to form a crystalline silicon film 1404. (Fig. 27 (C))
[0207]
Needless to say, the step of forming the crystalline silicon film 1404 can be used in place of the step of forming the crystalline silicon film described in any one of Examples 1 to 11.
[0208]
In the laser annealing treatment of this example, excimer laser beams 1502 and 1503 (wavelength 308 nm) were irradiated on the front and back surfaces of the amorphous silicon film 1403 by the method shown in FIG. The laser irradiation conditions here are energy density of 100 to 500 mJ / cm. ² As a result, the entire surface of the substrate on which the amorphous silicon film 1403 was formed was processed by scanning with the linear beam overlap ratio of 80 to 98%. However, here, a glass substrate (Corning 1737) having a transmittance of about 50% for an excimer laser having a wavelength of 308 nm is used. However, a quartz substrate having a transmittance of about 100% for an excimer laser having a wavelength of 308 nm may be used. .
[0209]
In FIG. 28, reference numeral 1400 denotes a light-transmitting substrate, on which a BCB film 1401, an insulating film 1402, and an amorphous semiconductor film (or microcrystalline semiconductor film) 1403 are formed. In addition, a reflector 1501 for reflecting the laser light is disposed under the translucent substrate 1400.
[0210]
As the light-transmitting substrate 1400, a glass substrate, a quartz substrate, a crystallized glass substrate, or a plastic substrate is used. The translucent substrate 1400 itself can adjust the effective energy intensity of the secondary laser light. As the insulating film 1802, an insulating film containing silicon such as a silicon oxide film or a silicon nitride oxide film (SiOxNy) may be used, and the effective energy intensity of the secondary laser light may be adjusted by the insulating film 1400.
[0211]
In the configuration of FIG. 28, the secondary laser beam 1503 is a laser beam reflected by the reflector 1501. Therefore, the effective energy intensity of the secondary laser light can be adjusted by the amorphous semiconductor film 1403. The amorphous semiconductor film 1403 includes a compound semiconductor film such as an amorphous silicon germanium film in addition to the amorphous silicon film.
[0212]
Further, the reflector 1501 may be a substrate on which a metal film is formed on the surface (laser light reflecting surface) or a substrate made of a metal element. In this case, any material may be used for the metal film. Typically, a metal film containing any element of silicon (Si), aluminum (Al), silver (Ag), tungsten (W), titanium (Ti), and tantalum (Ta) is used. For example, tungsten nitride (WN), titanium nitride (TiN), or tantalum nitride (TaN) may be used.
[0213]
Further, the reflector 1501 may be provided in contact with the light-transmitting substrate 1400 or may be provided separately. Further, instead of disposing the reflector 1501, it is also possible to form the above-described metal film directly on the back surface (surface opposite to the front surface) of the substrate 1400 and reflect the laser light there. In any case, the effective energy intensity of the secondary laser light can be adjusted by the reflectance of the reflector 1501. In the case where the reflector 1501 is provided apart from the light-transmitting substrate 1400, the energy intensity of the secondary laser light can be controlled by a gas (gas) filling the gap.
[0214]
Needless to say, the laser annealing treatment can be used in place of the laser annealing treatment described in any one of Examples 1 to 11.
[0215]
FIG. 29 is a SEM photograph showing the crystal grain size in the crystalline silicon film formed through the above steps. As shown in FIG. 29, a crystalline silicon film having a large crystal grain size of about 2 μm was obtained. If this large particle size region is used as a TFT channel formation region, a TFT having good TFT characteristics can be obtained.
[0216]
Further, FIG. 30 shows an SEM photograph observed after patterning a relatively large island-shaped semiconductor and irradiating a laser in order to examine the starting point position of crystal growth. As shown in FIG. 30, a crystalline silicon film laterally grown from the end portion was obtained.
[0217]
From the above experimental results, it was proved that the position of crystals in the crystalline semiconductor film can be controlled by the present invention.
[0218]
【The invention's effect】
By using the crystallization technique of the present invention, a crystalline semiconductor film in which the crystal position and the crystal grain size are controlled can be manufactured. The position of the crystalline semiconductor film having a large crystal grain size is determined according to the arrangement of the organic resin film having a predetermined shape. Further, by adjusting the material and film thickness of the organic resin film or the material and film thickness of the inorganic insulating film, a region having a large crystal grain size can be selectively formed. Further, the region having a large crystal grain size has a very small lattice defect density, and when this region is used as a channel formation region of a TFT, excellent electrical characteristics can be obtained.
[Brief description of the drawings]
FIG. 1 illustrates a configuration of the present invention.
FIGS. 2A and 2B are cross-sectional views illustrating a manufacturing process of a crystalline semiconductor film according to the present invention. FIGS.
FIG. 3 is a cross-sectional view showing a manufacturing process of a crystalline semiconductor film according to the present invention.
FIG. 4 is a diagram illustrating a configuration of the present invention. (Example 3)
FIG. 5 illustrates a structure of the present invention. Example 4
FIG. 6 is a cross-sectional view illustrating a manufacturing process of a TFT.
7 is a cross-sectional view illustrating a manufacturing process of a TFT. FIG.
FIG. 8 is a top view illustrating a manufacturing process of a TFT.
FIG. 9 is a cross-sectional view illustrating a manufacturing process of an active matrix substrate.
FIG. 10 is a cross-sectional view showing a manufacturing process of an active matrix substrate.
FIG. 11 is a cross-sectional view showing a manufacturing process of an active matrix substrate.
FIG. 12 is a cross-sectional view showing a manufacturing process of an active matrix substrate.
FIG. 13 is a cross-sectional view illustrating a manufacturing process of an active matrix substrate.
FIG. 14 is a top view illustrating a manufacturing process of an active matrix substrate.
FIG. 15 is a cross-sectional structure diagram of an active matrix liquid crystal display device.
FIG. 16 is a diagram showing the appearance of an AM-LCD.
FIG. 17 is a top view showing one pixel in an active matrix liquid crystal display device.
FIG. 18 is a diagram showing a configuration of a laser annealing apparatus.
FIG 19 is a cross-sectional view illustrating a structure of an EL display device.
FIG. 20 is a cross-sectional view illustrating a structure of an EL display device.
FIG. 21 is a top view illustrating a structure of an EL display device.
FIG 22 is a cross-sectional view illustrating a structure of an EL display device.
FIG. 23 is a circuit diagram illustrating a structure of an EL display device.
FIG 24 illustrates an example of an electronic device.
FIG 25 illustrates an example of an electronic device.
FIG 26 illustrates an example of an electronic device.
FIG. 27 is a cross-sectional view illustrating a manufacturing process.
FIG. 28 is a cross-sectional view illustrating a laser irradiation method.
FIG. 29 is a SEM photograph showing the crystal grain size.
FIG. 30 is a SEM photograph showing the position of crystal growth.

Claims (9)

After forming the organic resin film on the substrate, the organic resin film is patterned into islands or stripes,
An inorganic insulating film is formed so as to cover the patterned organic resin film,
An amorphous structure having a first region overlapping with the organic resin film via the inorganic insulating film and a second region not overlapping with the organic resin film via the inorganic insulating film on the inorganic insulating film. Forming a semiconductor film including,
By irradiating the semiconductor film containing the amorphous structure with laser light, a crystalline semiconductor film is formed,
The laser beam is irradiated simultaneously from the side on which the organic resin film and the inorganic insulating film are formed and the opposite side to the substrate,
A method for manufacturing a semiconductor device, comprising patterning the crystalline semiconductor film to form an island-shaped crystalline semiconductor film having only the first region. After forming the organic resin film on the substrate, the organic resin film is patterned into islands or stripes,
An inorganic insulating film is formed so as to cover the patterned organic resin film,
An amorphous structure having a first region overlapping with the organic resin film via the inorganic insulating film and a second region not overlapping with the organic resin film via the inorganic insulating film on the inorganic insulating film. Forming a semiconductor film including,
By irradiating the semiconductor film containing the amorphous structure with laser light, a crystalline semiconductor film is formed,
The laser beam is irradiated simultaneously from the side on which the organic resin film and the inorganic insulating film are formed and the opposite side to the substrate,
Patterning the crystalline semiconductor film to form an island-shaped crystalline semiconductor film having only the first region;
A thin film transistor is formed using the island-shaped crystalline semiconductor film as an active layer.   3. The method for manufacturing a semiconductor device according to claim 1, wherein in the crystalline semiconductor film, a crystal grain size in the first region is larger than a crystal grain size in the second region.   4. The method for manufacturing a semiconductor device according to claim 1, wherein the inorganic insulating film and the semiconductor film including the amorphous structure are continuously formed without being exposed to the air. In any one of claims 1 to 4, wherein the inorganic insulating film, a silicon oxide film, a silicon nitride film, and characterized in that it is a silicon oxynitride film single layer selected from or laminated films thereof, A method for manufacturing a semiconductor device. In any one of claims 1 to 5, a method for manufacturing a semiconductor device, characterized by having an insulating film between the substrate and the organic resin film. In any one of claims 1 to 6, the thermal conductivity of the organic resin film, a method for manufacturing a semiconductor device which is characterized in that less than 1.0 Wm ^-1 K ^-1. In any one of claims 1 to 7, wherein the organic resin film, a method for manufacturing a semiconductor device characterized by having photosensitivity. In any one of claims 1 to 8, wherein the organic resin film, BCB resin, polyimide resin, acrylic resin, siloxane-based resin, fluorine-added paraxylene, fluoridation parylene, Teflon, fluoro polyallyl ether, A method for manufacturing a semiconductor device, which is a single-layer film selected from PFCB and polysilazane, or a stacked film thereof.

Images